CN106732607A - A kind of nickeliferous boehmite and carrier prepared therefrom - Google Patents
A kind of nickeliferous boehmite and carrier prepared therefrom Download PDFInfo
- Publication number
- CN106732607A CN106732607A CN201510818869.1A CN201510818869A CN106732607A CN 106732607 A CN106732607 A CN 106732607A CN 201510818869 A CN201510818869 A CN 201510818869A CN 106732607 A CN106732607 A CN 106732607A
- Authority
- CN
- China
- Prior art keywords
- nickeliferous
- solution
- boehmite
- acid
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 title claims abstract description 76
- 229910001593 boehmite Inorganic materials 0.000 title claims abstract description 75
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 67
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000002360 preparation method Methods 0.000 claims abstract description 38
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 27
- 239000011148 porous material Substances 0.000 claims abstract description 13
- 239000013078 crystal Substances 0.000 claims abstract description 7
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 27
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 23
- 239000004033 plastic Substances 0.000 claims description 23
- 230000032683 aging Effects 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 16
- 150000002815 nickel Chemical class 0.000 claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 15
- 229910052593 corundum Inorganic materials 0.000 claims description 15
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 15
- -1 alkali metal aluminate Chemical class 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 13
- 239000004411 aluminium Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 159000000013 aluminium salts Chemical class 0.000 claims description 10
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 10
- 238000002441 X-ray diffraction Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 7
- 230000001376 precipitating effect Effects 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229910003303 NiAl2O4 Inorganic materials 0.000 claims description 5
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910052594 sapphire Inorganic materials 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 238000009423 ventilation Methods 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 2
- IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 claims description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 2
- 238000009790 rate-determining step (RDS) Methods 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 229910003158 γ-Al2O3 Inorganic materials 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 238000009938 salting Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 48
- 238000000034 method Methods 0.000 abstract description 27
- 230000000694 effects Effects 0.000 abstract description 17
- 230000008569 process Effects 0.000 abstract description 12
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000012876 carrier material Substances 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000000843 powder Substances 0.000 description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 26
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 239000007789 gas Substances 0.000 description 22
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 17
- 229910017604 nitric acid Inorganic materials 0.000 description 17
- 241000219782 Sesbania Species 0.000 description 15
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 13
- 238000000465 moulding Methods 0.000 description 13
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000001569 carbon dioxide Substances 0.000 description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- 239000012452 mother liquor Substances 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 235000011114 ammonium hydroxide Nutrition 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 230000002572 peristaltic effect Effects 0.000 description 7
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000004898 kneading Methods 0.000 description 6
- 229910001388 sodium aluminate Inorganic materials 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000790917 Dioxys <bee> Species 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- NWEKXBVHVALDOL-UHFFFAOYSA-N butylazanium;hydroxide Chemical compound [OH-].CCCC[NH3+] NWEKXBVHVALDOL-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000002803 maceration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical class [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NBFQLHGCEMEQFN-UHFFFAOYSA-N N.[Ni] Chemical compound N.[Ni] NBFQLHGCEMEQFN-UHFFFAOYSA-N 0.000 description 1
- WAKTWVHWRCNIKU-UHFFFAOYSA-N S(=O)(=O)(O)O.[AlH3] Chemical compound S(=O)(=O)(O)O.[AlH3] WAKTWVHWRCNIKU-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WPUINVXKIPAAHK-UHFFFAOYSA-N aluminum;potassium;oxygen(2-) Chemical compound [O-2].[O-2].[Al+3].[K+] WPUINVXKIPAAHK-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 1
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical class O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005360 mashing Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Abstract
The invention provides a kind of nickeliferous boehmite and carrier prepared therefrom, the nickeliferous boehmite prepared by the method organically combines nickel and boehmite, active component nickel is set to be effectively dispersed in boehmite, and form the alumina carrier containing Ni of specific crystal formation, the pore structure and acidity to carrier have preferable adjustment effect simultaneously, and final obtained catalyst has hydrogenation activity higher.With it is simple using preparation catalyst compared with, it is simple with process, while the advantages of carrier material performance easy modulation.
Description
Technical field
The present invention relates to a kind of nickeliferous boehmite and carrier prepared therefrom, hydrogenation is particularly well-suited to
The preparation method of the nickeliferous boehmite of catalyst carrier material.
Background technology
Hydrated alumina such as boehmite and boehmite etc. are used as the raw material quilt for preparing alumina support
Widely use, although such as pH value swing method can be used in carrying alumina production procedure, is added with
The methods such as machine expanding agent, hydro-thermal process improve the property as the aluminum oxide of carrier, but by this
A little methods are limited come the performance of the aluminum oxide for improving catalyst carrier for hydrgenating material.Prepare aluminum oxide
The property of the aqua oxidation aluminum feedstock used by carrier be produce excellent properties alumina support most critical because
One of element.
CN102029192B discloses a kind of preparation method of silicon-containing alumina, prepares first modified viscous
Soil, high-temperature roasting is carried out by clay original soil, is then reacted with mixed acid, mixed acid be strong acid and
The mixing of weak acid；Then carry out in Modified Clay Slurry liquid acid solution containing aluminium and alkaline solution into
Glue reacts, and the steps such as aging, filtering, washing, dry and roasting is carried out after cemented into bundles and obtains siliceous
Aluminum oxide, it is also possible to be not calcined after drying and obtain silicon-containing alumina dry glue, the silicon-containing alumina tool of preparation
Have the advantages that aperture is big, pore structure is suitable, can be used for preparing heavy oil or catalyst for hydrotreatment of residual oil.
