CN106744732A - The method of green syt two dimension transition metal carbide or nitride nano piece - Google Patents
The method of green syt two dimension transition metal carbide or nitride nano piece Download PDFInfo
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- CN106744732A CN106744732A CN201710021027.2A CN201710021027A CN106744732A CN 106744732 A CN106744732 A CN 106744732A CN 201710021027 A CN201710021027 A CN 201710021027A CN 106744732 A CN106744732 A CN 106744732A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
- C01P2004/22—Particle morphology extending in two dimensions, e.g. plate-like with a polygonal circumferential shape
Abstract
The invention discloses a kind of green syt two dimension transition metal carbide or the method for nitride nano piece, it includes：After corrosion intercalator mixes with ternary layered ceramic material and carry out corrosion intercalation, then two-dimentional transition metal carbide nanometer sheet or two dimension transition metal nitride nanometer sheet will be obtained by shearing decentralized processing.Two-dimentional transition metal carbide or nitride nano piece synthesis technique that the present invention is provided, environmental protection, process is simple, it is easy to operate, flow is safely controllable, time consumption and energy consumption is few, enriches the synthesis mode of two-dimentional transition metal carbide or nitride nano piece, can effectively facilitate the popularization and application of two-dimentional transition metal carbide or nitride nano piece.
Description
Technical field
The present invention be more particularly directed to a kind of green syt two dimension transition metal carbide or the method for nitride nano piece, belong to
Two-dimension nano materials preparing technical field.
Background technology
Two-dimension nano materials are as a kind of emerging nano material because its larger surface area and very thin thickness are wide
It is general to be paid close attention to by researchers.Particularly in recent years, researcher has found and has synthesized a kind of two-dimentional transition metal carbide
Or nitride nano piece, the presoma of this two-dimension nano materials shows class both from ternary layered ceramic material
The property of Graphene is similar to, so it can be two-dimentional transition metal carbide or nitride by Uniform Name.With research after
It is continuous, increasing two dimension transition metal carbide or nitride nano piece the energy, biomedicine, catalysis, lubrication and
Field of compound material shows huge application potential.At present, this class two-dimensional transition metal carbide or nitride nano piece master
If by the metal atomic layer in the method etching ternary layered ceramic material with selective corrosion, then peeled off by intercalation
Method and obtain.But such synthetic method can directly affect the surface nature of product, its range of application is limited, and due to anti-
Answering needs, using a large amount of fluorine-containing acid mediums, have huge harm to the safety of researcher in raw material.
Therefore, industry is badly in need of finding a kind of new two-dimentional transition metal carbide or nitride nano piece synthetic method, with
Improve the surface composition of sample, and reduce the usage amount of fluorine-containing material as far as possible.
The content of the invention
It is a primary object of the present invention to provide a kind of green syt two dimension transition metal carbide or nitride nano piece
Method, to overcome deficiency of the prior art.
To realize aforementioned invention purpose, the technical solution adopted by the present invention includes：
A kind of method that the embodiment of the invention provides green syt two dimension transition metal carbide or nitride nano piece,
It includes：Will be after corrosion intercalator mixes with ternary layered ceramic material and carries out corrosion intercalation, then by shearing dispersion
Treatment obtains two-dimentional transition metal carbide nanometer sheet or two-dimentional transition metal nitride nanometer sheet.
Further, the ternary layered ceramic material includes the first material layer of alternately laminated setting and the second material
Layer, the first material layer includes at least one element and transition metal in C and N, and the second material layer includes
At least one in Al, S, Si element.
Further, the transition metal is including Ti, Nb, V, Mo, Ga, Cr or Ta etc., and not limited to this.
Further, the ternary layered ceramic material includes ternary layered transition metal carbide or ternary layered
Transition metal nitride.
Further, the corrosion intercalator includes organic base.
Further, the mode of the shearing decentralized processing includes agitation, vibration or ultrasonic power.
Further, this method is also applicable other ternary layered ceramic materials and other corresponding organic bases, in view of three
First laminate ceramic is very easy to passivation, it is possible to acid medium, such as hydrochloric acid and fluoride, fluorine hydrogenation are added in synthesis
The pretreatment ternary ceramic material such as ammonium, hydrofluoric acid is used to Etch Passivation.
