CN106752077A - A kind of blue active dye composition and its production and use - Google Patents
A kind of blue active dye composition and its production and use Download PDFInfo
- Publication number
- CN106752077A CN106752077A CN201611072709.8A CN201611072709A CN106752077A CN 106752077 A CN106752077 A CN 106752077A CN 201611072709 A CN201611072709 A CN 201611072709A CN 106752077 A CN106752077 A CN 106752077A
- Authority
- CN
- China
- Prior art keywords
- component
- compound
- blue active
- weight portion
- blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 0 *c1ccc(**I)cc1 Chemical compound *c1ccc(**I)cc1 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0072—Preparations with anionic dyes or reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/10—Material containing basic nitrogen containing amide groups using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/248—Polyamides; Polyurethanes using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
A kind of blue active dye composition and its production and use, the composition include formula (I) compound in one or more compound groups into component A, formula (II) compound in one or more compound groups into component B, formula (III) compound in one or more compound groups into component C and optional auxiliary agent.The blue active dye composition is applied to the printing and dyeing of various fibers and its yarn fabric, and cost performance is high, and degree of fixation is high, rub resistance, the advantages of the every fastness properties of water-fastness and perspiration resistance are excellent.
Description
Technical field
The present invention relates to a kind of blue active dye composition and its production and use.
Background technology
With making constant progress for textile fabric kind and printing technology, people are to the requirement of textile ecological, environmental protective performance
Also more and more higher, the dyeability to reactive dye proposes requirement higher.Some have excellent dyeability energy and dissolving high
The dyestuff of degree is gradually developed, such as the NEW TYPE OF COMPOSITE reactive blue dye of publication CN 102391681A, possesses good
Dyeability, but this kind of price of dyestuff is costly, and production cost is high.The synthesis of current existing many blue active dyes
Effect is difficult to reach the desired value of people, therefore, research and develop a kind of existing excellent dyeability has cost performance higher again
Composite reactive blue dye, have great importance.
The content of the invention
The present invention provides a kind of blue active dye composition, and the composition has cost performance high, and degree of fixation is high, antifriction
Wipe, the advantages of the every fastness properties of water-fastness and perspiration resistance are excellent.In addition, present invention also offers the preparation of the composition
Method.
The present invention provides a kind of blue active dye composition, and it includes one or more compounds in formula (I) compound
In component A, formula (II) compound of composition one or more compound groups into component B, formula (III) compound in it is a kind of or with
Upper compound group into component C and optional auxiliary agent,
Wherein：
M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；X1It is halogen；
R1It is H ,-SO3M、-COOM、C1~C4Alkyl, C1~C4Alkoxy or R5-X2, R5It is C1~C4Alkylidene, X2For H,
Halogen or amino；
R2、R3、R4It is each independently-SO2CH=CH2Or-SO2C2H4OSO3M
Each M is each independently M1、M2Or M3；
Alternatively, the halogen is selected from：F、Cl.
Alternatively, the component A is selected from one or more in formula (I-1)~(I-10) compound,
Alternatively, the component B is selected from one or more in (II-1)~(II-5) compounds,
Alternatively, the component C is selected from one or more in formula (III-1)~(III-4) compound,
Alternatively, when the component A is selected from one or more in formula (I-1)~(I-10) compound, the component B
Selected from one or more in (II-1)~(II-5) compounds, the component C is selected from formula (III-1)~(III-4) compound
In one or more.
In the present invention, the selection to the auxiliary agent is not particularly limited, and can be conven-tional adjuvants.Alternatively, institute
State auxiliary agent and be selected from dispersant, filler and other performance improvement auxiliary agents.
Alternatively, the dispersant is selected from least one in Dispersant MF, dispersant NNO, and the filler is bright for unit
Powder, described other performance improvement auxiliary agents are selected from least one in dust-proofing agent, solubility improver.
Alternatively, in the blue active dye composition, the content of component A is 1~80 weight portion, preferably 2~
75 weight portions, are further preferably 3~70 weight portions, more preferably 4~65 weight portions；The content of component B is 1~80 weight portion, excellent
Elect 2~75 weight portions as, be further preferably 3~70 weight portions, more preferably 4~65 weight portions；The content of component C is 1~45 weight
Amount part, preferably 1~40 weight portion is further preferably 1~35 weight portion, more preferably 1~30 weight portion；The content of auxiliary agent is 0
~80 weight portions, preferably 0~75 weight portion, more preferably 0~70 weight portion, are further preferably 0~65 weight portion.
The present invention also provides a kind of preparation method of above-mentioned blue active dye composition, and it is included component A in proportion
Dry powder or slurry, the dry powder of component B or slurry, the dry powder of component C or slurry and the mixing of optional auxiliary agent, by directly mixing
Or optional drying process is obtained.
In the present invention, there is no particular limitation for the equipment for being mixed to the dry powder, alternatively, using taper, rolling
The blender of cartridge type or pears blade is mixed, and test analysis are qualified after being well mixed packs again.In addition, being mixed to the slurry
There is no particular limitation for conjunction method, alternatively, mixing is stirred in a reservoir.In addition, the present invention is to the drying process institute
The equipment of use is also without special restriction, it is preferred to use spray tower, drying room or flash distillation dryer etc. are dried and obtain granular
Or powder product.
The present invention also provides purposes of the above-mentioned composition as blue active dye.
Alternatively, the blue active dye is used for fiber or the printing and dyeing of its yarn fabric.
Alternatively, the blue active dye is used for cellulose fibre, Fypro, protein fibre or their spinning
The printing and dyeing of fabric.
Alternatively, the cellulose fibre includes cotton fiber, flaxen fiber and regenerated fiber.
Alternatively, the printing and dyeing include dyeing and/or stamp, and the reactive blue dye is used for cellulose fiber peacekeeping and regenerates fibre
The stamp of dimension.
In the present invention, in order to obtain the composite active dye composition of excellent combination property, to each dyestuff list
, it is necessary to the aspect for considering is numerous when body is selected, relate generally between cost, each dye monomer of each dye monomer
Can obtain being expected after compatibility, compatibility that degree of fixation can be obtained after the reactive dye compound of coloured light and compatibility, solubility,
Reactive dye compounds of excellent combination property such as every color fastness etc.；And those skilled in the art can not simply basis
Color theory selects the dye monomer of corresponding coloured light just to obtain existing above-mentioned excellent dyeability cost performance higher again
Compound blue reactive dye compound, i.e., to those skilled in the art, several dye monomers carry out compatibility and obtain this Shen
Blue active dye composition that please be described, needs to pay creative work, not can simply be foreseen.
The present inventor obtains the above-mentioned blue active with specific compatibility of the invention by in-depth study
Dye composite, the reactive dye compound has advantages below：Cost performance is high, and degree of fixation is high, rub resistance, water-fastness and sweat proof
The advantages of stain color items fastness properties are excellent.Blue active dye composition of the invention is suitable for cellulosic fibre material
Printing and dyeing, such as printing and dyeing of cotton, fiber crops, regenerated fiber and its yarn fabric, be also applied in addition Fypro, protein fibre and its
The printing and dyeing of yarn fabric.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.It should be appreciated that described herein specific
Illustrate to being for illustration only property of implementation method, but protection scope of the present invention is not limited to this.
Compound employed in following embodiments can be synthesized by existing method, can also use commercially available prod.
Embodiment 1
By the component A of 36.5 weight portion formulas (I-3), the component B of 42.5 weight portion formulas (II-2), 9.5 weight portion formula (III-
2) component C and the glauber salt of 11.5 weight portions carries out dry powder blend by blender, obtains final product blue active dye composition 1,
Using the composition as reactive blue dye, by cotton dyeing au bleu,
Embodiment 2
By the component A of 38.6 weight portion formulas (I-5), the component B of 35.0 weight portion formulas (II-2), 5 weight portion formulas (III-2)
Component C and the glauber salt of 21.4 weight portions dry powder blend is carried out by blender, obtain final product blue active dye composition 2, will
The composition as reactive blue dye, by cotton dyeing au bleu,
Comparative example 1
The glauber salt of the component of 50.2 weight portion formulas (IV), the component of 2.9 weight portion formulas (V) and 46.9 weight portions is passed through
Blender carries out dry powder blend, obtains final product blue active dye composition 3, and the composition as reactive blue dye knits cotton
Thing printing and dyeing au bleu,
Dye test：
To the blue active dye that the blue active dye composition 1-2 and comparative example 1 that are obtained by embodiment 1-2 are obtained
Each 2g of composition 3 respectively with each 1000g of dye liquor that 45g sodium chloride is made in, be separately added into 100g baftas, with 1 DEG C/minute intensification
It is the sodium carbonate liquor of 20g/L to 100g concentration is added in each dye liquor to after 60 DEG C, and dyeing 1 hour at this temperature, then
Dyeing and weaving thing is rinsed, is rinsed again after being soaped 15 minutes with nonionic detergent and dried.Respectively according to GB/T 2391-
2014th, the method for GB/T 3920-2008, GB/T 3921-2008 and GB/T 3922-2013 test its degree of fixation, rub resistance,
Water-fastness and colour fastness to perspiration, test result is as shown in table 1 below：
Table 1
Cost performance compares：
The cost of the reactive blue dye of the embodiment of the present invention 1 and comparative example 1 is shown in Table 2, and data are one ton of dyestuff (standard of production
Product control under intensity for needed for 100%) each component cost (unit).
Table 2
As shown in Table 1, blue active dye composition of the invention, when being applied to dyeing as blue active dye, Gu
Color rate is high, and washing fastness and fastness to perspiration are good, and every fastness properties are excellent, and combination property is protruded.Additionally, can by table 2
Know, embodiment 1 often produces cost of material needed for 1 ton of dyestuff for 19716.6 yuan；Comparative example 1 often produce raw material needed for 1 ton of dyestuff into
This is 34170.0 yuan.When intensity under standard control is 100%, blue active dye composition of the invention, as
When reactive blue dye is applied to dyeing, often producing 1 ton of dyestuff can be economized in raw materials 14453.4 yuan of cost, and batch production will be carried substantially
Economic benefit high, hence it is evident that better than the reactive blue dye shown in comparative example 1.
Blue active dye composition of the invention in sum, cost performance compares higher, excellent combination property.
Claims (10)
1. a kind of blue active dye composition, it is characterised in that including one or more compound groups in formula (I) compound into
Component A, formula (II) compound in one or more compound groups into component B, formula (III) compound in one or more change
The component C and optional auxiliary agent of compound composition,
Wherein：
M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；X1It is halogen；
R1It is H ,-SO3M、-COOM、C1~C4Alkylidene, C1~C4Alkylene oxide group or R5-X2, R5It is C1~C4Alkylidene, X2For H,
Halogen or amino；
R2、R3、R4It is each independently-SO2CH=CH2Or-SO2C2H4OSO3M；
Each M is each independently M1、M2Or M3；
Alternatively, the halogen is selected from：F、Cl.
2. blue active dye composition according to claim 1, it is characterised in that the component A be selected from formula (I-1)~
(I-10) one or more in compound,
3. blue active dye composition according to claim 1, it is characterised in that the component B be selected from (II-1)~
(II-5) one or more in compound,
4. blue active dye composition according to claim 1, it is characterised in that the component C is selected from formula (III-1)
One or more in~(III-4) compounds,
5. the blue active dye composition according to any one of claim 1-4, it is characterised in that as the component A
During selected from one or more in formula (I-1)~(I-10) compound, the component B is selected from (I-1)~(I-5) compounds
One or more, the component C is selected from one or more in formula (III-1)~(III-4) compound.
6. the blue active dye composition according to any one of claim 1-5, it is characterised in that the auxiliary agent is selected from
Dispersant, filler and other performance improvement auxiliary agents；
Alternatively, the dispersant is selected from least one in Dispersant MF, dispersant NNO, and the filler is glauber salt, institute
State at least one during other performance improvement auxiliary agents are selected from dust-proofing agent, solubility improver.
7. the blue active dye composition according to any one of claim 1-6, it is characterised in that described blue living
Property dye composite in, the content of component A is 1~80 weight portion, and preferably 2~75 weight portions are further preferably 3~70 weight
Part, more preferably 4~65 weight portions；The content of component B is 1~80 weight portion, preferably 2~75 weight portions, further preferably for 3~
70 weight portions, more preferably 4~65 weight portions；The content of component C is 1~45 weight portion, preferably 1~40 weight portion, then excellent
Elect 1~35 weight portion, more preferably 1~30 weight portion as；The content of auxiliary agent is 0~80 weight portion, preferably 0~75 weight
Part, more preferably 0~70 weight portion is further preferably 0~65 weight portion.
8. a kind of preparation method of the blue active dye composition any one of claim 1-7, it is characterised in that bag
Include and in proportion mix the dry powder or slurry of component A, the dry powder of component B or slurry, the dry powder of component C or slurry and optional auxiliary agent
Close, be obtained by directly mixing or optional drying process.
9. the composition any one of claim 1-7 as blue active reactive dye purposes.
10. purposes according to claim 9, it is characterised in that the blue active reactive dye are used for fiber or its spinning
The printing and dyeing of fabric；
Alternatively, the blue active dye is used for cellulose fibre, Fypro, protein fibre or their yarn fabric
Printing and dyeing；
Alternatively, the cellulose fibre includes cotton fiber, flaxen fiber and regenerated fiber；
Alternatively, the printing and dyeing include dyeing and/or stamp, and the reactive blue dye is used for cellulose fiber peacekeeping regenerated fiber
Stamp.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072709.8A CN106752077B (en) | 2016-11-28 | 2016-11-28 | A kind of blue active dye composition and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072709.8A CN106752077B (en) | 2016-11-28 | 2016-11-28 | A kind of blue active dye composition and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106752077A true CN106752077A (en) | 2017-05-31 |
| CN106752077B CN106752077B (en) | 2018-07-24 |
Family
ID=58904291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611072709.8A Active CN106752077B (en) | 2016-11-28 | 2016-11-28 | A kind of blue active dye composition and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106752077B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110983822A (en) * | 2019-12-30 | 2020-04-10 | 张家港三得利染整科技有限公司 | Coating composition for yarn pigment dyeing |
| CN112662199A (en) * | 2020-12-10 | 2021-04-16 | 上海雅运新材料有限公司 | Black dye compound and preparation method and dyeing application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6443568A (en) * | 1987-08-10 | 1989-02-15 | Sumitomo Chemical Co | Reactive dye composition and dyeing |
| US5356444A (en) * | 1992-11-02 | 1994-10-18 | Bayer Aktiengesellschaft | Phthalocyanine reactive dyestuff mixture |
| US5709717A (en) * | 1995-05-12 | 1998-01-20 | Bayer Aktiengesellschaft | Phthalocyanine reactive dyestuff mixture |
| CN1202549A (en) * | 1997-06-17 | 1998-12-23 | 希巴特殊化学控股公司 | Process for printing textile fibre materials in accordance with ink-jet printing process |
| CN1202550A (en) * | 1997-06-17 | 1998-12-23 | 希巴特殊化学控股公司 | Process for printing textile fibre materials in accordance with ink-jet printing process |
| CN1222542A (en) * | 1997-12-11 | 1999-07-14 | 西巴特殊化学品控股有限公司 | Process for dyeing or printing and novel reactive dyes |
| CN1646641A (en) * | 2002-04-12 | 2005-07-27 | 克莱里安特财务(Bvi)有限公司 | Composition for printing recording materials |
-
2016
- 2016-11-28 CN CN201611072709.8A patent/CN106752077B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6443568A (en) * | 1987-08-10 | 1989-02-15 | Sumitomo Chemical Co | Reactive dye composition and dyeing |
| US5356444A (en) * | 1992-11-02 | 1994-10-18 | Bayer Aktiengesellschaft | Phthalocyanine reactive dyestuff mixture |
| US5709717A (en) * | 1995-05-12 | 1998-01-20 | Bayer Aktiengesellschaft | Phthalocyanine reactive dyestuff mixture |
| CN1202549A (en) * | 1997-06-17 | 1998-12-23 | 希巴特殊化学控股公司 | Process for printing textile fibre materials in accordance with ink-jet printing process |
| CN1202550A (en) * | 1997-06-17 | 1998-12-23 | 希巴特殊化学控股公司 | Process for printing textile fibre materials in accordance with ink-jet printing process |
| CN1222542A (en) * | 1997-12-11 | 1999-07-14 | 西巴特殊化学品控股有限公司 | Process for dyeing or printing and novel reactive dyes |
| CN1646641A (en) * | 2002-04-12 | 2005-07-27 | 克莱里安特财务(Bvi)有限公司 | Composition for printing recording materials |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110983822A (en) * | 2019-12-30 | 2020-04-10 | 张家港三得利染整科技有限公司 | Coating composition for yarn pigment dyeing |
| CN112662199A (en) * | 2020-12-10 | 2021-04-16 | 上海雅运新材料有限公司 | Black dye compound and preparation method and dyeing application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106752077B (en) | 2018-07-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106833017B (en) | A kind of blue active dye composition and its preparation method and application | |
| CN105778560B (en) | A kind of red reactive dye composition and its production and use | |
| CN106752076B (en) | A kind of blue active dye composition and its preparation method and application | |
| CN101935466B (en) | Active red dye composition | |
| CN105778561B (en) | A kind of Black reactive dye composition and its production and use | |
| CN101880473B (en) | Active orange dye composition | |
| CN105694530B (en) | A kind of orange active dye compound, a kind of orange active dye composition and its preparation method and application | |
| CN105802278B (en) | A kind of Black reactive dye composition and its production and use | |
| CN105647238B (en) | A kind of grey reactive dye compound and its production and use | |
| CN105778559A (en) | Black active dye composition and preparation method and use thereof | |
| KR20130100133A (en) | Mixtures of fibre-reactive dyes and their use in a method for trichromatic dyeing or printing | |
| CN106752077B (en) | A kind of blue active dye composition and its preparation method and application | |
| KR101871556B1 (en) | Acid dye composition,and dyeing method using same | |
| CN104448927A (en) | Composite active blue dye | |
| CN102433030B (en) | Active yellow dye composition | |
| CN101880474B (en) | Orange red reactive dyestuff composition | |
| CN104231668B (en) | A kind of Yellow active dye composition and its production and use, and the yarn fabric of the fiber obtained by its printing and dyeing or fiber | |
| CN101880475B (en) | Active scarlet dye composition | |
| CN111334086B (en) | Maotai-red reactive dye composition and preparation method and application thereof | |
| CN111032790B (en) | Reactive dye composition and dyeing method using same | |
| CN105778563B (en) | A kind of Black reactive dye composition and its production and use | |
| CN102504594B (en) | Reactive red dye composition | |
| CN110387143B (en) | Yellow reactive dye composition and preparation method and application thereof | |
| CN102268194A (en) | Red active dye composition | |
| CN102977638A (en) | Composition, preparation method and application thereof, textile and textile product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |