CN106732466A - A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof - Google Patents
A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof Download PDFInfo
- Publication number
- CN106732466A CN106732466A CN201710107338.0A CN201710107338A CN106732466A CN 106732466 A CN106732466 A CN 106732466A CN 201710107338 A CN201710107338 A CN 201710107338A CN 106732466 A CN106732466 A CN 106732466A
- Authority
- CN
- China
- Prior art keywords
- parts
- formaldehyde
- ticl
- reaction
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 100
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 28
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 13
- 238000006757 chemical reactions by type Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 30
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 21
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910003074 TiCl4 Inorganic materials 0.000 claims abstract description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 15
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 14
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940043237 diethanolamine Drugs 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002635 polyurethane Polymers 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 9
- 239000012153 distilled water Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000005292 vacuum distillation Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 239000004519 grease Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 239000010936 titanium Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 229930040373 Paraformaldehyde Natural products 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009830 intercalation Methods 0.000 abstract description 2
- 230000002687 intercalation Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 229920002866 paraformaldehyde Polymers 0.000 abstract description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- 235000019256 formaldehyde Nutrition 0.000 description 23
- 239000000463 material Substances 0.000 description 5
- 150000002148 esters Chemical group 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 238000006845 Michael addition reaction Methods 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000003905 indoor air pollution Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of adsorption reaction type formaldehyde eliminating agent, it is made up of the raw material of following weight portion：6 15 parts of diethanol amine, 56 84 parts of methyl alcohol, 12 28 parts of methyl acrylate, 37 52 parts of montmorillonite, 31 42 parts of trimethylolpropane, 38 parts of p-methyl benzenesulfonic acid, 58 84 parts of diethyl malonate, 27 parts of Anhydrous potassium carbonate, TiCl4 21 36 parts, appropriate hydrochloric acid solution distills appropriate amount of water, appropriate absolute ethyl alcohol.The present invention utilizes the layer structure of montmorillonite, realize the stable curing to titanium deoxide catalyst, improve the photocatalytic degradation efficiency of PARA FORMALDEHYDE PRILLS(91,95), hyperbranched polyurethane intercalation modifying montmorillonite is utilized afterwards, the physical absorption of formaldehyde and chemical reaction are combined, finally formaldehyde is changed into nontoxic, tasteless substance, accomplish to eliminate the purpose of formaldehyde in absorption, reach the effect of quick, lasting purify air.
Description
Technical field
The present invention relates to a kind of formaldehyde scavenger, and in particular to a kind of adsorption reaction type formaldehyde eliminating agent and its preparation side
Method.
Background technology
Formaldehyde is a kind of extremely strong bactericide, is widely used in industrial production.Formaldehyde is manufacture synthetic resin, paint, modeling
The raw material of material and staple fibre, is the weight of wood-based panel industry manufacture urea-formaldehyde resin adhesive, melamine resin adehsive and phenolic resin glue
Want raw material.Formaldehyde is more highly toxic material, and formaldehyde is in second on China's toxic chemical priority acccess control list.Formaldehyde
It is defined as carcinogenic by the World Health Organization and causes deformed material, be generally acknowledged allergen, is also prominent potential strong cause
Become one of thing.
At present, the main method that people eliminate formaldehyde in indoor air pollution is to use formaldehyde eliminating agent.But existing market
The common formaldehyde eliminating agent product of upper sale formaldehyde elimination amount within a certain period of time is limited and persistence of effect is poor, leads to
The term of validity of normal these formaldehyde eliminating agents only has several days time.
Wang Xuechuan, Yuan Xuzheng et al. are at it《The synthesis and application of active methylene group class dissaving polymer methanal trapping agent》
It is that raw material is obtained AB by Michael addition reactions with diethanol amine (DEA) and methyl acrylate (MA) in one text2Type monomer,
Under Catalyzed by p-Toluenesulfonic Acid, there is ester exchange reaction with trimethylolpropane, be obtained a kind of superbrnaching end-hydroxy it is poly- (amine-
Ester), afterwards and diethyl malonate, terminal groups modification is carried out to terminal hydroxy group hyperbranched poly (amine -ester) by ester exchange reaction, so that
Active methylene group class dissaving polymer (HPAM) is prepared, formaldehyde can be effectively caught, but its acquisition procedure is slower.
