CN106751029A - A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue - Google Patents
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue Download PDFInfo
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- CN106751029A CN106751029A CN201611161027.4A CN201611161027A CN106751029A CN 106751029 A CN106751029 A CN 106751029A CN 201611161027 A CN201611161027 A CN 201611161027A CN 106751029 A CN106751029 A CN 106751029A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
- C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue, its raw material includes by weight:25 35 parts of ethylene propylene diene rubber,10 30 parts of chlorosulfonated polyethylene,10 20 parts of polypropylene,Modified 20 30 parts of sand yellow soil,40 50 parts of talcum powder,5 15 parts of sepiolite powder,10 20 parts of vermiculite power,5 15 parts of glass fibre,0.5 1.5 parts of silane coupler,14 parts of polypropylene grafted maleic anhydride,26 parts of glycerin residue,0.5 1.5 parts of epoxidized soybean oil,0.2 0.6 parts of dicyclohexyl phthalate,12 parts of poly- decanedioic acid propylene glycol ester,0.5 1 parts of stearic acid,2,5 dimethyl 2,Double (ethyl hexanoyl of peroxidating 2) 0.5 2.8 parts of the hexanes of 5-,0.1 0.6 parts of ammonium dichromate sodium,0.2 0.4 parts of captax,0.5 1.5 parts of Vulcanization accelerator TMTD,215 12 parts of antioxidant AT.
Description
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue.
Background technology
Glycerine is a kind of important industrial chemicals, widely used.The source of glycerine has naturally, chemical synthesis, fermentation method,
The also by-product glycerin of grease hydrolysis or alcoholysis.China's glycerol production 2010 up to 400,000 tons, grinds up to 200,000 tons within 2008
Study carefully and show 1 ton of 100% pure glycerin of every production, to produce 0.19 ton of bottoms.Glycerin residue is semi-solid pitch shape, its component
Complexity, removal of impurities, decolouring are extremely difficult, and the treatment to glycerin residue at present utilizes the simple and effective side for not yet finding at home
Method, substantial amounts of glycerin residue is piled up as glycerol production business problem urgently to be resolved hurrily, while also having aggravated environmental pressure.It is existing
Research still suffers from part residue after laying particular emphasis on the Hydrolysis kinetics glycerine from synthetic glycerine bottoms, but extraction polyglycerol,
Simply improve the part value of glycerin residue, it is impossible to thoroughly solve the accumulation problem of glycerin residue, and separation and Extraction work
Skill is complicated, and equipment investment is relatively costly.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of ethylene-propylene-diene monomer glue material containing glycerin residue
Material, water proofing property is fabulous, and shear strength, shock resistance are extremely excellent, and antibiotic property is good, and toughness reached with hardness it is balanced,
It is not easily broken, while glycerin residue complete resource is utilized, is produced without new accessory substance, meet environmental protection concept, improves sweet
The added value of oil production, alleviates fossil resources anxiety trend, and environmental protection is good in economic efficiency.
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
EP rubbers 25-35 parts, chlorosulfonated polyethylene 10-30 parts, polypropylene 10-20 parts, 20-30 parts of the sand yellow that is modified soil, talcum powder 40-
50 parts, sepiolite powder 5-15 parts, vermiculite power 10-20 parts, glass fibre 5-15 parts, silane coupler 0.5-1.5 parts, polypropylene connects
1-4 parts of maleic anhydride of branch, glycerin residue 2-6 parts, epoxidized soybean oil 0.5-1.5 parts, dicyclohexyl phthalate 0.2-0.6
Part, 1-2 parts of poly- decanedioic acid propylene glycol ester, stearic acid 0.5-1 parts, 2,5- dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls)
Hexane 0.5-2.8 parts, 0.1-0.6 parts of ammonium dichromate sodium, captax 0.2-0.4 parts, Vulcanization accelerator TMTD 0.5-1.5 parts, antioxygen
Agent AT-2151-2 parts.
