CN106747161A - The roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture - Google Patents

The roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture Download PDF

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Publication number
CN106747161A
CN106747161A CN201710034391.2A CN201710034391A CN106747161A CN 106747161 A CN106747161 A CN 106747161A CN 201710034391 A CN201710034391 A CN 201710034391A CN 106747161 A CN106747161 A CN 106747161A
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weight portions
stabilizing agent
soil body
compound
roadbase
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CN201710034391.2A
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Chinese (zh)
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包宗义
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Priority to CN201710034391.2A priority Critical patent/CN106747161A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0418Wet materials, e.g. slurries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Road Paving Structures (AREA)

Abstract

The present invention relates to a kind of roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture, the roadbase compound prepares primary compound of the material by 100 weight portions, the soil body stabilizing agent composition of the cement of 38 weight portions and 0.01 0.1 weight portions, the primary compound by 100 weight portions municipal wet mud, the quick lime of 15 20 weight portions, and solid waste composition, the soil body stabilizing agent by 100 weight portions water, the surfactant of 1 15 weight portions, boric acid or the borate composition of 0.1 10 weight portions, the consumption of the solid waste is 7 13 times of municipal wet mud and the mixed cumulative volume of quick lime.Roadbase compound of the invention has good compression strength.

Description

The roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture
Technical field
The present invention relates to a kind of roadbase compound, especially, it is related to using special soil body stabilizing agent recycling treatment The roadbase mixing of municipal sludge manufacture.
Background technology
Municipal sludge refers to the clod or mud cake of discharge after the concentrated dehydration in municipal sewage plant, and general moisture content exists 80% or so, and containing nutrients such as abundant organic matters and N, P, K, also contain the nuisance such as heavy metal and pathogen Matter, if mishandling, not only easily causes environmental pollution, also can waste of resources is caused.With China's economy and urbanization Fast development, the generation of municipal wastewater and its quantity are sharply increased.
With being further exacerbated by for urbanization, the municipal sludge of China is more and more, is badly in need of a kind of new technique and technology, So that municipal sludge obtains disposal of resources.
Existing road building technology, constructs roadbase(Upper and lower basic unit, underlayment)All it is with graded broken stone(Primary rock Stone, through broken, screening composition graded broken stone)It is material of main part, then lime is mixed by match ratio, flyash, cement, is made " two Ash broken stones " or " cement stabilized grading crushed stones ", as the material for constructing roadbase.The major defect of this technology, is destruction Ecological environment(Fried mountain takes stone or digs river and takes stone), largely consume Resources and cost be too high.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of special soil body stabilizing agent recycling treatment municipal sludge The roadbase compound of manufacture, the roadbase compound prepares primary compound, 3-8 of the material by 100 weight portions The soil body stabilizing agent composition of the cement of weight portion and 0.01-0.1 weight portions, the primary compound by 100 weight portions city Political affairs wet mud, the quick lime of 15-20 weight portions and solid waste composition, the soil body stabilizing agent is by 100 weight portions Water, the surfactant of 1-15 weight portions, boric acid or the borate composition of 0.1-10 weight portions, the consumption of the solid waste It is 7-13 times of municipal wet mud and the mixed cumulative volume of quick lime.
The moisture content of the municipal wet mud is 70-85%.
The cement is 425# Portland cements.
The pH value of the soil body stabilizing agent is adjusted to 8-10.
The solid waste is one or more in metal tailings, industrial residue, building waste.
The surfactant is butyl naphthalene sulfonate.
Surfactant of the invention can be adsorbed in the surface of bulky grain, change the hydrophily of particle surface so that Grain has the effect of shield water, reduces the water imbibition of particle, and what is prepared is non-burning brick with good permeability resistance, and then has There is good compression strength.Present invention employs a small amount of cement, boric acid or borate are added, substantially increased non-burning brick Compression strength, employs soil body stabilizing agent of the invention, and the usage amount that can in large quantities reduce cement is unburned without reducing shaping The compression strength of brick.
The non-burning brick porous calcium silicate for preparing material also including 1-5 weight portions and 0.01-0.5 weight portions to ammonia Base salicylic acid.
Due to containing substantial amounts of heavy metal in municipal sludge, relative to the heavy metal that other are originated, the weight in municipal sludge The dissolution of metal is more easy, can effectively reduce municipal sludge roadbase heavy metal using above-mentioned scheme, especially zinc Dissolution.
A kind of non-burning brick preparation method, comprises the following steps:
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, non-burning brick compound is obtained;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Due to containing substantial amounts of harmful bacteria, heavy metal in municipal sludge, it is impossible to used as agricultural fertilizer source.This hair It is bright directly to make non-burning brick using municipal wet mud, wet mud concentration, dewatering process are eliminated, high temperature sintering brickmaker is not used Skill, cost is substantially reduced.Making obtain it is non-burning brick meet national standard requirement, excellent mechanical.
Existing road building technology, constructs roadbase(Upper and lower basic unit, underlayment)All it is with graded broken stone(Primary rock Stone, through broken, screening composition graded broken stone)It is material of main part, then lime is mixed by match ratio, flyash, cement, is made " two Ash broken stones " or " cement stabilized grading crushed stones ", as the material for constructing roadbase.The present invention is only with municipal sludge powder conduct The material of main part of roadbase compound, takes full advantage of municipal sludge.The road that disposal of resources municipal sludge is prepared Basic unit meets the requirement of national standard.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
Optimum moisture content of the invention refers to that compound reaches measured during maximum dry density indoors under compaction test Water content is optimum moisture content, and due to the presence for having cement, optimum moisture content can be converted using filler optimum moisture content. Optimum moisture content can be obtained by actual tests.
It is the soil body stabilizing agent of main body that the present invention uses boric acid or borate, substantially increases municipal sludge non-active ingredient Crosslinking active, coordinate with a small amount of cement, the roadbase compound being prepared from meets the relevant criterion of country.
Those methods that the forming method of roadbase compound of the invention can be commonly used using other prior arts are entered Row shaping.The method that the present invention is mixed using two benches, the particle diameter after the crushing of municipal sludge is 0.1-3mm, works as municipal sludge Level is unfavorable for obtaining more preferable compression strength with powder particle size more than 3mm.The method mixed using two benches can improve unburned The mechanical strength of brick.Compared with being mixed together, the compression strength of roadbase 10%-25% or so can be improved.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only Illustrate and it is nonrestrictive.If without other explanations, raw materials used is all commercially available.
The present invention is described in detail referring to several examples.
Embodiment 1
The preparation of the roadbase compound of the present embodiment is comprised the following steps:
Municipal sludge is crushed to the no more than particle diameter of 3mm, the second pond that municipal sludge comes from Hangzhou sewage treatment plant is dirty Mud, moisture content 80%;
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;Gu Body discarded object is the building waste crushed by concrete.
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, adds appropriate water to mix with optimum moisture content, Obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
By the shaping of roadbase compound, diameter and the test specimen for being 150mm high are made, place test in 28 days and obtain it Compression strength 9.38MPa.
Average grain diameter is fully crushed to after roadbase compound test specimen is placed 28 days for 2mm particles, 500g is taken and is placed in In permeable bucket, gondola water faucet is placed in directly over bucket, regulation leaching flow quantity is 60ml/min, and the pH value of leaching liquor is 6, After leaching 12 hours, Zn-ef ficiency in the roadbase before analysis leaching and after leaching is calculated the loss amount 5.3% of Zn-ef ficiency.
Embodiment 2
The preparation of the roadbase compound of the present embodiment is comprised the following steps:
Municipal sludge is crushed to the no more than particle diameter of 3mm, municipal sludge comes from the primary sludge of Xuzhou sewage treatment plant(Just Heavy pond and second pond sludge), moisture content 80%;
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;Gu Body discarded object is the building waste crushed by concrete.
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, adds appropriate water to mix with optimum moisture content, Obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
By the shaping of roadbase compound, diameter and the test specimen for being 150mm high are made, place test in 28 days and obtain it Compression strength 8.98MPa.
Average grain diameter is fully crushed to after roadbase compound test specimen is placed 28 days for 2mm particles, 500g is taken and is placed in In permeable bucket, gondola water faucet is placed in directly over bucket, regulation leaching flow quantity is 60ml/min, and the pH value of leaching liquor is 6, After leaching 12 hours, Zn-ef ficiency in the roadbase before analysis leaching and after leaching is calculated the loss amount 7.3% of Zn-ef ficiency.
Embodiment 3
The preparation of the roadbase compound of the present embodiment is comprised the following steps:
Municipal sludge is crushed to the no more than particle diameter of 3mm, the preliminary sedimentation tank that municipal sludge comes from Yiwu sewage treatment plant is dirty Mud, moisture content 70%;
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;Gu Body discarded object is the building waste crushed by concrete.
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, adds appropriate water to mix with optimum moisture content, Obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
By the shaping of roadbase compound, diameter and the test specimen for being 150mm high are made, place test in 28 days and obtain it Compression strength 8.34MPa.
Average grain diameter is fully crushed to after roadbase compound test specimen is placed 28 days for 2mm particles, 500g is taken and is placed in In permeable bucket, gondola water faucet is placed in directly over bucket, regulation leaching flow quantity is 60ml/min, and the pH value of leaching liquor is 6, After leaching 12 hours, Zn-ef ficiency in the roadbase before analysis leaching and after leaching is calculated the loss amount 5.8% of Zn-ef ficiency.
It is same as Example 1 by Data Comparison, soil body stabilizing agent of the invention is not used, the roadbase examination for obtaining The part compression strength of 28 days is 4.13Mpa, and the loss amount of Zn-ef ficiency is 4.7%.As can be seen that it is steady to employ the soil body of the invention Determining agent can greatly improve the compression strength of roadbase.
Embodiment 4-6
Embodiment 4-6 is identical with previous embodiment 1-3 respectively, the difference is that adding many of 3 weight portions in the second blending bunker The PAS of hole calcium silicates and 0.08 weight portion.
Comparative example 1, it is same as Example 1, the difference is that adding the porous silicic acid of 3 weight portions in the second blending bunker Calcium.
Comparative example 2, it is same as Example 1, unlike added in the second blending bunker 0.08 weight portion to amino Salicylic acid.
Comparative example 2, it is same as Example 1, the difference is that adding the porous calcium silicate of 3 weight portions in the second blending bunker With the salicylic acid of 0.08 weight portion.
The compression strength and Zn-ef ficiency loss late of roadbase compound are tested using foregoing method, embodiment 4 is obtained The roadbase test specimen compression strength of 28 days be 9.70Mpa, the loss amount of Zn-ef ficiency is 0.34%.The road that embodiment 5 is obtained Basic unit's test specimen compression strength of 28 days is 8.63Mpa, and the loss amount of Zn-ef ficiency is 0.89%.The roadbase examination that embodiment 6 is obtained The part compression strength of 28 days is 8.28Mpa, and the loss amount of Zn-ef ficiency is 0.74%.The roadbase test specimen that comparative example 1 is obtained 28 days Compression strength be 9.25Mpa, the loss amount of Zn-ef ficiency is 4.2%.The roadbase test specimen resistance to compression of 28 days that comparative example 2 is obtained Intensity is 6.33Mpa, and the loss amount of Zn-ef ficiency is 3.8%.The roadbase test specimen compression strength of 28 days that comparative example 3 is obtained is 9.44Mpa, the loss amount of Zn-ef ficiency is 4.4%.As can be seen that using the roadbase Zn-ef ficiency for preparing of the invention Dissolution is lower, reduces the pollution of environment.
The above, only presently preferred embodiments of the present invention is not intended to limit the scope of the present invention.It is every The impartial change done according to present invention and modification, are encompassed by the scope of the claims of the invention.

Claims (8)

1. a kind of roadbase compound that special soil body stabilizing agent recycling treatment municipal sludge is manufactured, it is characterised in that institute That states roadbase compound prepares material by the primary compound of 100 weight portions, the cement and 0.01-0.1 of 3-8 weight portions Weight portion soil body stabilizing agent composition, the primary compound by 100 weight portions municipal wet mud, 15-20 weight portions life Lime and solid waste are constituted, the soil body stabilizing agent by 100 weight portions water, the surfactant of 1-15 weight portions, Boric acid or the borate composition of 0.1-10 weight portions, after the consumption of the solid waste is for municipal wet mud and quick lime mixing 7-13 times of cumulative volume.
2. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the moisture content of the municipal wet mud is 70-85%.
3. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the cement is 425# Portland cements.
4. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the pH value of the soil body stabilizing agent is adjusted to 8-10.
5. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the solid waste is one or more in metal tailings, industrial residue, building waste.
6. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the surfactant is butyl naphthalene sulfonate.
7. a kind of roadbase of special soil body stabilizing agent recycling treatment municipal sludge manufacture according to claim 1 is mixed Close material, it is characterised in that the non-burning brick material for preparing also includes the porous calcium silicate and 0.01-0.5 weight of 1-5 weight portions The PAS of part.
8. a kind of non-burning brick preparation method, it is characterised in that comprise the following steps:
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, non-burning brick compound is obtained;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
CN201710034391.2A 2017-01-18 2017-01-18 The roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture Pending CN106747161A (en)

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CN201710034391.2A CN106747161A (en) 2017-01-18 2017-01-18 The roadbase compound of special soil body stabilizing agent recycling treatment municipal sludge manufacture

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Publication number Priority date Publication date Assignee Title
CN109722968A (en) * 2019-01-10 2019-05-07 江苏工程职业技术学院 A kind of high-performance permeable concrete system and preparation method thereof of building waste preparation
CN111548098A (en) * 2020-06-12 2020-08-18 北京土木禾天环保科技有限公司 Road base layer mixture made from coal gasification waste residue and manufacturing method thereof
WO2020215774A1 (en) * 2019-04-24 2020-10-29 中国科学院广州能源研究所 Roadbed material containing municipal sludge residue
CN112390596A (en) * 2020-12-04 2021-02-23 福建汇达建筑工程有限公司 Roadbed material containing municipal sludge
CN112876190A (en) * 2021-02-03 2021-06-01 中科聚垚环保新材料科技有限公司 Novel fiber-cured road surface layer mixture and preparation method thereof

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CN203334155U (en) * 2013-06-20 2013-12-11 北京市政路桥科技发展有限公司 Road structure with sub-base layer(s) containing lime-dried sludge inorganic mixture
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109722968A (en) * 2019-01-10 2019-05-07 江苏工程职业技术学院 A kind of high-performance permeable concrete system and preparation method thereof of building waste preparation
WO2020215774A1 (en) * 2019-04-24 2020-10-29 中国科学院广州能源研究所 Roadbed material containing municipal sludge residue
CN111548098A (en) * 2020-06-12 2020-08-18 北京土木禾天环保科技有限公司 Road base layer mixture made from coal gasification waste residue and manufacturing method thereof
CN112390596A (en) * 2020-12-04 2021-02-23 福建汇达建筑工程有限公司 Roadbed material containing municipal sludge
CN112876190A (en) * 2021-02-03 2021-06-01 中科聚垚环保新材料科技有限公司 Novel fiber-cured road surface layer mixture and preparation method thereof

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