Montmorillonite (MMT) is the two-dimensional layer silicate mineral that a class interlayer has exchangeable cations, with good swollen
Swollen property, adsorptivity and cation exchange property, favourable bar is provided for many intercalated materials carry out the compound insertion reaction of interlayer
Part.Therefore can be realized using montmorillonite it is immobilized to stablizing for catalyst, while can be used to formaldehyde adsorption, to reach purify air
Purpose.
The content of the invention
The present invention is in view of the shortcomings of the prior art, there is provided a kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof.
A kind of adsorption reaction type formaldehyde eliminating agent, is made up of the raw material of following weight portion：Diethanol amine 6-15 parts, methyl alcohol
56-84 parts, methyl acrylate 12-28 parts, montmorillonite 37-52 parts, trimethylolpropane 31-42 parts, p-methyl benzenesulfonic acid 3-8 parts,
Diethyl malonate 58-84 parts, Anhydrous potassium carbonate 2-7 parts, TiCl4 21-36 parts, appropriate hydrochloric acid solution distills appropriate amount of water, anhydrous
Appropriate amount of ethanol.
Comprise the following steps that：
（1）Prepare TiCl4Pillaring agent：
By TiCl4It is added in hydrochloric acid solution, with distilled water diluting to Ti4+0.8mol/L and 0.2- are respectively with HCl concentration
0.4mol/L, obtains final product TiCl4Pillaring agent；
（2）Montmorillonite is dispersed in distilled water, above-mentioned TiCl is slowly added dropwise4Pillaring agent, stirring reaction 4-5 hours, adjusts pH value
To 2-3, stirring reaction 3-5 hours, centrifugation afterwards with absolute ethanol washing, suction filtration, was washed, dried, at 500 DEG C afterwards
Lower calcination product 45-70 minutes, through cooling, grinding, obtains final product Titania Pillared Montmorillonites；
（3）The synthesis of reaction monomers：
Add diethanol amine and methyl alcohol, mixture to be stirred at room temperature to diethanol amine after being completely dissolved in there-necked flask, delay
Slow that methyl acrylate is added dropwise, charging is warming up to 30-40 DEG C insulation reaction 3-5 hours, then vacuumizes removing methyl alcohol, obtains after finishing
To grease；
（4）The preparation of superbrnaching end-hydroxy Polyurethane modified montmorillonoid：
Step is added in there-necked flask（2）Titania Pillared Montmorillonites, trimethylolpropane and p-methyl benzenesulfonic acid, stirring are mixed
Compound 10-25 minutes, 110-120 DEG C is warming up to, starts to stir and be added dropwise step（3）Reaction monomers, 110-130 DEG C of reaction 30-
After 50 minutes, continuation is reacted in being transferred to Rotary Evaporators, untill system is bloated there is no bubble, obtains terminal hydroxy group over-expense
Change Polyurethane modified montmorillonoid；
（5）Diethyl malonate and catalyst Anhydrous potassium carbonate are added in there-necked flask, after stirring, is to slowly warm up to
95-105 DEG C, start to be slowly added to step（4）Product, charging is finished latter insulation reaction 4-5 hours, then vacuum distillation, takes out true
Vacancy is managed, and is obtained final product.
Wherein, the concentration of described hydrochloric acid solution is 2.0mol/L.
Wherein, step（1）Prepare TiCl4During pillaring agent, Ti:HCl mol ratios are 2:1.
Wherein, step（2）Middle drying condition is drying temperature at 65-73 DEG C, drying time 3-6 hours.
Compared with prior art, the present invention has advantages below：
（1）The present invention is prepared for superbrnaching end-hydroxy Polyurethane intercalation modifying montmorillonite, reacts right with diethyl malonate afterwards
Polymer carries out blocking modification, and hyperbranched polyurethane is a three-dimensional molecular structure for nearly ball-type, exists in the inside of molecule empty
Chamber, PARA FORMALDEHYDE PRILLS(91,95) small molecule has certain suction-operated, while using the absorption property of montmorillonite, by formaldehyde fast Acquisition, absorption
On remover, in addition because its a large amount of active methylene group functional group contained can react with formaldehyde, first can be effectively reduced
The content of aldehyde.
