CN106752185A - A kind of bloom ceramic insulation coating - Google Patents
A kind of bloom ceramic insulation coating Download PDFInfo
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- CN106752185A CN106752185A CN201611190174.4A CN201611190174A CN106752185A CN 106752185 A CN106752185 A CN 106752185A CN 201611190174 A CN201611190174 A CN 201611190174A CN 106752185 A CN106752185 A CN 106752185A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of bloom ceramic insulation coating, its raw materials by weight portion proportioning is as follows：100 parts of polyvinyl acetate emulsion, 8 12 parts of mica powder, 20 40 parts of talcum powder, 5 25 parts of expanded vermiculite, 10 50 parts of bentonite, 6 10 parts of phenmethylol, 48 parts of polyvinyl alcohol, 10 14 parts of sierozem power, 25 45 parts of calcite in powder, 20 40 parts of alundum (Al2O3), 0.02 0.08 parts of ultramarine, 60 parts of TDI20,0.6 1 parts of triethanolamine, 40 80 parts of acrylate.Bloom ceramic insulation coating of the invention can long-term storage, outward appearance good hand touch, abrasion resistance is good, and the 3h of surface drying 1 does solid work 20 24h；1 20 μm of fineness, the 100J of impact strength 60,12 grades of adhesive force；Alkali resistance immerses 4 8d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；Do not condense, do not lump, do not separate, anti-scratch load is high, scrub resistance 1,300 1700 times can extensively be produced and constantly replace current material.
Description
Technical field
The present invention relates to insulating moulding coating field, more particularly to a kind of bloom ceramic insulation coating.
Background technology
The high temperature resistant heat insulation coating of High Performance Thin, has widely applied space flight, military project, metallurgy, electric power, petrochemical industry, traffic etc.
Key areas, in heat-barrier material that cannot replace, the technological improvement for applying brush material plays conclusive to its excellent performance
Effect, energy saving, stability, science and technology is unprecedented, is real epoch-making heat-insulated for the development of entire society
Material, helps the energy saving economy of enterprise to create greater achievements.
Earlier 1970s, U.S. coating expert utilizes material under vacuum conditions, its molecular vibration heat transfer
The characteristic being wholly absent with convection current conduction two ways, using NASA spacecraft heat-barrier material technologies, by particle diameter 6-10um's
Spherical hollow ceramics microvesicle is filled out and is suspended from inertia latex binder (aqueous), obtains a kind of high-performance, the heat insulating material of high-quality
Material --- ceramic microvesicle heat insulating coatings.Since then, use hollow particle as filler with the excellent thermal insulation coatings of processability
Focus as the research of particular function coating.
This particular function coating is in one layer very thin of brushing of building element surface, so that it may effectively strengthen the heat-insulated of building
Heat insulation effect, not only can make room temperature improve 3-5 DEG C in heating season, and summer can make the same even lower temperature of indoor reduction.
Due to this coating in itself it is special by atomic small hollow ceramic microvesicle and the environmentally friendly emulsion adaptable with it constitute it is aqueous
Coating system so that the coating can not only be effectively adiabatic, but also has excellent waterproof, protection against the tide, anticorrosion, antiultraviolet
The performances such as aging, acid and alkali-resistance, salt spray resistance, material unharmful substance composition, its solidfied material content is high, and ductility, tack are good, apply
Work is easy, long service life.The substrate such as it and wall, metal, woodwork has stronger adhesive force, is directly smeared in matrix surface
0.3mm or so can reach heat-insulation and heat-preservation purpose.Due to the special composition and coat inside design feature of coating, so in coating
The heat of accumulation seldom, forms up to 95% insulation effect, reduces building energy consumption and may be up to 30-60%.
Ceramic coating weatherability and processing characteristics are excellent, bear dirty and resistant to damage.Although conventional ceramic coating resistant to damage,
But if carrying out bending machining to the part after application, easily crack, and fluorine resin paints and organic coating, hold
Easily damaged by sandstone, dust etc..
