CN106750496A - The sheet material and its preparation technology of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber - Google Patents

The sheet material and its preparation technology of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber Download PDF

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Publication number
CN106750496A
CN106750496A CN201611197160.5A CN201611197160A CN106750496A CN 106750496 A CN106750496 A CN 106750496A CN 201611197160 A CN201611197160 A CN 201611197160A CN 106750496 A CN106750496 A CN 106750496A
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CN
China
Prior art keywords
epdm rubber
expanded perlite
high temperature
micro mist
cell foam
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Pending
Application number
CN201611197160.5A
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Chinese (zh)
Inventor
张云
丁荣华
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Panasian Microvent Tech Jiangsu Corp
Original Assignee
PAN-ASIAN AUTOMOTIVE GARNISHRY (CHANGZHOU) Co Ltd
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Priority to CN201611197160.5A priority Critical patent/CN106750496A/en
Publication of CN106750496A publication Critical patent/CN106750496A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/365Coating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16Ethene-propene or ethene-propene-diene copolymers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses the sheet material and its preparation technology of a kind of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber, sheet material includes:EPDM EPDM rubber sheet layer, EPDM rubber sheet layer surface recombination has the heat-insulated film layer that expanded perlite micro mist high temperature resistant heat insulation paint is formed after solidifying;Preparation technology:1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and dry;By EPDM rubber closed-cell foam sheet surface corona polarizing;In expanded perlite micro mist high temperature resistant heat insulation paint of the EPDM rubber closed-cell foam sheet surface airless spraying thickness less than 0.5mm, and thermal insulating coating is dried;If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.Through the above way, the present invention has the performances such as more excellent insulation, sealing, heat-insulated ageing-resistant, vibration damping;To weaken adverse effect of the temperature to EPDM rubber closed-cell foam sheet material so that the consistency of performance of EPDM rubber closed-cell foam sheet material effectively keeps.

