CN106747244A - A kind of magnesia oxychloride cement sill, preparation method and its application in preventing and fixing sand - Google Patents

A kind of magnesia oxychloride cement sill, preparation method and its application in preventing and fixing sand Download PDF

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Publication number
CN106747244A
CN106747244A CN201710156881.XA CN201710156881A CN106747244A CN 106747244 A CN106747244 A CN 106747244A CN 201710156881 A CN201710156881 A CN 201710156881A CN 106747244 A CN106747244 A CN 106747244A
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CN
China
Prior art keywords
sand
oxychloride cement
magnesia oxychloride
magnesia
plate
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710156881.XA
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Chinese (zh)
Inventor
肖学英
郑卫新
屈建军
文静
李颖
常成功
董金美
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Qinghai Institute of Salt Lakes Research of CAS
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Qinghai Institute of Salt Lakes Research of CAS
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Priority to CN201710156881.XA priority Critical patent/CN106747244A/en
Publication of CN106747244A publication Critical patent/CN106747244A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/21Efflorescence resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The present invention discloses a kind of magnesia oxychloride cement sill, preparation method and its application in preventing and fixing sand.A kind of magnesia oxychloride cement sill, is made up of following components:Magnesia(MgO), fine sand, bischofite(MgCl2·6H2O)And water, each component is 1 by weight ratio:(1~30):(0.5~4):(0.5~3);A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, comprises the following steps:By bischofite(MgCl2·6H2O)With water(H2O)Baume degrees is made into for 15 ~ 32Be ' magnesium chloride solutions;By magnesia, fine sand, magnesium chloride solution ratio 1 by weight:(1~30):(1 ~ 7) is mixed to form magnesia oxychloride cement concrete material;Magnesia oxychloride cement concrete material is imported and conserved in tabular mould, the demoulding is made magnesia oxychloride cement sill and fixes the sand plate after slurry solidifies completely.The magnesia oxychloride cement that will the be made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, plays a part of preventing and fixing sand.Magnesia oxychloride cement sill of the present invention and plate convenient material drawing of fixing the sand, simple production process are with low cost, and preventing and fixing sand effect is good, with good application value.

Description

A kind of magnesia oxychloride cement sill, preparation method and its application in preventing and fixing sand
Technical field
The invention belongs to desert treatment technical field, more particularly to a kind of magnesia oxychloride cement sill, preparation method and Its application in preventing and fixing sand.
Background technology
China is one of more serious country of desertification hazard in the world, and desert treatment is received as an important state basic policy To great attention.The key of desert treatment is preventing and fixing sand.The major way of control of desert is that physics fixes the sand both at home and abroad at present (Such as cubic meter of stone lattice, earthwork lattice)And sand consolidation with biologic(Such as serike).It is common several to fix the sand mode for example:Straw checkerboard barrier sand-protecting barrier is to use The materials such as wheat straw, straw, reed are bundled into grid-like windbreak on moving dunes, to weaken the erosion of wind-force.Straw checkerboard barrier is husky Although barrier low cost, construction are simple, the efficiency high of preventing and fixing sand.Yet with sand-protecting barrier material it is most of be wheat straw or straw, The life-span of its sand-proof is generally 3-4 or so, often changes the consumption that straw checkerboard barrier sand-protecting barrier is also brought along in manpower and materials and financial resources Take.The cubic meter of stone lattice barrier that fixes the sand is that cobble is piled on sand dune 20-30 meter high high of the ridge, and spacing 1-2 meters, trend is vertical with wind direction, Its construction of fixing the sand is simple, and sand-fixing effect is relatively good, however it is necessary that substantial amounts of cobble, building stones of transporting for long-distance are needed for desert area Deng, high cost, and engineering control is provisional measures for sand prevention.The macromolecules such as sediment trapping net or chemical sand-fixing method, weather-proof energy Power, water resistance, freeze-thaw resistance are good, but part macromolecular sand-fixation material is easy after desert area intensive ultraviolet sunlight Decompose, cause secondary pollution.
The content of the invention
It is an object of the invention to provide a kind of new magnesia oxychloride cement sill, preparation method and its in preventing and fixing sand In application, it is short to solve preventing and fixing sand material lifetime present in prior art, high cost, effect difference and easily cause secondary The problems such as pollution.
The technical scheme that the present invention is provided is as follows:
A kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and water.
Further, described magnesia oxychloride cement sill each component is by weight ratio:Magnesia, fine sand, water chlorine magnesium Stone and water=1:(1~30):(0.5~4): (0.5~3).
Further, described magnesia oxychloride cement sill each component optimum proportioning by weight is 1:10:1.5:1.3.
A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, it is characterised in that comprise the following steps:
S1, by bischofite(MgCl2·6H2O)With water(H2O)It is made into the magnesium chloride solution that Baume degrees is 15 ~ 32Be ';
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:(1~30):(1 ~ 7) is mixed to form chlorine Oxygen magnesium cement concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
Further, the size of tabular mould is in the step s3:Length × width × height=1m × 0.2m × 0.025m.
A kind of new magnesia oxychloride cement sill fixes the sand application of the plate in preventing and fixing sand, it is characterised in that will be above-mentioned The magnesia oxychloride cement that method the is made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, plays a part of preventing and fixing sand.
Compared with prior art, the present invention has following advantage:
1st, magnesia of the present invention is formed by magnesite or dolomite mineral calcining, and filler takes from desert fine sands, material materials It is convenient, and 80% be fine sand in material, can gather materials on the spot, the cost of preventing and fixing sand greatly reduces;
2nd, magnesia oxychloride cement sill wind erosion ability of the present invention, water resistance, cold-resistant anti-freezing property are excellent, usage cycles It is long, do not result in secondary pollution;
3rd, magnesia oxychloride cement sill of the present invention fix the sand plate manufacture craft it is simple, it is not necessary to large-scale equipment, production Cycle is short, easy for installation, preventing and fixing sand effect is good;
4th, magnesia oxychloride cement sill of the present invention fix the sand plate be installed on desert surface formed cross grid form, take up an area Area is minimum, and the growth of the intrinsic plant in desert is not influenceed, the combination for answering this chemical sand-fixing and physics to fix the sand, and not only secures stream Sand, and the growth of plant is maintained, improve ecological environment;
5th, magnesia oxychloride cement sill of the present invention has weatherability, anticorrosive, weathering resistance, power than other sand prevention materials Function admirable is learned, strong, the attractive in appearance advantage of globality is installed;
6th, higher level, compression strength are attained by by testing fix the sand plate material compression strength, rupture strength of magnesium cement> 13MPa, rupture strength>2MPa.
Brief description of the drawings
Fig. 1 fixes the sand board mold figure for magnesia oxychloride cement sill
Fig. 2 fixes the sand setting figure for the magnesia oxychloride cement sill plate that fixes the sand.
Specific embodiment
Below in conjunction with the accompanying drawings, the present invention is described further.
Embodiment 1
A kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and water.
The magnesia oxychloride cement sill, magnesia, fine sand, bischofite and water ratio by weight is 1:10:1.5: 1.3。
A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, comprises the following steps:
S1, by bischofite(MgCl2·6H2O)With water(H2O)It is made into the magnesium chloride solution that Baume degrees is 25Be ';
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:10:2.8 are mixed to form chlorine oxygen magnesium water Cement concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
The magnesia oxychloride cement that the above method the is made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, sand prevention is played and is consolidated Husky effect.
Embodiment 2
A kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and water.
The magnesia oxychloride cement sill, magnesia, fine sand, bischofite and water ratio by weight is 1: 1:0.5: 0.5。
A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, comprises the following steps:
S1, by bischofite(MgCl2·6H2O)With water(H2O)It is made into the magnesium chloride solution that Baume degrees is 15Be ';
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:1:1 is mixed to form magnesia oxychloride cement Concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
The magnesia oxychloride cement that the above method the is made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, sand prevention is played and is consolidated Husky effect.
Embodiment 3
A kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and water.
The magnesia oxychloride cement sill, magnesia, fine sand, bischofite and water ratio by weight is 1: 30: 4: 3。
A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, comprises the following steps:
S1, by bischofite(MgCl2·6H2O)With water(H2O)It is made into the magnesium chloride solution that Baume degrees is 32Be ';
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:30:7 are mixed to form chlorine oxygen magnesium water Cement concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
The magnesia oxychloride cement that the above method the is made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, sand prevention is played and is consolidated Husky effect.
Embodiment 4
A kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and water.
The magnesia oxychloride cement sill, magnesia, fine sand, bischofite and water ratio by weight is 1: 8:0.8: 0.8。
A kind of magnesia oxychloride cement sill fixes the sand the preparation method of plate, comprises the following steps:
S1, by bischofite(MgCl2·6H2O)With water(H2O)It is made into the magnesium chloride solution that Baume degrees is 22Be ';
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:8:1.6 are mixed to form chlorine oxygen magnesium water Cement concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
The magnesia oxychloride cement that the above method the is made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, sand prevention is played and is consolidated Husky effect.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, it is possible to understand that These embodiments can be carried out with various changes, modification, replacement without departing from the principles and spirit of the present invention and become Type, the scope of the present invention be defined by the appended.

Claims (6)

1. a kind of magnesia oxychloride cement sill, it is characterised in that be made up of following components:Magnesia, fine sand, bischofite and Water.
2. a kind of magnesia oxychloride cement sill according to claim 1, it is characterised in that described magnesia oxychloride cement base material Expect that each component is by weight ratio:Magnesia, fine sand, bischofite and water=1:1~30:0.5~4: 0.5~3.
3. a kind of magnesia oxychloride cement sill according to claim 1, it is characterised in that described magnesia oxychloride cement base material Expect that each component is by weight ratio:1:1~30:0.5~4: 0.5~3.
4. a kind of magnesia oxychloride cement sill fixes the sand the making Preparation Method of plate, it is characterised in that comprise the following steps:
S1, bischofite and water are made into Baume degrees be 15 ~ 32Be ' magnesium chloride solution;
S2, by s1 steps gained magnesia, fine sand, magnesium chloride solution ratio 1 by weight:1~30:1 ~ 7 is mixed to form chlorine oxygen magnesium Cement concrete material;
S3, will magnesia oxychloride cement concrete material import tabular mould in conserved, the demoulding is made after slurry solidifies completely Fixed the sand plate into magnesia oxychloride cement sill.
5. a kind of magnesia oxychloride cement sill according to claim 4 fixes the sand the making Preparation Method of plate, it is characterised in that institute The size for stating tabular mould in step s3 is:Length × width × height=1m × 0.2m × 0.025m.
6. application of the plate in preventing and fixing sand of fixing the sand that a kind of new magnesia oxychloride cement sill is made, it is characterised in that will The magnesia oxychloride cement the being made plate that fixes the sand is arranged on Shamian Island by the form of ten grids, plays a part of preventing and fixing sand.
CN201710156881.XA 2017-03-16 2017-03-16 A kind of magnesia oxychloride cement sill, preparation method and its application in preventing and fixing sand Pending CN106747244A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107151983A (en) * 2017-07-02 2017-09-12 陈佑生 A kind of road and bridge use bearing pad stone construction method
CN107352947A (en) * 2017-08-03 2017-11-17 何明驹 Pour gel material with and preparation method thereof
CN110438970A (en) * 2019-08-09 2019-11-12 中国建筑股份有限公司 A kind of pin-connected panel gangue celluar concrete fixes the sand plate and preparation method thereof
CN113277829A (en) * 2021-07-01 2021-08-20 深圳市明远建筑科技有限公司 Magnesium oxychloride cement-based material, sand prevention and fixation plate and preparation method thereof
CN113927711A (en) * 2020-07-14 2022-01-14 中国科学院青海盐湖研究所 Mold for manufacturing sand fixing plate connecting piece, manufacturing method and application

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432623A (en) * 2002-01-15 2003-07-30 张景连 Green sand-fixing liquid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432623A (en) * 2002-01-15 2003-07-30 张景连 Green sand-fixing liquid

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107151983A (en) * 2017-07-02 2017-09-12 陈佑生 A kind of road and bridge use bearing pad stone construction method
CN107151983B (en) * 2017-07-02 2019-01-22 江西省交通工程集团有限公司 A kind of road and bridge bearing pad stone construction method
CN107352947A (en) * 2017-08-03 2017-11-17 何明驹 Pour gel material with and preparation method thereof
CN110438970A (en) * 2019-08-09 2019-11-12 中国建筑股份有限公司 A kind of pin-connected panel gangue celluar concrete fixes the sand plate and preparation method thereof
CN110438970B (en) * 2019-08-09 2024-04-09 中国建筑股份有限公司 Assembled gangue porous concrete sand fixation plate and preparation method thereof
CN113927711A (en) * 2020-07-14 2022-01-14 中国科学院青海盐湖研究所 Mold for manufacturing sand fixing plate connecting piece, manufacturing method and application
CN113277829A (en) * 2021-07-01 2021-08-20 深圳市明远建筑科技有限公司 Magnesium oxychloride cement-based material, sand prevention and fixation plate and preparation method thereof

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Application publication date: 20170531