Compared with prior art, the present invention is provided a kind of two-dimentional transition metal carbide or nitride nano piece synthesis work
Skill environmental protection, process is simple, and easy to operate, flow is safely controllable, and time consumption and energy consumption is few, enrich two-dimentional transition metal carbide or
The synthesis mode of person's nitride nano piece, the popularization that can effectively facilitate two-dimentional transition metal carbide or nitride nano piece should
With.
Brief description of the drawings
Fig. 1 is the photo of two-dimentional transition metal carbide nanometer sheet dispersion liquid in the embodiment of the present invention 4；
Fig. 2 is the transmission electron microscope picture of two-dimentional transition metal carbide nanometer sheet in the embodiment of the present invention 4；
Fig. 3 is the atomic force microscope images of two-dimentional transition metal carbide nanometer sheet in the embodiment of the present invention 4.
Specific embodiment
In view of deficiency of the prior art, inventor is able to propose of the invention through studying for a long period of time and largely put into practice
Technical scheme.The technical scheme, its implementation process and principle etc. will be further explained in conjunction with specific embodiments as follows
It is bright.
The method of a kind of green syt two dimension transition metal carbide provided in an embodiment of the present invention or nitride nano piece
Including：Will be after corrosion intercalator mixes with ternary layered ceramic material and carries out corrosion intercalation, then by shearing at dispersion
Reason obtains two-dimentional transition metal carbide nanometer sheet or two-dimentional transition metal nitride nanometer sheet.
Further, the ternary layered ceramic material includes the first material layer of alternately laminated setting and the second material
Layer, the first material layer includes at least one element and transition metal in C and N, and the second material layer includes
At least one in the major elements such as Al, S, Si.
Further, the transition metal is including Ti, Nb, V, Mo, Ga, Cr or Ta etc., and not limited to this.
Further, the ternary layered ceramic material is replaced by a plurality of first material layers and a plurality of second material layers
Stacking is formed.
Further, the ternary layered ceramic material includes ternary layered transition metal carbide or ternary layered
Transition metal nitride.
For example, the ternary layered ceramic material can include but is not limited to Ti2AlC, Ti2AlN, Ti2AlC0.5N0.5,
Ti2SC, (Ti0.5,Nb0.5)2AlC, (Ti0.5,V0.5)2AlC, V2AlC, Nb2AlC, Mo2GaC, Ti3AlC2, Ti3SiC2, (V0.5,
Cr0.5)3AlC2, Ti3AlCN, (Ti0.5,V0.5)3AlC2, Ta4AlC3, Nb4AlC3Or (V0.5,Nb0.5)4AlC3In any one or
Two or more combinations, and not limited to this.
Further, the corrosion intercalator is preferably organic base.
For example, the corrosion intercalator can include but is not limited to TMAH (TMAOH), tetrabutylammonium hydroxide
Ammonium (TBAOH), triethanolamine (TEA), sodium ethylene diamine tetracetate, urea, dimethyl sulfoxide (DMSO) (DMSO), methylamine, ethamine, ethanol
Amine, ethylenediamine, isopropylamine, 1,3- propane diamine, 1,2- propane diamine, tripropyl amine (TPA), triethanolamine, butylamine, isobutyl amine, tert-butylamine, oneself
Amine, octylame, aniline, benzylamine, cyclohexylamine, pyridine, hexa, 2- chlorophenols, 3- chlorophenols, 4- chlorophenols, o-aminophenol,
Amino-phenol, para-aminophenol, ortho-aminotoluene, meta-aminotoluene, para-totuidine, any one in diphenylamines and benzidine or two
Plant the combination of the above, and not limited to this.
In some more preferred embodiment, the organic base is 5 with the usage ratio of ternary layered ceramic material
~15ml：1g.
Further, the mode of the shearing decentralized processing is including agitation, vibration or ultrasonic power etc., but is not limited to
This.
In some more specific embodiment, green syt two dimension transition metal carbide or nitride nano
The method of piece can include：
It is 5~15ml by usage ratio：The corrosion intercalator of 1g mixes with ternary layered ceramic material and carries out corrosion to be inserted
Layer reaction more than 12h, preferably 12~36h, isolate the solid formation in mixed reactant afterwards, then clean, and collect in obtaining
Between product；
The intermediate product is scattered in solvent afterwards, and carries out shearing decentralized processing, obtain two-dimentional transition metal carbon
Compound nanometer sheet or two-dimentional transition metal nitride nanometer sheet.