（2）The present invention realizes the stable curing to titanium deoxide catalyst using the layer structure of montmorillonite, improves to first
The photocatalytic degradation efficiency of aldehyde, the physical absorption of formaldehyde and chemical reaction are combined, and finally change into formaldehyde nontoxic, tasteless
Material, accomplishes to eliminate the purpose of formaldehyde in absorption, the effect of quick, lasting purify air is reached, to sky when actually used
Other poisonous odor gas in gas also have stronger suction-operated, and practical effect is good.
Specific embodiment
A kind of adsorption reaction type formaldehyde eliminating agent, is made up of the raw material of following weight portion：11 parts of diethanol amine, methyl alcohol 63
Part, 24 parts of methyl acrylate, 42 parts of montmorillonite, 37 parts of trimethylolpropane, 4 parts of p-methyl benzenesulfonic acid, 76 parts of diethyl malonate,
6 parts of Anhydrous potassium carbonate, TiCl4 26 parts, appropriate hydrochloric acid solution distills appropriate amount of water, appropriate absolute ethyl alcohol.
Comprise the following steps that：
（1）Prepare TiCl4Pillaring agent：
By TiCl4It is added in hydrochloric acid solution, with distilled water diluting to Ti4+0.8mol/L and 0.3mol/ are respectively with HCl concentration
L, obtains final product TiCl4Pillaring agent；
（2）Montmorillonite is dispersed in distilled water, above-mentioned TiCl is slowly added dropwise4Pillaring agent, stirring reaction 4 hours adjusts pH value extremely
2.5, stirring reaction 4 hours, afterwards centrifugation with absolute ethanol washing, suction filtration, is washed, dried afterwards, is forged at 500 DEG C
Burn product 60 minutes, through cooling, grinding, obtain final product Titania Pillared Montmorillonites；
（3）The synthesis of reaction monomers：
Add diethanol amine and methyl alcohol, mixture to be stirred at room temperature to diethanol amine after being completely dissolved in there-necked flask, delay
Slow to be added dropwise methyl acrylate, charging is warming up to 35 DEG C of insulation reactions 4 hours after finishing, then vacuumize removing methyl alcohol, obtains oil
Shape thing；
（4）The preparation of superbrnaching end-hydroxy Polyurethane modified montmorillonoid：
Step is added in there-necked flask（2）Titania Pillared Montmorillonites, trimethylolpropane and p-methyl benzenesulfonic acid, stirring are mixed
Compound 20 minutes, is warming up to 115 DEG C, starts to stir and be added dropwise step（3）Reaction monomers, after 120 DEG C are reacted 40 minutes, are transferred to
Continue to react in Rotary Evaporators, untill system is bloated there is no bubble, obtain the ester modified illiteracy of superbrnaching end-hydroxy polyamine
De- soil；
（5）Diethyl malonate and catalyst Anhydrous potassium carbonate are added in there-necked flask, after stirring, is to slowly warm up to
100 DEG C, start to be slowly added to step（4）Product, charging finishes rear insulation reaction 4 hours, and then vacuum distillation vacuumizes place
Reason, obtains final product.
Wherein, the concentration of described hydrochloric acid solution is 2.0mol/L.
Wherein, step（1）Prepare TiCl4During pillaring agent, Ti:HCl mol ratios are 2:1.
Wherein, step（2）Middle drying condition is drying temperature at 65-73 DEG C, drying time 3-6 hours.
Claims (5)
1. a kind of adsorption reaction type formaldehyde eliminating agent, it is characterised in that be made up of the raw material of following weight portion：Diethanol amine 6-15
Part, methyl alcohol 56-84 parts, methyl acrylate 12-28 parts, montmorillonite 37-52 parts, trimethylolpropane 31-42 parts, p-methyl benzenesulfonic acid
3-8 parts, diethyl malonate 58-84 parts, Anhydrous potassium carbonate 2-7 parts, TiCl4 21-36 parts, appropriate hydrochloric acid solution, distilled water is fitted
Amount, appropriate absolute ethyl alcohol.