Description

The sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber and its preparation Technique
Technical field
The present invention relates to the sheet material and its preparation work of a kind of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber Skill.
Background technology
EPDM rubber be ethylene propylene diene rubber closed-cell foam sheet material make parts can be widely applied to automobile, air-conditioning, The small space component of thermal cell, electronic device, high temperature, small sized pipeline, microelectronic component etc. insulation, sealing, it is heat-insulated it is ageing-resistant, subtract Shake, in the engineering such as the cold and hot pipeline in space docking.
But existing EPDM rubber, at the initial stage for using, the effect of its sealing can meet requirement;Through after a while Under the service load temperature action of alternating hot and cold, there is the phenomenon for having leaked poorly sealed infiltration gas, reason is closed-cell foam sheet material Composition closed pore membranous wall molecule segment stress relaxation so that microgap occurs in hole wall to be caused gas diffusion and causes gas pressure Decline or hole wall elongation so that the decrement failure that original engineer applied needs, elasticity is not enough;EPDM rubber closed cell foamed material Stress relaxation of the stress relaxation process comprising molecule segment and cause gas pressure to decline caused pine because of gas diffusion Two aspects of relaxation.Cause the infiltration of EPDM rubber closed cell foamed material seal rainy day or gas leakage, buffer shock-absorbing reduced capability;Temperature The change of degree is the main cause for causing the closed pore of EPDM rubber closed cell foamed material lax.
The content of the invention
The present invention solves the technical problem of provide it is a kind of with more excellent insulation, sealing, it is heat-insulated it is ageing-resistant, subtract The sheet material and its preparation technology of the expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber of the performance such as shake.
In order to solve the above technical problems, one aspect of the present invention is:A kind of expanded perlite micro mist is provided High temperature resistant heat insulation paint coats the sheet material of EPDM rubber, including:EPDM EPDM rubber closed-cell foam sheet layer, EPDM rubber is closed Hole foam sheet layer surface is compounded with the heat-insulated film layer formed after the solidification of expanded perlite micro mist high temperature resistant heat insulation paint, described heat-insulated Film layer is the three-dimensional hollow structural system of the closing being joined together to form by multiple heat-insulated microballons of nanoscale expanded perlite.
In a preferred embodiment of the present invention, the single side surface of EPDM rubber closed-cell foam sheet layer is compounded with thermal isolation film Layer.
In a preferred embodiment of the present invention, the double-sided surface of EPDM rubber closed-cell foam sheet layer is compounded with heat-insulated Film layer
In a preferred embodiment of the present invention, the outer surface of EPDM rubber closed-cell foam sheet layer is coated with heat-insulated film layer.
The invention further relates to a kind of preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber, Comprise the following steps:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and dry;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)EPDM rubber closed-cell foam sheet surface airless spraying thickness less than 0.5mm expanded perlite micro mist high temperature resistant every Heat paint, and thermal insulating coating is dried;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
In a preferred embodiment of the present invention, step 1)In, drying uses low temperature drying, temperature 70 DEG C -83 DEG C it Between.
In a preferred embodiment of the present invention, step 3)In drying using 75 DEG C -85 DEG C temperature drying 30- 40min。
The beneficial effects of the invention are as follows:The present invention EPDM rubber be ethylene propylene diene rubber closed-cell foam sheet material surface without Gas blowout applies expanded perlite micro mist high temperature resistant heat insulation paint, treats that its expanded perlite micro mist high temperature resistant heat insulation paint solidifies in sheet surface The heat-insulated film layer of layer of surface is formed afterwards, and this sheet material has the performances such as more excellent insulation, sealing, heat-insulated ageing-resistant, vibration damping.This hair Bright is to weaken temperature to the adverse effect of EPDM rubber closed-cell foam sheet material so that the performance of EPDM rubber closed-cell foam sheet material is held It is effective long to keep.
Brief description of the drawings
Technical scheme in order to illustrate more clearly the embodiments of the present invention, below will be to that will make needed for embodiment description Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for For those of ordinary skill in the art, on the premise of not paying creative work, other can also be obtained according to these accompanying drawings Accompanying drawing, wherein:
Fig. 1 is the structure of the preferred embodiment of sheet material one of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber of the present invention Schematic diagram;
Fig. 2 is another preferred embodiment of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber of the present invention Structural representation.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
Fig. 1 and Fig. 2 is referred to, the embodiment of the present invention includes:
A kind of expanded perlite micro mist high temperature resistant heat insulation paint coats the sheet material of EPDM rubber, including:EPDM EPDM rubber is closed Hole foam sheet layer 2, the surface recombination of EPDM rubber closed-cell foam sheet layer 2 has expanded perlite micro mist high temperature resistant heat insulation paint to solidify The heat-insulated film layer 1 for being formed afterwards, the heat-insulated film layer 1 is joined together to form by multiple heat-insulated microballons of nanoscale expanded perlite Closing three-dimensional hollow structural system.
EPDM rubber is ethylene propylene diene rubber closed-cell foam sheet material, with its characteristic of completely separated individual blisters, due to Large quantity of air or other gases are contained in expanded material closed pore inside, and should not circulate, and material can substantially slow down the conduction to heat, tool There are the thermal conductivity factor of pole root, more bond material flexibility in itself, and good resilience.Be it is a kind of have insulation, sealing, every The material of hot property.
Expanded perlite micro mist high temperature resistant heat insulation paint is mainly made up of nanoscale expanded perlite filler and specialist additive. Film forms a closing three-dimensional hollow structure linked together by the heat-insulated microballon of nanoscale expanded perlite in body surface System, the thermal conductivity factor of coating can reach 0.03 ~ 0.06W/ (mK) watts/ meter Du, can effectively prevent heat from conducting, and reach The purpose of insulation.After coating drying and forming-film, can waterproof, round-the-clock can be used in outdoor.
Expanded perlite is preheated perlite ore, and it is cellular that the one kind being made after TRANSIENT HIGH TEMPERATURE calcining expansion is internal The material of the white granular of structure.Its principle is:Perlite ore is through the broken ore in sand form for forming certain particle size, preheated roasting Burn, instant heating (more than 1000 DEG C), moisture vaporization in ore in sand form, softening containing vitreous ore in sand form internal expansion, formed Loose structure, the nonmetal mineral product perlites of 10-30 times of volumetric expansion are divided into according to its expansion process technology and purposes difference Three kinds of forms:Open bore (open cell), closed pore (closed cell), hollow hole (balloon).
Nanoscale expanded perlite microballon is formed through ultra-fine grinding, is a kind of lightweight, multifunctional novel shaped material.With apparent Density is light, thermal conductivity factor is low, chemical stability is good, temperature in use scope is wide, wettability power is small and nontoxic, tasteless, fire prevention, inhale The features such as sound, can be used for product of rubber and plastic, pigment, paint, ink, synthetic glass, insulating moulding coating and various deep coolings, freezer engineering Make inserts in the heat-insulated heat insulation layers such as the inwall of inwall, low-boiling point liquid, the storage inwall of gas and means of transport.
As shown in figure 1, the single side surface of EPDM rubber closed-cell foam sheet layer 2 is compounded with heat-insulated film layer 1.Or such as Fig. 2 institutes Show, the double-sided surface of EPDM rubber closed-cell foam sheet layer 2 is compounded with heat-insulated film layer 1.Or in EPDM rubber closed-cell foam piece The outer surface of material layer 2 is coated with heat-insulated film layer 1, not shown.
The sheet material is the surface airless spraying expanded perlite in the i.e. ethylene propylene diene rubber closed-cell foam sheet material of EPDM rubber Micro mist high temperature resistant heat insulation paint, after its expanded perlite micro mist high temperature resistant heat insulation paint sheet surface solidification after formed layer of surface every Hotting mask layer, this sheet material has the performances such as more excellent insulation, sealing, heat-insulated ageing-resistant, vibration damping.
The sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber can be widely applied to automobile, air-conditioning, heat The insulation such as the small space component of battery, electronic device, high temperature, small sized pipeline, microelectronic component, sealing, heat-insulated ageing-resistant, vibration damping In engineering.
Embodiment 1:The preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber, including following step Suddenly:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and with 72 DEG C of low temperature dryings;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)It is the resistance to height of expanded perlite micro mist of 0.33mm in EPDM rubber closed-cell foam sheet surface airless spraying a layer thickness Warm thermal insulating coating, and with 75 DEG C of low temperature drying 30min;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
Embodiment 2:The preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber, including following step Suddenly:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and with 78 DEG C of low temperature dryings;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)It is the expanded perlite micro mist high temperature resistant of 0.4mm in EPDM rubber closed-cell foam sheet surface airless spraying a layer thickness Thermal insulating coating, and with 78 DEG C of low temperature drying 35min;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
Embodiment 3:The preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber, including following step Suddenly:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and with 80 DEG C of low temperature dryings;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)It is the resistance to height of expanded perlite micro mist of 0.45mm in EPDM rubber closed-cell foam sheet surface airless spraying a layer thickness Warm thermal insulating coating, and with 80 DEG C of low temperature drying 30min;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
Embodiment 4:The preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber, including following step Suddenly:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and with 83 DEG C of low temperature dryings;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)It is the expanded perlite micro mist high temperature resistant of 0.5mm in EPDM rubber closed-cell foam sheet surface airless spraying a layer thickness Thermal insulating coating, and with 85 DEG C of low temperature drying 40min;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
The present invention weakens the adverse effect that temperature is ethylene propylene diene rubber closed-cell foam sheet material to EPDM rubber significantly so that EPDM rubber is that the consistency of performance of ethylene propylene diene rubber closed-cell foam sheet material effectively keeps.So that this sheet material is with more excellent The performances such as insulation, sealing, heat-insulated ageing-resistant, vibration damping.
The sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber has the property of the more longlasting low water suction of sealing Can, expanded closed-cell spaced apart from each other is not substantially affected by the high temperature, is not in that expanded closed-cell wall stress relaxes(Comprising strand The stress relaxation of section and gas pressure is caused to decline caused two aspects that relax because of gas diffusion), seal more reliable, make Rain leakage phenomenon is obtained to be eliminated.
The sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber has excellent heat-insulated resistance to gentle weather-proof Property, expanded perlite micro mist high temperature resistant heat insulation lacquer coat weakens temperature to EPDM rubber i.e. ethylene propylene diene rubber closed-cell foam significantly The adverse effect of sheet material so that EPDM rubber is that the consistency of performance of ethylene propylene diene rubber closed-cell foam sheet material effectively keeps.
The heat-insulated heat resistance of sheet material of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber is good, it is had More excellent rebound characteristics, are more suitable for buffering under insulation, vibration damping and the engineering applications application such as shockproof.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (7)

1. a kind of expanded perlite micro mist high temperature resistant heat insulation paint coats the sheet material of EPDM rubber, it is characterised in that including:Ternary second Third EPDM rubber closed-cell foam sheet layer, EPDM rubber closed-cell foam sheet layer surface recombination has expanded perlite micro mist high temperature resistant The heat-insulated film layer formed after thermal insulating coating solidification, the heat-insulated film layer is connected to by multiple heat-insulated microballons of nanoscale expanded perlite The three-dimensional hollow structural system of the closing for being formed together.
2. the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 1, it is characterised in that The single side surface of EPDM rubber closed-cell foam sheet layer is compounded with heat-insulated film layer.
3. the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 1, it is characterised in that The double-sided surface of EPDM rubber closed-cell foam sheet layer is compounded with heat-insulated film layer.
4. the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 1, it is characterised in that The outer surface of EPDM rubber closed-cell foam sheet layer is coated with heat-insulated film layer.
5. the preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 1, It is characterised in that it includes following steps:
1)By EPDM rubber closed-cell foam sheet surface cleaning showers, and dry;
2)By EPDM rubber closed-cell foam sheet surface corona polarizing;
3)EPDM rubber closed-cell foam sheet surface airless spraying thickness less than 0.5mm expanded perlite micro mist high temperature resistant every Heat paint, and thermal insulating coating is dried;
4)If desired coating is thickeied, the multiple circulation step 3 after coated and dried), until reaching the thickness of demand.
6. the preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 5, Characterized in that, step 1)In, drying uses low temperature drying, and temperature is between 70 DEG C -83 DEG C.
7. the preparation technology of the sheet material of expanded perlite micro mist high temperature resistant heat insulation paint EPDM rubber according to claim 5, Characterized in that, step 3)In drying using 75 DEG C -85 DEG C temperature drying 30-40min.
CN201611197160.5A 2016-12-22 2016-12-22 The sheet material and its preparation technology of expanded perlite micro mist high temperature resistant heat insulation paint coating EPDM rubber Pending CN106750496A (en)

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528843A (en) * 2003-10-13 2004-09-15 王长青 Heat-insulating anticorrosive paint and preparing method thereof
CN102135222A (en) * 2010-01-07 2011-07-27 阿玛赛尔企业有限公司 Elastomeric low temperature insulation
CN103359993A (en) * 2013-07-17 2013-10-23 江西佰科建筑节能材料有限公司 Novel preparation technique of energy conservation material for buildings
CN203810351U (en) * 2014-04-16 2014-09-03 常州市泛亚汽车饰件有限公司 Waterproof vehicle lamp sealing pad
CN104194045A (en) * 2014-07-24 2014-12-10 北京化工大学 Method for preparing polymer composite material by expanded perlite

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528843A (en) * 2003-10-13 2004-09-15 王长青 Heat-insulating anticorrosive paint and preparing method thereof
CN102135222A (en) * 2010-01-07 2011-07-27 阿玛赛尔企业有限公司 Elastomeric low temperature insulation
CN103359993A (en) * 2013-07-17 2013-10-23 江西佰科建筑节能材料有限公司 Novel preparation technique of energy conservation material for buildings
CN203810351U (en) * 2014-04-16 2014-09-03 常州市泛亚汽车饰件有限公司 Waterproof vehicle lamp sealing pad
CN104194045A (en) * 2014-07-24 2014-12-10 北京化工大学 Method for preparing polymer composite material by expanded perlite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
韩喜林: "《节能建筑设计与施工》", 31 May 2008 *

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Effective date of registration: 20190103

Address after: 213165 28-8 Liban Road, Bangshang Village, Lijia Town, Wujin District, Changzhou City, Jiangsu Province

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Application publication date: 20170531