CN106731567A - Ammonium paratungstate production spray column - Google Patents

Ammonium paratungstate production spray column Download PDF

Info

Publication number
CN106731567A
CN106731567A CN201611150660.3A CN201611150660A CN106731567A CN 106731567 A CN106731567 A CN 106731567A CN 201611150660 A CN201611150660 A CN 201611150660A CN 106731567 A CN106731567 A CN 106731567A
Authority
CN
China
Prior art keywords
spray column
spray
vaporific
waste gas
column
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611150660.3A
Other languages
Chinese (zh)
Inventor
贺建昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
South-East Nonferrous Metal Ltd Hengyang Hunan
Original Assignee
South-East Nonferrous Metal Ltd Hengyang Hunan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by South-East Nonferrous Metal Ltd Hengyang Hunan filed Critical South-East Nonferrous Metal Ltd Hengyang Hunan
Priority to CN201611150660.3A priority Critical patent/CN106731567A/en
Publication of CN106731567A publication Critical patent/CN106731567A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8681Acidic components
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00Compounds of tungsten

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a kind of ammonium paratungstate production spray column, including spray column, the bottom of the spray column is provided with acid waste gas inlet port, the top of the spray column is provided with gas outlet, the inner cavity top of the spray column is provided with vaporific spray head, the bottom of the spray column is provided with liquid outlet, in the bottom of the spray column, interleaved is provided with some flow-disturbing swash plates successively from the bottom to top, the surface of each flow-disturbing swash plate is coated with exhaust gas catalyst, the pH of the vaporific spray liquid for spraying out by the vaporific spray head is 12~14, the NaOH of the vaporific spray liquid and the proportioning of water are 1:15~20.The acid waste gas produced during ammonium paratungstate production prevent from causing acid waste gas to pollute by after effect of the invention, obtaining neutral waste gas.

Description

Ammonium paratungstate production spray column
Technical field
The present invention relates to ammonium paratungstate production apparatus field, more particularly to a kind of ammonium paratungstate production spray column.
Background technology
Ammonium paratungstate (APT) is the important intermediate compound for producing tungsten powder, tungsten filament, tungsten-bast alloy and all tungsten materials, is also Large exporting of China.Acid waste gas can be produced during production ammonium paratungstate, there is presently no to this generation The device that acid waste gas are reclaimed.
The content of the invention
A kind of above-mentioned not enough and defect it is an object of the invention to be directed to prior art, there is provided ammonium paratungstate production spray Tower, to solve the above problems.
Technical problem solved by the invention can be realized using following technical scheme:
Ammonium paratungstate production spray column, including spray column, acid waste gas inlet port is provided with the bottom of the spray column, The top of the spray column is provided with gas outlet, the inner cavity top of the spray column is provided with vaporific spray head, the spray The bottom of tower is provided with liquid outlet, it is characterised in that in the bottom of the spray column, interleaved is provided with successively from the bottom to top Some flow-disturbing swash plates, the surface of each flow-disturbing swash plate is coated with exhaust gas catalyst, the mist for spraying out by the vaporific spray head The pH of shape spray liquid is 12~14, and the NaOH of the vaporific spray liquid and the proportioning of water are 1:15~20.
As a result of technical scheme as above, the acid waste gas produced during ammonium paratungstate production are by of the invention After effect, the waste gas of neutrality is obtained, prevent from causing acid waste gas to pollute.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation of an embodiment of the present invention.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, enter below One step illustrates the present invention.
Ammonium paratungstate production spray column shown in Figure 1, including spray column 100, are provided with the bottom of spray column 100 Acid waste gas inlet port 110, gas outlet 120 is provided with the top of spray column 100, and the inner cavity top of spray column 100 is provided with Vaporific spray head 130, the bottom of spray column is provided with liquid outlet 140.In the bottom of spray column 100, interval is handed over successively from the bottom to top Mistake is provided with some flow-disturbing swash plates 210, and the surface of each flow-disturbing swash plate 210 is coated with exhaust gas catalyst, by vaporific spray head 130 The pH of spray vaporific spray liquid 131 out is 12~14, and the NaOH of vaporific spray liquid 131 and the proportioning of water are 1:15~ 20。
Operation principle of the invention is as follows:
The acid waste gas produced during ammonium paratungstate production enter the inner chamber of spray column 100 by acid waste gas inlet port 110, First neutralized with the reaction of the exhaust gas catalyst on the surface of flow-disturbing swash plate 210 when by flow-disturbing swash plate 210, then again with by vaporific spray First 130 spray pH out are that 12~14 vaporific spray liquid 131 reacts, and are neutrality by the waste gas of present invention discharge, are prevented Acid waste gas are caused to pollute.
General principle of the invention and principal character and advantages of the present invention has been shown and described above.The technology of the industry Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (1)

1. ammonium paratungstate production spray column, including spray column, acid waste gas inlet port is provided with the bottom of the spray column, The top of the spray column is provided with gas outlet, and the inner cavity top of the spray column is provided with vaporific spray head, the spray column Bottom be provided with liquid outlet, it is characterised in that if interleaved is provided with successively from the bottom to top in the bottom of the spray column Interference stream swash plate, the surface of each flow-disturbing swash plate is coated with exhaust gas catalyst, by the vaporific spray head spray out it is vaporific The pH of spray liquid is 12~14, and the NaOH of the vaporific spray liquid and the proportioning of water are 1:15~20.
CN201611150660.3A 2016-12-14 2016-12-14 Ammonium paratungstate production spray column Pending CN106731567A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611150660.3A CN106731567A (en) 2016-12-14 2016-12-14 Ammonium paratungstate production spray column