Preferably, the sand yellow that is modified soil is prepared using following technique:Sodium-based montmorillonite, water are heated up and is stirred, add the tetradecane
Base tributyl ammonium chloride, dodecyl tributyl ammonium bromide, heated up stirring, and filtering, solids is washed with ethanol solution, adds carbon
Sour calcium mixing and stirring, adds sand yellow soil, phosphate aqueous solution stirring, heats up, and adds sodium tetraborate to continue to stir, and filtering is empty
Atmosphere dry, pulverize and obtain modified sand yellow soil.
Preferably, the sand yellow that is modified soil is prepared using following technique:By weight by 5-15 parts of sodium-based montmorillonite, 40-60 parts
Water is heated up and stirs, and adds 0.5-1.5 parts of myristyl tributyl ammonium chloride, 1-2 parts of dodecyl tributyl ammonium bromide, and intensification is stirred
Mix, filter, solids is washed with ethanol solution, 2-10 parts of calcium carbonate mixing and stirring of addition, 20-40 parts of sand yellow soil of addition,
80-120 parts of concentration is stirred for the phosphate aqueous solution of 5-10wt%, is heated up, and adds 2-8 parts of sodium tetraborate to continue to stir, and filtering is empty
Atmosphere dry, pulverize and obtain modified sand yellow soil.
Preferably, the sand yellow that is modified soil is prepared using following technique:By weight by 5-15 parts of sodium-based montmorillonite, 40-60 parts
Water is warming up to 50-60 DEG C of stirring 15-35min, adds 0.5-1.5 parts of myristyl tributyl ammonium chloride, 1-2 parts of dodecyl three
Butylammonium bromide, is warming up to 65-75 DEG C of stirring 1-2h, and filtering, solids is washed with ethanol solution, adds 2-10 parts of calcium carbonate to mix
Conjunction stirs, and it is the phosphate aqueous solution stirring 3-8h of 5-10wt%, stirring to add 20-40 parts of sand yellow soil, 80-120 parts of concentration
Speed is 400-800r/min, is warming up to 85-95 DEG C, adds 2-8 parts of sodium tetraborate to continue to stir 20-50min, filtering, 105-
115 DEG C of air atmospheres dry 10-20h, and crushing obtains modified sand yellow soil.
Preferably, be modified sand yellow soil, glycerin residue, epoxidized soybean oil, dicyclohexyl phthalate, poly- decanedioic acid the third two
The weight ratio of alcohol ester is 22-28:3-5:0.8-1.2:0.3-0.5:1.2-1.8.
Preferably, modified sand yellow soil, talcum powder, sepiolite powder, vermiculite power, glass fibre, silane coupler, polypropylene connect
The weight ratio of branch maleic anhydride is 22-28:43-47:8-12:14-18:8-12:0.8-1.2:2-3.
Preferably, ethylene propylene diene rubber, chlorosulfonated polyethylene, polypropylene, modified sand yellow soil, 2,5- dimethyl -2,5-
Double-(peroxidating -2- ethyl hexanoyls) hexane, ammonium dichromate sodium, captax, the weight ratio of Vulcanization accelerator TMTD are 28-32:15-
25:12-18:22-28:1-2:0.3-0.5:0.25-0.35:0.8-1.2.
The present invention is obtained using conventional fabrication process.
In modified sand yellow soil of the invention, myristyl tributyl ammonium chloride, dodecyl tributyl under certain condition
Ammonium bromide is acted on sodium-based montmorillonite, be can be inserted into sodium-based montmorillonite interlayer structure, and not only adsorption activity is high, and antibacterial, resistance
Combustion and heat-proof quality are extremely excellent, and the absorption affinity with calcium carbonate, sand yellow soil is strong;And low phosphorus aqueous acid is carried out to sand yellow soil
Acidification, the granular built on stilts micro-structural of destruction sand yellow soil, then combined with sodium tetraborate, match somebody with somebody by between rationally control each component
Than, making that modified sand yellow soil shear strength is high, excellent shock resistance, water permeability resistance is fabulous, also with outstanding antibacterial, resistance
Combustion, heat-proof quality;Modified sand yellow soil and glycerin residue, epoxidized soybean oil, dicyclohexyl phthalate, poly- decanedioic acid propane diols
Ester coordinates, and can effectively strengthen the pliability of modified sand yellow soil, and low-temperature pliability is fabulous, with chlorosulfonated polyethylene, ethylene-propylene-diene monomer
Glue, polyacrylic mixing good dispersion, then through 2,5- dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) hexane, dichromic acid
Ammonium sodium, captax, Vulcanization accelerator TMTD collaboration solidification, make the present invention not only be crosslinked closely knit, and crosslinking degree is high, and water proofing property
Fabulous, shear strength, shock resistance are extremely excellent, and antibiotic property is good;Modified sand yellow soil and talcum powder, sepiolite powder, vermiculite
Powder, glass fibre under silane coupler, the cooperation of polypropylene grafted maleic anhydride, with chlorosulfonated polyethylene, ethylene-propylene-diene monomer
Glue, polyacrylic compatibility are good, and the well mixed performance of storeroom is good, make very high density of the present invention, waterproof, shear strength, anti-
Impact property is further enhanced, and it is balanced that toughness can be promoted to be reached with hardness, is not easily broken.
The present invention can utilize glycerin residue complete resource, be produced without new accessory substance, meet environmental protection concept, and raw material is sweet
Oil residue belongs to discarded object, abundance and cheap, and easy to use, considerable cost, market capacity is very big, economic benefit compared with
It is good, while the nervous situation of petroleum chemicals shortage of resources can be alleviated.The invention is directly used by by glycerin residue, is solved
Glycerin residue piles up the problem of environmental pollution for causing, and also improves the added value of glycerol production, while it is nervous to alleviate fossil resources
Trend, environmental protection is good in economic efficiency.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
25 parts of EP rubbers, 30 parts of chlorosulfonated polyethylene, 10 parts of polypropylene, 30 parts of the sand yellow that is modified soil, 40 parts of talcum powder, sepiolite powder 15
Part, 10 parts of vermiculite power, 15 parts of glass fibre, 0.5 part of silane coupler, 4 parts of polypropylene grafted maleic anhydride, 2 parts of glycerin residue,
1.5 parts of epoxidized soybean oil, 0.2 part of dicyclohexyl phthalate, 2 parts of poly- decanedioic acid propylene glycol ester, 0.5 part of stearic acid, 2,5-
Dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) 2.8 parts of hexane, 0.1 part of ammonium dichromate sodium, 0.4 part of captax promotees
Enter 0.5 part of agent TMTD, 2 parts of antioxidant AT-215.
Embodiment 2
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
35 parts of EP rubbers, 10 parts of chlorosulfonated polyethylene, 20 parts of polypropylene, 20 parts of the sand yellow that is modified soil, 50 parts of talcum powder, sepiolite powder 5
Part, 20 parts of vermiculite power, 5 parts of glass fibre, 1.5 parts of silane coupler, 1 part of polypropylene grafted maleic anhydride, 6 parts of glycerin residue,
0.5 part of epoxidized soybean oil, 0.6 part of dicyclohexyl phthalate, 1 part of poly- decanedioic acid propylene glycol ester, 1 part of stearic acid, 2,5- bis-
Methyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) 0.5 part of hexane, 0.6 part of ammonium dichromate sodium, 0.2 part of captax promotes
1 part of 1.5 parts of agent TMTD, antioxidant AT-215.
Modified sand yellow soil is prepared using following technique:Sodium-based montmorillonite, water are heated up and is stirred, add myristyl tributyl
Ammonium chloride, dodecyl tributyl ammonium bromide, heated up stirring, and filtering, solids is washed with ethanol solution, adds calcium carbonate mixing
Stir, add sand yellow soil, phosphate aqueous solution stirring, heat up, add sodium tetraborate to continue to stir, filtering, air atmosphere is dried,
Crushing obtains modified sand yellow soil.
Embodiment 3
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
32 parts of EP rubbers, 15 parts of chlorosulfonated polyethylene, 18 parts of polypropylene, 22 parts of the sand yellow that is modified soil, 47 parts of talcum powder, sepiolite powder 8
Part, 18 parts of vermiculite power, 8 parts of glass fibre, 1.2 parts of silane coupler, 2 parts of polypropylene grafted maleic anhydride, 5 parts of glycerin residue,
0.8 part of epoxidized soybean oil, 0.5 part of dicyclohexyl phthalate, 1.2 parts of poly- decanedioic acid propylene glycol ester, 0.8 part of stearic acid, 2,
5- dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) 1 part of hexane, 0.5 part of ammonium dichromate sodium, 0.25 part of captax promotees
Enter 1.2 parts of agent TMTD, 1.2 parts of antioxidant AT-215.
Modified sand yellow soil is prepared using following technique:10 parts of sodium-based montmorillonites, 50 parts of water are heated up and stirred by weight, plus
Enter 1 part of myristyl tributyl ammonium chloride, 1.5 parts of dodecyl tributyl ammonium bromides, heat up stirring, filtering, solids second
Alcoholic solution is washed, and adds 6 parts of calcium carbonate mixing and stirrings, and it is the phosphoric acid water of 8wt% to add 30 parts of sand yellow soil, 100 parts of concentration
Solution is stirred, and is heated up, and adds 5 parts of sodium tetraborates to continue to stir, filtering, and air atmosphere dry, pulverize and obtain modified sand yellow soil.
Embodiment 4
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
28 parts of EP rubbers, 25 parts of chlorosulfonated polyethylene, 12 parts of polypropylene, 28 parts of the sand yellow that is modified soil, 43 parts of talcum powder, sepiolite powder 12
Part, 14 parts of vermiculite power, 12 parts of glass fibre, 0.8 part of silane coupler, 3 parts of polypropylene grafted maleic anhydride, 3 parts of glycerin residue,
1.2 parts of epoxidized soybean oil, 0.3 part of dicyclohexyl phthalate, 1.8 parts of poly- decanedioic acid propylene glycol ester, 0.6 part of stearic acid, 2,
5- dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) 2 parts of hexane, 0.3 part of ammonium dichromate sodium, 0.35 part of captax promotees
Enter 0.8 part of agent TMTD, 1.8 parts of antioxidant AT-215.
Modified sand yellow soil is prepared using following technique:5 parts of sodium-based montmorillonites, 60 parts of water are warming up to 50 DEG C and stirred by weight
35min is mixed, 0.5 part of myristyl tributyl ammonium chloride, 2 parts of dodecyl tributyl ammonium bromides are added, 65 DEG C of stirrings are warming up to
2h, filtering, solids wash with ethanol solution, adds 2 parts of calcium carbonate mixing and stirrings, 40 parts of sand yellow soil of addition, 80 parts it is dense
Spend for the phosphate aqueous solution of 10wt% stirs 3h, mixing speed is 800r/min, is warming up to 85 DEG C, add 8 parts of sodium tetraborates after
Continuous stirring 20min, filtering, 115 DEG C of air atmospheres dry 10h, and crushing obtains modified sand yellow soil.
Embodiment 5
A kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue proposed by the present invention, its raw material includes by weight:Ternary
30 parts of EP rubbers, 20 parts of chlorosulfonated polyethylene, 15 parts of polypropylene, 25 parts of the sand yellow that is modified soil, 45 parts of talcum powder, sepiolite powder 10
Part, 16 parts of vermiculite power, 10 parts of glass fibre, 1 part of silane coupler, 2.5 parts of polypropylene grafted maleic anhydride, 4 parts of glycerin residue,
1 part of epoxidized soybean oil, 0.4 part of dicyclohexyl phthalate, 1.5 parts of poly- decanedioic acid propylene glycol ester, 0.7 part of stearic acid, 2,5-
Dimethyl -2,5- pairs-(peroxidating -2- ethyl hexanoyls) 1.5 parts of hexane, 0.4 part of ammonium dichromate sodium, 0.3 part of captax promotees
Enter 1 part of agent TMTD, 1.5 parts of antioxidant AT-215.
Modified sand yellow soil is prepared using following technique:15 parts of sodium-based montmorillonites, 40 parts of water are warming up to 60 DEG C by weight
Stirring 15min, adds 1.5 parts of myristyl tributyl ammonium chlorides, 1 part of dodecyl tributyl ammonium bromide, is warming up to 75 DEG C and stirs
1h is mixed, is filtered, solids is washed with ethanol solution, add 10 parts of calcium carbonate mixing and stirrings, add 20 parts of sand yellow soil, 120
Part concentration is the phosphate aqueous solution stirring 8h of 5wt%, and mixing speed is 400r/min, is warming up to 95 DEG C, adds 2 parts of sodium tetraborates
Continue to stir 50min, filtering, 105 DEG C of air atmospheres dry 20h, and crushing obtains modified sand yellow soil.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of ethylene propylene diene monomer (EPDM) material containing glycerin residue, it is characterised in that its raw material includes by weight:EPDM
Rubber 25-35 parts, chlorosulfonated polyethylene 10-30 parts, polypropylene 10-20 parts, 20-30 parts of the sand yellow that is modified soil, talcum powder 40-50
Part, it is sepiolite powder 5-15 parts, vermiculite power 10-20 parts, glass fibre 5-15 parts, silane coupler 0.5-1.5 parts, polypropylene grafted
Maleic anhydride 1-4 parts, glycerin residue 2-6 parts, epoxidized soybean oil 0.5-1.5 parts, dicyclohexyl phthalate 0.2-0.6 parts,
1-2 parts of poly- decanedioic acid propylene glycol ester, stearic acid 0.5-1 parts, 2,5- dimethyl -2,5- is double-(peroxidating -2- ethyl hexanoyls)
Alkane 0.5-2.8 parts, 0.1-0.6 parts of ammonium dichromate sodium, captax 0.2-0.4 parts, Vulcanization accelerator TMTD 0.5-1.5 parts, antioxidant
AT-215 1-2 parts.
2. the ethylene propylene diene monomer (EPDM) material of glycerin residue is contained according to claim 1, it is characterised in that modified sand yellow soil is used
It is prepared by following technique:Sodium-based montmorillonite, water are heated up and is stirred, add myristyl tributyl ammonium chloride, dodecyl tributyl
Ammonium bromide, heated up stirring, and filtering, solids is washed with ethanol solution, addition calcium carbonate mixing and stirring, addition sand yellow soil,
Phosphate aqueous solution is stirred, and is heated up, and adds sodium tetraborate to continue to stir, filtering, and air atmosphere dry, pulverize and obtain modified sand yellow soil.
3. the ethylene propylene diene monomer (EPDM) material containing glycerin residue according to claim 1 or claim 2, it is characterised in that modified sand yellow soil
Prepared using following technique:5-15 parts of sodium-based montmorillonite, 40-60 parts of water are heated up and stirred by weight, 0.5-1.5 parts ten is added
Tetraalkyl tributyl ammonium chloride, 1-2 parts of dodecyl tributyl ammonium bromide, heated up stirring, and filtering, solids is washed with ethanol solution
Wash, add 2-10 parts of calcium carbonate mixing and stirring, it is the phosphorus of 5-10wt% to add 20-40 parts of sand yellow soil, 80-120 parts of concentration
Aqueous acid is stirred, and is heated up, and adds 2-8 parts of sodium tetraborate to continue to stir, and filtering, air atmosphere dry, pulverize and obtain modified sand yellow
Soil.
4. the ethylene propylene diene monomer (EPDM) material of glycerin residue is contained according to claim any one of 1-3, it is characterised in that modified sand
Loess is prepared using following technique:5-15 parts of sodium-based montmorillonite, 40-60 parts of water are warming up to 50-60 DEG C of stirring 15- by weight
35min, adds 0.5-1.5 parts of myristyl tributyl ammonium chloride, 1-2 parts of dodecyl tributyl ammonium bromide, is warming up to 65-75
DEG C stirring 1-2h, filtering, solids wash with ethanol solution, adds 2-10 parts of calcium carbonate mixing and stirring, 20-40 parts of addition
Sand yellow soil, 80-120 parts of concentration are the phosphate aqueous solution stirring 3-8h of 5-10wt%, and mixing speed is 400-800r/min, is heated up
To 85-95 DEG C, 2-8 parts of sodium tetraborate is added to continue to stir 20-50min, filtering, 105-115 DEG C of air atmosphere dries 10-20h, powder
It is broken to obtain modified sand yellow soil.
5. the ethylene propylene diene monomer (EPDM) material of glycerin residue is contained according to claim any one of 1-4, it is characterised in that modified sand
Loess, glycerin residue, epoxidized soybean oil, dicyclohexyl phthalate, the weight ratio of poly- decanedioic acid propylene glycol ester are 22-28:
3-5:0.8-1.2:0.3-0.5:1.2-1.8.
6. the ethylene propylene diene monomer (EPDM) material of glycerin residue is contained according to claim any one of 1-5, it is characterised in that modified sand
Loess, talcum powder, sepiolite powder, vermiculite power, glass fibre, silane coupler, the weight ratio of polypropylene grafted maleic anhydride are
22-28:43-47:8-12:14-18:8-12:0.8-1.2:2-3.
7. the ethylene propylene diene monomer (EPDM) material of glycerin residue is contained according to claim any one of 1-6, it is characterised in that ternary second
Third rubber, chlorosulfonated polyethylene, polypropylene, modified sand yellow soil, 2,5- dimethyl -2,5- be double-and (peroxidating -2- ethyl hexanoyls)
Hexane, ammonium dichromate sodium, captax, the weight ratio of Vulcanization accelerator TMTD are 28-32:15-25:12-18:22-28:1-2:0.3-
0.5:0.25-0.35:0.8-1.2.
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CN105153600A (en) * | 2015-07-16 | 2015-12-16 | 安徽华宇电缆集团有限公司 | Low-temperature resistant and aging-resistant cable for vessels |
CN105440424A (en) * | 2015-12-14 | 2016-03-30 | 安徽宁国市高新管业有限公司 | High-strength tear-resistant material for combustion gas pipe |
CN105585781A (en) * | 2016-02-18 | 2016-05-18 | 繁昌县菲德通讯材料设计有限公司 | Impact-resistant heat-insulating rubber cable material |
CN105713294A (en) * | 2016-03-25 | 2016-06-29 | 安徽特种电缆集团有限公司 | Waterproof cable material with excellent mechanical properties |
-
2016
- 2016-12-15 CN CN201611161027.4A patent/CN106751029A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105153600A (en) * | 2015-07-16 | 2015-12-16 | 安徽华宇电缆集团有限公司 | Low-temperature resistant and aging-resistant cable for vessels |
CN105440424A (en) * | 2015-12-14 | 2016-03-30 | 安徽宁国市高新管业有限公司 | High-strength tear-resistant material for combustion gas pipe |
CN105585781A (en) * | 2016-02-18 | 2016-05-18 | 繁昌县菲德通讯材料设计有限公司 | Impact-resistant heat-insulating rubber cable material |
CN105713294A (en) * | 2016-03-25 | 2016-06-29 | 安徽特种电缆集团有限公司 | Waterproof cable material with excellent mechanical properties |
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Application publication date: 20170531 |