CN106738144A - A kind of anticorrosive mildewproof technique of bamboo wood - Google Patents

A kind of anticorrosive mildewproof technique of bamboo wood Download PDF

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Publication number
CN106738144A
CN106738144A CN201611254693.2A CN201611254693A CN106738144A CN 106738144 A CN106738144 A CN 106738144A CN 201611254693 A CN201611254693 A CN 201611254693A CN 106738144 A CN106738144 A CN 106738144A
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CN
China
Prior art keywords
bamboo wood
mould inhibitor
bamboo
technique
superheated steam
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611254693.2A
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Chinese (zh)
Inventor
连健昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUJIAN LONGTAI BAMBOO INDUSTRY Inc Co
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FUJIAN LONGTAI BAMBOO INDUSTRY Inc Co
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Priority to CN201611254693.2A priority Critical patent/CN106738144A/en
Publication of CN106738144A publication Critical patent/CN106738144A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/08Impregnating by pressure, e.g. vacuum impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0228Spraying apparatus, e.g. tunnels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/0085Thermal treatments, i.e. involving chemical modification of wood at temperatures well over 100°C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002Cane, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/06Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by burning or charring, e.g. cutting with hot wire
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of anticorrosive mildewproof technique for the treatment of effeciency bamboo wood high, including:Bamboo wood is positioned over superheated steam 0.4~0.6MPa of pressure, 80~100min is processed in the environment that 125~135 DEG C of vapor (steam) temperature;When bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms of mould inhibitor stostes.The beneficial effects of the present invention are:Under high pressure and superheated steam state, bamboo material surface is carbonized, alien insect is avoided to rest on bamboo material surface, and being added high pressure under high temperature can thoroughly kill bacterium and worm's ovum inside bamboo wood, vacuum state can extract sugared part, air, impurity inside bamboo wood etc. out simultaneously, moth needed nutrient matter is removed, wood fibre is left behind, bacteriological aftergrowth is prevented and is difficult to be damaged by worms.

Description

A kind of anticorrosive mildewproof technique of bamboo wood
Technical field
The present invention relates to a kind of anticorrosive mildewproof technique of bamboo wood.
Background technology
Bamboo wood contains more hemicelluloses, starch, sugared part and protein than timber, and bamboo wood people is made even across hot pressing The plate such as product such as automobile compartment floor, bamboo flooring, bamboo recombined material is made, these artificial bamboo board products such as run into use Suitable temperature and temperature, it is easy to occur going mouldy with it is rotten.Particularly when these products are used out of doors, because weather becomes Change, inevitably temperature and humidity meets the condition of mould and rotten bacteria growing.Slight the going mouldy of early stage appears in Bamboo product surface, only influences outward appearance, but as the development of mould, mycelia can be goed deep into bamboo product, rot fungi can also develop Get up, bamboo wood microstructure is produced change, so as to not only influence outward appearance, also greatly reduce the intensity of bamboo product, reduce bamboo The service life of product.For bamboo wood, the treatment of effective fungus-proof antisepsis is still Chemical treatment, and most of is used The fungusproof anti-corrosion agent of organic solvent type, constructs and is had greater environmental impacts when using.At present, the country is about research institution and production Enterprise recognizes the benefit of water mildow-proof preservative, develops several efficient, aqueous bamboo Wood protecting agents of low toxicity, but use Immersion, the artificial processing method such as brush, treatment effeciency is low, operative when can contact fungusproof anti-corrosion agent, health of human body is also deposited Necessarily influenceing.
The content of the invention
The technical problems to be solved by the invention are:A kind of anticorrosive mildewproof technique for the treatment of effeciency bamboo wood high is provided.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:A kind of anticorrosive mildewproof technique of bamboo wood, bag Include:Bamboo wood is positioned over superheated steam 0.4~0.6MPa of pressure, in the environment that 125~135 DEG C of vapor (steam) temperature process 80~ 100min。
The present invention provide another technical scheme be:A kind of anticorrosive mildewproof technique of bamboo wood, it is characterised in that including:
Step 1, isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat different thiophene Oxazoline ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, long-chain carboxylic acid's class Additive, and butanedioic acid salt or APEO salt ion type surfactant, heat and stir, prepared by missible oil Into, missible oil plus deionized water are diluted, that is, obtain mould inhibitor stoste;
Step 2, bamboo wood is positioned over superheated steam pressure 0.5MPa, 90min is processed in the environment that 130 DEG C of vapor (steam) temperature; When bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms Mould inhibitor stoste.
The beneficial effects of the present invention are:Under high pressure and superheated steam state, bamboo material surface carbonization, it is to avoid alien insect Rest in bamboo material surface, and added high pressure under high temperature and can thoroughly kill bacterium and worm's ovum inside bamboo wood, while vacuum state Sugared part, air, impurity inside bamboo wood etc. can be extracted out, remove moth needed nutrient matter, leave behind wood fibre, prevent thin Bacterium regenerates and is difficult to be damaged by worms;When this 3 states are carried out simultaneously, mould inhibitor stoste is added, can be thin by mould inhibitor feeding bamboo wood Intracellular portion, further prevents bacteriological aftergrowth.
Specific embodiment
To describe technology contents of the invention, the objects and the effects in detail, it is explained below in conjunction with implementation method.
The design of most critical of the present invention is:Under high pressure and superheated steam state, bamboo material surface carbonization, it is to avoid external elder brother Worm rests on bacterium and the worm's ovum for being added high pressure under bamboo material surface, high temperature and can thoroughly being killed inside bamboo wood, while vacuum state can Sugared part inside bamboo wood is extracted out, bacteriological aftergrowth is prevented
The present invention provides a kind of anticorrosive mildewproof technique of bamboo wood, including:By bamboo wood be positioned over superheated steam pressure 0.4~ 0.6MPa, processes 80~100min in the environment that 125~135 DEG C of vapor (steam) temperature.
Knowable to foregoing description, the beneficial effects of the present invention are:Under high pressure and superheated steam state, bamboo material surface carbon Change, it is to avoid alien insect is rested in bamboo material surface, and added high pressure under high temperature and can thoroughly kill bacterium and worm inside bamboo wood Ovum, while vacuum state can extract sugared part, air, impurity inside bamboo wood etc. out, removes moth needed nutrient matter, leaves behind Wood fibre, prevents bacteriological aftergrowth and is difficult to be damaged by worms;It is environment friendly and pollution-free, it is particularly suited for processing indoor bamboo product.