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611150660.3A CN106731567A (en) 2016-12-14 2016-12-14 Ammonium paratungstate production spray column

Publications (1)

Publication Number Publication Date
CN106731567A true CN106731567A (en) 2017-05-31

Family

ID=58887407

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611150660.3A Pending CN106731567A (en) 2016-12-14 2016-12-14 Ammonium paratungstate production spray column

Country Status (1)

Country Link
CN (1) CN106731567A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112691528A (en) * 2020-12-28 2021-04-23 厦门钨业股份有限公司 Acid waste gas treatment system

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2605917Y (en) * 2003-03-19 2004-03-10 龙际银 Dustproof environmental protection system
CN2721210Y (en) * 2004-09-16 2005-08-31 石家庄市宏晟环保科技有限公司 Adsorptive gas purifier
CN101850205A (en) * 2010-05-27 2010-10-06 阳足开 Waste gas purification apparatus
CN202778248U (en) * 2012-07-12 2013-03-13 成都爱信雅克科技有限公司 Improved flue gas desulfurizer for atmospheric pressure hot water boiler
CN204365072U (en) * 2014-12-25 2015-06-03 湖州恒新商标制带有限公司 Fabrics workshop waste water dust arrester
CN204816153U (en) * 2015-06-09 2015-12-02 江苏德明新材料有限公司 Phenol -formaldehyde resin exhaust treatment device
CN204911127U (en) * 2015-09-07 2015-12-30 江苏锦润光电有限公司 Tail gas processing apparatus is used in LCD liquid crystal display production
CN205672762U (en) * 2016-05-11 2016-11-09 山东日科橡塑科技有限公司 A kind of air displacer for liquid chlorine storage tank
CN206391844U (en) * 2016-12-14 2017-08-11 衡阳市南东有色金属有限公司 Ammonium paratungstate production spray column

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2605917Y (en) * 2003-03-19 2004-03-10 龙际银 Dustproof environmental protection system
CN2721210Y (en) * 2004-09-16 2005-08-31 石家庄市宏晟环保科技有限公司 Adsorptive gas purifier
CN101850205A (en) * 2010-05-27 2010-10-06 阳足开 Waste gas purification apparatus
CN202778248U (en) * 2012-07-12 2013-03-13 成都爱信雅克科技有限公司 Improved flue gas desulfurizer for atmospheric pressure hot water boiler
CN204365072U (en) * 2014-12-25 2015-06-03 湖州恒新商标制带有限公司 Fabrics workshop waste water dust arrester
CN204816153U (en) * 2015-06-09 2015-12-02 江苏德明新材料有限公司 Phenol -formaldehyde resin exhaust treatment device
CN204911127U (en) * 2015-09-07 2015-12-30 江苏锦润光电有限公司 Tail gas processing apparatus is used in LCD liquid crystal display production
CN205672762U (en) * 2016-05-11 2016-11-09 山东日科橡塑科技有限公司 A kind of air displacer for liquid chlorine storage tank
CN206391844U (en) * 2016-12-14 2017-08-11 衡阳市南东有色金属有限公司 Ammonium paratungstate production spray column

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112691528A (en) * 2020-12-28 2021-04-23 厦门钨业股份有限公司 Acid waste gas treatment system

Similar Documents

Publication Publication Date Title
CN106731567A (en) Ammonium paratungstate production spray column
CN206391844U (en) Ammonium paratungstate production spray column
CN206391851U (en) Ammonium paratungstate production exhaust treatment system
CN201578964U (en) Venturi scrubber for scrubbing calcined tail gas of titanium white by sulfuric acid process
CN203108430U (en) Device for removing low-concentration sulfur dioxide from phosphate concentrate
CN209386758U (en) A kind of atomizing dry tower of the heat sensitive material of double funnel structures
CN204018102U (en) A kind of novel paint spray booth
CN206799753U (en) A kind of new pot for smelted copper
CN106512721A (en) Improved waste gas treatment system for ammonium paratungstate production
CN206508986U (en) Modified form ammonium paratungstate decomposer
CN102179668B (en) Boiler and pressure vessel pressing seal head and manufacture method
CN209715439U (en) A kind of new-type fan nozzle
CN104690909B (en) Stuffiness-proof mold
CN203803497U (en) Ethoxylation reaction device
CN203935977U (en) A kind of semi-automatic flush coater for the processing of graphite boat plate surface anti sticking layer
CN206935625U (en) One kind sealing spray plate
CN207646293U (en) A kind of end socket production pickler
CN202398456U (en) Long jet range conical pneumatic nozzle
CN206660897U (en) A kind of waste gas dividing processing environmental protecting device
CN204337968U (en) Gas washing dust arrester
CN205340531U (en) Waste gas treatment device
CN207308163U (en) A kind of vertical rotary flush coater
CN206838946U (en) A kind of stamping die swings clamping device
CN212263217U (en) Reduction system and discharge device thereof
CN214181823U (en) Powdery alkali-free accelerator spray drying device

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531

RJ01 Rejection of invention patent application after publication