CN106724601A - A kind of drinking water glass with anti-scald performance - Google Patents
A kind of drinking water glass with anti-scald performance Download PDFInfo
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- CN106724601A CN106724601A CN201710129288.6A CN201710129288A CN106724601A CN 106724601 A CN106724601 A CN 106724601A CN 201710129288 A CN201710129288 A CN 201710129288A CN 106724601 A CN106724601 A CN 106724601A
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Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
- A47G19/2227—Drinking glasses or vessels with means for amusing or giving information to the user
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
Abstract
The invention discloses a kind of drinking water glass with anti-scald performance, including cup and cup lid；Sealing ring is laid with the inside of the cup lid；The surface of the cup is coated with film layer；Cup lower section is provided with a purifying vessel, and purifying vessel is detachably connected with connection member；The connection member extends and its open top straight up along the bottom of cup.Drinking water glass of the present invention, structure simplicity generosity attractive in appearance.Solve the problems, such as that drinking water glass purposes is single.
Description
Technical field
The present invention relates to cup field, more particularly to a kind of drinking water glass with anti-scald performance.
Background technology
Thermos cup be it is a kind of by vacuum or other heat-barrier materials make cup so that wherein liquid insulating
Drinking device.Double-deck thermos cup is very common in daily life, vacuum layer is set in double-layer vacuum cup, although this thermos cup
Heat insulation effect can be with, but function is relatively simple.
In order to solve the problems, such as that drinking water glass is anti-scald, in the prior art generally to glass holder in cup outer cover, but it is only
It is merely to play a part of to prevent hand from scalding, winter is generally very cool using wall of cup, and when needing to drink water, the water of the inside is often
Scald very much again, user is worried when drinking, can usually scald oral cavity even esophagus because of the water for overheating, it is extremely dangerous.
The content of the invention
The present invention is intended to provide a kind of energy-conserving and environment-protective corrugated sheet, to solve above-mentioned technical problem.
Above-mentioned purpose of the invention is achieved by the following technical programs：.
A kind of drinking water glass with anti-scald performance, including cup and cup lid；Sealing ring is laid with the inside of the cup lid；
The surface of the cup is coated with film layer；Cup lower section is provided with a purifying vessel, and purifying vessel is detachable with connection member
Connection；The connection member extends and its open top straight up along the bottom of cup.
Used as another embodiment of the presently claimed invention, the main body of the purifying vessel is cylindrical hollow configuration, its outer wall
On be provided with the Purge holes that several drinking water made after purification pass through, the purifying vessel lower body part is provided with the outer spiral shell of clarifier
Line, the purifying vessel also includes a base matched with the main body of clarifier container, is provided with base on the base convex
Part is played, the pedestal lobe part is to be threadedly coupled with the main body of the purifying vessel；It is provided with the connection member and clarifier
The internal thread that external screw thread matches.
Used as another embodiment of the presently claimed invention, bottom to the middle part of the purifying vessel main body is provided with purification
Device external screw thread, the pedestal lobe part is internally provided with the internal thread matched with clarifier external screw thread.
Used as another embodiment of the presently claimed invention, main body and the connection member junction of the purifying vessel are provided with ring
V-shaped ring.
Used as another embodiment of the presently claimed invention, the thickness of the film layer is 0.2~0.4mm.
As another embodiment of the presently claimed invention, described film layer be followed successively by from bottom to top thermochromic layers, fungi-proofing layer and
Light change layer；Thermochromic layers make film layer that thermochromism to occur, and fungi-proofing layer stops that bacterium enters film layer, and it is purple that photochromic change layer occurs film layer
Outer fluorescence discoloration.