2. the preparation method of a kind of adsorption reaction type formaldehyde eliminating agent according to claims 1, it is characterised in that specific
Step is as follows：
（1）Prepare TiCl4Pillaring agent：
By TiCl4It is added in hydrochloric acid solution, with distilled water diluting to Ti4+0.8mol/L and 0.2- are respectively with HCl concentration
0.4mol/L, obtains final product TiCl4Pillaring agent；
（2）Montmorillonite is dispersed in distilled water, above-mentioned TiCl is slowly added dropwise4Pillaring agent, stirring reaction 4-5 hours, adjusts pH value extremely
2-3, stirring reaction 3-5 hours, centrifugation afterwards with absolute ethanol washing, suction filtration, was washed, dried, at 500 DEG C afterwards
Calcination product 45-70 minutes, through cooling, grinding, obtain final product Titania Pillared Montmorillonites；
（3）The synthesis of reaction monomers：
Add diethanol amine and methyl alcohol, mixture to be stirred at room temperature to diethanol amine after being completely dissolved in there-necked flask, delay
Slow that methyl acrylate is added dropwise, charging is warming up to 30-40 DEG C insulation reaction 3-5 hours, then vacuumizes removing methyl alcohol, obtains after finishing
To grease；
（4）The preparation of superbrnaching end-hydroxy Polyurethane modified montmorillonoid：
Step is added in there-necked flask（2）Titania Pillared Montmorillonites, trimethylolpropane and p-methyl benzenesulfonic acid, stirring are mixed
Compound 10-25 minutes, 110-120 DEG C is warming up to, starts to stir and be added dropwise step（3）Reaction monomers, 110-130 DEG C of reaction 30-
After 50 minutes, continuation is reacted in being transferred to Rotary Evaporators, untill system is bloated there is no bubble, obtains terminal hydroxy group over-expense
Change Polyurethane modified montmorillonoid；
（5）Diethyl malonate and catalyst Anhydrous potassium carbonate are added in there-necked flask, after stirring, is to slowly warm up to
95-105 DEG C, start to be slowly added to step（4）Product, charging is finished latter insulation reaction 4-5 hours, then vacuum distillation, takes out true
Vacancy is managed, and is obtained final product.
3. a kind of preparation method of the adsorption reaction type formaldehyde eliminating agent according to claims 1,2, it is characterised in that institute
The concentration of the hydrochloric acid solution stated is 2.0mol/L.
4. a kind of preparation method of the adsorption reaction type formaldehyde eliminating agent according to claims 2, it is characterised in that step
（1）Prepare TiCl4During pillaring agent, Ti:HCl mol ratios are 2:1.
5. a kind of preparation method of the adsorption reaction type formaldehyde eliminating agent according to claims 2, it is characterised in that step
（2）Middle drying condition is drying temperature at 65-73 DEG C, drying time 3-6 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710107338.0A CN106732466A (en) | 2017-02-27 | 2017-02-27 | A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710107338.0A CN106732466A (en) | 2017-02-27 | 2017-02-27 | A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106732466A true CN106732466A (en) | 2017-05-31 |
Family
ID=58960709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710107338.0A Pending CN106732466A (en) | 2017-02-27 | 2017-02-27 | A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106732466A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108837807A (en) * | 2018-06-27 | 2018-11-20 | 王秀玲 | A kind of material for air purification and preparation method thereof for atmosphere pollution |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1724358A (en) * | 2004-07-22 | 2006-01-25 | 中国地质大学（北京） | Key tech. for preparing titanium dioxide post-ylene-montmorilloid by titanium tetrachloride hydrolysis process |
| CN102249369A (en) * | 2011-04-29 | 2011-11-23 | 中国地质大学（武汉） | Pumice-carried cyanobacteria scavenger capable of floating on water surface |
| CN103933930A (en) * | 2014-04-21 | 2014-07-23 | 康美药业股份有限公司 | Application of nano pillared montmorillonite in preparing air purifying agent and preparation method of nano pillared montmorillonite |
| CN105688798A (en) * | 2016-01-29 | 2016-06-22 | 常州达奥新材料科技有限公司 | Preparation method of photosensitive high-thermal-stability pillar bearing clay material |
| CN106111143A (en) * | 2016-06-27 | 2016-11-16 | 郭迎庆 | A kind of preparation method of near infrared light catalysis column clay catalyst |
-
2017
- 2017-02-27 CN CN201710107338.0A patent/CN106732466A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1724358A (en) * | 2004-07-22 | 2006-01-25 | 中国地质大学（北京） | Key tech. for preparing titanium dioxide post-ylene-montmorilloid by titanium tetrachloride hydrolysis process |
| CN102249369A (en) * | 2011-04-29 | 2011-11-23 | 中国地质大学（武汉） | Pumice-carried cyanobacteria scavenger capable of floating on water surface |
| CN103933930A (en) * | 2014-04-21 | 2014-07-23 | 康美药业股份有限公司 | Application of nano pillared montmorillonite in preparing air purifying agent and preparation method of nano pillared montmorillonite |
| CN105688798A (en) * | 2016-01-29 | 2016-06-22 | 常州达奥新材料科技有限公司 | Preparation method of photosensitive high-thermal-stability pillar bearing clay material |
| CN106111143A (en) * | 2016-06-27 | 2016-11-16 | 郭迎庆 | A kind of preparation method of near infrared light catalysis column clay catalyst |
Non-Patent Citations (2)
| Title |
|---|
| 王雪川 等: "活泼亚甲基类超支化聚合物甲醛捕获剂的合成及应用", 《中国皮革》 * |
| 董梦琴: "纳米二氧化钛/蒙脱土复合材料的制备及其催化活性研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108837807A (en) * | 2018-06-27 | 2018-11-20 | 王秀玲 | A kind of material for air purification and preparation method thereof for atmosphere pollution |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106893064A (en) | A kind of hyperbranched polyurethane/montmorillonite modified polyurethane slurry and preparation method thereof | |
| CN101712583B (en) | Preparation of laminated clay modified ammonification lignin fertilizer | |
| CN103013197A (en) | Preparation method of nano anti-fogging agent | |
| CN102350318A (en) | Formaldehyde adsorption resin and preparation method thereof | |
| CN110559868B (en) | Preparation method and application of click chemical imprinting-based o-cloxacillin molecular composite membrane | |
| CN108689411A (en) | A kind of preparation method of waterproof high tenacity porous silica | |
| CN104437388A (en) | Indoor methanol remover formula | |
| CN106732466A (en) | A kind of adsorption reaction type formaldehyde eliminating agent and preparation method thereof | |
| CN104492234A (en) | Indoor solid aldehyde removing agent and preparation method thereof | |
| CN106823768A (en) | A kind of titanium dioxide hyperbranched polyurethane montmorillonite Composite fiber filter material and preparation method thereof | |
| CN116285852A (en) | Adhesive and preparation method thereof | |
| CN108219708A (en) | A kind of preparation method of environmental protection glutinous rice glue | |
| CN102532346A (en) | Environmentally-friendly method for preparing chitosan quaternary ammonium salt in ion liquid | |
| CN103041784B (en) | Glycine graft crosslinking chitosan microball adsorbent for heavy metal | |
| CN102600453B (en) | Preparation method of colistin sulfate premixing agents | |
| CN101117422A (en) | Method for preparing alta-mud composite highly-absorbent resin by optical polymerization process | |
| CN106833234A (en) | Interior finish of purifying formaldehyde and preparation method thereof under a kind of physical absorption and photocatalysis double acting | |
| CN104841398A (en) | Indoor formaldehyde-removal adsorbent and preparation method thereof | |
| CN102675484A (en) | Synthetic method of 4-hydrazoic benzoyl chitosan | |
| CN106832674A (en) | A kind of environment-friendly type interior decoration film of removable formaldehyde and preparation method thereof | |
| CN101851442A (en) | Water-resistant interior and exterior wall putty capable of absorbing and burying carbon dioxide in air | |
| CN1359992A (en) | Blocking absorbent of formaldehyde and its preparing process and application | |
| CN114015319B (en) | Formaldehyde-resistant self-cleaning wall paint and preparation method thereof | |
| CN105906238A (en) | Healthy and environmentally-friendly wall material and preparation method thereof | |
| CN108421366A (en) | Gelatin hydrolysate removes aldehyde composite material and preparation method with diatomite covalent bonding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |