CN106744756A - Phosphine gas produce and using and nitrogen dilution system - Google Patents
Phosphine gas produce and using and nitrogen dilution system Download PDFInfo
- Publication number
- CN106744756A CN106744756A CN201610366915.3A CN201610366915A CN106744756A CN 106744756 A CN106744756 A CN 106744756A CN 201610366915 A CN201610366915 A CN 201610366915A CN 106744756 A CN106744756 A CN 106744756A
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- CN
- China
- Prior art keywords
- nitrogen
- phosphine
- gas
- alarm
- generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/06—Hydrogen phosphides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/16—Preserving with chemicals
- A23B9/18—Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Alarm Devices (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
A kind of phosphine gas producing and using and nitrogen dilution system, the phosphine gas produce with using and nitrogen dilution system include power supply, source nitrogen, nitrogen gas purity detector, pressure sensor, phosphine generator, phosphine concentration detector, connecting line and control valve, alarm and protection circuit；The source nitrogen gas outlet is connected with phosphine generator air inlet, can be to pure nitrogen gas are injected in phosphine generator, for the concentration of the phosphine gas of dilution phosphine generator generation.
Description
(1) technical field
The present invention relates to a kind of producing and use device and dilution device for phosphine gas, and in particular to hydrogen phosphide occurs
Device and nitrogen dilution accessory system.
(2) background technology
Carbon dioxide is required for when phosphine generator is used in the market to dilute the phosphine gas of generation
Concentration, to reach the purpose of safety in production.
(3) content of the invention
The technical problems to be solved by the invention are to be required for carbon dioxide when being used for existing phosphine generator
Gas dilutes the present situation of the concentration of the phosphine gas of generation, there is provided one kind easily produces, inexpensive, and Non-combusting gas dilute
The method of the concentration of phosphine gas.
A kind of phosphine gas of the invention produce and using and nitrogen dilution system, the phosphine gas produce
Include power supply, phosphine generator, source nitrogen (various nitrogen making machines, small nitrogen, elevated pressure nitrogen with use and nitrogen dilution system
Gas cylinder or tank), connecting line and control valve, pressure sensor, nitrogen gas purity detector, phosphine concentration detector, alarm
And protection circuit；
The phosphine generator provides the phosphine gas that aluminum phosphate medicament is produced with water reaction；
It is higher than 98.5% that the source nitrogen (various nitrogen making machines, small nitrogen, high-pressure nitrogen bottle or tank) provides purity
Nitrogen；
The connecting line and control valve are used to connect source nitrogen, phosphine generator and grain depot circulation fumigating system.
Preferably, the phosphine generator can be shown in that fragment is counted and control system, the patent No. 201210374239.6.
It has the function of controlling the aluminum phosphate unit interval to feed intake quantity.
The beneficial effects of the present invention are：
(1) nitrogen is generally nonflammable and does not support burning, meets as the condition of diluent gas, plays safety in production
Effect.
(2) nitrogen produce it is easier than carbon dioxide because nitrogen (N2) accounts for 78%, carbon dioxide in air
(CO2) 0.03% is accounted for.
(3) nitrogen making machine can be minimized.
(4) producing for nitrogen greatly reduces energy consumption than same volume carbon dioxide preparation, reduces pollutant emission, net to air
Change contributes.
(5) system operatio safety, and cost is cheap, is suitable for basic unit's grain depot application.
(4) illustrate
Fig. 1 is structured flowchart of the invention；
Fig. 2 is workflow diagram of the invention；
(5) specific embodiment
Embodiment and accompanying drawing are explained to the present invention simultaneously below, but protection scope of the present invention is not limited to
This.
Reference picture 1, a kind of phosphine generator and nitrogen dilution system, the phosphine generator and nitrogen dilution system
Including power supply, source nitrogen, nitrogen gas purity detector, pressure sensor, phosphine generator, phosphine concentration detector, connection
Pipeline and control valve, alarm and protection circuit；
The power supply is connected with source nitrogen, phosphine generator, for providing electric energy；
The source nitrogen gas outlet is connected with phosphine generator air inlet, can be to injecting purity nitrogen in phosphine generator
Gas, the concentration of the phosphine gas produced for dilution phosphine generator；
The pressure sensor is connected with the air accumulator of nitrogen making machine, for detecting the pressure in air accumulator；
The nitrogen gas purity detector is connected with the export pipeline of source nitrogen, the concentration for detecting nitrogen；
The phosphine concentration detector is connected with the export pipeline of phosphine generator, for detecting phosphine gas
Concentration；
The connecting line and control valve are connected with source nitrogen, phosphine generator and recirculation fumigation loop, construction nitrogen,
Gas passage between phosphine gas and recirculation fumigation loop；
The alarm of the pressure sensor is used to be reported when the pressure in the air accumulator of nitrogen making machine is less than 0.05Mpa
It is alert；
The alarm of the nitrogen gas purity detector is used to be alarmed when nitrogen gas concn value is less than 98.5%；
The alarm of the phosphine concentration detector is used for when phosphine concentration value is higher than 1.79% (26g/m3) when enter
Row alarm.
Reference picture 2, when the present invention is used, starts nitrogen making machine first, the pressure of air accumulator is more than 0.05Mpa.Then it is right
The alarming value of pressure sensor, nitrogen gas purity detector and phosphine concentration detector is set.Next step opens source nitrogen
Section door, then starts phosphine generator, and the phosphine gas that phosphine generator is produced dilute through pure nitrogen gas, and concentration value reaches
Less than 1.79% (26g/m3) after, into recirculation fumigation loop.In this course when the reservoir pressure of nitrogen making machine is less than
The alarm of pressure sensor will alarm during 0.05Mpa, while the protection circuit of correlation makes phosphine generator out of service.
When the reservoir pressure of nitrogen making machine is more than 0.05Mpa, phosphine generator can restart.When the gas purity of source nitrogen
When value is less than 98.5%, the alarm of nitrogen gas purity detector will alarm, while the protection circuit of correlation occurs hydrogen phosphide
Device is out of service.When the Reinheitszahl of nitrogen is higher than 98.5%, phosphine generator can restart.Work as phosphine generator
Concentration value is higher than 1.79% (26g/m after the phosphine gas of generation dilute through pure nitrogen gas3) standard value when, phosphine concentration detection
The alarm of instrument will alarm, while the protection circuit of correlation makes phosphine generator out of service.Treat that phosphine generator is produced
Concentration value is less than 1.79% (26g/m after raw phosphine gas dilute through pure nitrogen gas3) standard value when, phosphine generator can be with
Restarting.
Concentration value is less than 1.79% (26g/m3) phosphine gas of standard value are delivered to recirculation fumigation loop by the road.
Claims (3)
1. a kind of phosphine gas produce and using and nitrogen dilution system, it is characterised in that：The system of the phosphine gas
Take includes power supply, phosphine generator, source nitrogen (various nitrogen making machines, small nitrogen, high pressure with use and nitrogen dilution system
Nitrogen cylinder or tank), connecting line, control valve, pressure sensor and alarm, nitrogen gas purity detector and alarm, hydrogen phosphide
Gas concentration detector and alarm and protection circuit；
The power supply is connected with source nitrogen, phosphine generator, for providing electric energy；
The source nitrogen gas outlet is connected with phosphine generator air inlet, can be used to pure nitrogen gas are injected in phosphine generator
The concentration of the phosphine gas produced in dilution phosphine generator；
The pressure sensor and alarm are connected with the nitrogen air accumulator of nitrogen making machine, for detecting the pressure in nitrogen air accumulator
Value；
The nitrogen gas purity detector and alarm are connected with the export pipeline of source nitrogen, the concentration value for detecting nitrogen；
The phosphine concentration detector and alarm are connected with the export pipeline of phosphine generator, for detecting phosphatization hydrogen
The concentration value of body；
The connecting line and control valve are dense with source nitrogen, phosphine generator, nitrogen gas purity detector and alarm, hydrogen phosphide
Degree detector and alarm and the connection of recirculation fumigation loop, construction nitrogen, the gas between phosphine gas and recirculation fumigation loop
Body passage；The phosphine gas produce with using and nitrogen dilution system running in when the reservoir pressure of nitrogen making machine
The alarm of pressure sensor will alarm during less than 0.05Mpa, while the protection circuit of correlation stops phosphine generator
Operation, when the reservoir pressure of nitrogen making machine is more than 0.05Mpa, phosphine generator can restart；When the gas of source nitrogen
When body Reinheitszahl is less than 98.5%, the alarm of nitrogen gas purity detector will alarm, while the protection circuit of correlation makes phosphatization
Hydrogen generator is out of service, and when the Reinheitszahl of nitrogen is higher than 98.5%, phosphine generator can restart；Work as hydrogen phosphide
Concentration value is higher than 1.79% (26g/m after the phosphine gas that generator is produced dilute through pure nitrogen gas3) standard value when, hydrogen phosphide is dense
The alarm for spending detector will alarm, while the protection circuit of correlation makes phosphine generator out of service, treat that hydrogen phosphide is sent out
Concentration value is less than 1.79% (26g/m after the phosphine gas that raw device is produced dilute through pure nitrogen gas3) standard value when, hydrogen phosphide occur
Device can restart；Concentration value is less than 1.79% (26g/m after being diluted through pure nitrogen gas3) standard value phosphine gas by the road
It is delivered to recirculation fumigation loop.
2. a kind of phosphine gas according to claim 1 produce and using and nitrogen dilution system, it is characterised in that
The source nitrogen can be small-size molecular-sieve space division method nitrogen making machine.
3. a kind of phosphine gas according to claim 1 produce and using and nitrogen dilution system, it is characterised in that
The phosphine generator can see that fragment is counted and control system, the patent No. 201210374239.6.It has control phosphorus
Changing the aluminium unit interval feeds intake the function of quantity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610366915.3A CN106744756B (en) | 2016-05-31 | 2016-05-31 | Phosphine gas produce with use and nitrogen dilution system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610366915.3A CN106744756B (en) | 2016-05-31 | 2016-05-31 | Phosphine gas produce with use and nitrogen dilution system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106744756A true CN106744756A (en) | 2017-05-31 |
| CN106744756B CN106744756B (en) | 2019-07-09 |
Family
ID=58972138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610366915.3A Active CN106744756B (en) | 2016-05-31 | 2016-05-31 | Phosphine gas produce with use and nitrogen dilution system |
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| Country | Link |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2402144Y (en) * | 2000-01-13 | 2000-10-25 | 沈美庆 | High-efficiency fumigant producing and delivery and dispensing device |
| CN2403045Y (en) * | 2000-01-13 | 2000-10-25 | 沈美庆 | High-efficiency insect prevention and killing automatic monitoring device |
| CN201697767U (en) * | 2010-06-25 | 2011-01-05 | 国合建设集团有限公司 | Device for taking various tests on air tightness of concrete fumigating storehouse |
| CN102284224A (en) * | 2005-05-03 | 2011-12-21 | 高级技术材料公司 | Fluid supply system, fumigating system and application method thereof |
| CN103714380A (en) * | 2012-10-08 | 2014-04-09 | 黄建 | Fragment counting and control system |
| CN103889894A (en) * | 2011-08-23 | 2014-06-25 | 先进技术材料股份有限公司 | Systems and methods for supplying phosphine for fumigation applications |
-
2016
- 2016-05-31 CN CN201610366915.3A patent/CN106744756B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2402144Y (en) * | 2000-01-13 | 2000-10-25 | 沈美庆 | High-efficiency fumigant producing and delivery and dispensing device |
| CN2403045Y (en) * | 2000-01-13 | 2000-10-25 | 沈美庆 | High-efficiency insect prevention and killing automatic monitoring device |
| CN102284224A (en) * | 2005-05-03 | 2011-12-21 | 高级技术材料公司 | Fluid supply system, fumigating system and application method thereof |
| CN201697767U (en) * | 2010-06-25 | 2011-01-05 | 国合建设集团有限公司 | Device for taking various tests on air tightness of concrete fumigating storehouse |
| CN103889894A (en) * | 2011-08-23 | 2014-06-25 | 先进技术材料股份有限公司 | Systems and methods for supplying phosphine for fumigation applications |
| CN103714380A (en) * | 2012-10-08 | 2014-04-09 | 黄建 | Fragment counting and control system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106744756B (en) | 2019-07-09 |
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