Further, when bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is every 1 vertical Square meter Zhu Cai sprays 1.54 kilograms of mould inhibitor stostes.
Seen from the above description, when this 3 states are carried out simultaneously, mould inhibitor stoste is added, mould inhibitor can be sent into bamboo Material cell interior, further prevents bacteriological aftergrowth.
Further, described mould inhibitor stoste is prepared from by the following method:Isothiazolinone active compound is dissolved in In esters solvent, and alcohols or ethers cosolvent;Treat that isothiazolinone active compound is completely dissolved, after forming oil phase, add poly- Oxygen ethene ethers nonionic surface active agent, long-chain carboxylic acid's class additive, and butanedioic acid salt or APEO salt Ionic surfactant, is heated and stirs, and missible oil is prepared and completed, and missible oil plus deionized water are diluted, that is, obtain mould proof Agent stoste.
Seen from the above description, the mould inhibitor stoste for being prepared by the above method extremely can rapidly be distributed to superheated steam In, and exist with atomic small state, enter in bamboo wood such that it is able to rapid osmotic.
Further, the course of dissolution of isothiazolinone active compound is completed in 60 DEG C~80 DEG C of condition;Isothiazoline Ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, the addition of long-chain carboxylic acid's class Agent, and butanedioic acid salt or APEO salt ion type surfactant, heat under the conditions of 60 DEG C~80 DEG C, and with The speed of 200rpm~1000rpm stirs 3~10min.
Embodiment 1
A kind of anticorrosive mildewproof technique of bamboo wood, including:
Step 1, isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat different thiophene Oxazoline ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, long-chain carboxylic acid's class Additive, and butanedioic acid salt or APEO salt ion type surfactant, heat and stir, prepared by missible oil Into, missible oil plus deionized water are diluted, that is, obtain mould inhibitor stoste;
Step 2, bamboo wood is positioned over superheated steam pressure 0.4MPa, 80min is processed in the environment that 125 DEG C of vapor (steam) temperature; When bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms Mould inhibitor stoste.
Embodiment 2
A kind of anticorrosive mildewproof technique of bamboo wood, including:
Step 1, isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat different thiophene Oxazoline ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, long-chain carboxylic acid's class Additive, and butanedioic acid salt or APEO salt ion type surfactant, heat and stir, prepared by missible oil Into, missible oil plus deionized water are diluted, that is, obtain mould inhibitor stoste;
Step 2, bamboo wood is positioned over superheated steam pressure 0.5MPa, 90min is processed in the environment that 130 DEG C of vapor (steam) temperature; When bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms Mould inhibitor stoste.
Embodiment 3
A kind of anticorrosive mildewproof technique of bamboo wood, including:
Step 1, isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat different thiophene Oxazoline ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, long-chain carboxylic acid's class Additive, and butanedioic acid salt or APEO salt ion type surfactant, heat and stir, prepared by missible oil Into, missible oil plus deionized water are diluted, that is, obtain mould inhibitor stoste;
Step 2, bamboo wood is positioned over superheated steam pressure 0.6MPa, 100min is processed in the environment that 135 DEG C of vapor (steam) temperature; When bamboo wood carries out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms Mould inhibitor stoste.
After testing, the treated bamboo wood fungicidal properties of the method for embodiment 1~3 reaches national 0 grade of standard, bamboo after mould proof treatment Organic volatile (VOC) release of product reaches European standard.
In sum, the beneficial effect of the anticorrosive mildewproof technique of the bamboo wood that the present invention is provided is:Steamed in high pressure and overheat Under vaporous state, bamboo material surface carbonization, it is to avoid alien insect is rested in bamboo material surface, and is added high pressure under high temperature and can thoroughly killed Bacterium and worm's ovum inside bamboo wood, while vacuum state can extract sugared part, air, impurity inside bamboo wood etc. out, remove moth Needed nutrient matter, leaves behind wood fibre, prevents bacteriological aftergrowth and is difficult to be damaged by worms;When this 3 states are carried out simultaneously, plus Enter mould inhibitor stoste, mould inhibitor can be sent into inside bamboo culm, further prevent bacteriological aftergrowth.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair The equivalents that bright description is made, or the technical field of correlation is directly or indirectly used in, similarly it is included in this hair In bright scope of patent protection.

Claims (5)

1. the anticorrosive mildewproof technique of a kind of bamboo wood, it is characterised in that including:By bamboo wood be positioned over superheated steam pressure 0.4~ 0.6MPa, processes 80~100min in the environment that 125~135 DEG C of vapor (steam) temperature.
2. the anticorrosive mildewproof technique of bamboo wood according to claim 1, it is characterised in that:Bamboo wood carries out superheated steam treatment When, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1 cubic metre of bamboo wood sprays 1.54 kilograms of mould inhibitor stostes.
3. the anticorrosive mildewproof technique of bamboo wood according to claim 2, it is characterised in that:Described mould inhibitor stoste is by as follows Method is prepared from:Isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat isothiazole Quinoline ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, and long-chain carboxylic acid's class adds Plus agent, and butanedioic acid salt or APEO salt ion type surfactant, heating and stir, missible oil is prepared and completed, Missible oil plus deionized water are diluted, that is, obtain mould inhibitor stoste.
4. the anticorrosive mildewproof technique of bamboo wood according to claim 3, it is characterised in that:The dissolving of isothiazolinone active compound Process is completed in 60 DEG C~80 DEG C of condition;Isothiazolinone active compound is completely dissolved, and after forming oil phase, adds polyoxyethylene Ether nonionic type surfactant, long-chain carboxylic acid's class additive, and butanedioic acid salt or APEO salt ion type Surfactant, heats under the conditions of 60 DEG C~80 DEG C, and stirs 3~10min with the speed of 200rpm~1000rpm.
5. the anticorrosive mildewproof technique of a kind of bamboo wood, it is characterised in that including:
Step 1, isothiazolinone active compound is dissolved in esters solvent, and alcohols or ethers cosolvent;Treat isothiazoline Ketone active compound is completely dissolved, and after forming oil phase, adds polyethenoxy ether class nonionic surface active agent, the addition of long-chain carboxylic acid's class Agent, and butanedioic acid salt or APEO salt ion type surfactant, are heated and stir, and missible oil is prepared and completed, will Missible oil adds deionized water to be diluted, that is, obtain mould inhibitor stoste;
Step 2, bamboo wood is positioned over superheated steam pressure 0.5MPa, 90min is processed in the environment that 130 DEG C of vapor (steam) temperature;Bamboo wood When carrying out superheated steam treatment, to mould inhibitor stoste is sprayed in steam, fountain height is that every 1.54 kilograms of 1 cubic metre of bamboo wood spray is mould proof Agent stoste.
CN201611254693.2A 2016-12-30 2016-12-30 A kind of anticorrosive mildewproof technique of bamboo wood Pending CN106738144A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108908594A (en) * 2018-08-02 2018-11-30 安徽信达家居有限公司 A kind of processing method extending mould-proof-type bamboo wood effective time
CN108943232A (en) * 2018-05-10 2018-12-07 宜华生活科技股份有限公司 Fast growing wood silica solution dipping is modified and method of modifying is combined in superheated steam processing
CN110238932A (en) * 2019-07-18 2019-09-17 中南林业科技大学 A kind of fungus-proof antisepsis high-strength cement particieboard and preparation method thereof
CN110487104A (en) * 2019-09-04 2019-11-22 山东阳光环保科技有限公司 A kind of bamboo water collection device production method
CN111730711A (en) * 2020-07-13 2020-10-02 福建省竹家缘工贸有限公司 Bamboo board carbonizing process and equipment thereof
CN112008819A (en) * 2020-07-13 2020-12-01 福建龙泰竹家居股份有限公司 Bamboo wood anticorrosion and mildew-proof treatment method

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CN103878839A (en) * 2014-01-27 2014-06-25 浙江农林大学 Production method for manufacturing sliced veneer by bamboo split recombined bamboo wood
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108943232A (en) * 2018-05-10 2018-12-07 宜华生活科技股份有限公司 Fast growing wood silica solution dipping is modified and method of modifying is combined in superheated steam processing
CN108908594A (en) * 2018-08-02 2018-11-30 安徽信达家居有限公司 A kind of processing method extending mould-proof-type bamboo wood effective time
CN110238932A (en) * 2019-07-18 2019-09-17 中南林业科技大学 A kind of fungus-proof antisepsis high-strength cement particieboard and preparation method thereof
US11702362B2 (en) 2019-07-18 2023-07-18 Central South University Of Forestry And Technology Mildewproof and antirot high-strength cement particle board and preparation method thereof
CN110487104A (en) * 2019-09-04 2019-11-22 山东阳光环保科技有限公司 A kind of bamboo water collection device production method
CN111730711A (en) * 2020-07-13 2020-10-02 福建省竹家缘工贸有限公司 Bamboo board carbonizing process and equipment thereof
CN112008819A (en) * 2020-07-13 2020-12-01 福建龙泰竹家居股份有限公司 Bamboo wood anticorrosion and mildew-proof treatment method

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