CN1123392C describes a kind of alumina carrier containing Ni and preparation method thereof, will be through alkali process
The nickel compound containing and the mixture of carbon black crossed and aluminum hydroxide solid elastomer powder kneading, through extruded moulding and dry
Dry, roasting and be obtained it is a kind of it is nickeliferous be 2.0%~14.0% alumina support, the carrier pore volume is
0.4cm3/ g~1.0cm3/ g, specific surface area are 160m2/ g~420m2/ g, average pore size be 8.0nm~
15.0nm, accounts for more than the 85% of its total hole more than the ratio in 6.0nm holes, and pore volume, average pore size are larger,
Macropore proportion is more, is particularly suited for the carrier as hydrorefining catalyst for heavy oil.
CN200710179630.X discloses a kind of preparation method of nickel-coated alumina powder, and its feature exists
Suspension is made in the mixed liquor of the nano aluminium oxide by dispersant is added, stirring is lower to add nickel salt solution,
After stirring, ammoniacal liquor is instilled in mixed liquor, add distilled water, obtain the cooperation of navy blue nickel ammonia
Thing ([Ni (NH3)6]2+)-Aluminum oxide mixed solution C, then by hydrothermal aging, filter, wash, dry,
Obtain cladding product in the middle of green；Reduction roasting is carried out again, obtains black Ni-Coated alumina powder.
CN1102862C discloses a kind of nickel-containing hydrogenationcatalysts, contains：In terms of nickel oxide, 65-80%
Nickel, in terms of silica, the silicon of 10-25%, in terms of zirconium oxide, the zirconium of 2-10%, with aluminum oxide
Meter, the aluminium of 0-10%, its precondition is that the content sum of silica and aluminum oxide is at least 15% (weight
Amount %, based on the gross weight of catalyst), this catalyst be by by nickel, zirconium, if necessary,
The acidic aqueous solution of the also salt of aluminium is added to silicon, if necessary, the also alkaline water of the compound of aluminium
In solution or suspension, the pH of the mixture of such acquisition is reduced at least 6.5, then pass through into
One step is added alkaline solution and pH value regulation is arrived into 7-8, separates the solid of so deposition, is dried, is molded
And sinter what is obtained.In addition also disclose the method for preparing catalyst, and its prepare medicinal white oils,
The method of high-purity medical paraffin and low boiling low arene content or aromatic free hydrocarbon mixture.Should
The preparation method of catalyst is commonly used to prepare high-activity component content catalyst, but uses party's legal system
Standby catalyst activity is poor.
Article " the changes induced by calcination temperature in of Agudo A L etc.
hydrodesulfurization activity of NiCo-Mo/Al2O3Catalysis, Applied Catalysis,
1987,30:185-188 ", has investigated sintering temperature to NiCoMo/A12O3Catalyst rhohene desulfiirization is lived
The influence of property.Result shows that the desulphurizing activated of catalyst activated at 500 DEG C is significantly higher than 600
The catalyst activated under the conditions of DEG C, this is due to metal and aluminum oxide in the catalyst when activating for 600 DEG C
Spinel structure is generated there is strong interaction so as to cause catalyst activity to be remarkably decreased in carrier.Activation
Temperature is higher, and the nickel aluminate phase content of generation is higher, and the activity decrease of catalyst is more obvious.
“Influence of support-interaction on the sulfidation behavior and
hydrodesulfurization activity of Al2O3Support W, CoW and NiW model
Catalysts, J Phys Chem B, 2002,106:5897-5906 " equally draws similar conclusion.
Because nickel and alumina support can occur strong interaction generation spinelle knot in high-temperature calcination process
Structure, so as to cause catalyst activity to be remarkably decreased, therefore all cautiously made as far as possible before high-temperature roasting
With both, it is to avoid the generation of spinel structure.Because being generally required when preparing catalyst carrier with it
High-temperature roasting is carried out, people is suspected, so, rare nickeliferous plan thin water different from other metals
Aluminium stone is reported.
The catalyst with hydrogenation activity higher is prepared, corresponding active metal component content also will height.
Simple application infusion process prepares hydrotreating catalyst, it is necessary to prepare high activity metal constituent content
Solution carries out dipping to carrier and is obtained.Therefore there are the following problems in dipping process：(1) due to carrying
The water absorption rate of body is certain, using the maceration extract given volume of incipient impregnation method, active metal component
Addition is too high to cause dissolving incomplete；(2) prepare and need in catalyst process repeatedly dipping activity
Component, twice, three times even four times could be by the activity component impregnation of certain content to carrier, this
The problems such as having resulted in cumbersome preparation section, long preparation period, loss of active component；(3) repeatedly leaching
During stain, generally require to add organic or inorganic dispersant to increase active metal in maceration extract
The decentralization of component, but can there is removing in last handling process in these.
In the preparation process of catalyst carrier, by the compound containing active metal component with kneading
Form is introduced, and the compound for containing a certain amount of active metal component in shaping carrier is reached drop
The problem of the load difficulty run into low high content active metal component catalyst preparation process.But it is logical
Kneading method is crossed in the form of kneading by active metallic compound and aluminum hydroxide solid elastomer powder or alumina powder
Direct mixed-forming, the method has that brilliant mix particles are uneven and catalyst strength,
It is not easy to combine to form specific skeleton structure between simple kneading each component simultaneously.
The content of the invention
In view of the shortcomings of the prior art, by technical improvement, tradition and prejudice have been abolished, with new
Mode be loaded into metallic nickel, prepare nickeliferous boehmite.
The invention provides a kind of nickeliferous boehmite and carrier prepared therefrom, prepared by the method
Nickeliferous boehmite nickel and boehmite are organically combined, while intending thin water to nickeliferous
The pore structure and acidity of aluminium stone have preferable adjustment effect, because the nickeliferous boehmite is mainly used
In catalyst carrier, particularly carrier of hydrogenating catalyst, thus the nickeliferous boehmite and by
The carrier that it is prepared has suitable pore-size distribution simultaneously.
It is salic with institute in nickeliferous boehmite the invention provides a kind of nickeliferous boehmite
Weight is 100% meter, and nickel content is 0.1wt%~10wt%, preferably 0.5wt%~5wt%；Specific surface
300~420m of product2/ g, pore volume is 0.7cm3/ g~1.2cm3/ g, aperture is 5nm~10nm；This contains
Nickel boehmite has acid-base neutralization and plastic process in preparation process.
