CN106744875A - A kind of method that ball milling peels off white graphite alkene - Google Patents
A kind of method that ball milling peels off white graphite alkene Download PDFInfo
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Abstract
The present invention relates to field of nanometer material technology, a kind of method that ball milling peels off white graphite alkene is specifically disclosed, specially：It is 1 by the mass volume ratio of white graphite alkene powder and surfactant:1‑500:1；It is 2 that white graphite alkene adds mass ratio with ball-milling medium:1‑1:After 10 raw material mixed dissolution, sealing ball milling is carried out under using ball milling speed for 200 800rpm；Per ball milling for a period of time after, continue to add above-mentioned ball-milling medium, the addition of ball-milling medium is 5% the 40% of white graphite alkene mass percent, and total Ball-milling Time is 120 480h；After the completion of grinding, gained powder uses ethanol wash, then dries drying, obtains white graphite alkene dispersion.This method can be effectively peeled off white graphite alkene particle, and prepared white graphite alkene has the characteristics of particle is uniform, the number of plies is few, area is big, purity is high, and can be good be dispersed in alcohol equal solvent preserves tens of days and do not produce reunion settlement action.
Description
Technical field
The present invention relates to field of nanometer material technology, and in particular to a kind of method that ball milling peels off white graphite alkene.
Background technology
White graphite alkene (h-BN) essence is the h-BN of individual layer or few layer.
The discovery of Graphene has triggered scientific circles to the research boom of two-dimensional material, and white graphite alkene piece is used as a kind of new
Two-dimensional material, because there is excellent performance widely to be studied for it.In two-dimentional h-BN, B atoms and N atoms with sp2 hydridization,
B and N presses 1:1 forms covalent bond, obtains the two dimensional surface of the side's honeycomb structure of class Graphene six, but it is on third dimension direction upper strata
Combined by Van der Waals force between layer, constituted Van der Waals stratified material.
Based on the unique two-dimensional structures of h-BN, two-dimentional h-BN materials possess many excellent performances.Two-dimentional h-BN density is low,
Specific strength is high, can apply to modified multifunctional composite；Coefficient of friction is low, is a kind of conventional lubricant；High temperature resistant,
Still possess chemical stability in 1000 DEG C of air above, can apply to the fields such as ORC；Thermal conductivity factor is big, can be used as leading
The filler of hot composite；Stratiform h-BN energy gaps are 5.0-6.0ev, with excellent insulating properties, individual layer H-BN tunnels
Its barrier height of the property in road 3.07eV, breakdown voltage 7.95MV/cm, with SO2Property it is close, and h-BN layer surfaces it is smooth,
Dangling bonds relatively less, carrier traps it is few, h-BN is the ideal carrier platform of grapheme transistor；Simultaneously because its energy gap
Greatly, it is also possible to make Ultra-Violet Laser sensitive detection parts.And h-BN is a kind of good gas sensitive, to CO2, CH4、O2, H2, NO2Deng tool
Standby high sensitivity.
Although h-BN two-dimensional materials possess above-mentioned many superperformances, at present for the extensive excellent h- of processability
BN still requires study.Prepared white graphite alkene (h-BN) yield of traditional micromechanics stripping is too low, is suitable only for Laboratory Production；Change
Learn liquid phase stripping etc. and commonly use poisonous and hazardous organic solvent, and oxidation and ion insertion etc. to its physical arrangement and electronic structure
There is certain influence, prepared h-BN electric properties are not good.Chemical vapor deposition is commonly used to prepare high performance individual layer or few
Layer h-BN, but its with high costs and yield is restricted.Current white graphite alkene still can not largely produce pure in the method for low cost
Degree is high, the white graphite alkene of function admirable, and this greatly limits its application, it is that current white graphite alkene grinds to improve white graphite alkene production capacity
One of emphasis studied carefully.Additionally, similar to many other nano materials, there is huge specific surface area in white graphite alkene, in Van der Waals
In the presence of power, the sector-meeting of white graphite alkene produces irreversible reunion, therefore its dispersive property has a strong impact on its performance and application, carries
H-BN dispersivenesses high are equally the emphasis of current research.
The content of the invention
In view of this, it is necessary to for above-mentioned problem, there is provided a kind of ball milling peels off the method for white graphite alkene, this method energy
White graphite alkene particle is effectively peeled off, the white graphite alkene that stripping is obtained has the spy that particle is uniform, the number of plies is few, area is big, purity is high
Point, good can be dispersed in alcohol equal solvent and preserve tens of days and do not produce reunion settlement action.And the method operating process letter
Single, low cost, production efficiency is high, suitable for mass industrialized production.
To achieve the above object, the present invention takes following technical scheme：
The method that ball milling of the invention peels off white graphite alkene, concretely comprises the following steps：
Step 1) by white graphite alkene (h-BN) powder, surfactant, ball-milling medium mixed dissolution after, using ball milling speed
To carry out sealing ball milling under 200-800rpm；
White graphite alkene (h-BN) powder is 1 with the mass ratio of surfactant:1-500:1, preferably 10:1-100:1；
It is 2 that the white graphite alkene (h-BN) adds mass ratio with ball-milling medium:1-1:10, preferably 1:1-1:5；
Step 2) per ball milling for a period of time after, continue add step 1 in ball-milling medium, the addition of ball-milling medium is white
The 5%-40% of Graphene mass percent, total Ball-milling Time is 120-480h；
Step 3) after the completion of grinding, gained powder uses ethanol wash, then dries drying, obtains ball milling white graphite alkene point
A prose style free from parallelism.
In mechanical milling process, abrading-ball is ceramics or metal grinding ball to the present invention, and ratio of grinding media to material is 3:1, the surface of ball-milling medium
Can be close to (the 25-40mJ/m during energy of the surface of white graphite alkene2), mechanical stripping has optimal efficiency and quality, meanwhile, addition is suitable
The range of viscosities of the impulsive force of zirconium ball and adjustment ball milling system when the ball-milling medium of amount can buffer ball milling.
Due to the change of h-BN stripping process ball millings system viscosity greatly, mill must be supplemented with ball-milling medium to control after a period of time
The viscosity of ball milling system is in the reasonable scope.
Surfactant can be effectively adsorbed in two-dimentional h-BN space forming surfaces steric hindrance and electric charge steric hindrance, prepared
White graphite alkene can be dispersed in the aqueous solution such as alcohol, acetone for a long time, and the phenomenons such as reunion sedimentation are not produced.
Further, in step 2 mechanical milling process, preceding 24h adds a ball-milling medium per 2h；After Ball-milling Time is more than 24h
A ball-milling medium is added per 24h.
Further, the ball-milling medium is low-molecular-weight alcohol and/or the ketone aqueous solution.
As preferred, in the low-molecular-weight alcohol and/or the ketone aqueous solution, the quality of low-molecular-weight alcohol and/or ketone and water
Than being 1:10-2:1, more preferably 1:5-2:1.
Used as preferred, the low-molecular-weight alcohol is：In methyl alcohol, ethanol, isopropanol, the tert-butyl alcohol, ethylene glycol at least one
Kind；The low-molecular-weight ketone is acetone.
Further, the surfactant is in having a surfactant of long-chain lewis acid or long-chain lewis base
It is at least one.
As preferred, the surfactant be have higher fatty acids of the lewis acidic C atomicities of long-chain more than 14,
At least one in aliphatic ketone, alicyclic ketone, aromatic ketone etc. and its corresponding derivative；Or alkene, the fragrance of tool long-chain lewis base
At least one in compound, amine, ether etc..
As it is further preferred that the lewis acidic surfactant of the long-chain is：Palmitic acid, palmitic acid, stearic acid,
Oleic acid, linoleic acid, palmitic acid, 18 ketone, 3- methyl cyclotridecanone, ring tetradecane ketone, the ketone of 3- 16, palmital, arbricolin, two
At least one in ten alkanals etc.；
The surfactant of the long-chain lewis base is：Palmitamide, heptadecyl-amine, octadecylamine, oleyl amine, Cholestyramine, end
Amido polyethylene glycol, polyphenylacetylene, polythiophene, kayexalate, detergent alkylate, 4- dodecyl polyanilines, polyoxy second
At least one in alkene octane alkylphenol ether, glycidol 12-14 alkyl ethers, six polyethyleneglycol margarons etc..
In h-BN there is π keys, present invention tool long-chain lewis acid, long link in B, N atom respectively with faint positive electricity, negative point
The surfactant of easy this alkali, can fully adsorb to form steric hindrance and electric charge steric hindrance on h-BN, can promote grinding, prevent
The h-BN nanometer sheets of separation are reunited.
Beneficial effects of the present invention are：
White graphite alkene piece particle diameter that the present invention is peeled off is big, thickness of thin, specific surface area are big：Thickness is respectively less than 10nm, thin skin
Thickness can as little as 1 nanometer, grain size is distributed in hundreds of nanometers to a few micrometers, and specific surface area is up to 100-1500m2/g。
Without strong acid/base raw material, toxic organic additive etc. in preparation process of the present invention, environmental protection, production efficiency is high,
Yield is big, and equipment is simple, with low cost, has a good application prospect.
Brief description of the drawings
Fig. 1 is the SEM photograph of the prepared white graphite alkene for obtaining of embodiment 1；
Fig. 2 is the AFM photos of the prepared white graphite alkene for obtaining of embodiment 1.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the embodiment of the present invention, to this hair
Bright technical scheme is made further clearly and completely to describe.It should be noted that described embodiment is only the present invention one
Section Example, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not doing
Go out the every other embodiment obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1
The specific step of preparation process of the present embodiment：Weigh 100g white graphites alkene (h-BN), 100g ethanol and 100g deionizations
Water, measures 4g polythiophenes, is put into ball grinder, and stirring is allowed to be completely dissolved.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 500rpm ball millings 240h.24h before ball milling,
25g ethanol water (ethanol is added per 2h：Water quality ratio is 1:1)；Ball-milling Time reaches 24-72h, and 25g ethanol waters are added per 24h
Solution.Ball-milling Time adds 10g ethanol waters more than every 24h after 72h, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
Fig. 1 is the SEM photograph of the present embodiment products obtained therefrom, it can be seen that being peeled off by ball milling, resulting white stone
Black alkene nanometer sheet particle diameter is more than 250nm, and nanometer sheet thickness is below 10nm；Fig. 2 is that AFM detects photo, h-BN pieces
Thickness be 6nm, part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 180m2/g。
Embodiment 2
The specific step of preparation process of the present embodiment：Weigh 100g white graphites alkene (h-BN), 100g ethanol and 100g deionizations
Water is stirred in ball grinder with glass bar.10g oleyl amines are measured, is put into ball grinder, stirring is completely dissolved it.
Sealing ball grinder, is fixed on ball mill, starts ball mill, with 450rpm ball millings 240h.In mechanical milling process
Preceding 24h, 25g ethanol waters are added per 2h.Ball-milling Time reaches 24-72h, and 25g ethanol waters are added per 24h.Ball-milling Time
After more than 72h, 10g ethanol waters are added per 24h, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 4nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 320m2/g。
Embodiment 3
The specific step of preparation process of the present embodiment：Weigh 100g white graphites alkene (h-BN), 100g acetone and 100g deionizations
Water is stirred in ball grinder with glass bar.2g palmitic acid is measured, is put into ball grinder, same stirring is completely dissolved it.
Sealing ball grinder, is fixed on planetary ball mill, starts ball mill, with 450rpm ball millings 240h.Ball milling mistake
Preceding 24h in journey, 25g aqueous acetone solutions are added per 2h.Ball-milling Time reaches 24-72h, and 25g aqueous acetone solutions are added per 24h.Ball milling
Time adds 10g aqueous acetone solutions more than every 24h after 72h, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 4nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 280m2/g。
Embodiment 4
The specific step of preparation process of the present embodiment：Weigh 100g white graphites alkene (h-BN), 50g acetone and 150g deionizations
Water, measures 4g octadecylamines, is put into ball grinder, and stirring is completely dissolved it.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 500rpm ball millings 240h.In mechanical milling process
Preceding 24h adds 25g aqueous acetone solutions per 2h.Ball-milling Time reaches 24-72h, and 25g aqueous acetone solutions are added per 24h.Ball-milling Time surpasses
Every 24 addition 10g aqueous acetone solutions after 72h are crossed, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm, big portion
The thickness for dividing h-BN pieces is 3nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 380m2/g。
Embodiment 5
The specific step of preparation process of the implementation case：Weigh 100g white graphites alkene (h-BN), 100g acetone and 100g go from
Sub- water, measures 4g 3- methyl cyclotridecanones, is put into ball grinder, and stirring is allowed to be completely dissolved.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 500rpm ball millings 240h.In mechanical milling process
Preceding 24h adds 25g aqueous acetone solutions per 2h.Ball-milling Time reaches 24-72h, and 25g aqueous acetone solutions are added per 24h.Ball-milling Time surpasses
10g aqueous acetone solutions are added per 24h after crossing 72h, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 4nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 250m2/g。
Embodiment 6
The specific step of preparation process of the implementation case：Weigh 100g white graphites alkene (h-BN), the 25g tert-butyl alcohols, 25g acetone and
50g deionized waters, measure 1g 3- methyl cyclotridecanones, are put into ball grinder, and stirring is allowed to be completely dissolved.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 700rpm ball millings 150h.In mechanical milling process
The preceding 24h addition 40g tert-butyl alcohols/aqueous acetone solutions per 2h.Ball-milling Time reaches 24-72h, the addition 25g tert-butyl alcohols/acetone water per 24h
Solution.Ball-milling Time adds the 20g tert-butyl alcohols/aqueous acetone solution more than every 24h after 72h, to ensure that ball milling system possesses suitable
Viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 4nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 380m2/g。
Embodiment 7
The specific step of preparation process of the implementation case：Weigh 100g white graphites alkene (h-BN), 250g methyl alcohol, 250g acetone and
150g deionized waters, measure 3g palmitals, are put into ball grinder, and stirring is allowed to be completely dissolved.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 300rpm ball millings 400h.In mechanical milling process
Preceding 24h adds the 10g methanol/acetone aqueous solution per 2h.Ball-milling Time reaches 24-72h, and the 8g methanol/acetone aqueous solution is added per 24h.
Ball-milling Time adds the 8g methanol/acetone aqueous solution more than every 24h after 72h, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 5nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 550m2/g。
Embodiment 8
The specific step of preparation process of the implementation case：Weigh 100g white graphites alkene (h-BN), 200g methyl alcohol, 200 isopropanols
With 300g deionized waters, 0.3g polyoxyethylene octane alkylphenol ethers are measured, be put into ball grinder, stirring is allowed to be completely dissolved.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 600rpm ball millings 300h.In mechanical milling process
Preceding 24h adds the 10g methanol/isopropanol aqueous solution per 2h.Ball-milling Time reaches 24-72h, and 20g methanol/isopropanol water is added per 24h
Solution.Ball-milling Time adds the 8g methanol/isopropanol aqueous solution more than every 24h after 72h, to ensure that ball milling system possesses suitable gluing
Degree.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, and nanometer sheet thickness is below 10nm；Big portion
The thickness for dividing h-BN pieces is 2nm, and part h-BN thickness can as little as 1nm or so.By detecting that specific surface area is 120m2/g。
Comparative example 1
The specific step of preparation process of this comparative example：Weigh 100g white graphites alkene (h-BN), 50g acetone and 150g deionizations
Water, measures 4g octadecylamines, is put into ball grinder, and stirring is completely dissolved it.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 500rpm ball millings 240h.In mechanical milling process
Decentralized medium is not supplemented, decentralized medium is all escaped in system after discovery ball milling 48h, and system dries up.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.
White graphite alkene nanometer sheet particle diameter obtained by the present embodiment gained is more than 250nm, nanometer sheet thickness major part h-BN
The thickness of piece is 40nm.By detecting that specific surface area is 10m2/g。
Comparative example 2
The specific step of preparation process of this comparative example：Weigh 100g white graphites alkene (h-BN), 50g acetone and 150g deionizations
Water, is not added with surfactant.
It is fixed on planetary ball mill after ball grinder sealing, starts ball mill, with 500rpm ball millings 240h.In mechanical milling process
Preceding 24h adds 25g aqueous acetone solutions per 2h.Ball-milling Time reaches 24-72h, and 25g aqueous acetone solutions are added per 24h.Ball-milling Time surpasses
Every 24 addition 10g aqueous acetone solutions after 72h are crossed, to ensure that ball milling system possesses suitable viscosity.
Ball milling is finished white graphite alkene by after ethanol wash, 60 DEG C of drying and processings obtain ball milling white graphite in Muffle furnace
Alkene product.White graphite alkene nanometer sheet particle diameter obtained by the present embodiment is more than 250nm, nanometer sheet thickness 40nm or so.By inspection
Survey specific surface area is 28m2/g。
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Shield scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (9)
1. a kind of method that ball milling peels off white graphite alkene, it is characterised in that concretely comprise the following steps：
Step 1) by white graphite alkene powder, surfactant, ball-milling medium mixed dissolution after, it is 200- to use ball milling speed
Sealing ball milling is carried out under 800rpm；
The white graphite alkene powder is 1 with the mass volume ratio of surfactant:1-500:1；The white graphite alkene is situated between with ball milling
It is 2 that matter adds mass ratio:1-1:10；
Step 2) per ball milling for a period of time after, continue to add the ball-milling medium in step 1, the addition of ball-milling medium is white graphite
The 5%-40% of alkene mass percent, total Ball-milling Time is 120-480h；
Step 3) grinding after the completion of, gained powder uses ethanol wash, then dries drying, obtain ball milling white graphite alkene dispersion
Body.
2. the method that ball milling according to claim 1 peels off white graphite alkene, it is characterised in that the white graphite alkene (h-BN)
Powder is 10 with the mass ratio of surfactant:1-100:1；The white graphite alkene (h-BN) and ball-milling medium add the mass ratio to be
1:1-1:5。
3. the method that ball milling according to claim 1 and 2 peels off white graphite alkene, it is characterised in that step 2 mechanical milling process
In, preceding 24h adds a ball-milling medium per 2h；Ball-milling Time adds a ball-milling medium more than every 24h after 24h.
4. the method that ball milling according to claim 1 and 2 peels off white graphite alkene, it is characterised in that the ball-milling medium is
Low-molecular-weight alcohol and/or the ketone aqueous solution.
5. the method that ball milling according to claim 4 peels off white graphite alkene, it is characterised in that the low-molecular-weight alcohol and/
Or the ketone aqueous solution, it is low-molecular-weight alcohol and/or ketone and the mass ratio of water is 1:10-2:1.
6. the method that ball milling according to claim 4 peels off white graphite alkene, it is characterised in that the low-molecular-weight alcohol is：
At least one in methyl alcohol, ethanol, isopropanol, the tert-butyl alcohol, ethylene glycol；The low-molecular-weight ketone is acetone.
7. the method that ball milling according to claim 1 and 2 peels off white graphite alkene, it is characterised in that the surfactant
It is at least one in the surfactant of tool long-chain lewis acid or long-chain lewis base.
8. the method that ball milling according to claim 7 peels off white graphite alkene, it is characterised in that the surfactant is tool
In higher fatty acids of the lewis acidic C atomicities of long-chain more than 14, aliphatic ketone, alicyclic ketone, aromatic ketone and its corresponding derivative
At least one；Or at least one in alkene, aromatic compound, amine, the ether of tool long-chain lewis base.
9. the method that ball milling according to claim 8 peels off white graphite alkene, it is characterised in that the long-chain is lewis acidic
Surfactant is：Palmitic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, palmitic acid, 18 ketone, 3- methyl cyclotridecanone, ring
Tetradecane ketone, at least one in the ketone of 3- 16, palmital, arbricolin, eicosane aldehyde；
The surfactant of the long-chain lewis base is：Palmitamide, heptadecyl-amine, octadecylamine, oleyl amine, Cholestyramine, end amido
Polyethylene glycol, polyphenylacetylene, polythiophene, kayexalate, detergent alkylate, 4- dodecyl polyanilines, polyoxyethylene are pungent
At least one in alkylbenzene phenolic ether, glycidol 12-14 alkyl ethers, six polyethyleneglycol margarons.
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| CN201611140745.3A CN106744875A (en) | 2016-12-12 | 2016-12-12 | A kind of method that ball milling peels off white graphite alkene |
| CN201710714410.6A CN107352516A (en) | 2016-12-12 | 2017-08-18 | A kind of method that ball milling peels off white graphite alkene |
| PCT/CN2017/098056 WO2018107795A1 (en) | 2016-12-12 | 2017-08-18 | Method for exfoliating hexagonal boron nitride (h-bn) by means of ball milling |
| CN201710713135.6A CN107381643A (en) | 2016-12-12 | 2017-08-18 | A kind of mechanical stripping Van der Waals stratified material prepares the universal method of two-dimensional material |
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| CN201710713135.6A Pending CN107381643A (en) | 2016-12-12 | 2017-08-18 | A kind of mechanical stripping Van der Waals stratified material prepares the universal method of two-dimensional material |
| CN201710714410.6A Pending CN107352516A (en) | 2016-12-12 | 2017-08-18 | A kind of method that ball milling peels off white graphite alkene |
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| CN201710714410.6A Pending CN107352516A (en) | 2016-12-12 | 2017-08-18 | A kind of method that ball milling peels off white graphite alkene |
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| WO2018107795A1 (en) * | 2016-12-12 | 2018-06-21 | 广东纳路纳米科技有限公司 | Method for exfoliating hexagonal boron nitride (h-bn) by means of ball milling |
| CN109749374A (en) * | 2019-01-08 | 2019-05-14 | 常州兴烯石墨烯科技有限公司 | Modified white graphite alkene terylene compound slice of a kind of in-situ polymerization and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018107795A1 (en) * | 2016-12-12 | 2018-06-21 | 广东纳路纳米科技有限公司 | Method for exfoliating hexagonal boron nitride (h-bn) by means of ball milling |
| CN109749374A (en) * | 2019-01-08 | 2019-05-14 | 常州兴烯石墨烯科技有限公司 | Modified white graphite alkene terylene compound slice of a kind of in-situ polymerization and preparation method thereof |
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| CN107381643A (en) | 2017-11-24 |
| WO2018107795A1 (en) | 2018-06-21 |
| CN107352516A (en) | 2017-11-17 |
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