At present, ceramic microvesicle heat insulating coatings come into Chinese market, and in building, bridge, traffic, marine brill
The aspects such as well platform, chemical storage tank, petroleum pipeline have had successfully to be used.As can be seen here, the development of insulating mold coating for construction
The function boundary of traditional architecture coating is breached, has just quickly been sent out towards function composite and using nanometer technology direction
Exhibition.
With social city, technicalization, hommization development, a kind of design good, adhesive force of viscosity is strong, glossiness is high,
The bloom ceramic insulation coating that thixotropy is good and chemical resistance is good, to meet the market demand, is very important.
The content of the invention
The technical problem of solution：
The application is for existing coating effect of heat insulation is poor, chemical resistance is poor, adhesive force is low, wear no resistance the skill low with hardness
A kind of art problem, there is provided bloom ceramic insulation coating.
Technical scheme：
A kind of bloom ceramic insulation coating, raw materials by weight portion proportioning is as follows：100 parts of polyvinyl acetate emulsion, mica powder 8-
12 parts, talcum powder 20-40 parts, expanded vermiculite 5-25 parts, bentonite 10-50 parts, phenmethylol 6-10 parts, polyvinyl alcohol 4-8 parts, ash
Calcium powder 10-14 parts, calcite in powder 25-45 parts, alundum (Al2O3) 20-40 parts, ultramarine 0.02-0.08 parts, TDI20-60 parts, three second
Hydramine 0.6-1 parts, acrylate 40-80 parts.
As a preferred technical solution of the present invention：The raw materials by weight portion proportioning of the bloom ceramic insulation coating
It is as follows：100 parts of polyvinyl acetate emulsion, mica powder 9-11 parts, talcum powder 25-35 parts, expanded vermiculite 10-20 parts, bentonite 20-
40 parts, phenmethylol 7-9 parts, polyvinyl alcohol 5-7 parts, sierozem power 11-13 parts, calcite in powder 30-40 parts, alundum (Al2O3) 25-35
Part, ultramarine 0.04-0.06 parts, TDI30-50 parts, triethanolamine 0.7-0.9 parts, acrylate 50-70 parts.
As a preferred technical solution of the present invention：The raw materials by weight portion proportioning of the bloom ceramic insulation coating
It is as follows：100 parts of polyvinyl acetate emulsion, 9 parts of mica powder, 25 parts of talcum powder, 10 parts of expanded vermiculite, 20 parts of bentonite, phenmethylol 7
Part, 5 parts of polyvinyl alcohol, 11 parts of sierozem power, 30 parts of calcite in powder, 25 parts of alundum (Al2O3), 0.04 part of ultramarine, TDI30 parts, three second
0.7 part of hydramine, 50 parts of acrylate.
As a preferred technical solution of the present invention：The raw materials by weight portion proportioning of the bloom ceramic insulation coating
It is as follows：100 parts of polyvinyl acetate emulsion, 11 parts of mica powder, 35 parts of talcum powder, 20 parts of expanded vermiculite, 40 parts of bentonite, phenmethylol
9 parts, 7 parts of polyvinyl alcohol, 13 parts of sierozem power, 40 parts of calcite in powder, 35 parts of alundum (Al2O3), 0.06 part of ultramarine, TDI50 parts, three
0.9 part of monoethanolamine, 70 parts of acrylate.
As a preferred technical solution of the present invention：The raw materials by weight portion proportioning of the bloom ceramic insulation coating
It is as follows：100 parts of polyvinyl acetate emulsion, 10 parts of mica powder, 30 parts of talcum powder, 15 parts of expanded vermiculite, 30 parts of bentonite, phenmethylol
8 parts, 6 parts of polyvinyl alcohol, 12 parts of sierozem power, 35 parts of calcite in powder, 30 parts of alundum (Al2O3), 0.05 part of ultramarine, TDI40 parts, three
0.8 part of monoethanolamine, 60 parts of acrylate.
Beneficial effect：
A kind of bloom ceramic insulation coating of the present invention, using above technical scheme compared to the prior art, with following skill
Art effect：1st, coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 1-3h does solid work 20-24h；2nd, fineness 1-20 μ
M, impact strength 60-100J, adhesive force 1-2 grades；3rd, alkali resistance immerse 40% NaOH in 4-8d, crack-free, foaming, peeling,
Soften and dissolution phenomenon；4th, do not condense, do not lump, do not separate, anti-scratch load is high, scrub resistance 1300-1700 times, Ke Yiguang
General production simultaneously constantly replaces current material.