Nickeliferous boehmite of the invention is not boehmite and nickel compound containing or nickel salt solution
Simple physical blending or coat, but there is acid-base reaction, it is final that tool is obtained with plastic process
There are specific nickel and aluminium to mix the carrier of crystalline form.
The carrier is preferably obtained by following methods, and preparation process comprises the following steps：
(1) addition bottom water in kettle is neutralized, bottom water is deionized water, is heated to 50~90 DEG C；
(2) acid aluminum saline solution, acid nickel salt aqueous solution are prepared respectively, by the acid aluminium salt aqueous solution
It is well mixed with acid nickel salt aqueous solution, obtain the acidic aqueous solution of aluminium containing salt and nickel salt, regulation mixing
Solution temperature is 50~90 DEG C, and wherein acid aluminium salt concentration of aqueous solution is 10~80g Al2O3/ L, it is acid
Nickel salt aqueous solution concentration is 3~50gNiO/L；
(3) alkali metal aluminate solution is prepared, alkali metal aluminate solution concentration is 50~300g
Al2O3/L；
(4) by (2) and (3) cocurrent addition (1), constant ventilation is stirred；
(5) 50~90 DEG C of rate-determining steps (4) gelling temperature, plastic pH value 7~10；
(6) after cemented into bundles, through aging, filtering, washing, prepared nickeliferous boehmite is dried.
Tank bottom can be passed through air in the preparation method step (1)；Step (5) plastic pH value is preferred
7~9.
Preferably 60~80 DEG C of temperature in preparation method of the present invention described in step (1)；Step (2) institute
Preferably 60~80 DEG C of temperature is stated, stablizes 3~5min.Acid aluminium salt and nickel salt mixed solution, alkali metal
Aluminate solution is with the positive and negative temperature difference of solution temperature in plastic cans preferably no more than 3 DEG C, and three's temperature is best
It is identical.The alkaline precipitating agent aqueous solution can be also added in step (3) in alkali metal aluminate solution.Alkali
Metal aluminate solution (or its formed with the alkaline precipitating agent aqueous solution mixed solution) pH value is 9~
14, preferable ph 12~14.
The present invention provide a kind of nickeliferous boehmite preparation method described in aluminium salt, nickel salt and
Alkaline precipitating agent can use the raw material of industry.The described acid aluminium salt aqueous solution can be aluminium chloride, sulphur
The mixed solution of one or more in sour aluminium and aluminum nitrate, preferably sulfuric acid aluminum solutions.Described acidity
Nickel salt aqueous solution can be the mixed of one or more in nickel chloride, nickel sulfate, nickelous bromide and nickel nitrate
Close solution, preferably nickel nitrate solution.Acid aluminium salt and acid nickel salt mixed solution pH value are 2~5,
Preferable ph 2~4.Described alkali metal aluminate solution refers to sodium metaaluminate or potassium metaaluminate solution；
Described alkaline precipitating agent refers to ammonium bicarbonate soln, sodium bicarbonate solution, ammonia spirit, hydroxide
Sodium solution or aqua calcis, preferably ammonia spirit, NH3Content is 50~120g/L.
The aging of step (6) described material refers to after plastic is made under continuing ventilation stirring or inactive state
Solution keep certain hour at certain temperature and pH value.Wherein aging temperature is 50~80 DEG C,
Ageing time is 10~60min.
The mode of washing of step (6) described material is general knowledge as well known to those skilled in the art, can be used
Added water during filtering washing, mashing washing, using lower alcohols wash etc. mode, temperature is controlled during washing
40~80 DEG C, pH value 4~8, wash time is 20~40min, and washing times are 2~5 times.
Drying mode described in step (6) can using oven drying, spray drying, mesh-belt kiln drying,
Fluidized bed drying, natural drying, microwave drying etc., drying temperature are 70~150 DEG C, drying time 2~
24h, preferably with different temperatures stage drying.
The present invention also provides a kind of nickeliferous oxidation as obtained from nickeliferous boehmite through shaping, roasting
Alumina supporter.
A kind of alumina carrier containing Ni, is obtained by nickeliferous boehmite through shaping, roasting, is contained
δ-Al2O3、δ-NiAl26O40、NiAl2O40.45≤B1/B2≤0.85 in crystal formation, and XRD spectra,
B1 refer in XRD spectra 2 θ be 34.2~39.8 ° peak integrated intensity, B2 refers to XRD spectra
In 2 θ be 43.3~48.5 ° peak integrated intensity.
In obtained alumina carrier containing Ni of the invention, contain δ-Al2O3、δ-NiAl26O40、NiAl2O4
The mixed crystal of crystal formation, best δ-Al2O3、δ-NiAl26O40And NiAl2O4Account for alumina carrier containing Ni gross weight
The 30%~100% of amount.θ-Al can also be contained in carrier2O3、α-Al2O3And/or γ-Al2O3, best α-
Al2O3Less than 30wt%.
Final alumina carrier containing Ni application target is regarded in the present invention different, the system of nickeliferous boehmite
Preparation Method, nickel source, nickel content, alumina carrier containing Ni preparation method, calcination for activation temperature etc. can be with
It is different.Best nickel content is 0.1wt%~10wt% in alumina carrier containing Ni of the invention, preferably
0.5wt%~7.5wt%.Specific surface area 20m2/ g~230m2/ g, pore volume is 0.10cm3/ g~
0.65cm3/ g, aperture is 7nm~30nm.