Used as another implementation method of the invention, the preparation process of film layer is as follows：Fungi-proofing layer is coated with thermochromic layers,
Lighting change layer is applied on fungi-proofing layer；Wherein,
S1, weigh methyl ethyl ketone, ultraviolet-induced fluorescence pigment, diphenol propane, 3,3- double (4- dimethylamino phenyls)-
6- Dimethylaminobenzenes peptide, carinex particle, are 280 according to mass ratio:2.8:3.5:3.5:Sequentially add at 70,27 DEG C
Enter in reaction vessel, stir 3 hours, form uniform temperature changing resin, the content of ultraviolet-induced fluorescence pigment is whole Wen Bianshu
The 0.25% of fat, the uniform liquid material that will be formed；
S2,0.5L ultra-pure water are inserted in separatory funnel, and the resistance that ultra-pure water is used is 18.0 Ω .cm3, it is then respectively adding
2.8g carbonyl diamides and 2.8g polyvinylpyrrolidones, add 1.8g sodium chloride, rock 10 minutes, slow to its using liquid-transfering gun
Silver nitrate solution is added dropwise, after rocking 10 minutes, appropriate TiO is added dropwise2Solution, adds appropriate ZnSO4Solution, 80 DEG C of water-baths
27 DEG C are cooled to after 120 minutes, 0.05L dibasicity sodium radio-phosphate,P-32 solutions are added, rocked 30 minutes；Add 0.01L absolute ethanols
When shaking 0.5；Precipitation after washing traditional vacuum with distilled water, acid solution, absolute ethanol successively；It is drying precipitated；After grinding precipitation
Calcination in Muffle furnace is placed on, room temperature is down to naturally after terminating, then cross 300 mesh sieves, obtain final product fungi-proofing powder；
S3, a certain amount of vinyl benzene monomer is dissolved into absolute ethanol and water mixed solution, is heated to 55 DEG C, and constant temperature is protected
0.5h is held, 95 DEG C are again heated to, constant temperature keeps 0.5h, polyvinylpyrrolidone is fully dissolved, and is subsequently adding sodium sulphate high molten
Liquid, reacts 5h, and reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；The wherein body of absolute ethanol and water
Product is than being 70:30；It is pre-configured certain density to weigh a certain amount of polystyrene microsphere and be added to certain density phthalic anhydride
In solution, nitrogen protection adds aluminium chloride while stirring, 50 DEG C of reaction 10h, obtain surface it is modified-polystyrene microsphere, by table
Face is modified-and polystyrene microsphere is put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinolines spiro-pyrans-ethanol solution absorption
10h, centrifugation is dried, and the surface photosensitive microballoon of modified-polystyrene-is obtained, by the surface photosensitive microballoon of modified-polystyrene-
Soaked overnight in certain density PVA solution is added to, centrifugation is placed in absolute ethanol and is disperseed, centrifugation, done
It is dry, the modified photosensitive microballoon of-polystyrene-in dried PVA@surfaces is put into 48h is soaked in tin oxide solution, then do for 95 DEG C
It is dry standby；
It is prepared by S4, film layer：
A. according to 3:1~2:2~3 mass ratio, weighs appropriate made via the hot color changing material prepared by S1, S2 respectively
Light prepared by standby fungi-proofing material and S3 becomes material；
B. hot color changing material is dissolved in methyl ethyl ketone solution, forms the first solution, 1.5h is standby for stirring；
C. fungi-proofing material is dissolved in methyl ethyl ketone solution, forms the second solution, 2h is standby for stirring；
D. light color changing material is dissolved in methyl benzole soln, forms the 3rd solution, 3h is standby for stirring；
E., first solution is uniformly coated on the surface of cup, 6h is dried in negative pressure 0.4MPa vacuum drying chambers so that cup
The surface of body forms the thermochromic layers of appearance uniform, and the thickness of the thermochromic layers is 20~80nm；
F. the second solution coating is dried into 8h in the thermochromic layers surface of cup, negative pressure 0.25MPa vacuum drying chambers, is taken
After going out as603h is irradiated under Co rays, fungi-proofing layer is obtained, the thickness of the fungi-proofing layer is 50~60nm；
G. by the 3rd solution coating cup fungi-proofing layer surface, natural film forming on fungi-proofing layer, be vacuum dried 24h, i.e.,
Can, the thickness of light change layer is 20~80nm.
Used as another embodiment of the presently claimed invention, the thickness of the thermochromic layers is 30~70nm；The fungi-proofing layer
Thickness is 55nm；The thickness of the smooth change layer is 70nm.
Used as another embodiment of the presently claimed invention, the film layer also includes one layer of light-absorption layer, and the light-absorption layer is painted on
The smooth change layer top.
Relative to prior art, beneficial effects of the present invention：
1st, drinking water glass of the present invention, structure simplicity generosity attractive in appearance.
2nd, drinking water glass of the present invention, is provided with light thermochromic layers on the surface of cup, the thermochromic layers energy root
Temperature height according to the water in cup is changed colour, and instead of the temperature display element installed inside cup in the prior art,
While saving production cost, water temperature condition intuitively can also be learnt according to the color outside cup, serve early warning
Effect；Avoid due to the problem of the scald mucous membrane of mouth that water temperature over-high causes, with simple structure, processing cost is low, anti-scald
The advantages of effect is good.