Specific embodiment
Embodiment 1:
Proportioning weighs 100 parts of polyvinyl acetate emulsion by weight, and 8 parts of mica powder, 20 parts of talcum powder, 5 parts of expanded vermiculite is swollen
10 parts of profit soil, 6 parts of phenmethylol, 4 parts of polyvinyl alcohol, 10 parts of sierozem power, 25 parts of calcite in powder, 20 parts of alundum (Al2O3), ultramarine
0.02 part, TDI20 parts, 0.6 part of triethanolamine, 40 parts of acrylate.
Polyvinyl acetate emulsion, mica powder, TDI and triethanolamine input are provided with the reactor of agitator and thermometer
In, 75 DEG C are warming up to, 20min is stirred, mixing speed is 800 revs/min.
90 DEG C are warming up to, surplus stock is added, mix 80min, be cooled to 40 DEG C, the ball milling 15min in grinder, filtering
Discharging tinning.
Coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 3h does solid work 24h；20 μm of fineness, impact strength
60J, 2 grades of adhesive force；Alkali resistance immerses 4d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；Do not coagulate
It is poly-, do not lump, do not separate, anti-scratch load is high, scrub resistance 1300 times, can extensively produce and constantly replace current material.
Embodiment 2:
Match by weight and weigh 100 parts of polyvinyl acetate emulsion, 12 parts of mica powder, 40 parts of talcum powder, 25 parts of expanded vermiculite,
50 parts of bentonite, 10 parts of phenmethylol, 8 parts of polyvinyl alcohol, 14 parts of sierozem power, 45 parts of calcite in powder, 40 parts of alundum (Al2O3), ultramarine
0.08 part, TDI60 parts, 1 part of triethanolamine, 80 parts of acrylate.
Polyvinyl acetate emulsion, mica powder, TDI and triethanolamine input are provided with the reactor of agitator and thermometer
In, 85 DEG C are warming up to, 60min is stirred, mixing speed is 1000 revs/min.
100 DEG C are warming up to, surplus stock is added, mix 120min, be cooled to 50 DEG C, the ball milling 35min in grinder, mistake
Leach material tinning.
Coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 2.5h does solid work 23h；15 μm of fineness, impact is strong
Degree 70J, 2 grades of adhesive force；Alkali resistance immerses 5d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；No
Cohesion, does not lump, and does not separate, and anti-scratch load is high, scrub resistance 1400 times, can extensively produce and constantly replace existing material
Material.
Embodiment 3:
Match by weight and weigh 100 parts of polyvinyl acetate emulsion, 9 parts of mica powder, 25 parts of talcum powder, 10 parts of expanded vermiculite,
20 parts of bentonite, 7 parts of phenmethylol, 5 parts of polyvinyl alcohol, 11 parts of sierozem power, 30 parts of calcite in powder, 25 parts of alundum (Al2O3), ultramarine
0.04 part, TDI30 parts, 0.7 part of triethanolamine, 50 parts of acrylate.
Polyvinyl acetate emulsion, mica powder, TDI and triethanolamine input are provided with the reactor of agitator and thermometer
In, 75 DEG C are warming up to, 20min is stirred, mixing speed is 800 revs/min.
90 DEG C are warming up to, surplus stock is added, mix 80min, be cooled to 40 DEG C, the ball milling 15min in grinder, filtering
Discharging tinning.
Coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 2h does solid work 22h；10 μm of fineness, impact strength
80J, 2 grades of adhesive force；Alkali resistance immerses 6d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；Do not coagulate
It is poly-, do not lump, do not separate, anti-scratch load is high, scrub resistance 1500 times, can extensively produce and constantly replace current material.
Embodiment 4:
Match by weight and weigh 100 parts of polyvinyl acetate emulsion, 11 parts of mica powder, 35 parts of talcum powder, 20 parts of expanded vermiculite,
40 parts of bentonite, 9 parts of phenmethylol, 7 parts of polyvinyl alcohol, 13 parts of sierozem power, 40 parts of calcite in powder, 35 parts of alundum (Al2O3), ultramarine
0.06 part, TDI50 parts, 0.9 part of triethanolamine, 70 parts of acrylate.
Polyvinyl acetate emulsion, mica powder, TDI and triethanolamine input are provided with the reactor of agitator and thermometer
In, 85 DEG C are warming up to, 60min is stirred, mixing speed is 1000 revs/min.
100 DEG C are warming up to, surplus stock is added, mix 120min, be cooled to 50 DEG C, the ball milling 35min in grinder, mistake
Leach material tinning.
Coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 1.5h does solid work 21h；5 μm of fineness, impact is strong
Degree 90J, adhesion 1 grade；Alkali resistance immerses 7d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；No
Cohesion, does not lump, and does not separate, and anti-scratch load is high, scrub resistance 1600 times, can extensively produce and constantly replace existing material
Material.
Embodiment 5:
Match by weight and weigh 100 parts of polyvinyl acetate emulsion, 10 parts of mica powder, 30 parts of talcum powder, 15 parts of expanded vermiculite,
30 parts of bentonite, 8 parts of phenmethylol, 6 parts of polyvinyl alcohol, 12 parts of sierozem power, 35 parts of calcite in powder, 30 parts of alundum (Al2O3), ultramarine
0.05 part, TDI40 parts, 0.8 part of triethanolamine, 60 parts of acrylate.
Polyvinyl acetate emulsion, mica powder, TDI and triethanolamine input are provided with the reactor of agitator and thermometer
In, 80 DEG C are warming up to, 40min is stirred, mixing speed is 900 revs/min.
95 DEG C are warming up to, surplus stock is added, mix 100min, be cooled to 45 DEG C, the ball milling 25min in grinder, mistake
Leach material tinning.
Coating can long-term storage, outward appearance good hand touch, abrasion resistance is good, and surface drying 1h does solid work 20h；1 μm of fineness, impact strength
100J, adhesion 1 grade；Alkali resistance immerses 8d, crack-free, foaming, peeling, softening and dissolution phenomenon in 40% NaOH；Do not coagulate
It is poly-, do not lump, do not separate, anti-scratch load is high, scrub resistance 1700 times, can extensively produce and constantly replace current material.
All components in above example can be with commercially available.
The above embodiments are intended to illustrate the present invention, rather than limitation, therefore with it is of the invention
Any change in claims suitable implication and scope, is all considered as being included within the scope of the claims.
Claims (5)
1. a kind of bloom ceramic insulation coating, it is characterised in that：The raw materials by weight portion of the bloom ceramic insulation coating is matched somebody with somebody
Than as follows：100 parts of polyvinyl acetate emulsion, mica powder 8-12 parts, talcum powder 20-40 parts, expanded vermiculite 5-25 parts, bentonite
10-50 parts, phenmethylol 6-10 parts, polyvinyl alcohol 4-8 parts, sierozem power 10-14 parts, calcite in powder 25-45 parts, alundum (Al2O3)
20-40 parts, ultramarine 0.02-0.08 parts, TDI20-60 parts, triethanolamine 0.6-1 parts, acrylate 40-80 parts.
2. a kind of bloom ceramic insulation coating according to claim 1, it is characterised in that：The bloom ceramic insulation coating
Raw materials by weight portion proportioning it is as follows：100 parts of polyvinyl acetate emulsion, mica powder 9-11 parts, talcum powder 25-35 parts, expansion
Vermiculite 10-20 parts, bentonite 20-40 parts, phenmethylol 7-9 parts, polyvinyl alcohol 5-7 parts, sierozem power 11-13 parts, calcite in powder 30-
40 parts, alundum (Al2O3) 25-35 parts, ultramarine 0.04-0.06 parts, TDI30-50 parts, triethanolamine 0.7-0.9 parts, acrylate
50-70 parts.