The nickeliferous boehmite of the present invention before shaping, can as needed add peptizing agent, help crowded
One or more in agent and aluminum oxide dry glue powder, the specific material for using and addition can be by abilities
The existing knowledge in domain is determined.Such as, the peptizing agent can be nitric acid, phosphoric acid, hydrochloric acid, sulfuric acid
In one or more, addition is need molded samples gross weight 3~10%；The extrusion aid can be with
It is sesbania powder, its consumption is need molded samples gross weight 2~6%；The aluminum oxide dry glue powder is used
Conventional method is obtained, but addition is again well less than the 10% of nickeliferous boehmite gross mass.
The method of roasting and condition are that catalyst carrier is calcined common method and condition, can be used vertical
Stove, converter and mesh-belt kiln are calcined, and the roasting condition of the carrier is preferably：800~1200 DEG C of roastings
Burn 4~10h.
In the preparation process of catalyst used carrier precursor, the compound containing active component is first introduced,
Make the compound containing a certain amount of active metal component in obtained carrier, work higher can be substantially reduced
The preparation difficulty of property metal component content catalyst.On the basis of catalyst performance is ensured, letter is reached
Change catalyst preparation process, the purpose of optimization preparation technology.
Nickeliferous boehmite and its carrier of preparation that the present invention is provided, advantage be can by nickel and
Boehmite organically combines, and active component nickel is effectively dispersed in boehmite, and
The alumina carrier containing Ni of specific crystal formation is formed, while having preferably to the pore structure and acidity of carrier
Adjustment effect, and final obtained catalyst has hydrogenation activity higher.With simple using dipping
Method prepares catalyst and compares, simple with process, while the advantages of carrier material performance easy modulation.
Specific embodiment
Nickel content is measured using atom absorption method in boehmite in the present invention；Infrared acidity is used
Pyridine-infrared is measured；The D8 Advance type X-rays produced using German Bruker companies
Powder diffractometer (XRD) determines the crystal formation of carrier, actual conditions：CuK α are radiated, 40 kilovolts, 40
Milliampere, 0.02 ° of sweep speed/step, 0.5 second/step, B1 referred to that 2 θ are 34.2~39.8 ° in XRD spectra
Peak integrated intensity, B2 refer in XRD spectra 2 θ be 43.3~48.5 ° peak integrated intensity.
Analysis method：
Oil distillation：Determined using oil product test method SYB-2110-60；
Bromine valency：Using SH/T 0236-92 standard tests；
Diene：Using SH/T 0714-2002 standard tests；
Specific surface：Using the standard tests of GB/T 19587；
Pore volume, aperture and pore-size distribution：GB/T 21650.2-2008 standard tests；
Water content：Using GB/T 11133-89 standard tests；
Sulfur content：Determined using WK-2B microcoulombs instrument；
Nitrogen content：Determined using KY-3000N chemiluminescences azotometer；
Arsenic content：Determined using DV-4300 Atomic Emission Spectrometer AESs.
The present invention is further illustrated below by embodiment, but is not regarded as present invention is limited only by this.
Embodiment 1
(1) nickeliferous boehmite
It is 50g Al by 1L concentration2O3The aluminum sulfate solution and 1L concentration of/L are the nitric acid of 13g NiO/L
Nickel solution is well mixed in the container for loading high level, and compound concentration is 140g Al2O3/ L sodium metaaluminates
Solution 1L load high level container in, connect under two containers peristaltic pump carry out flow control flow into be equipped with
The belt stirrer and tank bottom of 5L bottoms water can be passed through in the rustless steel container of gas, 55 DEG C of reaction temperature, control
Flow-rate adjustment reacting system PH value processed is 9, is 9.5 by the way that ammoniacal liquor is added dropwise to adjust slurry pH value, instead
Aging 30 minutes after should terminating, mother liquor is separated by filtration, washed.3h, 120 DEG C of dryings are dried at 90 DEG C
2h, obtains nickeliferous boehmite N1.
(2) nickeliferous aluminum oxide
The nickeliferous boehmite N1 100g of preparation are weighed, 5ml nitric acid, 2ml phosphoric acid, 7g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 950 DEG C of roastings at 120 DEG C
4h is burnt, carrier Z1 is obtained.
Embodiment 2
(1) nickeliferous boehmite
It is 50g Al by 1L concentration2O3The aluminum sulfate solution and 0.5L concentration of/L are the nitre of 5.2g NiO/L
Sour nickel solution is well mixed in the container for loading high level, and compound concentration is 150g Al2O3/ L meta-aluminic acids
Sodium solution 1L load high level container in, connect under two containers peristaltic pump carry out flow control flow into be equipped with
The belt stirrer and tank bottom of 5L bottoms water can be passed through in the rustless steel container of gas, 60 DEG C of reaction temperature, control
Flow-rate adjustment reacting system PH value processed is 9, is 9.5 by the way that ammoniacal liquor is added dropwise to adjust plasm PH value, instead
Aging 20 minutes after should terminating, mother liquor is separated by filtration, washed.3h, 120 DEG C of dryings are dried at 90 DEG C
2h, obtains sample N2.
(2) nickeliferous aluminum oxide
Weigh the nickeliferous boehmite N2 100g of preparation, add 5.5ml nitric acid, 1.8ml phosphoric acid,
Then 7.5g sesbania powders and water mixer kneader into plastic, extruded moulding dry 4h, 1000 DEG C at 120 DEG C
Roasting 4h, obtains carrier Z2.
Embodiment 3
(1) nickeliferous boehmite
It is 30g Al by 1L concentration2O3The aluminum sulfate solution and 2L concentration of/L are the nitric acid of 10g NiO/L
Nickel solution is well mixed in the container for loading high level, and compound concentration is 150g Al2O3/ L sodium metaaluminates
Solution 1L load high level container in, connect under two containers peristaltic pump carry out flow control flow into be equipped with
The belt stirrer and tank bottom of 5L bottoms water can be passed through in the rustless steel container of gas, 65 DEG C of reaction temperature, control
Flow-rate adjustment pH value of reaction system processed is 9, is 9.5 by the way that ammoniacal liquor is added dropwise to adjust slurry pH value, reaction
Aging 40 minutes after end, mother liquor is separated by filtration, washed.3h, 120 DEG C of dryings are dried at 90 DEG C
2h, obtains sample N3.
