CN106750920A - A kind of new material of low smoke, halogen free, burn-resisting - Google Patents

A kind of new material of low smoke, halogen free, burn-resisting Download PDF

Info

Publication number
CN106750920A
CN106750920A CN201611136850.XA CN201611136850A CN106750920A CN 106750920 A CN106750920 A CN 106750920A CN 201611136850 A CN201611136850 A CN 201611136850A CN 106750920 A CN106750920 A CN 106750920A
Authority
CN
China
Prior art keywords
low smoke
agent
burn
auxiliary agent
new material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611136850.XA
Other languages
Chinese (zh)
Inventor
彭静敏
萧正中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Ding Xin New Mstar Technology Ltd
Original Assignee
Shanghai Ding Xin New Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Ding Xin New Mstar Technology Ltd filed Critical Shanghai Ding Xin New Mstar Technology Ltd
Priority to CN201611136850.XA priority Critical patent/CN106750920A/en
Publication of CN106750920A publication Critical patent/CN106750920A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of new material of low smoke, halogen free, burn-resisting, it is characterised in that：Including following components：30 60% polymer, 10 20% resinous polymers, 5 15% compatilizers, 30 50% flame retardants, 5 10% resistance to combustion auxiliary agent groups and 5 10% auxiliary agent races；The polymer is hydrogenated styrene or conjugated diene copolymer；The resinous polymer is vistanex；The auxiliary agent race includes antioxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, laser carving agent；The present invention reaches the resistance to fuel efficiency of high intensity really using flame retardant and using the lighter flame retardant compounding aid mixture of component；The requirement of low smoke and zero halogen is realized using hydrogenated styrene or conjugated diene copolymer, vistanex etc. simultaneously, the requirement of environmental protection is met.

Description

A kind of new material of low smoke, halogen free, burn-resisting
Technical field
The present invention relates to a kind of flame resistant material, more particularly to a kind of low smoke, halogen free, burn-resisting material, belong to electronic product packaging Applied technical field.
Background technology
At present, SBS or SIS materials flame resistance is poor on the market, particularly exists in SBS or SIS copolymers substantial amounts of The performance such as unsaturated linkage and its weatherability, heat resistance, oxygen resistence is all poor, in order to improve the flame resistance of material, majority production The inorganic metal auxiliary agent such as magnesium hydroxide that producer often accelerates very big in the material and aluminium hydroxide, while needing to coordinate Substantial amounts of flame retardant, can be only achieved the effect of resistance to combustion,
Although above-mentioned material can reach the effect of resistance to combustion, such that the mechanical property of the material declines, proportion increases, with other Polymer compatibility is poor, and finished material surface scratch resistance is poor, and adverse consequences is caused to materials'use；In addition, largely adding inorganic Auxiliary agent cannot also meet the requirement of environmental protection.
The content of the invention
The present invention is in order to make up the deficiencies in the prior art, there is provided a kind of low smoke, halogen free, burn-resisting material, and the material has very strong Flame resistance；
To achieve the above object, the present invention is adopted the technical scheme that：
A kind of new material of low smoke, halogen free, burn-resisting, it is characterised in that：Including following components：30-60% polymer, 10-20% resins The resistance to combustion auxiliary agent group of polymer, 5-15% compatilizers, 30-50% flame retardants, 5-10% and 5-10% auxiliary agents race；
Further improve, the polymer is hydrogenated styrene or conjugated diene copolymer；
Further improve, the resinous polymer is vistanex；
Further improve, the auxiliary agent race includes antioxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, radium Carving agent；
Further improve, above-mentioned new material is specifically made up of the raw material of following weight portion：The SEBS or SEEPS or SEPS of 30-60% Or any two or various mixtures in the middle of SEBS, SEEPS, SEPS；The PP or POE or LLDPE or ADPE or EVA of 10-20% Or EEA or EBA or LDPE or EMA or EPR or POP or PP, POE, LLDPE, ADPE, EVA, EEA, EBA, LDPE, EMA, EPR, Any two or various mixtures in the middle of POP；The MAH-G-SEBA or NH2-G-SEES or MAH-G-POE or MAH- of 5-15% Any two or various mixtures in the middle of G-SEBA, NH2-G-SEES, MAH-G-POE；The flame retardant of 30-50%；5-10%'s Resistance to combustion auxiliary agent group；3-10% is by helping that antioxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, laser carving agent are constituted Agent race；
Compared with prior art, using such scheme, the beneficial effects of the invention are as follows：The present invention is using flame retardant and uses component Compare light flame retardant compounding aid mixture, reach the resistance to fuel efficiency of high intensity really；Simultaneously using hydrogenated styrene or conjugation two Alkene copolymer, vistanex etc. realize the requirement of low smoke and zero halogen, meet the requirement of environmental protection.
Specific embodiment
With reference to specific embodiment, the present invention is further described.
A kind of new material of low smoke, halogen free, burn-resisting, it is characterised in that：Including following components：30-60% polymer, 10-20% The resistance to combustion auxiliary agent group of resinous polymer, 5-15% compatilizers, 30-50% flame retardants, 5-10% and 5-10% auxiliary agents race；
Further, the polymer is hydrogenated styrene or conjugated diene copolymer；
Further, the resinous polymer is vistanex；
Further, the auxiliary agent race includes antioxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, laser carving Agent；
Further, above-mentioned new material is specifically made up of the raw material of following weight portion：The SEBS or SEEPS or SEPS of 30-60% or Any two or various mixtures in the middle of SEBS, SEEPS, SEPS；The PP or POE or LLDPE or ADPE or EVA of 10-20% or EEA or EBA or LDPE or EMA or EPR or POP or PP, POE, LLDPE, ADPE, EVA, EEA, EBA, LDPE, EMA, EPR, POP Central any two or various mixtures；The MAH-G-SEBA or NH2-G-SEES or MAH-G-POE or MAH-G- of 5-15% Any two or various mixtures in the middle of SEBA, NH2-G-SEES, MAH-G-POE；The flame retardant of 30-50%；5-10%'s is resistance to Combustion auxiliary agent group；The auxiliary agent that 3-10% is made up of antioxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, laser carving agent Race；
Specific implementation example one:
Choose SEBS 30%, PP 50%, flame retardant 30%, MAH-G-SEBA 5%, resistance to combustion auxiliary agent group 5%, auxiliary agent race 3%；By this After a little material mixing, extruded by extruder melt blending, dried after cooling and dicing, obtain final product the new of required low smoke, halogen free, burn-resisting Material；
Specific implementation example two:
Choose SEBS 60%, PP 20%, flame retardant 30%, MAH-G-SEBA 15%, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%； After these materials are mixed, extruded by extruder melt blending, dried after cooling and dicing, obtain final product required low smoke, halogen free, burn-resisting New material；
Specific implementation example three:
Choose SEEPS 60%, ADPE 20%, flame retardant 30%, NH2-G-SEES 15%, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%；After these materials are mixed, extruded by extruder melt blending, dried after cooling and dicing, obtain final product required low smoke and zero halogen The new material of resistance to combustion；
Specific implementation example four:
Choose SEEPS 60%, ADPE 20%, flame retardant 30%, NH2-G-SEES 15%, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%；After these materials are mixed, extruded by extruder melt blending, dried after cooling and dicing, obtain final product required low smoke and zero halogen The new material of resistance to combustion；
Specific implementation example five:
Choose SEPS 40%, EVA 20%, flame retardant 30%, MAH-G-POE 15%, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%； After these materials are mixed, extruded by extruder melt blending, dried after cooling and dicing, obtain final product required low smoke, halogen free, burn-resisting New material；
Specific implementation example six:
Choose the mixture 40%, EVA and mixture 15%, the flame retardant 30%, MAH-G-POE of POP of SEPS and SEEPS 15%th, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%；After these materials are mixed, extruded by extruder melt blending, cooling is cut Dried after grain, the new material of the low smoke, halogen free, burn-resisting needed for obtaining final product；
Specific implementation example seven:
Choose the mixture 50% of SEPS and SEEPS；The mixture 20% of PP, POE, LLDPE, ADPE and EVA；Flame retardant 30%th, MAH-G-POE 15%, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%；After these materials are mixed, melted altogether by extruder Mixed extrusion, dries after cooling and dicing, the new material of the low smoke, halogen free, burn-resisting needed for obtaining final product；
Specific implementation example eight:
Choose mixture 10%, the flame retardant 30%, MAH-G-POE of the mixture 30%, EPR, POP and EMA of SEPS and SEBS 15%th, resistance to combustion auxiliary agent group 10%, auxiliary agent race 10%；After these materials are mixed, extruded by extruder melt blending, cooling is cut Dried after grain, the new material of the low smoke, halogen free, burn-resisting needed for obtaining final product；
The various materials of the present invention can as needed be carried out flexibly choosing and matched, and collocation mode is more flexible, meets different rings The materials demand of border combustion intensity resistance to difference；Under the situation for reaching resistance to combustion, the mechanical property of material is kept, and material will not be increased The proportion of material, while the material increases compatilizer so that new material of the invention is more preferable with the compatibility of other polymers, also increases The strong scratch resistance on finished material surface, improves the using effect of material；
The present invention reaches the resistance to fuel efficiency of high intensity using flame retardant and using the lighter flame retardant compounding aid mixture of component Really；The requirement of low smoke and zero halogen is realized using hydrogenated styrene or conjugated diene copolymer, vistanex etc. simultaneously, ring is met The requirement of guarantor；
The present invention is not limited to above-mentioned specific embodiment, one of ordinary skill in the art from above-mentioned design, without Performing creative labour is crossed, done a variety of conversion are within the scope of the present invention.

Claims (5)

1. a kind of new material of low smoke, halogen free, burn-resisting, it is characterised in that：Including following components：30-60% polymer, 10-20% trees The resistance to combustion auxiliary agent group of lipopolymer, 5-15% compatilizers, 30-50% flame retardants, 5-10% and 5-10% auxiliary agents race.
2. the new material of a kind of low smoke, halogen free, burn-resisting according to claim 1, it is characterised in that：The polymer is hydrogenation Styrene or conjugated diene copolymer.
3. the new material of a kind of low smoke, halogen free, burn-resisting according to claim 1, it is characterised in that：The resinous polymer is Vistanex.
4. the new material of a kind of low smoke, halogen free, burn-resisting according to claim 1, it is characterised in that：The auxiliary agent race includes anti- Oxidant, heat-resistant aging agent, anti-copper oxidant, antiseptic, coupling agent, laser carving agent.
5. the new material of a kind of low smoke, halogen free, burn-resisting according to claim 1, it is characterised in that：Specifically by following weight portion Raw material be made：Any two or various mixing in the middle of the SEBS or SEEPS or SEPS or SEBS, SEEPS, SEPS of 30-60% Thing；The PP or POE or LLDPE or ADPE or EVA or EEA or EBA or LDPE or EMA or EPR or POP or PP of 10-20%, POE, Any two or various mixtures in the middle of LLDPE, ADPE, EVA, EEA, EBA, LDPE, EMA, EPR, POP；The MAH- of 5-15% Any two in the middle of G-SEBA or NH2-G-SEES or MAH-G-POE or MAH-G-SEBA, NH2-G-SEES, MAH-G-POE Or various mixtures；The flame retardant of 30-50%；The auxiliary agent of the resistance to combustion group of 5-10%；3-10% is by antioxidant, heat-resistant aging agent, anti-copper Oxidant, antiseptic, coupling agent, the auxiliary agent race of laser carving agent composition.
CN201611136850.XA 2016-12-12 2016-12-12 A kind of new material of low smoke, halogen free, burn-resisting Pending CN106750920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611136850.XA CN106750920A (en) 2016-12-12 2016-12-12 A kind of new material of low smoke, halogen free, burn-resisting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611136850.XA CN106750920A (en) 2016-12-12 2016-12-12 A kind of new material of low smoke, halogen free, burn-resisting

Publications (1)

Publication Number Publication Date
CN106750920A true CN106750920A (en) 2017-05-31

Family

ID=58875320

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611136850.XA Pending CN106750920A (en) 2016-12-12 2016-12-12 A kind of new material of low smoke, halogen free, burn-resisting

Country Status (1)

Country Link
CN (1) CN106750920A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108250555A (en) * 2017-12-20 2018-07-06 苏州希普拉斯新材料有限公司 Flame resistance irradiation is crosslinked the preparation process of low-smoke low-halogen polyolefine material
CN111621081A (en) * 2020-04-21 2020-09-04 广东聚石化学股份有限公司 Antibacterial environment-friendly flame-retardant elastomer material and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786067A (en) * 2005-11-22 2006-06-14 台橡股份有限公司 Thermoplastic elastomer and its manufacturing method
CN101230170A (en) * 2008-01-04 2008-07-30 台橡股份有限公司 Thermoplastic elastomer
CN101328294A (en) * 2008-07-31 2008-12-24 苏州德尔泰高聚物有限公司 Plastic for low-smoke halogen-free high flame-retardant electric wire and cable
CN102295818A (en) * 2010-06-24 2011-12-28 上海凯波特种电缆料厂有限公司 Zero-halogen, low-smoke and flame-retardant TPE (Thermoplastic Elastomer) cable material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786067A (en) * 2005-11-22 2006-06-14 台橡股份有限公司 Thermoplastic elastomer and its manufacturing method
CN101230170A (en) * 2008-01-04 2008-07-30 台橡股份有限公司 Thermoplastic elastomer
CN101328294A (en) * 2008-07-31 2008-12-24 苏州德尔泰高聚物有限公司 Plastic for low-smoke halogen-free high flame-retardant electric wire and cable
CN102295818A (en) * 2010-06-24 2011-12-28 上海凯波特种电缆料厂有限公司 Zero-halogen, low-smoke and flame-retardant TPE (Thermoplastic Elastomer) cable material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108250555A (en) * 2017-12-20 2018-07-06 苏州希普拉斯新材料有限公司 Flame resistance irradiation is crosslinked the preparation process of low-smoke low-halogen polyolefine material
CN111621081A (en) * 2020-04-21 2020-09-04 广东聚石化学股份有限公司 Antibacterial environment-friendly flame-retardant elastomer material and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN104151735B (en) A kind of high-strength anti-flaming cable and application thereof
CN109627567A (en) A kind of B1 grades of fire-retardant irradiated crosslinking low-smoke and halogen-free insulated cable material and preparation method thereof
CN102146193B (en) Non-halogen flame-retardant thermoplastic elastomer composite with SEBS (Styrene-Ethylene/Butylene-Styrene) as base material and preparation method thereof
CN109837040B (en) Adhesive, preparation method and application thereof, and plywood
WO2021129217A1 (en) Low-smoke and halogen-free building wire and cable material, and preparation method therefor
CN103965541A (en) 105 DEG C thermoplastic, halogen-free, low-smoke, fire-retardant and ultraviolet-resistant covering material capable of preventing mice and ants and resisting cracking and preparation method thereof
CN105504480A (en) Oil-resistant irradiation-crosslinking low-smoke halogen-free flame-retardant polyolefin material for locomotive wires and cables
CN107586411A (en) A kind of highly polar fire-resistant waterproof sheet material of high puncturing resistance intensity and preparation method thereof
CN111154427B (en) Aluminum ceiling glue film structure and aluminum ceiling structure thereof
CN102731888A (en) Multilayer coated red phosphorus low-smoke halogen-free flame-retardant polyolefin cable sheath material and preparation method thereof
CN106432886A (en) Environment-friendly anti-adhesion polyolefin cable material
CN111117524B (en) Adhesive resin for aluminum ceiling
CN106750920A (en) A kind of new material of low smoke, halogen free, burn-resisting
CN104004263B (en) Flame-proof polyolefine cable material, its preparation method and purposes
CN106147190A (en) PC/ASA intermingling material that a kind of low gloss high-strength halogen-free is fire-retardant and preparation method thereof
CN103724792A (en) Low-smoke zero-halogen environment-friendly EVA/LLDPE flame resistant composite material
CN113214561A (en) Low-smoke halogen-free intumescent flame-retardant optical cable sheath material and preparation method thereof
CN112226049A (en) Flame-retardant oil-resistant mildew-proof elastomer heat-shrinkable tube material and preparation method of master batch thereof
CN107082971A (en) A kind of flame retardant type PVC waterproof rolls
CN104231396A (en) Halogen-free flame-retardant wire
CN106905603A (en) A kind of flame-retardant modified plastics
CN106543546A (en) A kind of soft type oil resistant low temperature resistant non-halogen flame-retardant cable used for rolling stock and preparation method thereof
CN106977813A (en) A kind of dynamic vulcanization has fire-retardant TPV composites of halogen and preparation method thereof
CN109280263A (en) A kind of new material of low smoke, halogen free, burn-resisting
CN105348633B (en) A kind of low-smoke halogen-free polyolefin cable material and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170531