3. a kind of bloom ceramic insulation coating according to claim 1, it is characterised in that：The bloom ceramic insulation coating
Raw materials by weight portion proportioning it is as follows：100 parts of polyvinyl acetate emulsion, 9 parts of mica powder, 25 parts of talcum powder, expanded vermiculite 10
Part, 20 parts of bentonite, 7 parts of phenmethylol, 5 parts of polyvinyl alcohol, 11 parts of sierozem power, 30 parts of calcite in powder, 25 parts of alundum (Al2O3), group
It is blue or green 0.04 part, TDI30 parts, 0.7 part of triethanolamine, 50 parts of acrylate.
4. a kind of bloom ceramic insulation coating according to claim 1, it is characterised in that：The bloom ceramic insulation coating
Raw materials by weight portion proportioning it is as follows：100 parts of polyvinyl acetate emulsion, 11 parts of mica powder, 35 parts of talcum powder, expanded vermiculite 20
Part, 40 parts of bentonite, 9 parts of phenmethylol, 7 parts of polyvinyl alcohol, 13 parts of sierozem power, 40 parts of calcite in powder, 35 parts of alundum (Al2O3), group
It is blue or green 0.06 part, TDI50 parts, 0.9 part of triethanolamine, 70 parts of acrylate.
5. a kind of bloom ceramic insulation coating according to claim 1, it is characterised in that：The bloom ceramic insulation coating
Raw materials by weight portion proportioning it is as follows：100 parts of polyvinyl acetate emulsion, 10 parts of mica powder, 30 parts of talcum powder, expanded vermiculite 15
Part, 30 parts of bentonite, 8 parts of phenmethylol, 6 parts of polyvinyl alcohol, 12 parts of sierozem power, 35 parts of calcite in powder, 30 parts of alundum (Al2O3), group
It is blue or green 0.05 part, TDI40 parts, 0.8 part of triethanolamine, 60 parts of acrylate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611190174.4A CN106752185A (en) | 2016-12-21 | 2016-12-21 | A kind of bloom ceramic insulation coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611190174.4A CN106752185A (en) | 2016-12-21 | 2016-12-21 | A kind of bloom ceramic insulation coating |
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| CN106752185A true CN106752185A (en) | 2017-05-31 |
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| CN201611190174.4A Pending CN106752185A (en) | 2016-12-21 | 2016-12-21 | A kind of bloom ceramic insulation coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189520A (en) * | 2017-06-20 | 2017-09-22 | 苏州乔纳森新材料科技有限公司 | A kind of preparation method of medical anti-rusting antibiotic imitation porcelain coating |
| CN112876951A (en) * | 2021-01-18 | 2021-06-01 | 广东歌丽斯化学有限公司 | Heat-insulating powder coating and preparation method and application thereof |
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| CN104031491A (en) * | 2014-06-17 | 2014-09-10 | 苏州靖羽新材料有限公司 | Polyvinyl acetate emulsion ground paint |
| CN104877481A (en) * | 2015-04-29 | 2015-09-02 | 苏州市湘园特种精细化工有限公司 | Polyvinyl acetate coating and preparation method thereof |
| CN105968992A (en) * | 2016-07-19 | 2016-09-28 | 董芬芳 | Rust removal antirust coating for metal |
-
2016
- 2016-12-21 CN CN201611190174.4A patent/CN106752185A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031491A (en) * | 2014-06-17 | 2014-09-10 | 苏州靖羽新材料有限公司 | Polyvinyl acetate emulsion ground paint |
| CN104877481A (en) * | 2015-04-29 | 2015-09-02 | 苏州市湘园特种精细化工有限公司 | Polyvinyl acetate coating and preparation method thereof |
| CN105968992A (en) * | 2016-07-19 | 2016-09-28 | 董芬芳 | Rust removal antirust coating for metal |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189520A (en) * | 2017-06-20 | 2017-09-22 | 苏州乔纳森新材料科技有限公司 | A kind of preparation method of medical anti-rusting antibiotic imitation porcelain coating |
| CN112876951A (en) * | 2021-01-18 | 2021-06-01 | 广东歌丽斯化学有限公司 | Heat-insulating powder coating and preparation method and application thereof |
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Application publication date: 20170531 |