CN106751287A - Artificial snow imitation and manufacturing method thereof - Google Patents
Artificial snow imitation and manufacturing method thereof Download PDFInfo
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- CN106751287A CN106751287A CN201611024444.4A CN201611024444A CN106751287A CN 106751287 A CN106751287 A CN 106751287A CN 201611024444 A CN201611024444 A CN 201611024444A CN 106751287 A CN106751287 A CN 106751287A
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- high molecular
- aqueous solvent
- molecular polymer
- inorganic salts
- snow
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 71
- 239000002245 particle Substances 0.000 claims abstract description 54
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 239000000243 solution Substances 0.000 claims description 39
- 150000003839 salts Chemical class 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- -1 halide ion Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 235000015110 jellies Nutrition 0.000 claims description 5
- 239000008274 jelly Substances 0.000 claims description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Chemical class 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Chemical class 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Chemical class 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical class CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229920000891 common polymer Polymers 0.000 claims 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract description 6
- 239000000084 colloidal system Substances 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 238000010586 diagram Methods 0.000 description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000013016 damping Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000019013 Viburnum opulus Nutrition 0.000 description 2
- 244000071378 Viburnum opulus Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000533950 Leucojum Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229920002627 poly(phosphazenes) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229920000247 superabsorbent polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/24—Materials not provided for elsewhere for simulating ice or snow
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
An artificial snow imitation comprising: a plurality of particles of an inorganic salt; and a polymer solution layer which is in a colloid shape and coats the surface of the inorganic salt particles, wherein the polymer solution layer is composed of a water-soluble water-absorbing polymer and an aqueous solvent. The artificial snow-imitation is similar to natural snow in appearance, touch and mechanical properties, and can be manufactured and laid on a ski slope in a normal temperature environment, so that the production cost can be greatly reduced.
Description
Technical field
The present invention relates to one kind based on inorganic salts particle, and the particulate composition of Polymer Solution is combined as normal
The artificial imitative snow of temperature, it is low temperature snowmaking that main body is made to be different from water.
Background technology
General snowmaking is that, based on water, (0 DEG C or so) makes snowflake using snowmaker at low ambient temperatures, because
This is not suitable in subtropical zone artificial snow-making, or is only capable of in the low temperature space artificial snow-making with room conditioning.The method is subject to natural environment
The limitation of condition, and water-cooled need to be frozen into snow by manufacturing process through hot swapping, snowmaking process can significantly consumed energy and have
The misgivings of environmental protection.
Therefore, people develop following various normal temperature snowmaking that can be applied to non-cold district successively.For example,
Based on super absorbent polymer, this polymer can rapidly absorb moisture to known snowmaking, in a short time expansion and gel
Change, form a kind of spherical artificial's snow particle of the similar natural snow of color, outward appearance, shatter value.However, being touched after this Gelation
Sense becomes soft, sticky, and does not stick each other between particle, it is impossible to the sense of touch of real simulation natural snow.
To increase the mechanical property of snowmaking, one kind is developed in recent years based on strontium ferrite and with magnetic people
Artificial snow-making.Strontium ferrite powder body through overmolding, sinter, clean, dry, magnetize and produce snowmaking, it has good coherency, resistance
Buddhist nun's dispersiveness and lubricity.But its Making programme need to be by multiple tracks formality, and sintering temperature is up to 1000~1300 DEG C, equally
Consume many energy.
Separately have a kind of to plastify " drought snow " technology that material is fixed on ground, its moulding includes brush and sac like, comb shape or gold
The shapes such as pin mushroom, in the way of similar carpet be layed in ground uses for skiing.But this method is limited to be fixed on the pattern on ground,
Only provide wheel function, it is impossible to for other snowfields amusement such as make a snowman or have a snowball fight.
In view of this, need at present it is a kind of in outward appearance, sense of touch and mechanical performance all similar to the normal temperature people of natural snow
Imitative snow is made, and its manufacturing process is simple and is easily largely layed on sloping course.
The content of the invention
The present invention provides a kind of artificial imitative snow, the spy such as outward appearance, sense of touch, coherency and damping dispersiveness that it simulates natural snow
Property, thus can be used on slideway is laid under normal temperature for various snowfield amusement (such as ski, make a snowman and have a snowball fight).Additionally,
This it is artificial it is imitative snow material can natural decomposition it is in the Nature therefore relatively environment-friendly.
The present invention provides a kind of preparation method of artificial imitative snow again, and its manufacturing process is simple, can implement at room temperature and complete
Low temperature environment is not required to entirely, and be easily largely layed on slideway, to reach the effect of low power consuming, low cost.