3rd, drinking water glass of the present invention, the surface of cup is further coated with light change layer, and light change layer is combined with thermochromic layer
Effect, the color of beauty is formed according to intensity of illumination so that the outward appearance aestheticism of the cup in cup surface, with intelligent color-changing effect
Really, the aesthetic of cup is improved, the body and mind for enhancing user experiences comfort level.
4th, drinking water glass of the present invention, is laid with fungi-proofing layer between thermochromic layers and light change layer, in the fungi-proofing layer
Containing titanium dioxide-zinc ion-silver ion complex antimicrobials, optically catalytic TiO 2 make use of to decompose, silver ion is to light and heat
More sensitive the characteristics of so that the drinking water glass possesses antibacterial action, acted on light change layer and hot change layer synergistic combinations, enhanced
The service life of the drinking water glass.
Brief description of the drawings
Accompanying drawing herein is merged in specification and constitutes the part of this specification, shows and meets implementation of the invention
Example, and be used to explain principle of the invention together with specification.
Fig. 1 is structural representation of the invention.
Fig. 2 is the structural representation of base shown in Fig. 1 and purifying vessel.
Fig. 3 is the structural representation of the membrane element shown in Fig. 1.
Wherein：1- cup lids, 2- cups, 3- purifying vessels, 3-1- Purge holes, 3-2- purifying vessel external screw threads, 3-3- bases
Projection piece, 3-4- bases, 3-5- base internal threads, 6- seal cups, 7- film layers, 11- thermochromic layers, the fungi-proofing layers of 12-, 13- light becomes
Layer.
Specific embodiment
The invention will be further described with the following Examples.
As shown in figure 1, a kind of drinking water glass with anti-scald performance, including cup 2 and cup lid 1；The inner side of the cup lid 1
It is laid with sealing ring 6；The surface of the cup 2 is coated with film layer 7；The lower section of cup 2 is provided with a purifying vessel 3, and purification is held
Device 3 is detachably connected with connection member 8；The connection member 8 extends and its open top straight up along the bottom of cup 2.
Further, as shown in Fig. 2 the main body of the purifying vessel 3 is cylindrical hollow configuration, it is provided with its outer wall
The Purge holes 3-1 that several drinking water made after purification pass through, the lower body part of the purifying vessel 3 is provided with the outer spiral shell of purifying vessel
Line 3-2, the purifying vessel 3 also includes a base 3-4 matched with the main body of clarifier container 3, is set on base 3-4
Pedestal lobe 3-3 parts are equipped with, the pedestal lobe part 3-3 is to be threadedly coupled with the main body of the purifying vessel 3；The connection member
The internal thread matched with purifying vessel external screw thread 3-2 is provided with 8.
Further, the bottom of the main body of the purifying vessel 3 to middle part is provided with purifying vessel external screw thread 3-2,
The pedestal lobe part 3-3 is internally provided with the internal thread matched with purifying vessel external screw thread 3-2.
Further, the main body of the purifying vessel 3 is provided with the sealing ring 6 of annular with the junction of connection member 8.
Further, the thickness of the film layer 7 is 0.2~0.4mm.
Further, described film layer 7 is followed successively by thermochromic layers 11 as shown in Figure 3, fungi-proofing layer 12 and light from bottom to top
Change layer 13；Thermochromic layers 11 make film layer 7 that thermochromism to occur, and fungi-proofing layer 12 stops that bacterium enters film layer 7, and light change layer 13 makes film layer
7 there is Ultraluminescence discoloration.
Further, the preparation process of film layer 7 is as follows：Fungi-proofing layer 12 is coated with thermochromic layers 11, is coated with fungi-proofing layer 12
Light change layer 13；Step is as follows：
S1, weigh methyl ethyl ketone, ultraviolet-induced fluorescence pigment, diphenol propane, 3,3- double (4- dimethylamino phenyls)-
6- Dimethylaminobenzenes peptide, carinex particle, are 280 according to mass ratio:2.8:3.5:3.5:Sequentially add at 70,27 DEG C
Enter in reaction vessel, stir 3 hours, form uniform temperature changing resin, the content of ultraviolet-induced fluorescence pigment is whole Wen Bianshu
The 0.25% of fat, the uniform liquid material that will be formed；
S2,0.5L ultra-pure water are inserted in separatory funnel, and the resistance that ultra-pure water is used is 18.0 Ω .cm3, it is then respectively adding
2.8g carbonyl diamides and 2.8g polyvinylpyrrolidones, add 1.8g sodium chloride, rock 10 minutes, slow to its using liquid-transfering gun
Silver nitrate solution is added dropwise, after rocking 10 minutes, appropriate TiO is added dropwise2Solution, adds appropriate ZnSO4Solution, 80 DEG C of water-baths
27 DEG C are cooled to after 120 minutes, 0.05L dibasicity sodium radio-phosphate,P-32 solutions are added, rocked 30 minutes；Add 0.01L absolute ethanols
When shaking 0.5；Precipitation after washing traditional vacuum with distilled water, acid solution, absolute ethanol successively；It is drying precipitated；After grinding precipitation
Calcination in Muffle furnace is placed on, room temperature is down to naturally after terminating, then cross 300 mesh sieves, obtain final product fungi-proofing powder；
S3, a certain amount of vinyl benzene monomer is dissolved into absolute ethanol and water mixed solution, is heated to 55 DEG C, and constant temperature is protected
0.5h is held, 95 DEG C are again heated to, constant temperature keeps 0.5h, polyvinylpyrrolidone is fully dissolved, and is subsequently adding sodium sulphate high molten
Liquid, reacts 5h, and reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；The wherein body of absolute ethanol and water
Product is than being 70:30；It is pre-configured certain density to weigh a certain amount of polystyrene microsphere and be added to certain density phthalic anhydride
In solution, nitrogen protection adds aluminium chloride while stirring, 50 DEG C of reaction 10h, obtain surface it is modified-polystyrene microsphere, by table
Face is modified-and polystyrene microsphere is put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinolines spiro-pyrans-ethanol solution absorption
10h, centrifugation is dried, and the surface photosensitive microballoon of modified-polystyrene-is obtained, by the surface photosensitive microballoon of modified-polystyrene-
Soaked overnight in certain density PVA solution is added to, centrifugation is placed in absolute ethanol and is disperseed, centrifugation, done
It is dry, the modified photosensitive microballoon of-polystyrene-in dried PVA@surfaces is put into 48h is soaked in tin oxide solution, then do for 95 DEG C
It is dry standby；
It is prepared by S4, film layer：
A. according to 3:1~2:2~3 mass ratio, weighs appropriate made via the hot color changing material prepared by S1, S2 respectively
Light prepared by standby fungi-proofing material and S3 becomes material；
B. hot color changing material is dissolved in methyl ethyl ketone solution, forms the first solution, 1.5h is standby for stirring；
C. fungi-proofing material is dissolved in methyl ethyl ketone solution, forms the second solution, 2h is standby for stirring；
D. light color changing material is dissolved in methyl benzole soln, forms the 3rd solution, 3h is standby for stirring；
E., first solution is uniformly coated on the surface of cup, 6h is dried in negative pressure 0.4MPa vacuum drying chambers so that cup
The surface of body forms the thermochromic layers of appearance uniform, and the thickness of the thermochromic layers is 20~80nm；
F. the second solution coating is dried into 8h in the thermochromic layers surface of cup, negative pressure 0.25MPa vacuum drying chambers, is taken
After going out as603h is irradiated under Co rays, fungi-proofing layer is obtained, the thickness of the fungi-proofing layer is 50~60nm；
G. by the 3rd solution coating cup fungi-proofing layer surface, natural film forming on fungi-proofing layer, be vacuum dried 24h, i.e.,
Can, the thickness of light change layer is 20~80nm.
Further the, the thickness of the thermochromic layers 11 is 30~70nm；The thickness of the fungi-proofing layer 12 is 55nm；It is described
The thickness of light change layer 13 is 70nm.
Further, the film layer 7 also includes one layer of light-absorption layer, and the light-absorption layer is painted on the top of the smooth change layer 13.
Photic phenomenon to drinking water glass of the present invention is detected：1. the detection of Ultraluminescence is carried out, is used
Uviol lamp on cash inspecting machine is detected.2. sunlight, Indoor Natural light are used.
The phototropic experimental result of table 2
Drinking water glass of the present invention shows pink under the conditions of darkness, the light change layer color hair under sunlight irradiation
Changing, shows purple, and lilac is showed in room conditions.Under ultra violet lamp, color is red.
Further, the Reversible temperature denaturation to drinking water glass of the present invention is detected：Directly by uniform temperature
Hot water splash on drinking water glass of the present invention, the color of drinking water glass of the present invention changes at once, by
Navy blue is changed into very shallow blue or almost colourless, and initial navy blue is then then restored to quickly.This detection method ten
Divide convenient, as long as splashed with hot water at one's side can just detect soon but also intuitively not only, significantly facilitate the drink of the present invention
With the detection of cup, its range of application has been widened.
The thermo-color experimental result of table 2
In 82 DEG C~62 DEG C of temperature, color change is most obvious, is changed into blue from navy blue, and it is very high to become chromatic sensitivity, runs into
The hot water that temperature reaches more than minimum temperature changes colour at once, recovery time section, and about 4s is then restored to priming color.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of scope is protected, although being explained to the present invention with reference to preferred embodiment, one of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent, without deviating from the reality of technical solution of the present invention
Matter and scope.
Claims (9)
1. a kind of drinking water glass with anti-scald performance, including cup and cup lid；Characterized in that, the inner side of the cup lid is laid
There is sealing ring；The surface of the cup is coated with film layer；Cup lower section is provided with a purifying vessel, purifying vessel and connecting portion
Part is detachably connected；The connection member extends and its open top straight up along the bottom of cup.
2. a kind of drinking water glass with anti-scald performance according to claim 1, it is characterised in that the purifying vessel
Main body is cylindrical hollow configuration, and the Purge holes that several drinking water made after purification pass through, the purification are provided with its outer wall
Container body bottom is provided with clarifier external screw thread, and the purifying vessel also matches including one with the main body of clarifier container
Base, pedestal lobe part is provided with the base, the main body of the pedestal lobe part and the purifying vessel is to be threadedly coupled；Institute
State the internal thread for being provided with connection member and being matched with purifying vessel external screw thread.
3. a kind of drinking water glass with anti-scald performance according to claim 1, it is characterised in that the purifying vessel master
The bottom of body to middle part is provided with purifying vessel external screw thread, and the pedestal lobe part is internally provided with and the outer spiral shell of purifying vessel
The internal thread that line matches.
4. a kind of drinking water glass with anti-scald performance according to claim 2, it is characterised in that the purifying vessel
Main body is provided with annular sealing ring with connection member junction.
5. a kind of drinking water glass with anti-scald performance according to claim 4, it is characterised in that the thickness of the film layer
It is 0.2~0.4mm.
6. a kind of drinking water glass with anti-scald performance according to claim 1, it is characterised in that described film layer is under
It is followed successively by thermochromic layers, fungi-proofing layer and light change layer upwards；Thermochromic layers make film layer that thermochromism to occur, and fungi-proofing layer stops that bacterium enters
Enter film layer, photochromic change layer makes film layer that Ultraluminescence discoloration to occur.
7. a kind of drinking water glass with anti-scald performance according to claim 1, it is characterised in that the preparation process of film layer
It is as follows：Fungi-proofing layer is coated with thermochromic layers, lighting change layer is applied on fungi-proofing layer；Wherein,
S1, weighs double (4- the dimethylamino phenyls) -6- two of methyl ethyl ketone, ultraviolet-induced fluorescence pigment, diphenol propane, 3,3-
Methylamino benzene peptide, carinex particle, are 280 according to mass ratio:2.8:3.5:3.5:Sequentially added at 70,27 DEG C anti-
Answer in container, stir 3 hours, form uniform temperature changing resin, the content of ultraviolet-induced fluorescence pigment is whole temperature changing resin
0.25%, the uniform liquid material that will be formed；
S2,0.5L ultra-pure water are inserted in separatory funnel, and the resistance that ultra-pure water is used is 18.0 Ω .cm3, it is then respectively adding 2.8g
Carbonyl diamide and 2.8g polyvinylpyrrolidones, add 1.8g sodium chloride, rock 10 minutes, are slowly added dropwise to it using liquid-transfering gun
Silver nitrate solution, after rocking 10 minutes, is added dropwise appropriate TiO2Solution, adds appropriate ZnSO4Solution, 80 DEG C of 120 points of water-baths
27 DEG C are cooled to after clock, 0.05L dibasicity sodium radio-phosphate,P-32 solutions are added, rocked 30 minutes；Add the concussion of 0.01L absolute ethanols
