CN106715285A - Packaging with tamper resistance - Google Patents

Packaging with tamper resistance Download PDF

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Publication number
CN106715285A
CN106715285A CN201480082187.2A CN201480082187A CN106715285A CN 106715285 A CN106715285 A CN 106715285A CN 201480082187 A CN201480082187 A CN 201480082187A CN 106715285 A CN106715285 A CN 106715285A
Authority
CN
China
Prior art keywords
packaging
seal
medium
closure
bottle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201480082187.2A
Other languages
Chinese (zh)
Inventor
T·巴克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polisco AG
Polysecure GmbH
Original Assignee
Polisco AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polisco AG filed Critical Polisco AG
Publication of CN106715285A publication Critical patent/CN106715285A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D55/00—Accessories for container closures not otherwise provided for
    • B65D55/02—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure
    • B65D55/06—Deformable or tearable wires, strings, or strips; Use of seals, e.g. destructible locking pins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/62—Secondary protective cap-like outer covers for closure members
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D55/00—Accessories for container closures not otherwise provided for
    • B65D55/02—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure
    • B65D55/026—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure initial opening or unauthorised access being indicated by a visual change using indicators other than tearable means, e.g. change of colour, pattern or opacity
    • G—PHYSICS
    • G07—CHECKING-DEVICES
    • G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
    • G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
    • G07D7/005—Testing security markings invisible to the naked eye, e.g. verifying thickened lines or unobtrusive markings or alterations
    • G—PHYSICS
    • G07—CHECKING-DEVICES
    • G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
    • G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
    • G07D7/15—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using heating means
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F3/0291—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
    • G09F3/0292—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F3/03—Forms or constructions of security seals
    • G09F3/0305—Forms or constructions of security seals characterised by the type of seal used
    • G09F3/0341—Forms or constructions of security seals characterised by the type of seal used having label sealing means
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0272—Labels for containers
    • G09F2003/0273—Labels for bottles, flasks
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0276—Safety features, e.g. colour, prominent part, logo
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/028—Labels containing microcapsules, e.g. ink microcapsules for indicia transfer

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Theoretical Computer Science (AREA)
  • Computer Security & Cryptography (AREA)
  • Closures For Containers (AREA)
  • Packages (AREA)

Abstract

The present invention relates to packaging (2) that is closed by a cap, wherein a seal (1) made of thermosetting polymer is attached to the cap, said seal (1) preferably being in contact with the packaging, wherein the seal is not removable from the cap and/or the packaging without destruction and the seal comprises means for identifying the originality of the packaging, means for registering input of thermal energy and/or means for detecting that a defined temperature has been exceeded.

