CN106752803A - A kind of industrial machinery antirust agent and preparation method thereof - Google Patents
A kind of industrial machinery antirust agent and preparation method thereof Download PDFInfo
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Abstract
The present invention proposes a kind of industrial machinery antirust agent and preparation method thereof, is made up of following mass fraction：13 parts of triethanolamine oleate, 34 parts of inorganic additive, 13 parts of sodium tetraborate, 0.5 2 parts of aqueous nano bentonite, 13 parts of epoxyeicosatrienoic acid zinc, 24 parts of AEO, 14 parts of diene base succimide, 1.5 4 parts of sodium lauroyl sarcosine, 69 parts of n-butanol, 60 80 parts of water, by mixing, heating, stirring, the steps such as ultrasound are made, obtained antirust agent is in acid, alkali, excellent rustless property is respectively provided with the conditions of salt fog etc., and safety and environmental protection, composition is uniform, the planarization and slickness of metal surface can be effectively ensured, useful life was up to more than 2 years.
Description
Technical field
The present invention relates to field of metal surface treatment technology, and in particular to a kind of industrial machinery antirust agent and its preparation side
Method.
Background technology
Industrial machinery is generally metal material, and metal in an atmosphere under certain condition can and oxygen, water and other materials occur
Chemistry or electrochemical action and produce corrosion, this not only influences the outward appearance of material, or even directly affects its service life, causes huge
Big economic loss.Therefore, often smearing antirust agent to metal surface in the prior art carries out protective treatment, but early stage antirust agent
In mostly containing severe toxicity nitrite, except it can pollute in addition to, one layer of bloom can be also formed after metal surface is applied to, mistake
Remove due rust-proof effect.In addition, industrial wide variety of antirust agent is discharged into also mostly containing phosphorus containg substances such as phosphate
Eutrophication can be produced in water body, and contains heavy metal and carcinogen in antirust oil, environment and health of people are caused
Very big harm.Therefore, develop favorable rust preventing effect, Environmental Safety novel antirust agent it is significant.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of industrial machinery antirust agent and preparation method thereof, passes through
The steps such as mixing, heating, stirring, ultrasound are made, and obtained antirust agent is respectively provided with excellent anti-under the conditions of acid, alkali, salt fog etc.
Rust performance, and safety and environmental protection, composition are uniform, and the planarization and slickness of metal surface can be effectively ensured, useful life was up to 2 years
More than.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of industrial machinery antirust agent, is made up of following mass fraction：Triethanolamine oleate 1-3 parts, inorganic additive
3-4 parts, sodium tetraborate 1-3 parts, aqueous nano bentonite 0.5-2 parts, 1-3 parts of epoxyeicosatrienoic acid zinc, AEO 2-4
Part, 1-4 parts, sodium lauroyl sarcosine 1.5-4 parts, n-butanol 6-9 parts, water 60-80 parts of diene base succimide.
Preferably, triethanolamine oleate 2-3 parts, inorganic additive 3.5-4 parts, sodium tetraborate 3-3 parts, water nano swelling
Native 1-2 parts, 2-3 parts of epoxyeicosatrienoic acid zinc, AEO 3-4 parts, 3-4 parts of diene base succimide, lauroyl flesh ammonia
Sour sodium 3-4 parts, n-butanol 8-9 parts, water 70-80 parts.
Preferably, the inorganic additive is mass ratio 1-2:1 sodium metasilicate and sodium tungstate.
Preferably, the preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 15-20min, obtains mixed liquor one；
2) mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol are blended, then ultrasonically treated 8-10min,
Obtain mixed liquor two；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 20-30min obtains base
Liquid；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 15-20min.
Preferably, step 1) in heating-up temperature be 75 DEG C, mixing speed is 60-70rpm.
Preferably, step 2) in it is ultrasonically treated be specially 35 DEG C of temperature, frequency 22-24kHz.
Preferably, step 3) in heating-up temperature be 60 DEG C, mixing speed is 80-100rpm.
Due to using above-mentioned technical scheme, the beneficial effects of the invention are as follows：It is of the invention to pass through mixing, heating, stir, surpass
The steps such as sound are made, and obtained antirust agent is respectively provided with excellent rustless property under the conditions of acid, alkali, salt fog etc., and safety and environmental protection,
Composition is uniform, and the planarization and slickness of metal surface can be effectively ensured, and useful life was up to more than 2 years.
Triethanolamine oleate, AEO, sodium lauroyl sarcosine have cleaning, antirust, inhibition, emulsification etc.