Further, the solvent includes water, ethanol, acetone and water and the mixing of these organic solvent different proportions
Thing, it may be preferred to be water, using water as solvent, not only safer environmental protection, low cost, and preferably can cure using biological
Learn and energy field, with wide applicability and adaptability.
In some more specifically case study on implementation, green syt two dimension transition metal carbide or nitride nano
The method of piece can include：By organic base and ternary layered ceramic material according to 5~15ml：The ratio of 1g is sufficiently mixed, and goes forward side by side
Row corrosion 12~36h of intercalation, removes unnecessary organic base using ultra-pure water centrifuge washing afterwards, then scattered by shearing
Be dispersed in the precipitation of collection in ultra-pure water and keep dispersion liquid to be uniformly dispersed by method, is centrifuged off unstripped particle, obtains
Obtain required two-dimentional transition metal carbide or nitride nano piece dispersion liquid.
Postscript, in view of ternary layered ceramic material may be passivated during preservation and form passivation layer on surface,
And then ternary layered ceramic material may be hindered and corrode the reaction between intercalator, to overcome such problem, can be to entering
Row ternary ceramic material is pre-processed, and is used to remove the passivation layer.
Accordingly, in some embodiments, described green syt two dimension transition metal carbide or nitride nano
The method of piece may also include：Removed with corrosive agent and covered in the passivation layer of ternary layered ceramic material surface, afterwards again by ternary
Laminate ceramic mixes with corrosion intercalator carries out corrosion intercalation.
Preferably, the corrosive agent includes hydrochloric acid, fluoride, ammonium acid fluoride or hydrofluoric acid etc., and not limited to this.
Technical scheme is more specifically illustrated below in conjunction with some embodiments and accompanying drawing.
Embodiment 1：By TMAOH slowly and V2AlC powder be sufficiently mixed (both ratios be 10ml：1g), using TMAOH pairs
V2AlC carries out corroding intercalation 36h at room temperature, using ultra-pure water centrifuge washing, washes away unnecessary organic base, collects precipitation, passes through
The precipitation collected is dispersed in the ultra-pure water of 300ml and keeps dispersion liquid to be uniformly dispersed by ultrasonic power, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal vanadium carbide nanometer sheet dispersion liquid of presentation stablized.
Reference examples 1：With the V that embodiment 1 is addressed2AlC powder as raw material, by 50%HF and V2AlC powder is sufficiently mixed
(both ratios are 10ml：1g), carry out corroding intercalation 90h at room temperature, ultra-pure water centrifuge washing is collected and precipitated, ultrasonic disperse,
Obtain two-dimentional transition metal vanadium carbide nanometer sheet dispersion liquid.But two-dimentional transition metal vanadium carbide nanometer sheet obtained in conventional method
There are a large amount of obvious affected zones on surface, and edge is irregular.
Embodiment 2：By TMAOH slowly and Nb2AlC powder be sufficiently mixed (both ratios be 10ml：1g), using TMAOH
To Nb2AlC carries out corroding intercalation 36h at room temperature, using ultra-pure water centrifuge washing, washes away unnecessary organic base, collects precipitation, leads to
Cross ultrasonic power to be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed the precipitation collected, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal niobium carbide nanometer sheet dispersion liquid of presentation stablized.
Reference examples 2：With the Nb that embodiment 2 is addressed2AlC powder as raw material, by 50%HF and Nb2AlC powder is sufficiently mixed
(both ratios are 10ml：1g), carry out corroding intercalation 90h at room temperature, ultra-pure water centrifuge washing is collected and precipitated, ultrasonic disperse,
Obtain two-dimentional transition metal niobium carbide nanometer sheet dispersion liquid.But two-dimentional transition metal niobium carbide nanometer sheet obtained in conventional method
There are a large amount of obvious affected zones on surface, and edge is irregular.
Embodiment 3：By TMAOH slowly and Ti2AlC powder be sufficiently mixed (both ratios be 10ml：1g), using TMAOH
To Ti2AlC carries out corroding intercalation 12h at room temperature, using ultra-pure water centrifuge washing, washes away unnecessary organic base, collects precipitation, leads to
Cross hand mode to be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed the precipitation collected, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Reference examples 3：With the Ti that embodiment 3 is addressed2AlC powder as raw material, by 10%HF and Ti2AlC powder is sufficiently mixed
(both ratios are 10ml：1g), carry out corroding intercalation 10h at room temperature, ultra-pure water centrifuge washing is collected and precipitated, hand dispersion,
Obtain two-dimentional transition metal carbide nanometer sheet dispersion liquid.But two-dimentional transition metal carbide nanometer sheet obtained in conventional method
There are a large amount of obvious affected zones on surface, and edge is irregular.
Embodiment 4：By TMAOH slowly and Ti3AlC2Powder be sufficiently mixed (both ratios be 10ml：1g), using TMAOH
To Ti3AlC2Carry out corroding intercalation 24h at room temperature, using ultra-pure water centrifuge washing, wash away unnecessary organic base, collect precipitation, lead to
Cross mode of oscillation to be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed the precipitation collected, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Reference examples 4：With the Ti that embodiment 4 is addressed3AlC2Powder as raw material, by 50%HF and Ti3AlC2Powder is fully mixed
(both ratios are 10ml for conjunction：1g), carry out corroding intercalation 2h at room temperature, ultra-pure water centrifuge washing collects precipitation, vibration point
Dissipate, obtain two-dimentional transition metal carbide nanometer sheet dispersion liquid.But two-dimentional transition metal carbide is received obtained in conventional method
There are a large amount of obvious affected zones on rice piece surface, and edge is irregular.
Embodiment 5：By TMAOH slowly and Ti3AlCN powder be sufficiently mixed (both ratios be 10ml：1g), using TMAOH
To Ti3AlCN carries out corroding intercalation 18h at room temperature, using ultra-pure water centrifuge washing, washes away unnecessary organic base, collects precipitation,
By mode of oscillation by collect precipitation be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed, 3500rpm from
Heart 15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Reference examples 5：With the Ti that embodiment 5 is addressed3AlCN powder as raw material, by 30%HF and Ti3AlCN powder is fully mixed
(both ratios are 10ml for conjunction：1g), carry out corroding intercalation 18h at room temperature, ultra-pure water centrifuge washing collects precipitation, vibration point
Dissipate, obtain two-dimentional transition metal carbide nanometer sheet dispersion liquid.But two-dimentional transition metal carbide is received obtained in conventional method
There are a large amount of obvious affected zones on rice piece surface, and edge is irregular.
Embodiment 6：By TBAOH slowly and Ti3AlC2Powder be sufficiently mixed (both ratios be 10ml：1g), using TBAOH
To Ti3AlC2Carry out corroding intercalation 20h at room temperature, using ultra-pure water centrifuge washing, wash away unnecessary organic base, collect precipitation, lead to
Cross ultrasonic power to be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed the precipitation collected, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Embodiment 7：By TEA slowly and Ti3AlC2Powder be sufficiently mixed (both ratios be 10ml：1g), using TEA pairs
Ti3AlC2Carry out corroding intercalation 28h at room temperature, using ultra-pure water centrifuge washing, wash away unnecessary organic base, collect precipitation, pass through
The precipitation collected is dispersed in the ultra-pure water of 300ml and keeps dispersion liquid to be uniformly dispersed by ultrasonic power, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Embodiment 8：By the sodium ethylene diamine tetracetate aqueous solution slowly and Ti3AlC2Powder is sufficiently mixed that (both ratio are
10ml：1g), using the sodium ethylene diamine tetracetate aqueous solution to Ti3AlC2Carry out corroding intercalation 20h at room temperature, be centrifuged using ultra-pure water
Washing, washes away unnecessary organic base, collects precipitation, and the precipitation collected is dispersed in the ultra-pure water of 300ml by ultrasonic power
And keep dispersion liquid to be uniformly dispersed, 3500rpm centrifugations 15min removes unstripped particle, the presentation polygon stablized
Two-dimentional transition metal carbide nanometer sheet dispersion liquid.