Description

Packaging with false proof device
The present invention relates to a kind of with packing that closure is closed.
Product copy right piracy, i.e., be traded with the imitated product prepared similar to the purpose for obscuring original product Behavior, is common problem in commercial exchange, and brings obvious loss therewith to original manufacturer.In product piracy row In most cases, the name with manufacturer to be packed using identical.And pack in contained product composition, processing material And/or treatment is inferior, non-existent or substitute with insalubrity replaces.Institute of the pseudo- product in commercial exchange There is field, be known such as in software, clock and watch, clothes, medicine, automobile component or food.
Valuable wine is bought and sold with high price.Excessive risk is there is for the customer of valuable wine, so that being likely to purchase To fake wine or buy in the original wine stored under the conditions of prejudicial to wine.This kind of valuable wine is often regarded as being a kind of throwing Money.Finally, the customer is unless opened and cannot check this bottle of quality of wine.But thus block purchase.Inspection before same purchase It is also infeasible to test.
By it is known in the art it is various be subject to the method for original protection to bottle and label, but still there may be forgery may Property, such as by filling with fake wine original bottle again or peddling wine through Overheating Treatment (thermisch ü berlagertem).
For example by CN 202518596, CN 202464386, CN 202557987, CN 202400409, CN 102582945th, the equipment that CN 202346084 and CN2806357 become known for wine bottle anti-counterfeiting.
Therefore, it is an object of the invention to provide the false proof of packaging, particularly bottle such as bottle is false proof, existing to overcome The shortcoming of technology.A kind of packaging is especially to provide, the packaging prevents the fraud possibility by abusing original packaging, and it is right such as to prevent The refilling of the original bottle of expensive wine.
This purpose be by it is a kind of closed with closure pack and realize, wherein at the closure and/or A seal being made up of thermosetting polymer is directly applied with the closure, the seal is preferably in contact with the packaging, Wherein the seal can not be separated nondestructively with the closure and/or the packaging, and the seal includes for recognizing the seal Thus the medium of the primitiveness of the packaging and/or for record heat energy input medium and/or for recognize exceed regulation temperature The medium of degree.
The all of packaging for the purpose of transporting or decorate can be preferred for the packaging of good product, be considered as the present invention Packaging.In addition to for the particularly preferred vial for storing and transporting quality liquor, can will also be used to storing quality liquor, alcohol-free Other vials, ceramics of beverage, cosmetics, pharmaceutical preparation or pick-me-up such as cognac wine, champagne, whiskey etc. Bottle, soil property bottle or plastic bottle are considered as packaging of the invention.
For packing Premium Brands product such as clock and watch, clothes, jewellery, perfume, cosmetics, pharmaceutical preparation, material components, electricity The carton of sub- device, data medium etc., box, bag bag and similar packaging can be considered packaging of the invention.
It is preferably herein, the packaging is packaging for foodstuff, preferably bottle, particularly preferably vial, particularly preferably wine Bottle.
In an especially preferred embodiment, the packaging is preferably to be filled with the bottle of inclusion e.g. wine, excellent Select vial.
Preferably, the packaging is bottle and closure is cork.
Additionally, the thermosetting polymer is acrylic polymer, preferably modified acrylic polymer.It is applicable Thermosetting polymer in market, it is known that be Permabond Engineering Additives companies brand it is entitledThe product of UV681 or UV 683.
In one embodiment, the seal has at least one through hole.The through hole has preferably been formed when prepared by seal, The placeholders (Platzhalter) formed by polytetrafluoroethylene (PTFE) or the like are provided herein, and applying liquid around the placeholders gathers Compound.Can go to apply the placeholders after the polymer is hardened, and be consequently formed the through hole.
Can be in an alternative embodiment that the seal is obviously without through hole.If the forgery of the package contents is pre- Meter is that by means of the through hole if being injected with pin, then the embodiment is preferably suitable to realize the purpose of the present invention.When this When packaging is containing filling solution, this scheme is then favourable.
In another embodiment, this be used to recognizing primitiveness medium contain it is visible by instrument eyes Particle, such as particle containing colour coding, natural structure thing such as Diatomeae, and/or the mark substance for needing detecting devices to recognize is such as Chemical markers, Stokes pigment (Stokes-Pigmente) or anti-Stokes pigment (Anti-Stokes- Pigmente)。
It is preferably by the present invention, the medium for being used to record heat energy input contains a kind of porous material, and the material is included Composition that is being disengaged by thermal diffusion and can triggering chromatic effect when disengaging, and/or the medium contains a kind of material, the material Material can be decomposed by heat energy, and disengage composition that is a kind of being contained in the material and triggering chromatic effect.
Particularly preferably, the material is micro porous and/or is organic or inorganic.
It is also preferred that the composition triggers chromatic effect in itself or by combining object reaction with one kind.
Finally it is preferably, the medium for recognizing the temperature for exceeding regulation contains a kind of compound of irreversible thermochromatic effect And/or the colouring agent of microcyst.
Present inventors have unexpectedly found that, the packaging that this is referred to has an insurance system, and the insurance system not only can recognize that and fake, Also can recognize that the package contents are preferably the heat treatment of wine.
It is important in this that, the seal is made up of thermoset copolymer material.The seal be applied at the closure and/or On the closure, closure particularly cork, and glass preferably also with the material such as bottle of the packaging is in contact.Herein The seal is connected with sealing cover material and/or packaging, and can not be through lossless removal.Additionally, it has surprisingly been found that, in the seal material Various safety labels can be also added in material and is recorded and marked, these marks make the further false proof and heat of the package contents The inspection for the treatment of is possibly realized.This safety label and record mark are Jie for recognizing the primitiveness of the seal and the packaging Matter, for recording the medium of heat energy introducing and/or the medium for exceeding set point of temperature being packed for identification.
Seal
The seal is made up of a kind of thermosetting polymer, and the thermosetting polymer is in a liquid state form for example can be with certain Depth is applied between the closure (cork) and the packaging (the bottle edge of vial), and with the closure and particularly should Glass is firmly connected.As the mode of the replacement of aforementioned manner, or as the arbitrary way of aforementioned manner, the seal may be used also Comprising the piece being made up of a kind of thermoset copolymer material, the piece can be embedded between closure and bottle edge with above-mentioned depth, And pass through added liquid thermosetting polymeric and be connected with closure and glass
The seal can preferably include through hole, so as to be capable of achieving the ventilation of package contents by the closure (cork). As long as using the embedded chip being made up of thermosets, then decorative element such as embossing or rag can be provided for the piece.
The seal preferably may be designed to raised, flushing or recessed.Its true qualities preferably can be colored or monochrome, preferably It is white or colourless, it is particularly preferably colourless.
Thermosetting plastics (also referred to as duromer) is the no longer deformable plastics after its hardening.The plastics are the glass of hard Glass is birdsed of the same feather flock together compound material, and it is through chemical primary bond in three-dimensional firmly crosslinking.Particularly preferably, the thermosetting plastics is when it is hardened Only disengage considerably less heat or be used to harden without calorific requirement, because the heat may be impaired is contained in safety label therein Marked with recording.The thermosets preferably should also tolerate the usual conditions during packing and storing, and be occurred without during storing The optically and mechanically change of aspect.
Particularly preferably, using the thermosetting polymer in its mechanical properties through so modulating as seal material, I.e. in removal or in point-like mechanical stress such as when stopper bottle-opener is inserted, the seal is broken into many small monolithics, so that In the case of not destroying the seal, it is impossible to remove the closure.
This kind of material for hardening under uv radiation preferably can be used in the present invention as thermosets, such as modified propylene Acid polymer, this kind of polymer is known in the repairing of glass of automobile glass plate, and particularly has fabulous connection to glass Property and with required long-time stability.
Preferably, the seal is applied directly on closure, i.e., do not configure other packagings between closure and seal Material such as calotte, pipe or the like.Here, closure should mean to be directly connected to part between portion and outer package within a package. For example in the case of bottle, the cork is exactly to be sealed lid, and the plastic foil of the non-protected cork or metal foil.
Further, it is also preferred that, the seal is said three-dimensional body, i.e. volumentary geometry body.Equally, the thing of the seal or monoblock Body.
Can be in an especially preferred embodiment, in the thermosetting seal formed with bulk form, the envelope Print may include Stokes pigment or anti-Stokes pigment.
In the present invention preferably, the seal material expands in hardening.So, the seal and closure and/or bag are realized Especially firm between package material and by the favourable connection of the present invention.
Medium for recognizing primitiveness
The seal of present invention packaging contains a kind of medium for recognizing primitiveness.Within the scope of the present invention, for recognizing The medium of primitiveness should mean that this medium, the i.e. medium can make whether the closure on the packaging is still original seal lid Inspection is possibly realized.Medium for recognizing primitiveness can for example include the particle that be can be seen by instrument eyes, such as contain The particle of colour coding, such as described in the A2 of EP 1003146.In addition it is also possible that this medium may also include need to be set with detection The standby mark substance to realize identification.This kind of mark substance for example can be chemical markers (such as A1 of DE 102008060675 In known chemical markers), Stokes pigment or anti-Stokes pigment or the like.All Media can individually or group Conjunction is used.
Medium for recording heat energy input
The energy input recorded in the inclusion to packaging such as bottle is also critically important.The energy input is by absorbing How much heat energy is illustrated with the inclusion of the possible packaging that oneself is damaged.In the first embodiment, this medium may include many The material of pass, preferred microporous type or mesothyrid material, add has a kind of composition that can be disengaged by heat energy within this material.Should Composition can directly trigger chromatic effect, or trigger coloring to imitate by being reacted with another material being present in seal Should.
In second embodiment, the medium may include inorganic or organic material, and the material is divided by the heat energy for absorbing Solution, and disengage a kind of composition being contained in the material.These embodiments can be used alone or in combination, wherein the first embodiment It is preferred.
To being incorporated into composition in the medium, requirement high is proposed to its long-time stability aspect, so that it is preferred that making With inorganic compound or generation inorganic reaction.
Example for recording the medium of heat energy input is to be formed " Berlin blue ", i.e., iron (III) salt and six cyano group close iron (II) reaction of potassium：
4 Fe3++3[Fe+II(CN)6]4-→Fe+III[Fe+IIIFe+II(CN)6]3
The iron compound is present in a kind of micro porous polyester material, and wherein six cyano group closes iron (II) potassium and can be embedded in envelope In print material.The iron is migrated out from micro porous polyester material at leisure due to thermal process, and closes iron (II) potassium with six cyano group React generation blue compound.The discoloration of the appearance is proportional to spread iron, and the energy that the iron is proportional to heat again is defeated Enter.The system is calibrated accordingly by simulation climate room, it can be ensured that the relevance with true storage.
The detection of heat energy input can be compared or by suitably and through respective alignment mistake by with the visual of reference graduation Photometer measurement discoloration carry out.This photometer can also use relevant suitable medium feelings with corresponding combinations of detectors It is used to analyze identification primitiveness under condition.
All possible heat label thing is common, i.e., be not in when thermal energy is input into great-jump-forward discoloration it is anti- Should.But by slow temperature-driven spread and observe the medium color or color intensity and temperature and/or time phase The change of pass.In this approach, it is capable of achieving the qualitative assessment of the heat energy to being input into.It is all other in addition to the color of the medium The physical parameter surveyed changed with the reaction of diffusion control is used equally to this purpose.
For recognizing the medium more than set point of temperature
When bottle is stored, in the speciality circles, it is known that limiting temperature of the short time more than e.g., from about 40 DEG C is damaged to wine Evil.By the present invention, identification can be shown more than this temperature by the clear discoloration of the seal material.
May be designed as herein, this discoloration can by using the compound of irreversible thermochromatic effect and/or microcyst Toner is realized.The particularly colouring agent of microcyst, because transition temperature can accurately be set.
The colouring agent of microcyst is to provide the dyestuff or pigment of polymer or wax shell layer.The tone of the colouring agent is by involucrum Covered.The involucrum melts or decomposes at set temperature, so that can be seen that the colouring agent.In addition, it is also possible to use reaction Property colouring agent, here, a part of colouring agent inserts the seal in base material, another part exists with micro-encapsulated form.Super When crossing limiting temperature, the clad meltdown and/or decomposition, and two reaction partner forms colored compound.
Typical involucrum material is paraffin and low polymer, such as low molecular polyethylene (Fischer-Tropsch waxes). It is to the method for material microcyst known to those skilled in the art, and uses on an industrial scale.
In an especially preferred embodiment, the seal is comprising for recognizing the medium of primitiveness and for recording heat The medium that can be input into and the combination for recognizing the medium more than set point of temperature.
Other advantages and features of the invention are given by the detailed description of the embodiment of following refer to the attached drawing, and the accompanying drawing is with bottle 2 Form show the present invention packaging on seal 1 configuration.
Embodiment
Seal is prepared using following formula：
Pernabond is placed in container, remaining material is disperseed with dissolvers under cooling.Temperature is not to be exceeded 30 ℃。
It is bottle of the seal with cork, it is soft that the solution prepared above of accurate 1.5ml is added in into this by means of dosing pump On stopper.Lentiform drop is formed by the surface tension of solution.The drop is hardened by means of UV light.It is applied to vial On seal be shown graphically in the attached figures.
Become red by the light golden yellow seal, can be easy to be recognized beyond maximum storage temperature with bore hole.
When with the laser excitation of 980nm, the original marking thing may recognize that with its visible fluorescence.In addition, phase can be used The detector answered such as Polysecuree GmbH companiesF detectors analyze the attenuation characteristic of the fluorescence, It provides reliability higher.
The input of heat energy compares colour code that seal color and scale cross to determine by visual observation.The colour code passes through the seal material Expect that the experiment of the storage under controlled condition is made.
The preparation of A microcyst pigment
Red iron oxide (Bayferrox 120) is added in hot mixing device (such as Thyssen Henschel companies), and The paraffin of the fusing that fusing point is 40 DEG C is sprayed into the blender of operating.The ratio of pigment and wax is 70: 30.Than the pigment Particle is covered for wax layer.The mixture is blended until the size of particle reaches about 20-30 μm.Then it is transferred to cooling mixing In device, and it is cooled to room temperature.The shellac solution through discoloration for finally spraying into be dissolved in methyl alcohol 20% (is calculated as by the pigment 1%) methyl alcohol is removed in going, and in a vacuum.
The preparation of B Fe modified molecular sieve
Molecular sieve-4 A is in acid FeCl3Covered by Fe ions by ion exchange in solution.Then, the molecular sieve is through steaming Distilled water washing is tapped a blast furnace until no longer can detect on the surface.The product is in a vacuum through drying.
In this manual, the in the claims and in the accompanying drawings feature of present invention disclosed, not only individually And in any combination in its various embodiment to implement the present invention be important.

Claims (10)

1. a kind of with packing that a closure is closed, wherein being directly applied with the closure and/or on the closure One seal being made up of thermosetting polymer, the seal is preferably in contact with the packaging, wherein the seal can not nondestructively with The closure and/or the packaging separate, and the seal includes for recognizing the seal and the thus primitiveness of the packaging Medium and/or for record heat energy input medium and/or for recognize more than set point of temperature medium.
2. packaging according to claim 1, it is characterised in that the packaging is packaging for foodstuff, preferably bottle, particularly preferably It is vial, particularly preferably bottle.
3. packaging according to claim 1 and 2, it is characterised in that the packaging is bottle, and closure is cork.
4. according to the packaging that one of the claims are described, it is characterised in that the thermosetting polymer is acrylic Thing, preferably modified acrylic polymer.
5. according to the packaging that one of the claims are described, it is characterised in that the seal has at least one through hole.
6. according to the packaging that one of the claims are described, it is characterised in that this is used to recognizing the medium of primitiveness comprising borrowing Assistant engineer has the use visible particle of eyes, such as particle containing colour coding, natural structure thing such as Diatomeae, and/or needs detection Equipment is come the mark substance such as chemical markers, Stokes pigment or anti-Stokes pigment that recognize.
7. according to the packaging that one of the claims are described, it is characterised in that the medium for being used to record heat energy input contains A kind of porous material, the material is included and passes through composition that is that thermal diffusion can disengage and can triggering chromatic effect when disengaging, and/ Or the medium contains a kind of material, the material can be decomposed by heat energy, and disengaged a kind of being contained in the material and triggered coloring The composition of effect.
8. packaging according to claim 7, it is characterised in that the material is micro porous and/or is organic or inorganic.
9. according to one of claim 7 and 8 described packaging, it is characterised in that the composition is in itself or by anti-with combination object Answer and trigger chromatic effect.
10. according to the packaging that one of the claims are described, it is characterised in that the medium for recognizing the temperature for exceeding regulation The colouring agent of compound and/or microcyst containing a kind of irreversible thermochromatic effect.
CN201480082187.2A 2014-09-26 2014-09-26 Packaging with tamper resistance Pending CN106715285A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/DE2014/100343 WO2016045649A1 (en) 2014-09-26 2014-09-26 Packaging with tamper resistance

Publications (1)

Publication Number Publication Date
CN106715285A true CN106715285A (en) 2017-05-24

Family

ID=51842317

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480082187.2A Pending CN106715285A (en) 2014-09-26 2014-09-26 Packaging with tamper resistance

Country Status (5)

Country Link
EP (1) EP3197793B1 (en)
CN (1) CN106715285A (en)
DE (1) DE112014006988A5 (en)
DK (1) DK3197793T3 (en)
WO (1) WO2016045649A1 (en)

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