(2) nickeliferous aluminum oxide
The nickeliferous boehmite N3 100g of preparation are weighed, 6ml nitric acid, 1.5ml phosphoric acid, 7.2g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 850 DEG C of roastings at 120 DEG C
4h is burnt, carrier Z3 is obtained.
Comparative example 1
(1) boehmite
It is 50g Al by 1L concentration2O3The aluminum sulfate solution and 1.5L concentration of/L are 150g Al2O3/ L is inclined
Sodium aluminate solution is respectively charged into the container of high level, and peristaltic pump is connected under two containers carries out flow control stream
Entering belt stirrer and tank bottom equipped with 5L bottoms water can be passed through in the rustless steel container of gas, reaction temperature
55 DEG C, it is 9 to control Flow-rate adjustment pH value of reaction system, is by the way that ammoniacal liquor regulation slurry pH value is added dropwise
9.5, reaction terminates latter aging 30 minutes, is separated by filtration mother liquor, washs.3h, 120 DEG C are dried at 90 DEG C
2h is dried, boehmite A1 is obtained.
(2) aluminum oxide
The boehmite A1 100g of preparation are weighed, 5.5ml nitric acid, 2.2ml phosphoric acid, 7.5g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 900 DEG C of roastings at 120 DEG C
4h is burnt, carrier D1 is obtained.
Embodiment 4
(1) nickeliferous boehmite
It is 190g Al by 1L concentration2O3The sodium aluminate solution and 1L concentration of/L are the nitre of 8g NiO/L
Sour nickel solution is well mixed and is placed in belt stirrer and tank bottom and can be passed through in the rustless steel container of gas, is passed through
The mixed gas of carbon dioxide and air, carbon dioxide in gas mixture concentration is 60v%, flow
5Nm3/h.40 DEG C of reaction temperature, reaction end pH value 10, stopping is passed through carbon dioxide, aging 25
Minute, mother liquor is separated by filtration, wash.3h is dried at 90 DEG C, 120 DEG C dry 2h, obtain sample N4.
(2) nickeliferous aluminum oxide
Weigh the nickeliferous boehmite N4 100g of preparation, add 5.8ml nitric acid, 1.6ml phosphoric acid,
Then 6.8g sesbania powders and water mixer kneader into plastic, extruded moulding dry 4h, 1050 DEG C at 120 DEG C
Roasting 4h, obtains carrier Z4.
Embodiment 5
(1) nickeliferous boehmite
It is 185g Al by 1L concentration2O3The sodium aluminate solution and 1L concentration of/L are 15g NiO/L's
Nickel nitrate solution is well mixed and is placed in belt stirrer and tank bottom and can be passed through in the rustless steel container of gas, leads to
Enter the mixed gas of carbon dioxide and air, carbon dioxide in gas mixture concentration is 70v%, flow
3Nm3/h.35 DEG C of reaction temperature, reaction end pH value 9.5, stopping is passed through carbon dioxide, aging
45 minutes, mother liquor is separated by filtration, washed.120 DEG C dry 2h, obtain sample N5.
(2) nickeliferous aluminum oxide
Weigh the nickeliferous boehmite N5 100g of preparation, add 6.4ml nitric acid, 1.5ml phosphoric acid,
Then 7.2g sesbania powders and water mixer kneader into plastic, extruded moulding dry 4h, 950 DEG C at 110 DEG C
Roasting 4h, obtains carrier Z5.
Comparative example 2
(1) boehmite
It is 120g Al by 2L concentration2O3The sodium aluminate solution of/L is placed in belt stirrer and tank bottom and can be passed through
In the rustless steel container of gas, the mixed gas of carbon dioxide and air are passed through, dioxy in mixed gas
Change concentration of carbon is 60v%, flow 4Nm3/h.40 DEG C of reaction temperature, reaction end pH value 10 stops
Carbon dioxide is only passed through, aging 30 minutes, mother liquor is separated by filtration, washed.3h is dried at 90 DEG C,
120 DEG C dry 2h, obtain sample A2.
(2) aluminum oxide
The boehmite A2100g of preparation is weighed, 7.2ml nitric acid, 1.8ml phosphoric acid, 7.8g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 920 DEG C of roastings at 120 DEG C
4h is burnt, carrier D2 is obtained.
Embodiment 6
(1) nickeliferous boehmite
It is 180g Al by 1L concentration2O3The aluminum nitrate solution and 0.5L concentration of/L are 36g NiO/L's
Nickel nitrate solution is well mixed in the container for loading high level, and compound concentration is the ammonia spirit of 10wt%
Load in the container of high level, peristaltic pump is connected under two containers carry out flow control and flow into equipped with 3L bottoms water
Belt stirrer and tank bottom can be passed through in the rustless steel container of gas, 45 DEG C of reaction temperature, control flow is adjusted
Section reacting system PH value is 8, after reaction terminates, adds ammoniacal liquor regulation regulation plasm PH value 8.5,
Aging 30 minutes, mother liquor is separated by filtration, washed.3h is dried at 90 DEG C, 120 DEG C dry 2h, obtain
Sample N6.
(2) nickeliferous aluminum oxide
Weigh the nickeliferous boehmite N6 100g of preparation, add 5.5ml nitric acid, 2.2ml phosphoric acid,
Then 7.5g sesbania powders and water mixer kneader into plastic, extruded moulding dry 4h, 890 DEG C at 120 DEG C
Roasting 4h, obtains carrier Z6.
Embodiment 7
(1) nickeliferous boehmite
It is 195g Al by 1L concentration2O3The aluminum nitrate solution and 0.5L concentration of/L are 10g NiO/L's
Nickel nitrate solution is well mixed in the container for loading high level, and compound concentration is filled for the ammonia spirit of 8wt%
Enter in the container of high level, peristaltic pump is connected under two containers carries out flow control band of the inflow equipped with 5L bottoms water
Agitator and tank bottom can be passed through in the rustless steel container of gas, 50 DEG C of reaction temperature, controls Flow-rate adjustment
Reacting system PH value is 7.5, after reaction terminates, adds ammoniacal liquor regulation regulation plasm PH value 8.5, always
Change 60 minutes, be separated by filtration mother liquor, wash.3h is dried at 90 DEG C, 120 DEG C dry 2h, obtain sample
Product N7.
(2) nickeliferous aluminum oxide
Weigh the nickeliferous boehmite N7 100g of preparation, add 6.4ml nitric acid, 1.8ml phosphoric acid,
Then 7.2g sesbania powders and water mixer kneader into plastic, extruded moulding dry 4h, 940 DEG C at 120 DEG C
Roasting 4h, obtains carrier Z7.
Comparative example 3
(1) boehmite
It is 100g Al to prepare 2L concentration2O3The aluminum nitrate solution and concentration of/L are the ammonia spirit of 8wt%
It is respectively charged into the container of high level, peristaltic pump is connected under two containers carries out flow control inflow equipped with 3L bottoms
The belt stirrer and tank bottom of water can be passed through in the rustless steel container of gas, 45 DEG C of reaction temperature, controlling stream
Amount regulation reacting system PH value is 7.5, after reaction terminates, adds ammoniacal liquor regulation regulation plasm PH value
8.5, aging 30 minutes, mother liquor is separated by filtration, wash.3h is dried at 90 DEG C, 120 DEG C dry 2h,
Obtain sample A3.
(2) aluminum oxide
The boehmite A3 100g of preparation are weighed, 6.2ml nitric acid, 2.2ml phosphoric acid, 7.8g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 880 DEG C of roastings at 120 DEG C
4h is burnt, carrier D3 is obtained.
Embodiment 8
(1) nickeliferous boehmite
It is 100g Al by 2L concentration2O3The sodium aluminate solution of/L is placed in belt stirrer and tank bottom and can be passed through
In the rustless steel container of gas, the mixed gas of carbon dioxide and air are passed through, dioxy in mixed gas
Change concentration of carbon is 60v%, flow 3Nm3/h.35 DEG C of reaction temperature, reaction end pH value 10 stops
Only it is passed through carbon dioxide.Under blowing air stirring condition, it is the nitric acid of 24g NiO/L to add 0.5L concentration
Nickel solution, is 9.5 by the way that ammoniacal liquor is added dropwise to adjust plasm PH value after stablizing 20 minutes, and reaction terminates
Aging 40 minutes afterwards, mother liquor is separated by filtration, washed.3h is dried at 90 DEG C, 120 DEG C dry 2h,
Obtain sample N8.
(2) nickeliferous aluminum oxide
The nickeliferous boehmite N8 100g of preparation are weighed, 7ml nitric acid, 1.5ml phosphoric acid, 8g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 950 DEG C of roastings at 120 DEG C
4h is burnt, carrier Z8 is obtained.
Embodiment 9
(1) nickeliferous boehmite
It is 92g Al by 2L concentration2O3The sodium aluminate solution of/L is placed in belt stirrer and tank bottom and can be passed through
In the rustless steel container of gas, the mixed gas of carbon dioxide and air are passed through, dioxy in mixed gas
Change concentration of carbon is 80v%, flow 2Nm3/h.30 DEG C of reaction temperature, reaction end pH value 10.5,
Stopping is passed through carbon dioxide.Under blowing air stirring condition, it is the nitric acid of 7g NiO/L to add 1L concentration
Nickel solution, is 9.5 by the way that ammoniacal liquor is added dropwise to adjust plasm PH value after stablizing 30 minutes, and reaction terminates
Aging 30 minutes afterwards, mother liquor is separated by filtration, washed.3h is dried at 90 DEG C, 120 DEG C dry 2h,
Obtain sample N8.
(2) nickeliferous aluminum oxide
The nickeliferous boehmite N8 100g of preparation are weighed, 6ml nitric acid, 2.8ml phosphoric acid, 8g is added
Then sesbania powder and water mixer kneader into plastic, extruded moulding dry 4h, 980 DEG C of roastings at 120 DEG C
4h is burnt, carrier Z8 is obtained.
Comparative example 4
This comparative example prepares nickeliferous carrier according to the method that embodiment in CN1123392C is described, specifically
Step is as follows：
Weigh 100g aluminum hydroxide solid elastomer powder A5 and 5.0g sesbania powder it is well mixed after, then weigh 20g
After carbon black and 9.3g basic nickel carbonates are well mixed, four for previously having been measured with graduated cylinder are added wherein
Butyl ammonium hydroxide (wherein C16H37The content of NO about 10w%) 38ml, stirred with glass bar, make four
Butyl ammonium hydroxide solution is fully contacted with mixture, after placing 15 minutes, adds it to be mixed with field
In the aluminum hydroxide solid elastomer powder of cyanines powder, mix again；
Measure 6.3ml acetic acid and after 2.0g citric acids are dissolved in the deionized water of 95ml, be added to and be mixed with alkali
In the aluminum hydroxide solid elastomer powder of formula nickelous carbonate, carbon black and sesbania powder, kneading is into uniform paste plastic
Afterwards, the cloverleaf pattern bar of 2.0mm is extruded on banded extruder, after being dried 3.5 hours at 120 DEG C,
In being calcined 4 hours at 900 DEG C, alumina carrier containing Ni D4 is obtained.
Catalyst preparation：
Respectively by 13 carrier incipient impregnation active component nickel oxide and auxiliary agent cerium oxide, with same
Condition is dried, roasting, is prepared into catalyst, and prepared by embodiment alumina carrier containing Ni N1-N9 urges
Agent is respectively designated as C1~C9, and catalyst prepared by comparative example carrier D1-D4 is respectively designated as
C10~C13.Finally nickel and auxiliary agent cerium-oxide contents are identical in prepared catalyst.Wherein in terms of elemental nickel
Calculate, Nickel Content In Catalyst 12.8wt%, cerium oxide 3.0wt%.