One embodiment of the invention provides a kind of artificial imitative snow, comprising：Multiple inorganic salts particles；And Polymer Solution
Layer, the jelly surface of coated inorganic salt particle, wherein, Polymer Solution layer by water miscible water suction high molecular polymer and
Aqueous solvent is constituted.
In one embodiment, the percentage by weight of inorganic salts particle is 72%~97% in artificial imitative snow,
Remaining as Polymer Solution layer, Polymer Solution layer is by water miscible water suction high molecular polymer and aqueous molten
Agent is constituted, and the water suction high molecular polymer and the part by weight of the aqueous solvent are 1：100~1：20000.
In one embodiment, the cation of inorganic salts particle include group ia metal ion and ammonium ion, and the moon from
Attached bag contains halide ion, nitrate ion, sulfate ion, carbanion and phosphate anion.The group ia metal
Ion is preferably sodium or potassium.
In one embodiment, the particle size range of inorganic salts particle is less than 10mm.
In one embodiment, water suction high molecular polymer includes acrylamide, starch-grafted acrylonitrile, acrylates, first
The linear polymer or copolymer of base acrylates and carboxymethyl cellulose salt.
In one embodiment, aqueous solvent includes pure water and at least one containing ethanol, isopropanol and glycerine
The aqueous solution.
Another embodiment of the present invention provides a kind of manufacture method of artificial imitative snow, comprising：Mix water miscible macromolecule
Polymer and aqueous solvent, Polymer Solution is formed to allow high molecular polymer to be dissolved in aqueous solvent；And mixing macromolecule
Solution and multiple inorganic salts particles, high score is formed to allow Polymer Solution to be equably coated on the surface of inorganic salts particle
Sub- solution layer, completes artificial imitative snow.
Another embodiment of the present invention provides a kind of purposes of particulate composition as artificial imitative snow, the particulate composition
Comprising：Multiple inorganic salts particles；And Polymer Solution layer, the jelly surface of coated inorganic salt particle, wherein, high score
Sub- solution layer is made up of water miscible water suction high molecular polymer and aqueous solvent.
In one embodiment, particulate composition can be used as laying sloping course and the various stereo modelling of making.
Brief description of the drawings
Fig. 1 is represented with the schematic diagram of the structure of artificial imitative snow of the invention；
Fig. 2 represents the Making programme figure of artificial imitative snow of the invention；
Fig. 3 is represented with the schematic diagram of artificial imitative snow laying sloping course of the invention；
Fig. 4 represents the schematic diagram that three-dimensional contouring is made with artificial imitative snow of the invention；
Symbol description：
10 artificial imitative snow；12 inorganic salts particles；14 Polymer Solutions layer；100 sloping courses；
200 snowman.
Specific embodiment
Hereinafter, with reference to adjoint schema, describe in detail according to embodiments of the invention, so that this area person is apparent to.
Described creation can be using the implementation method of various changes, when being not limited to only these embodiments.The present invention omits ripe
Know the description of part (well-known part), and identical reference number represents identical component in the present invention.
Fig. 1 is shown with the schematic diagram of the structure of artificial imitative snow of the invention, artificial imitative snow 10 in the present embodiment, bag
Contain：Multiple inorganic salts particles 12；And Polymer Solution layer 14, the jelly surface of coated inorganic salt particle 12, wherein,
The Polymer Solution layer 14 is made up of water miscible water suction high molecular polymer and aqueous solvent.
Wherein, inorganic salts particle 12 is white crystals, is used to simulate the crystalline particle sense of touch and loose matter of natural snow
Ground, (solubility is more than 10 to dissolve in aqueous solvent-4M) in dissociation produce zwitterion, and produce ion not with polyphosphazene polymer
Compound reaction precipitation.Therefore inorganic salts particle 12 cation can be group ia metal ion and ammonium ion, and the moon from
Son can be halide ion, nitrate ion, sulfate ion, carbanion and phosphate anion.In the present embodiment, nothing
Machine salt particle 12 can be sodium chloride, but inorganic salts particle 12 also can be by sodium carbonate, sulphur in another embodiment not illustrated
The materials such as sour sodium, potassium phosphate, potassium nitrate, ammonium chloride are constituted.
Wherein, the general handy source of category of inorganic salts particle 12, has Van der Waals force and Coulomb force between particle
Thus attract one another, this attraction may be used to simulate the coherency of natural snow, when the particle diameter of particle is smaller, contact area is bigger
Coherency is also stronger；Additionally, solid of the inorganic salts particle 12 for dispersiveness, can produce damping dispersiveness, appropriate coherency
Help to carry out that the artificial imitative pressure of snow 10 easily is pinched into predetermined shape without scattering when snowfield is entertained, or damping dispersiveness can
The skiing experience that simulation shovel snow is turned.Therefore the particle diameter of inorganic salts particle 12 is less than 10mm, in the present embodiment, sodium chloride
The particle diameter of grain can be 100 μm~500 μm.
Wherein, Polymer Solution layer 14 composition can be Polymer Solution, by it is water miscible water suction high molecular polymer and
Aqueous solvent is formed.Polymer Solution layer 14 is uniformly coated on the surface of inorganic salts particle 12, can increase artificial imitative snow 10
Coherency and water-retaining property.In the present embodiment, Polymer Solution is the aqueous solution that Sodium Polyacrylate mixes with water.
Wherein, the high molecular polymer that absorbs water is dissolved in aqueous solvent, and can produce the molecule long-chain with electrical group.
The ion electrically different with molecule long-chain can be provided after inorganic salts particle 12 or water suction high molecular polymer dissolving, thus is made
Obtain ion and form bridge formation through electrostatic attraction with molecule interchain long, also contribute to the coherency of the artificial imitative snow 10 of increase.
Additionally, moisture in the absorbable air of water suction high molecular polymer, the speed that solvent evapotranspires can be slowed down through moisture is absorbed
Rate, allows water suction high molecular polymer to be maintained at dissociation and forms the state built bridge, so artificial imitative snow be able to maintain that its coherency and
What will not be become is dry, hard.Therefore in another embodiment not illustrated, water suction high molecular polymer also can be by acrylamide, starch
Graft polypropylene nitrile, carboxymethyl cellulose salt, acrylates, the linear polymer of methacrylate or copolymer are replaced
In generation, illustrate but be not limited to polyacrylamide, sodium carboxymethylcellulose etc..
Wherein, aqueous solvent is the solvent that can dissolve water suction high molecular polymer, or with more the solution of volatile materials.
When artificial imitative snow 10 is held in the hand, because evapotranspiring for aqueous solvent takes away a little heat, contact site can feel temperature drop,
Can simulative snow ice-cold sense of touch.Therefore in another embodiment not illustrated, aqueous solvent can be by concentration expressed in percentage by weight
The ethanol of 5-30%, isopropanol or both replace water according to the aqueous solvent that arbitrary proportion mixes.
Wherein, aqueous solvent is the solvent that can dissolve water suction high molecular polymer, or more containing many alcohol functional group molecules
Solution, the life-span is increased to improve the Water-saving effect of artificial imitative snow 10.Therefore in another embodiment not illustrated, aqueous solvent
Water can be replaced by the glycerine water solution of percentage by weight 1-20%.
Wherein, high molecular polymer and the part by weight of aqueous solvent can be 1 in Polymer Solution：100~1：20000,
The hydrogel of the gluey liquid solution with mobility rather than water-swellable is formed, can be equably mixed with inorganic salts particle 12
Close.The concentration of configured aqueous sodium polyacrylate can be 1 in the present embodiment：200~1：10000.
Wherein, the percentage by weight of inorganic salts particle 12 is for example 72%~97%, and the use of aforementioned proportion is 1：100
~1：When 20000 Polymer Solution is prepared, then the percentage by weight of the high molecular polymer that absorbs water can for 0.0001%~
0.27%, the percentage by weight of aqueous solvent can be 2%~27%.The weight of sodium chloride in the artificial imitative snow 10 of the present embodiment
Percentage can be 80%~95%, and use ratio is 1：200~1：When prepared by 10000 Polymer Solution, then polyacrylic acid
The percentage by weight of sodium can be 0.0004%~0.095%, and the percentage by weight of water can be 4%~19%.
Fig. 2 shows the Making programme figure of artificial imitative snow of the invention.The present embodiment can be produced according to step S01 and S02
The artificial imitative snow 10 of Fig. 1, but be not limited.Carry out step S01 first, mix water miscible high molecular polymer and aqueous molten
Agent, Polymer Solution is formed to allow high molecular polymer to be dissolved in aqueous solvent.For example, the Sodium Polyacrylate of 1g is dissolved in
The water of 200g, it is 1 to form concentration：200 aqueous sodium polyacrylate.Then carry out step S02, mixing Polymer Solution with it is many
Individual inorganic salts particle 12, with allow Polymer Solution equably the surface of coated inorganic salt particle 12 and form Polymer Solution
Layer 14.For example, above-mentioned aqueous sodium polyacrylate is poured into 100 μm~500 μm of particle size, the sodium chloride of gross weight 3500g
Stirred in grain, thus aqueous sodium polyacrylate layer is formed on the surface of sodium chloride particle, then complete that there is white
Particulate composition it is artificial imitative snow 10.Additionally, can also add appropriate during making artificial imitates snow 10 according to demand
The additives such as antiseptic.
According in the artificial imitative snow 10 that above-described embodiment is completed, the form of white particle composition is inorganic depending on what is used
The crystalline form (illustrate but be not limited to, sodium chloride is cubic crystal) and particle diameter of salt particle 12.
In other words, the particulate composition that inorganic salts particle 12 is constituted with Polymer Solution layer 14 can be used as artificial imitative
The purposes of snow 10.Particulate composition can be further applied to snowfield amusement, such as the sloping course schematic diagram of the 3rd figure, can will be above-mentioned
The artificial imitative snow 10 that embodiment makes directly is layed in sloping course 100, and lays appropriate thickness according to demand.Additionally,
The appropriate Polymer Solution of sprinkling or aqueous solvent is can pass through directly to be spread on using slideway after a while, or thereon
If one layer of new artificial imitative snow 10, you can improve Polymer Solution layer 14 because of the evapotranspiration of solvent, or because of the extruding of weight
So that hard, the crisp problem that artificial imitative snow 10 becomes.
Artificial imitative snow 10 is pinched in the pressure of external force, is easy to moulding through particle and intergranular coherency effect, can make
Make various stereo modelling without scattering.For example shown in snowman's schematic diagram of the 4th figure, what can be made above-described embodiment is artificial imitative
Avenge 10 kneadings into the main body of snowman 200.Additionally, after solvent evapotranspires the surface of snowman 200 can become it is hard, therefore can for a long time
This appearance is kept without scattering.
Through the artificial imitative snow 10 that the above embodiment of the present invention is provided, outward appearance, sense of touch, the coherency of natural snow can be simulated
And the characteristics such as dispersiveness are damped, easily largely it is layed on slideway, therefore can realize laying slideway for various snowfield under normal temperature
Amusement.Due to the low raw-material cost for using, manufacture reduces energy resource consumption under room temperature environment, therefore can be greatly reduced into
This.
Only, above disclosed diagram and explanation, only presently preferred embodiments of the present invention, non-is to limit this hair
Bright implementation, is familiar with its institute's spirit under this invention of the personage of this skill generally, and the change or modification made should all be covered
In the claim of following this case.
Claims (8)
1. a kind of artificial imitative snow, comprising：
Multiple inorganic salts particles, 72%~97% is accounted in the artificial imitative snow, be can dissolve and is produced
Zwitterion, and produce the zwitterion not with high molecular polymer reaction precipitation；And
Polymer Solution layer, jelly coats the surface of the inorganic salts particle, and the Polymer Solution layer is by water miscible
Water suction high molecular polymer and aqueous solvent are constituted, and high molecular polymer and the weight ratio of the aqueous solvent of absorbing water
Example is 1：100~1：20000.
2. artificial imitative snow according to claim 1, it is characterised in that the cation of the inorganic salts particle is included
Group ia metal ion and ammonium ion, and the anion includes halide ion, nitrate ion, sulfate ion, carbon
Acid ion and phosphate anion.
3. artificial imitative snow according to claim 1, it is characterised in that the particle diameter of the inorganic salts particle is less than 10mm.
4. artificial imitative snow according to claim 1, it is characterised in that the water suction high molecular polymer includes acryloyl
The linear polymer of amine, starch-grafted acrylonitrile, acrylates, methacrylate and carboxymethyl cellulose salt is common
Polymers.
5. artificial imitative snow according to claim 1, it is characterised in that the aqueous solvent is comprising pure water and contains second
At least one of aqueous solution of alcohol, isopropanol and glycerine.
6. a kind of manufacture method of artificial imitative snow, comprising：
Water miscible water suction high molecular polymer and the aqueous solvent of mixing, the water suction high molecular polymer and the aqueous solvent
Part by weight be 1：100~1：20000, form high score to allow the water suction high molecular polymer to be dissolved in the aqueous solvent
Sub- solution；And
Mix the Polymer Solution and multiple inorganic salts particles, it is described inorganic to allow the Polymer Solution equably to coat
The surface of salt particle and form Polymer Solution layer, complete the artificial imitative snow,
Wherein described inorganic salts particle accounts for 72%~97% in the artificial imitative snow, can dissolve and produces
Raw zwitterion, and the zwitterion for producing not with high molecular polymer reaction precipitation.
7. a kind of particulate composition as artificial imitative snow purposes, the particulate composition includes：
Multiple inorganic salts particles, 72%~97% is accounted in the particulate composition, be can dissolve and is produced
Raw zwitterion, and the zwitterion for producing not with high molecular polymer reaction precipitation；And
Polymer Solution layer, jelly coats the surface of the inorganic salts particle, and the Polymer Solution layer is by water miscible
Water suction high molecular polymer and aqueous solvent are constituted, and high molecular polymer and the weight ratio of the aqueous solvent of absorbing water
Example is 1：100~1：20000.
8. the purposes of artificial imitative snow according to claim 7, it is characterised in that the particulate composition can be slided as laying
Snowbank road and the various stereo modelling of making.
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| TW104141781A TWI570229B (en) | 2015-12-11 | 2015-12-11 | Artificial snow material and method of producing the same |
| TW104141781 | 2015-12-11 |
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| CN108003838A (en) * | 2017-11-17 | 2018-05-08 | 河北金丰新材料科技有限公司 | Colored snowmaking and preparation method thereof |
| CN108165236A (en) * | 2017-12-22 | 2018-06-15 | 北京德得创业科技有限公司 | A kind of snowmaking that shaping sizing can be recycled and preparation method thereof |
| CN108178893A (en) * | 2018-02-27 | 2018-06-19 | 临沂轶群包装制品有限公司 | A kind of snow spray and preparation method thereof |
| CN108192571A (en) * | 2017-12-22 | 2018-06-22 | 北京德得创业科技有限公司 | It is a kind of to be used to be laid with snowmaking of ski trail and preparation method thereof |
| CN108977175A (en) * | 2018-08-13 | 2018-12-11 | 惠州市豪美氏智能电气有限公司 | A kind of snowmaking powder |
| CN110938410A (en) * | 2019-10-28 | 2020-03-31 | 陈燕明 | Artificial snow composition with stable moisture and application thereof |
| CN111154137A (en) * | 2020-01-15 | 2020-05-15 | 北京理工大学 | Crystal snow material and preparation method thereof |
| CN111154033A (en) * | 2020-01-15 | 2020-05-15 | 北京理工大学 | Gel type ice and snow material with adjustable solidification temperature and transmittance and preparation method thereof |
| CN111253509A (en) * | 2020-03-06 | 2020-06-09 | 北京理工大学 | Molding and preparation method of personalized ice and snow product |
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| CN108003838A (en) * | 2017-11-17 | 2018-05-08 | 河北金丰新材料科技有限公司 | Colored snowmaking and preparation method thereof |
| CN108165236A (en) * | 2017-12-22 | 2018-06-15 | 北京德得创业科技有限公司 | A kind of snowmaking that shaping sizing can be recycled and preparation method thereof |
| CN108192571A (en) * | 2017-12-22 | 2018-06-22 | 北京德得创业科技有限公司 | It is a kind of to be used to be laid with snowmaking of ski trail and preparation method thereof |
| CN108165236B (en) * | 2017-12-22 | 2021-02-19 | 北京德得创业科技有限公司 | Recyclable plastic-shaped artificial snow and preparation method thereof |
| CN108192571B (en) * | 2017-12-22 | 2021-02-19 | 北京德得创业科技有限公司 | Artificial snow for paving ski tracks and preparation method thereof |
| CN108178893A (en) * | 2018-02-27 | 2018-06-19 | 临沂轶群包装制品有限公司 | A kind of snow spray and preparation method thereof |
| CN108977175A (en) * | 2018-08-13 | 2018-12-11 | 惠州市豪美氏智能电气有限公司 | A kind of snowmaking powder |
| CN108977175B (en) * | 2018-08-13 | 2021-03-05 | 费灶鑫 | Artificial snow powder |
| CN110938410A (en) * | 2019-10-28 | 2020-03-31 | 陈燕明 | Artificial snow composition with stable moisture and application thereof |
| CN111154137A (en) * | 2020-01-15 | 2020-05-15 | 北京理工大学 | Crystal snow material and preparation method thereof |
| CN111154033A (en) * | 2020-01-15 | 2020-05-15 | 北京理工大学 | Gel type ice and snow material with adjustable solidification temperature and transmittance and preparation method thereof |
| CN111253509A (en) * | 2020-03-06 | 2020-06-09 | 北京理工大学 | Molding and preparation method of personalized ice and snow product |
Also Published As
| Publication number | Publication date |
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| CN106751287B (en) | 2018-08-31 |
| TWI570229B (en) | 2017-02-11 |
| TW201720904A (en) | 2017-06-16 |
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