When 0.5；Precipitation after washing traditional vacuum with distilled water, acid solution, absolute ethanol successively；It is drying precipitated；By it after grinding precipitation
It is placed in Muffle furnace and is calcined, room temperature is down to naturally after terminating, then cross 300 mesh sieves, obtains final product fungi-proofing powder；
S3, a certain amount of vinyl benzene monomer is dissolved into absolute ethanol and water mixed solution, is heated to 55 DEG C, and constant temperature keeps
0.5h, is again heated to 95 DEG C, and constant temperature keeps 0.5h, polyvinylpyrrolidone is fully dissolved, and is subsequently adding metabisulfite solution high,
Reaction 5h, reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；The wherein volume ratio of absolute ethanol and water
It is 70:30；It is pre-configured certain density to weigh a certain amount of polystyrene microsphere and be added to certain density phthalic anhydride solution
In, nitrogen protection adds aluminium chloride while stirring, 50 DEG C of reaction 10h, obtain surface it is modified-polystyrene microsphere, surface is changed
Property-polystyrene microsphere is put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinolines spiro-pyrans-ethanol solution absorption 10h, from
The heart is separated, and is dried, and the surface photosensitive microballoon of modified-polystyrene-is obtained, and the modified photosensitive microballoon of-polystyrene-in surface is added to
Soaked overnight in certain density PVA solution, centrifugation is placed in absolute ethanol and is disperseed, centrifugation, dries, will
The modified photosensitive microballoon of-polystyrene-in dried PVA@surfaces soaks 48h in being put into tin oxide solution, and then 95 DEG C of dryings are standby
With；
It is prepared by S4, film layer：
A. according to 3:1~2:2~3 mass ratio, weighs appropriate via the hot color changing material prepared by S1, prepared by S2 respectively
Light prepared by fungi-proofing material and S3 becomes material；
B. hot color changing material is dissolved in methyl ethyl ketone solution, forms the first solution, 1.5h is standby for stirring；
C. fungi-proofing material is dissolved in methyl ethyl ketone solution, forms the second solution, 2h is standby for stirring；
D. light color changing material is dissolved in methyl benzole soln, forms the 3rd solution, 3h is standby for stirring；
E., first solution is uniformly coated on the surface of cup, 6h is dried in negative pressure 0.4MPa vacuum drying chambers so that cup
Surface forms the thermochromic layers of appearance uniform, and the thickness of the thermochromic layers is 20~80nm；
F. the second solution coating is dried into 8h in the thermochromic layers surface of cup, negative pressure 0.25MPa vacuum drying chambers, after taking-up
As for603h is irradiated under Co rays, fungi-proofing layer is obtained, the thickness of the fungi-proofing layer is 50~60nm；
G. by the 3rd solution coating cup fungi-proofing layer surface, natural film forming on fungi-proofing layer, be vacuum dried 24h, you can, light
The thickness of change layer is 20~80nm.
8. a kind of drinking water glass with anti-scald performance according to claim 7, it is characterised in that the thermochromic layers
Thickness is 30~70nm；The thickness of the fungi-proofing layer is 55nm；The thickness of the smooth change layer is 70nm.
9. a kind of drinking water glass with anti-scald performance according to claim 6, it is characterised in that the film layer also includes
One layer of light-absorption layer, the light-absorption layer is painted on the smooth change layer top.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710129288.6A CN106724601B (en) | 2017-03-06 | 2017-03-06 | A kind of drinking water glass with anti-scald performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710129288.6A CN106724601B (en) | 2017-03-06 | 2017-03-06 | A kind of drinking water glass with anti-scald performance |
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| Publication Number | Publication Date |
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| CN106724601A true CN106724601A (en) | 2017-05-31 |
| CN106724601B CN106724601B (en) | 2019-07-16 |
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Cited By (1)
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109303699A (en) * | 2018-10-27 | 2019-02-05 | 张东 | A kind of Feeding bottle with scald-proof function |
| CN109303699B (en) * | 2018-10-27 | 2021-01-05 | 黑龙江飞鹤乳业有限公司 | Anti-scald feeding bottle |
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| Publication number | Publication date |
|---|---|
| CN106724601B (en) | 2019-07-16 |
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Effective date of registration: 20190612 Address after: 321300 Chengxin Road 217, Yongkang Hardware Science and Technology Industrial Park, Zhejiang Province Applicant after: Zhejiang Green Tools Co., Ltd. Address before: 200000 Shanghai Songjiang District Songjiang District Mun Road No. 1 Applicant before: Shanghai Xun Ye Computer Technology Co. Ltd. |
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