Evaluating catalyst
It is raw material to use drippolene, and feedstock property is shown in Table 3, and C1~C13 catalyst is evaluated.
300h is evaluated respectively, and per 24h sampling analyses bromine valency and diene, average data see the table below 4.
Evaluating catalyst is carried out on 100ml adiabatic reactor hydrogenation reaction devices, and catalyst exists first
Reduced 10 hours under 350~450 DEG C of hydrogen, 35 DEG C are then cooled to, with containing DMDS
The hexamethylene passivation laggard feedstock oils of 2h of 1000ppm.Evaluate process conditions：Reaction pressure：2.8MPa,
Inlet temperature：50 DEG C, fresh feed oil air speed：3.0h-1, hydrogen and oil volume ratio：200: 1 (volume ratios
In terms of green oil).
The nickeliferous boehmite of table 1/boehmite property
2 alumina carrier containing Nis of table/carrying alumina volume property
The hydrogenating materials oil nature of table 3
The evaluating catalyst average data of table 4
As can be seen from Table 4：Evaluated under process conditions in identical, using nickeliferous oxidation of the invention
Catalyst prepared by alumina supporter, the diene of hydrogenated products, bromine valency are relatively low, and this has absolutely proved reality
Applying the catalyst prepared in example has hydrogenation activity and stability higher.
Claims (16)
1. a kind of nickeliferous boehmite, it is characterised in that salic with institute in nickeliferous boehmite
Weight is 100% meter, and nickel content is 0.1wt%~10wt%, preferably 0.5wt%~5wt%；This is nickeliferous
The specific surface area 300m of boehmite2/ g~420m2/ g, pore volume is 0.7cm3/ g~1.2cm3/ g,
Aperture is 5nm~10nm；There are acid-base neutralization and plastic mistake in the preparation process of the nickeliferous boehmite
Journey.
2. nickeliferous boehmite according to claim 1, it is characterised in that the nickeliferous thin water aluminium of plan
The preparation process of stone comprises the following steps：
(1) addition bottom water in kettle is neutralized, bottom water is deionized water, is heated to 50~90 DEG C；
(2) acid aluminum saline solution, acid nickel salt aqueous solution are prepared respectively, by the acid aluminium salt aqueous solution
It is well mixed with acid nickel salt aqueous solution, the acidic mixed solution of aluminium containing salt and nickel salt is obtained, regulation should
Acidic mixed solution temperature is 50~90 DEG C, and wherein acid aluminium salt concentration of aqueous solution is 10~80g
Al2O3/ L, acid nickel salt aqueous solution concentration is 3~50gNiO/L；
(3) alkali metal aluminate solution is prepared, alkali metal aluminate solution concentration is 50~300g
Al2O3/L；
(4) the alkali metal aluminic acid that the acidic mixed solution and step (3) for obtaining step (2) are obtained
Salting liquid cocurrent is added in the neutralization kettle in step (1), constant ventilation stirring, until plastic；
(5) 50~90 DEG C of rate-determining steps (4) gelling temperature, plastic pH value 7~10；
(6) after cemented into bundles, through aging, filtering, washing, prepared nickeliferous boehmite is dried.
3. nickeliferous boehmite according to claim 2, it is characterised in that in step (1)
The bottom of neutralization kettle be passed through air.
4. nickeliferous boehmite according to claim 2, it is characterised in that in step (2)
The temperature for adjusting the acidic mixed solution is 60~80 DEG C.
5. nickeliferous boehmite according to claim 2, it is characterised in that in step (3)
The alkaline precipitating agent aqueous solution is added in alkali metal aluminate solution.
6. nickeliferous boehmite according to claim 2, it is characterised in that in step (5),
60~80 DEG C of gelling temperature；Plastic pH value 7~9.
7. the nickeliferous boehmite according to claim 2 or 5, it is characterised in that composite alkali aluminum
The pH value of acid salt solution or its mixed solution formed with the alkaline precipitating agent aqueous solution is 9~14, preferably
PH value 12~14.
8. nickeliferous boehmite according to claim 2, it is characterised in that acid aluminium salt is water-soluble
Liquid is the mixed solution of one or more in aluminium chloride, aluminum sulfate and aluminum nitrate, and preferably sulfuric acid aluminium is molten
Liquid；Acid nickel salt aqueous solution is one or more in nickel chloride, nickel sulfate, nickelous bromide and nickel nitrate
Mixed solution, preferred nickel nitrate solution；Alkali metal aluminate solution refers to sodium metaaluminate or meta-aluminic acid
Potassium solution.
9. nickeliferous boehmite according to claim 2, it is characterised in that acid aluminium salt and acid
Property nickel salt mixed solution pH value be 2~5, preferable ph 2~4.
10. nickeliferous boehmite according to claim 5, it is characterised in that alkaline precipitating agent
Refer to ammonium bicarbonate soln, sodium bicarbonate solution, ammonia spirit, sodium hydroxide solution or calcium hydroxide
Solution, preferably ammonia spirit, NH3Content is 50~120g/L.
11. nickeliferous boehmites according to claim 2, it is characterised in that in step (6)
In, aging temperature is 50~80 DEG C, and ageing time is 10~60min.
12. a kind of alumina carrier containing Nis, it is characterised in that by nickeliferous boehmite through shaping, roasting
Burn and obtain, contain δ-Al2O3、δ-NiAl26O40、NiAl2O40.45 in crystal formation, and XRD spectra
≤ B1/B2≤0.85, B1 refer in XRD spectra 2 θ be 34.2~39.8 ° peak integrated intensity,
B2 refer in XRD spectra 2 θ be 43.3~48.5 ° peak integrated intensity.
13. alumina carrier containing Nis according to claim 12, it is characterised in that nickeliferous aluminum oxide
δ-Al in carrier2O3、δ-NiAl26O40And NiAl2O4Account for alumina carrier containing Ni gross weight
30%~100%.
14. alumina carrier containing Nis according to claim 12, it is characterised in that nickeliferous aluminum oxide
Contain θ-Al in carrier2O3、α-Al2O3And/or γ-Al2O3；Best α-Al2O3Less than 30wt%.
15. alumina carrier containing Nis according to claim 12, it is characterised in that：Roasting condition
For：800~1200 DEG C of 4~10h of roasting.
16. alumina carrier containing Nis according to claim 12, it is characterised in that：Nickeliferous oxidation
Best nickel content is 0.1wt%~10wt%, preferably 0.5wt%~7.5wt%, nickeliferous oxidation in alumina supporter
The specific surface area of alumina supporter is 20m2/ g~230m2/ g, pore volume is 0.10cm3/ g~0.65cm3/ g, hole
Footpath is 7nm~30nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510818869.1A CN106732607B (en) | 2015-11-23 | 2015-11-23 | Nickel-containing pseudo-boehmite and carrier prepared from same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510818869.1A CN106732607B (en) | 2015-11-23 | 2015-11-23 | Nickel-containing pseudo-boehmite and carrier prepared from same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106732607A true CN106732607A (en) | 2017-05-31 |
| CN106732607B CN106732607B (en) | 2020-02-14 |
Family
ID=58962951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510818869.1A Active CN106732607B (en) | 2015-11-23 | 2015-11-23 | Nickel-containing pseudo-boehmite and carrier prepared from same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106732607B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107930612A (en) * | 2017-10-31 | 2018-04-20 | 山东玉皇化工有限公司 | A kind of preparation method of more metal C5 catalyst carrier for hydrgenating |
| CN110639484A (en) * | 2019-09-25 | 2020-01-03 | 山东金滢新材料有限公司 | Preparation method of pseudo-boehmite |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103055922A (en) * | 2011-10-21 | 2013-04-24 | 中国石油化工股份有限公司 | Preparation method of bulk phase hydrocracking catalyst |
| CN103055876A (en) * | 2013-01-22 | 2013-04-24 | 新地能源工程技术有限公司 | Preparation method of wide-temperature methanation catalyst |
| CN103769104A (en) * | 2012-10-20 | 2014-05-07 | 中国石油化工股份有限公司 | Nickel base selective hydrogenation catalyst, preparation method and application thereof |
-
2015
- 2015-11-23 CN CN201510818869.1A patent/CN106732607B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103055922A (en) * | 2011-10-21 | 2013-04-24 | 中国石油化工股份有限公司 | Preparation method of bulk phase hydrocracking catalyst |
| CN103769104A (en) * | 2012-10-20 | 2014-05-07 | 中国石油化工股份有限公司 | Nickel base selective hydrogenation catalyst, preparation method and application thereof |
| CN103055876A (en) * | 2013-01-22 | 2013-04-24 | 新地能源工程技术有限公司 | Preparation method of wide-temperature methanation catalyst |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107930612A (en) * | 2017-10-31 | 2018-04-20 | 山东玉皇化工有限公司 | A kind of preparation method of more metal C5 catalyst carrier for hydrgenating |
| CN110639484A (en) * | 2019-09-25 | 2020-01-03 | 山东金滢新材料有限公司 | Preparation method of pseudo-boehmite |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106732607B (en) | 2020-02-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106179386B (en) | The preparation method of Hydrobon catalyst | |
| CN108855093A (en) | A kind of nickel-copper series hydrocatalyst and preparation method thereof | |
| CN106732636A (en) | A kind of sulphided state poor oil suspension bed hydrogenation catalyst and its preparation method and application | |
| CN108855106A (en) | A kind of nickel-zinc series hydrocatalyst and preparation method thereof | |
| CN107983406A (en) | A kind of hydrogenation catalyst and its preparation and application | |
| CN106732620B (en) | Nickel series hydrogenation catalyst and preparation method thereof | |
| CN106927476B (en) | The preparation method of Mo-SBA-15 molecular sieve and hydrogenation catalyst | |
| CN108855127B (en) | Hydrogenation catalyst and preparation method thereof | |
| CN108262047B (en) | Nickel-molybdenum series hydrogenation catalyst and preparation method thereof | |
| CN108855114A (en) | A kind of hydrogenation protecting agent and preparation method thereof | |
| CN106732607A (en) | A kind of nickeliferous boehmite and carrier prepared therefrom | |
| CN108865239B (en) | Selective hydrogenation method for pyrolysis gasoline | |
| CN108264586A (en) | A kind of method of hydrotreating of C 5 petroleum resin | |
| CN106179385B (en) | A kind of preparation method of Hydrobon catalyst | |
| CN108855128A (en) | A kind of selective hydrogenation catalyst and preparation method thereof | |
| CN108865243B (en) | Pre-hydrogenation treatment method of carbon tetra-alkylation raw material | |
| CN108863706A (en) | A kind of selection method of hydrotreating of the C-4-fraction containing alkynes | |
| CN108864368A (en) | C 5 petroleum resin method of hydrotreating | |
| CN108865238A (en) | A kind of method of hydrotreating of drippolene | |
| CN108865241B (en) | Selective hydrogenation method for cracked gasoline carbon eight fractions | |
| CN108863699A (en) | A kind of method of selective acetylene hydrocarbon hydrogenation recycling butadiene | |
| CN108855129A (en) | A kind of nickel-silver series hydrocatalyst and preparation method thereof | |
| CN108863697A (en) | A method of volume increase butadiene | |
| CN108865240B (en) | Selective hydrogenation method for pyrolysis gasoline | |
| CN108865242B (en) | Selective hydrogenation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |