CN106745833A - A kind of electrochemistry circulating water treatment method and device - Google Patents

A kind of electrochemistry circulating water treatment method and device Download PDF

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Publication number
CN106745833A
CN106745833A CN201611008160.6A CN201611008160A CN106745833A CN 106745833 A CN106745833 A CN 106745833A CN 201611008160 A CN201611008160 A CN 201611008160A CN 106745833 A CN106745833 A CN 106745833A
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CN
China
Prior art keywords
cooling tower
water
water pump
fec
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611008160.6A
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Chinese (zh)
Inventor
王欣鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Carbon Energy (shandong) Co Ltd
Original Assignee
China Carbon Energy (shandong) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Carbon Energy (shandong) Co Ltd filed Critical China Carbon Energy (shandong) Co Ltd
Priority to CN201611008160.6A priority Critical patent/CN106745833A/en
Publication of CN106745833A publication Critical patent/CN106745833A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02Softening water by precipitation of the hardness
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/02Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating liquids, e.g. brine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023Water in cooling circuits

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a kind of electrochemistry circulating water treatment method, comprise the following steps:Cooling tower bottom is connected with second circulation water pump to side, recirculated water enters filter by second circulation water pump from cooling tower, subsequently into FEC electrochemical treatments main frames, last recirculated water incrustation scale is adsorbed in FEC electrochemical treatments main frames, recirculated water after treatment is continued cycling through into cooling tower bottom cycle pond, cooling tower bottom cycle water enters heat exchanger by first circulation water pump from cooling tower bottom cycle pond, most enters cooling tower through heat exchanger afterwards.The present invention has following technique effect using such scheme:Impurities in water accumulation is reduced, notable dissolved organic matter simultaneously effective realizes the molten dirt of scale removal, while reach save water and energy, free of contamination effect;Traditional medicament method can only carry out continuous blowdown, cause substantial amounts of water resource waste, and sewer 70% can be reduced using the solution of the present invention, save water resource.

Description

A kind of electrochemistry circulating water treatment method and device
Technical field
The present invention relates to circulating cooling water purification field, more particularly to a kind of circulation of calcining furnace
The processing method and processing device of cooling water purification.
Background technology
Cooling circulating water is mainly used in factory, market, hospital etc. needs temperature controlled place, due to undressed Water can cause tube wall and fouling of heat exchangers and burn into recirculated water bacterium algae to be grown, and cause production to be normally carried out, so needs are right Water is processed.
Topmost processing mode is to add medicament in water to come antiscale, anti-corrosion, sterilization, algae removal at this stage.But medicament Method brings many negative effects simultaneously:Waste water, power-consuming, environmental pollution, a series of problems, such as turn out drug tolerant bacteria.Therefore medicine Agent method is makeshift, is not perfect processing method.Traditional chemical method mainly controls water to refer to using various medicaments Mark, it is impossible to the impurity in water is taken out and contains phosphorus in draining, be also easy to produce eutrophication, accumulated impurities in water and increase, it is necessary to Periodic replacement running water, waste water resource, secondly medicament is costly, increased production cost.
Traditional medicament method can only carry out continuous blowdown, cause substantial amounts of water resource waste, can using electro-chemical water facture To reduce sewer 70%, water resource has been saved;It is phosphorous in traditional medicament method draining, eutrophication is also easy to produce, use electro-chemical water Facture is free of any medicament, it is possible to achieve draining is pollution-free;Traditional chemical method must periodically carry out stopping production cleaning, pre- Film, electrochemical process need not stop production cleaning, and the descaling rate of itself can reach more than 98%, Ca2+,Mg2+Etc. being deposited on pole plate, More preferably, ion is stayed in water antiscaling effect, complexing, dispersion;Traditional medicament method needs substantial amounts of medicament expense, and electrochemical process only consumes Electric 3kw/h;Traditional medicament method needs the management of the maintenance of medicament storage tank, medicine machine etc., drug delivery, storage, preparation etc., electricity Chemical method only needs to Periodic scale removal.
Electro-chemical water treatment be electrolysis principle and polar water molecules with electrochemistry as theoretical foundation, the environmental protection for growing up New technology.The effect that it not only reaches with chemical Treatment, additionally it is possible to scale removal, molten dirt, dissolve from pipeline into solid dirt, Dissolved organic matter, water saving, energy-conservation, free of contamination new technology performance, are the directions of water process future development.
The content of the invention
The technical problem to be solved in the present invention is directed to the deficiencies in the prior art, there is provided one kind can reduce impurities in water product Tired, dissolved organic matter simultaneously effective realizes the molten dirt of scale removal, while water saving, energy-conservation, free of contamination electrochemistry circulating water treatment side Method;
In addition present invention also offers a kind of device of electrochemistry circulating water treatment.
Following technical scheme is used to solve the above-mentioned technical problem present invention:A kind of electrochemistry circulating water treatment method, bag Include following steps:Cooling tower bottom is connected with second circulation water pump to side, and recirculated water is by second circulation water pump from cooling Water tower enters filter, and subsequently into FEC electrochemical treatments main frames, last recirculated water incrustation scale is in FEC electrochemical treatments main frames Adsorbed, the recirculated water after treatment is continued cycling through into cooling tower bottom cycle pond, and cooling tower bottom cycle water passes through First circulation water pump enters heat exchanger from cooling tower bottom cycle pond, most enters cooling tower through heat exchanger afterwards.
A kind of electrochemistry circulating water treatment device, including cooling tower, cooling tower bottom are connected with first circulation water pump, First circulation water pump is connected with heat exchanger by pipeline, and heat exchanger is connected by pipeline with cooling tower top;
The bottom of cooling tower is also associated with second circulation water pump, and second circulation water pump is connected with filter by pipeline, filtering Device is connected with FEC electrochemical treatments main frames by pipeline, on the circulating water outlet of FEC electrochemical treatments main frames by pipeline with it is cold But water tower bottom connection.
The present invention has following technique effect using such scheme:Reduce impurities in water to accumulate, notable dissolved organic matter, The molten dirt of scale removal is simultaneously effective realized, while reach save water and energy, free of contamination effect;Traditional medicament method can only be arranged continuously Dirt, causes substantial amounts of water resource waste, and sewer 70% can be reduced using the solution of the present invention, has saved water resource;Traditional medicine It is phosphorous in agent method draining, eutrophication is also easy to produce, be free of any medicament using facture of the invention, it is possible to achieve draining is without dirt Dye;Traditional chemical method must periodically carry out stopping production cleaning, pre- film, and the method for the present invention need not stop production cleaning, itself Descaling rate can reach more than 98%, Ca2+,Mg2+Etc. being deposited on pole plate, more preferably, ion is stayed in water antiscaling effect, network Splitting or integrating dissipates;Traditional medicament method needs substantial amounts of medicament expense, the method for the present invention only power consumption 3kw/h;Traditional medicament method needs medicine The management of the maintenance of agent storage tank, medicine machine etc., drug delivery, storage, preparation etc., the method for the present invention only needs to periodically remove Dirt;The calcium hardness for processing Posterior circle water is reduced to below 400mg/L by 440.74mg/L, and total hardness is reduced from 1381.33mg/L To below 1100mg/L, total alkalinity is reduced to below 300mg/L by 335.22mg/L, and total Fe is reduced to by 0.33mg/L Below 0.25mg/L, CI-Below 700mg/L is reduced to by 1051.39mg/L;RO membrane reverse osmosis concentrated water salt content is high, for following Ring water system, can cause fouling, and this part concentrated water major part is discharged, by the way that after electro-chemical water treatment, concentrated water can be supplemented and followed Ring water, reduces by a supplement for water, reaches the purpose of water saving.
Brief description of the drawings
Accompanying drawing 1 is the structural representation of the present invention.
In figure:1- cooling towers;2- heat exchangers;3- first circulation water pumps;4- second circulation water pumps;5- filters;6-FEC Electrochemical treatments main frame.
Specific embodiment
Embodiment, as shown in figure 1, a kind of electrochemistry circulating water treatment method, including cooling tower 1, first circulation water pump 3, second circulation water pump 4, heat exchanger 2, filter 5 and FEC main frames 6.
The bottom of cooling tower 1 is connected with second circulation water pump 4 to side, and recirculated water is by second circulation water pump 4 from cooling Water tower enters filter 5, and subsequently into FEC electrochemical treatments main frame 6, last recirculated water incrustation scale is in FEC electrochemical treatments main frame 6 Interior adsorbed, the recirculated water after treatment is continued cycling through into the bottom cycle pond of cooling tower 1.
Recirculated water is constantly adsorbed by multiple iterative cycles, incrustation scale and impurity, be finally reached heat exchanger good antiscale property and Etch-proof purpose.A water need not be supplemented during this, it is only necessary to supplement counter-infiltration waste water, by electrochemical treatments, reached Circulating water quality index.
, to opposite side connection first circulation water pump 3, recirculated water is by first circulation water pump 3 from cooling for the bottom of cooling tower 1 The bottom cycle pond of water tower 1 enters heat exchanger 2, most enters cooling tower 1 through heat exchanger 2 afterwards.
The index for processing Posterior circle water is as follows:
The above is citing of the invention, wherein the part do not addressed in detail is the known normal of those of ordinary skill in the art Know.Protection scope of the present invention is defined by the content of claim, it is any carried out based on technical inspiration of the invention it is equivalent Conversion, also within protection scope of the present invention.

Claims (2)

1. a kind of electrochemistry circulating water treatment method, it is characterised in that:Comprise the following steps:Cooling tower(1)Bottom is to side It is connected with second circulation water pump(4), recirculated water is by second circulation water pump(4)Enter filter from cooling tower(5), Ran Houjin Enter FEC electrochemical treatments main frames(6), last recirculated water incrustation scale is in FEC electrochemical treatments main frames(6)It is interior adsorbed, after treatment Recirculated water enters cooling tower(1)Bottom cycle pond continues cycling through, cooling tower(1)Bottom cycle water passes through first circulation water Pump(3)From cooling tower(1)Bottom cycle pond enters heat exchanger(2), most afterwards through heat exchanger(2)Into cooling tower(1).
2. a kind of electrochemistry circulating water treatment device, it is characterised in that:Including cooling tower(1), cooling tower(1)Bottom connects There is first circulation water pump(3), first circulation water pump(3)Heat exchanger is connected with by pipeline(2), heat exchanger(2)By pipeline with Cooling tower(1)Top connects;
Cooling tower(1)Bottom be also associated with second circulation water pump(4), second circulation water pump(4)It was connected with by pipeline Filter(5), filter(5)FEC electrochemical treatments main frames are connected with by pipeline(6), FEC electrochemical treatments main frames(6)Follow Pass through pipeline and cooling tower on ring water out(1)Bottom connects.
CN201611008160.6A 2016-11-16 2016-11-16 A kind of electrochemistry circulating water treatment method and device Pending CN106745833A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611008160.6A CN106745833A (en) 2016-11-16 2016-11-16 A kind of electrochemistry circulating water treatment method and device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611008160.6A CN106745833A (en) 2016-11-16 2016-11-16 A kind of electrochemistry circulating water treatment method and device

Publications (1)

Publication Number Publication Date
CN106745833A true CN106745833A (en) 2017-05-31

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342616A (en) * 2019-07-02 2019-10-18 华电电力科学研究院有限公司 A kind of Controlling Auxiliaries in Power Plants cooling water treatment system and processing method
CN114590937A (en) * 2020-10-14 2022-06-07 青岛艾摩特环保科技有限公司 Treatment method of industrial circulating water

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058336A (en) * 2013-01-24 2013-04-24 沈阳惠丰环境科技有限公司 Direct-current electrolytic treatment process and equipment for circulating cooling water
CN105016432A (en) * 2015-08-07 2015-11-04 中国海洋石油总公司 Oil refining reclaimed water reuse high-concentration-ratio circulating water treatment method and device
CN105502585A (en) * 2016-01-30 2016-04-20 上海丁香环境科技有限公司 Electrochemical water treatment system
CN205313292U (en) * 2016-01-19 2016-06-15 沧州信昌化工股份有限公司 Middle -size and small -size energy -conserving cooling circulating water treatment system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058336A (en) * 2013-01-24 2013-04-24 沈阳惠丰环境科技有限公司 Direct-current electrolytic treatment process and equipment for circulating cooling water
CN105016432A (en) * 2015-08-07 2015-11-04 中国海洋石油总公司 Oil refining reclaimed water reuse high-concentration-ratio circulating water treatment method and device
CN205313292U (en) * 2016-01-19 2016-06-15 沧州信昌化工股份有限公司 Middle -size and small -size energy -conserving cooling circulating water treatment system
CN105502585A (en) * 2016-01-30 2016-04-20 上海丁香环境科技有限公司 Electrochemical water treatment system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342616A (en) * 2019-07-02 2019-10-18 华电电力科学研究院有限公司 A kind of Controlling Auxiliaries in Power Plants cooling water treatment system and processing method
CN114590937A (en) * 2020-10-14 2022-06-07 青岛艾摩特环保科技有限公司 Treatment method of industrial circulating water

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Application publication date: 20170531

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