Function is subject to aqueous nano bentonite composite ultraphonic and is modified as antirust main body, on the one hand improves the combination property of antirust, separately
On the one hand the uniformity and adhesiving effect of antirust agent are improve, the protection uniformity of antirust agent protective coating is substantially increased, is kept away
Exempted from uneven coating, corrugation, it is easily rupturable, easily the problems such as there is plaque, extend the antirust time limit.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
Embodiment 1：
A kind of industrial machinery antirust agent is made up of following mass fraction：2.5 parts of triethanolamine oleate, inorganic additive 4
Part, 2 parts of sodium tetraborate, 0.8 part of aqueous nano bentonite, 1.5 parts of epoxyeicosatrienoic acid zinc, 3.5 parts of AEO, diene base
4 parts of succimide, 1.5 parts of sodium lauroyl sarcosine, 8 parts of n-butanol, 70 parts of water.
The inorganic additive is mass ratio 1:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 20min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 65rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 8min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 23kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 20min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 85rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 15min.
Embodiment 2：
A kind of industrial machinery antirust agent is made up of following mass fraction：1 part of triethanolamine oleate, 3 parts of inorganic additive,
2.5 parts of sodium tetraborate, 1.5 parts of aqueous nano bentonite, 3 parts of epoxyeicosatrienoic acid zinc, 4 parts of AEO, double allyl butyrates two
1 part of acid imide, 4 parts of sodium lauroyl sarcosine, 7 parts of n-butanol, 75 parts of water.
The inorganic additive is mass ratio 1.5:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 15min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 70rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 9min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 22.5kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 25min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 95rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 18min.
Embodiment 3：
A kind of industrial machinery antirust agent is made up of following mass fraction：3 parts of triethanolamine oleate, inorganic additive 3.5
Part, 2 parts of sodium tetraborate, 2 parts of aqueous nano bentonite, 2.5 parts of epoxyeicosatrienoic acid zinc, 4 parts of AEO, double allyl butyrates two
2 parts of acid imide, 3.5 parts of sodium lauroyl sarcosine, 7 parts of n-butanol, 80 parts of water.
The inorganic additive is mass ratio 1:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 20min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 65rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 9min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 23.5kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 25min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 100rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 18min.
Embodiment 4：
A kind of industrial machinery antirust agent is made up of following mass fraction：1.5 parts of triethanolamine oleate, inorganic additive
3.8 parts, 1.5 parts of sodium tetraborate, 1 part of aqueous nano bentonite, 2 parts of epoxyeicosatrienoic acid zinc, 3 parts of AEO, diene base
3 parts of succimide, 3 parts of sodium lauroyl sarcosine, 6 parts of n-butanol, 80 parts of water.
The inorganic additive is mass ratio 2:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 20min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 65rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 9min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 24kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 30min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 95rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 20min.
Embodiment 5：
A kind of industrial machinery antirust agent is made up of following mass fraction：2 parts of triethanolamine oleate, inorganic additive 3.5
Part, 3 parts of sodium tetraborate, 0.5 part of aqueous nano bentonite, 2 parts of epoxyeicosatrienoic acid zinc, 3 parts of AEO, double allyl butyrates two
3.5 parts of acid imide, 2.5 parts of sodium lauroyl sarcosine, 9 parts of n-butanol, 65 parts of water.
The inorganic additive is mass ratio 2:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 18min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 60rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 10min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 24kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 25min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 90rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 15min.
Embodiment 6：
A kind of industrial machinery antirust agent is made up of following mass fraction：3 parts of triethanolamine oleate, inorganic additive 3.2
Part, 1.5 parts of sodium tetraborate, 1.8 parts of aqueous nano bentonite, 1 part of epoxyeicosatrienoic acid zinc, 2.5 parts of AEO, diene base
2 parts of succimide, 2 parts of sodium lauroyl sarcosine, 9 parts of n-butanol, 60 parts of water.
The inorganic additive is mass ratio 1.5:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 15min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 60rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 10min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 23.5kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 30min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 80rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 15min.
Embodiment 7：
A kind of industrial machinery antirust agent is made up of following mass fraction：2.5 parts of triethanolamine oleate, inorganic additive 3
Part, 1 part of sodium tetraborate, 2 parts of aqueous nano bentonite, 1 part of epoxyeicosatrienoic acid zinc, 2 parts of AEO, diene base succinyl
2.5 parts of imines, 1.5 parts of sodium lauroyl sarcosine, 6 parts of n-butanol, 70 parts of water.
The inorganic additive is mass ratio 1:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 15min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 70rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 8min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 22.5kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 20min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 100rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 20min.
Embodiment 8：
A kind of industrial machinery antirust agent is made up of following mass fraction：3 parts of triethanolamine oleate, 3 parts of inorganic additive,
2.5 parts of sodium tetraborate, 1.5 parts of aqueous nano bentonite, 1.5 parts of epoxyeicosatrienoic acid zinc, 2.5 parts of AEO, diene base
4 parts of succimide, 3.5 parts of sodium lauroyl sarcosine, 8 parts of n-butanol, 75 parts of water.
The inorganic additive is mass ratio 1:1 sodium metasilicate and sodium tungstate.
The preparation method of industrial machinery antirust agent, step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating
Stirring 18min, obtains mixed liquor one, and specific heating-up temperature is 75 DEG C, and mixing speed is 70rpm；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 8min, obtains
Mixed liquor two, it is ultrasonically treated to be specially 35 DEG C of temperature, frequency 22kHz；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 20min obtains base fluid,
Specific heating-up temperature is 60 DEG C, and mixing speed is 85rpm；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 18min.
Antirust agent common on embodiment of the present invention products and marketing is carried out into identical performance test, data are as follows：
Salt fog resistance：Using 5% sodium chloride solution, the product to be tested that will scribble antirust agent is placed in one, and observes its appearance
The time that foaming, flash-point, the phenomenon such as turn white need ,/h；
Alkali resistance：The product to be tested that antirust agent will be scribbled is immersed in 3% sodium hydroxide solution, observe it and occur turning white,
The time that loss of gloss, the phenomenon such as bubble, come off need ,/h；
Acid resistance：The product to be tested that antirust agent will be scribbled is immersed in 3% hydrogen chloride solution, is observed it and is occurred turning white, loses
The time that light, the phenomenon such as bubble, come off need ,/h；
| Salt fog resistance | Alkali resistance | Acid resistance | |
| Embodiment 1 | 58 | 54 | 53 |
| Embodiment 2 | 55 | 56 | 53 |
| Embodiment 3 | 57 | 55 | 52 |
| Embodiment 4 | 60 | 56 | 53 |
| Embodiment 5 | 54 | 52 | 48 |
| Embodiment 6 | 56 | 53 | 51 |
| Embodiment 7 | 55 | 52 | 50 |
| Embodiment 8 | 57 | 54 | 52 |
| Embodiment average value | 56.5 | 54 | 51.5 |
| Control group 1 | 43 | 40 | 35 |
| Control group 2 | 44 | 37 | 31 |
| Control cell mean | 43.5 | 38.5 | 33 |
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic；And these modification or
Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (7)
1. a kind of industrial machinery antirust agent, it is characterised in that be made up of following mass fraction：Triethanolamine oleate 1-3 parts, nothing
3-4 parts of machine additive, sodium tetraborate 1-3 parts, aqueous nano bentonite 0.5-2 parts, 1-3 parts of epoxyeicosatrienoic acid zinc, fatty alcohol polyoxy second
2-4 parts of alkene ether, 1-4 parts, sodium lauroyl sarcosine 1.5-4 parts, n-butanol 6-9 parts, water 60-80 parts of diene base succimide.
2. industrial machinery antirust agent according to claim 1, it is characterised in that be made up of following mass fraction：Oleic acid
Triethanolamine 2-3 parts, inorganic additive 3.5-4 parts, sodium tetraborate 3-3 parts, aqueous nano bentonite 1-2 parts, epoxyeicosatrienoic acid zinc 2-3
Part, AEO 3-4 parts, 3-4 parts of diene base succimide, sodium lauroyl sarcosine 3-4 parts, n-butanol 8-9
Part, water 70-80 parts.
3. the preparation method of industrial machinery antirust agent according to claim 1 and 2, it is characterised in that：It is described inorganic to add
Plus agent is mass ratio 1-2:1 sodium metasilicate and sodium tungstate.
4. the preparation method of industrial machinery antirust agent according to claim 1 and 2, it is characterised in that step is as follows：
1) raw material is weighed by weight, by triethanolamine oleate, AEO, sodium lauroyl sarcosine heating stirring
15-20min, obtains mixed liquor one；
2) by mixed liquor one and aqueous nano bentonite, epoxyeicosatrienoic acid zinc, n-butanol blending, then ultrasonically treated 8-10min, obtains mixed
Close liquid two；
3) by inorganic additive, sodium tetraborate, diene base succimide, water blending, heating stirring 20-30min obtains base fluid；
4) by step 2) in mixed liquor two add base fluid in, stirring at normal temperature 15-20min.
5. the preparation method of industrial machinery antirust agent according to claim 4, it is characterised in that：Step 1) middle heating temperature
It is 75 DEG C to spend, and mixing speed is 60-70rpm.
6. the preparation method of industrial machinery antirust agent according to claim 4, it is characterised in that：Step 2) in ultrasound at
Reason is specially 35 DEG C of temperature, frequency 22-24kHz.
7. the preparation method of industrial machinery antirust agent according to claim 4, it is characterised in that：Step 3) middle heating temperature
It is 60 DEG C to spend, and mixing speed is 80-100rpm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710053956.1A CN106752803A (en) | 2017-01-22 | 2017-01-22 | A kind of industrial machinery antirust agent and preparation method thereof |
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| CN201710053956.1A CN106752803A (en) | 2017-01-22 | 2017-01-22 | A kind of industrial machinery antirust agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109439147A (en) * | 2018-12-29 | 2019-03-08 | 苏州宝洪泰电子有限公司 | A kind of installation cover board for new-energy automobile charging electrical-mechanical assembly |
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