Embodiment 9：By DMSO slowly and Ti3AlC2Powder be sufficiently mixed (both ratios be 10ml：1g), using DMSO pairs
Ti3AlC2Carry out corroding intercalation 20h at room temperature, using ultra-pure water centrifuge washing, wash away unnecessary organic base, collect precipitation, pass through
The precipitation collected is dispersed in the ultra-pure water of 300ml and keeps dispersion liquid to be uniformly dispersed by ultrasonic power, 3500rpm centrifugations
15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Embodiment 10：By monoethanolamine slowly and Ti3AlC2Powder be sufficiently mixed (both ratios be 10ml：1g), using ethanol
Amine is to Ti3AlC2Carry out corroding intercalation 20h at room temperature, using ultra-pure water centrifuge washing, wash away unnecessary organic base, collect precipitation,
By ultrasonic power by collect precipitation be dispersed in the ultra-pure water of 300ml and keep dispersion liquid to be uniformly dispersed, 3500rpm from
Heart 15min removes unstripped particle, the polygonal two-dimentional transition metal carbide nanometer sheet dispersion liquid of presentation stablized.
Additionally, mode of the inventor referring also to embodiment 1~10, using the ternary layered pottery of other previously recited
Ceramic material and other corrosion intercalators are tested, and find obtain two-dimentional transition metal carbide nanometer sheet or two-dimentional mistake
Metal nitride nanometer sheet is crossed, and yield is higher, the dispersion that these two-dimensional nano pieces in a solvent can be uniform and stable, and still protect
Hold good surface nature.
The synthesis technique of two-dimentional transition metal carbide of the invention or nitride nano piece is used as raw material by organic base
Two-dimentional transition metal carbide or nitride nano piece with ternary layered ceramic materials synthesis, the technique are substantially distinguished from biography
The acid etching synthesis technique of system, environmental protection, building-up process is simple, and easy to operate, flow is safely controllable, and time consumption and energy consumption is few, no
Two-dimentional transition metal carbide or nitride nano piece synthesis mode can be only supplemented and enrich, and also to prepare in the future
New two-dimentional transition metal carbide or nitride nano piece and related application open new window.
It should be appreciated that above-described embodiment is only explanation technology design of the invention and feature, this is familiar with its object is to allow
The personage of item technology will appreciate that present disclosure and implement according to this that it is not intended to limit the scope of the present invention.It is all
According to the equivalent change or modification that spirit of the invention is made, should all be included within the scope of the present invention.
Claims (10)
1. the method for a kind of green syt two dimension transition metal carbide or nitride nano piece, it is characterised in that including：By corruption
After erosion intercalator and ternary layered ceramic material mix and carry out corrosion intercalation at room temperature, then by shearing decentralized processing
Obtain two-dimentional transition metal carbide nanometer sheet or two-dimentional transition metal nitride nanometer sheet.
2. according to claim 1 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The ternary layered ceramic material includes the first material layer and second material layer of alternately laminated setting, first material
The bed of material includes at least one element and transition metal in C and N, and the second material layer is included in Al, S, Si element
At least one；Preferably, the transition metal includes Ti, Nb, V, Mo, Ga, Cr or Ta.
3. according to claim 2 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The ternary layered ceramic material includes ternary layered transition metal carbide or ternary layered transition metal nitride.
4. according to claim 2 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The ternary layered ceramic material includes Ti2AlC, Ti2AlN, Ti2AlC0.5N0.5, Ti2SC, (Ti0.5,Nb0.5)2AlC,
(Ti0.5,V0.5)2AlC, V2AlC, Nb2AlC, Mo2GaC, Ti3AlC2, Ti3SiC2, (V0.5,Cr0.5)3AlC2, Ti3AlCN, (Ti0.5,
V0.5)3AlC2, Ta4AlC3, Nb4AlC3Or (V0.5,Nb0.5)4AlC3In any one or two or more combinations.
5. according to claim 1 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The corrosion intercalator includes organic base.
6. according to claim 5 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：It is described corrosion intercalator include TMAH, TBAH, triethanolamine, sodium ethylene diamine tetracetate,
Urea, dimethyl sulfoxide (DMSO), methylamine, ethamine, monoethanolamine, ethylenediamine, isopropylamine, 1,3- propane diamine, 1,2- propane diamine, tripropyl amine (TPA),
Triethanolamine, butylamine, isobutyl amine, tert-butylamine, hexylamine, octylame, aniline, benzylamine, cyclohexylamine, pyridine, hexa, 2- chlorine
Phenol, 3- chlorophenols, 4- chlorophenols, o-aminophenol, m-aminophenol, para-aminophenol, ortho-aminotoluene, meta-aminotoluene, para-totuidine,
Any one in diphenylamines and benzidine or two or more combinations.
7. according to claim 1 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The organic base is 5~15ml with the usage ratio of ternary layered ceramic material：1g.
8. according to claim 1 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The mode of the shearing decentralized processing includes agitation, vibration or ultrasonic power.
9. according to any one of claim 1-8 green syt two dimension transition metal carbide or nitride nano piece side
Method, it is characterised in that including：
It is 5~15ml by usage ratio：The corrosion intercalator of 1g mix with ternary layered ceramic material and carry out corrosion intercalation it is anti-
More than 12h, preferably 12~36h are answered, the solid formation in mixed reactant is isolated afterwards, then cleaned, collected and produced in the middle of obtaining
Thing；
The intermediate product is scattered in solvent afterwards, and carries out shearing decentralized processing, obtain two-dimentional transition metal carbide
Nanometer sheet or two-dimentional transition metal nitride nanometer sheet.
10. according to claim 9 green syt two dimension transition metal carbide or nitride nano piece method, its feature
It is：The solvent includes any one in water, ethanol, acetone or two or more compositions in any proportion.
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|---|---|---|---|---|
| CN108467273A (en) * | 2018-05-31 | 2018-08-31 | 西南交通大学 | Ternary layered Ti3AlCN ceramics and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104192967A (en) * | 2014-08-19 | 2014-12-10 | 浙江大学 | Application of Ti3C2 nanosheet in treating high-oxidizability toxic metal ions in water |
| CN104528721A (en) * | 2014-12-23 | 2015-04-22 | 陕西科技大学 | Preparation method of flaky two-dimensional nano-titanium carbide nanometre material |
| CN104762660A (en) * | 2015-04-13 | 2015-07-08 | 中国科学院宁波材料技术与工程研究所 | Carbide crystal material with two-dimensional lamellar structure and preparation method thereof |
| CN104817083A (en) * | 2015-05-25 | 2015-08-05 | 哈尔滨工业大学 | Rapid-heating-assisted ultrasonic stripping method for two-dimensional nanometer Ti3C2 lamella |
| CN104961131A (en) * | 2015-07-03 | 2015-10-07 | 河海大学 | Preparation method of sulfonated two-dimensional titanium carbide nanosheet |
| CN106025200A (en) * | 2016-05-24 | 2016-10-12 | 浙江大学 | Preparation method and application of nitrogen-doped MXene battery anode material |
-
2017
- 2017-01-11 CN CN201710021027.2A patent/CN106744732A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104192967A (en) * | 2014-08-19 | 2014-12-10 | 浙江大学 | Application of Ti3C2 nanosheet in treating high-oxidizability toxic metal ions in water |
| CN104528721A (en) * | 2014-12-23 | 2015-04-22 | 陕西科技大学 | Preparation method of flaky two-dimensional nano-titanium carbide nanometre material |
| CN104762660A (en) * | 2015-04-13 | 2015-07-08 | 中国科学院宁波材料技术与工程研究所 | Carbide crystal material with two-dimensional lamellar structure and preparation method thereof |
| CN104817083A (en) * | 2015-05-25 | 2015-08-05 | 哈尔滨工业大学 | Rapid-heating-assisted ultrasonic stripping method for two-dimensional nanometer Ti3C2 lamella |
| CN104961131A (en) * | 2015-07-03 | 2015-10-07 | 河海大学 | Preparation method of sulfonated two-dimensional titanium carbide nanosheet |
| CN106025200A (en) * | 2016-05-24 | 2016-10-12 | 浙江大学 | Preparation method and application of nitrogen-doped MXene battery anode material |
Non-Patent Citations (1)
| Title |
|---|
| JINNAN XUAN ET AL: "Organic-Base-Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance", 《ANGEW. CHEM.》 * |
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| CN110698204B (en) * | 2019-11-12 | 2022-06-07 | 中国工程物理研究院核物理与化学研究所 | Preparation method of MAX phase ceramic |
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| CN112320801A (en) * | 2020-11-12 | 2021-02-05 | 郑州伯利森新材料科技有限公司 | Method for preparing titanium carbide two-dimensional nanosheet through high-temperature vulcanization heat treatment method |
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