CN106710716B - A kind of preparation method of nanoelectronic slurry - Google Patents

A kind of preparation method of nanoelectronic slurry Download PDF

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Publication number
CN106710716B
CN106710716B CN201611174795.3A CN201611174795A CN106710716B CN 106710716 B CN106710716 B CN 106710716B CN 201611174795 A CN201611174795 A CN 201611174795A CN 106710716 B CN106710716 B CN 106710716B
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nano
slurry
powder
dispersion
preparation
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CN106710716A (en
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蒋国辉
苏冠贤
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Dongguan Corehelm Electronic Material Technology Co Ltd
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Dongguan Corehelm Electronic Material Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Colloid Chemistry (AREA)

Abstract

The invention discloses a kind of preparation methods of nanoelectronic slurry comprising: 1, low viscosity organic phase preparation step: it is stirred the 10 ~ 60% of auxiliary agent, solvent and metering resin;2, nano-powder dispersion steps: will metering nano-powder with low viscosity is organic is added to size barrel, ultrasonic wave added stirring is with obtained nano dispersion fluid;3, slurry tune glues filtration step: 40 ~ 90% resins of residue being added into nano dispersion fluid, is stirred at low speed with dispersion machine to resin and is completely dissolved, then filters pressing obtains nanoelectronic slurry.The preparation method have the advantage that 1, low viscosity organic phase be conducive to resin, auxiliary agent unfold completely with nano-powder formed surface bond, improve the dispersion stabilization of dispersion liquid;2, it is added when slurry tune is viscous after residual resin using stirring at low speed, molecular structure can be protected very well and guarantee slurry repetition stability;3, high to nano material dispersion efficiency, simple process is controllable, and slurry fineness is less than 2 μm.

Description

A kind of preparation method of nanoelectronic slurry
Technical field
The present invention relates to electronic component technical field of material more particularly to a kind of preparations of nanoelectronic slurry Method.
Background technique
It is controlled with military project and commercial communication (wired, wireless, network), aerospace, instrument and meter, data acquisition with intelligence The fields technologies such as system, video show, automotive electronics, consumer electronics, portable equipment and computer being constantly progressive and applying, it is desirable that Electronic component develops to high reliability, small size, ultrathin direction.
As the electric slurry of one of electronic component critical material, to a certain degree to the performance of electronic component performance On play a decisive role, for the needs for meeting the development of high-precision electronic component, electric slurry must have smaller fineness, more Good dispersed, higher printed resolution.
Nano material is to be less than a kind of structural material of 100nm in three-dimensional space at least one dimension size, with volume Effect, quantum size effect, quantum tunneling effect, Dielectric confinement effect;Relative to block materials, nano material is typically exhibited Special light, electricity, magnetic performance, belong to high-end basic material and application field are extensive.Wherein, Application of micron is starched in electronics Material can be that application of the electric slurry on High precision electronic component provides a strong guarantee, but nano material has strong surface Effect, surface can be relatively high, and nanometer base electric slurry has processing difficulties.
Summary of the invention
The purpose of the present invention is to solve the shortcomings of the prior art and a kind of preparation method of nanoelectronic slurry is provided, phase For existing preparation process, which is had the following advantages that, specifically: 1, nano-powder dispersing matrixes be low viscosity Organic phase, viscosity is low to be conducive to ultrasonic disperse, while low viscosity organic phase is conducive to unfolding completely for resin and auxiliary agent, with nanometer Powder surface forms bonding, prepares uniform and stable nano dispersion fluid;2, it is added when slurry tune is viscous after remaining resin using low Fast stirring technique, can be well protected molecular structure in this way, guarantee the repetition stability of slurry;3, the preparation method is for nanometer Material dispersion efficiency is high, and simple process is controllable, and slurry fineness is less than 2 μm.
In order to achieve the above objectives, the present invention is achieved through the following technical solutions.
A kind of preparation method of nanoelectronic slurry includes low viscosity organic phase preparation step, the nanometer successively carried out Powder dispersion steps, slurry tune glue filtration step;
The low viscosity organic phase preparation step are as follows: the 10% ~ 60% of resin, auxiliary agent and solvent will be measured and mixed, certain temperature Lower stirring to the resin of degree is completely dissolved, to complete the low viscosity organic phase preparation of clear homogeneous;
The nano-powder dispersion steps are as follows: by the nano-powder of metering with low viscosity is organic is added to size barrel, Size barrel is placed in ultrasonic equipment ultrasonic disperse while stirring, dispersion machine mixing speed is 200 ~ 1000r/min, processing 5 ~ 15h of time completes nano-powder dispersion steps and uniform and stable nano dispersion fluid is made;
The slurry tune glues filtration step are as follows: remaining 40% ~ 90% resin will be measured and be added into nano dispersion fluid, with point Scattered machine, which is stirred at low speed to resin, to be completely dissolved, and is then filtered slurry using pressure filtration method, to complete nanoelectronic slurry The preparation of material.
Wherein, the nano-powder includes metal-powder, oxide powder or glass powder.
Wherein, the partial size three-dimensional at least one dimension of the nano-powder is less than 100nm.
Wherein, the auxiliary agent includes dispersing agent, defoaming agent, levelling agent.
Wherein, in low viscosity organic phase preparation process, whipping temp is 50 ± 5 DEG C.
Wherein, it is glued in filter process in slurry tune, the speed that dispersion machine stirs at low speed is 100 ~ 800r/min.
The invention has the benefit that a kind of preparation method of nanoelectronic slurry of the present invention comprising have according to The low viscosity organic phase preparation step of secondary progress, nano-powder dispersion steps, slurry tune glue filtration step;The low viscosity is organic Phase preparation step are as follows: the 10% ~ 60% of resin, auxiliary agent and solvent will be measured and mixed, stirring to resin is completely dissolved under certain temperature, To complete the low viscosity organic phase preparation of clear homogeneous;The nano-powder dispersion steps are as follows: by the nano-powder of metering with it is low Viscosity is organic to be added to size barrel, size barrel is placed in ultrasonic equipment ultrasonic disperse while stirring, dispersion machine stirs Mixing speed is 200 ~ 1000r/min, handles 5 ~ 15h of time, completes nano-powder dispersion steps and uniform and stable nanometer is made Dispersion liquid;The slurry tune glues filtration step are as follows: remaining 40% ~ 90% resin will be measured and be added into nano dispersion fluid, with point Scattered machine, which is stirred at low speed to resin, to be completely dissolved, and is then filtered slurry using pressure filtration method, to complete nanoelectronic slurry The preparation of material.It is designed by above-mentioned processing step, which has the following advantages that, specifically: 1, nano-powder dispersion base Body is low viscosity organic phase, and viscosity is low to be conducive to ultrasonic disperse, while low viscosity organic phase is conducive to the complete of resin and auxiliary agent Unfold, is bonded with nano powder surface formation, prepares uniform and stable nano dispersion fluid;2, remaining tree is added when slurry tune is viscous Using technique is stirred at low speed after rouge, it can be well protected molecular structure in this way, guarantee the repetition stability of slurry;3, the preparation side Method is high for nano material dispersion efficiency, and simple process is controllable, and slurry fineness is less than 2 μm.
Specific embodiment
Below with reference to specific embodiment, the present invention will be described.
Embodiment one, a kind of preparation method of nanoelectronic slurry include the low viscosity organic phase preparation successively carried out Step, nano-powder dispersion steps, slurry tune glue filtration step;
Low viscosity organic phase preparation step are as follows: defoam 1g ethyl cellulose, 0.5g levelling agent, 0.5g dispersing agent, 0.5g Agent, 90g two end number mixing ester (DBE) mix, and stirring to ethyl cellulose is completely dissolved at 50 DEG C, mixing speed 500r/min, Complete the low viscosity organic phase preparation of clear homogeneous;
Nano-powder dispersion steps are as follows: nano-silver powder (partial size 50nm) 40g and glass powder (partial size 50nm) 10g is added low Size barrel is placed in ultrasonic equipment ultrasonic disperse while stirring, mixing speed 500r/min, ultrasonic agitation by viscosity organic phase Time 8h completes nano-powder dispersion, uniform nano dispersion fluid is made;
Slurry tune glues filtration step are as follows: 9g ethyl cellulose is added in above-mentioned nano dispersion fluid, is existed using dispersion machine Stirring to ethyl cellulose is completely dissolved under the mixing speed of 300r/min, then filters pressing product, and much filtrate is target slurry, carefully Degree is 1.5 μm.
Embodiment two, a kind of preparation method of nanoelectronic slurry include the low viscosity organic phase preparation successively carried out Step, nano-powder dispersion steps, slurry tune glue filtration step;
Low viscosity organic phase preparation step are as follows: defoam 2g ethyl cellulose, 0.5g levelling agent, 0.5g dispersing agent, 0.5g Agent, 90g two end number mixing ester (DBE) mix, and stirring to ethyl cellulose is completely dissolved at 50 DEG C, mixing speed 500r/min, Complete the low viscosity organic phase preparation of clear homogeneous;
Nano-powder dispersion steps are as follows: low viscosity organic phase is added in nano-silver powder (partial size 50nm) 50g, size barrel is set Time 10h is stirred by ultrasonic in ultrasonic disperse, mixing speed 700r/min while stirring in ultrasonic equipment, completes nano-powder Dispersion, is made uniform nano dispersion fluid;
Slurry tune glues filtration step are as follows: 8g ethyl cellulose is added in above-mentioned nano dispersion fluid, is existed using dispersion machine Stirring to ethyl cellulose is completely dissolved under the mixing speed of 400r/min, then filters pressing product, and much filtrate is target slurry, carefully Degree is 1.5 μm.
Embodiment three, a kind of preparation method of nanoelectronic slurry include the low viscosity organic phase preparation successively carried out Step, nano-powder dispersion steps, slurry tune glue filtration step;
Low viscosity organic phase preparation step are as follows: defoam 3g ethyl cellulose, 0.5g levelling agent, 0.5g dispersing agent, 0.5g Agent, 90g two end number mixing ester (DBE) mix, and stirring to ethyl cellulose is completely dissolved at 50 DEG C, mixing speed 500r/min, Complete the low viscosity organic phase preparation of clear homogeneous;
Nano-powder dispersion steps are as follows: nano-silver powder (partial size 50nm) 30g and glass powder (partial size 50nm) 20g is added low Size barrel is placed in ultrasonic equipment ultrasonic disperse while stirring, mixing speed 1000r/min by viscosity organic phase, and ultrasound is stirred Time 12h is mixed, nano-powder dispersion is completed, uniform nano dispersion fluid is made;
Slurry tune glues filtration step are as follows: 7g ethyl cellulose is added in above-mentioned nano dispersion fluid, is existed using dispersion machine Stirring to ethyl cellulose is completely dissolved under the mixing speed of 500r/min, then filters pressing product, and much filtrate is target slurry, carefully Degree is 1.5 μm.
The above is only a preferred embodiment of the present invention, for those of ordinary skill in the art, according to the present invention Thought, there will be changes in the specific implementation manner and application range, and the content of the present specification should not be construed as to the present invention Limitation.

Claims (2)

1. a kind of preparation method of nanoelectronic slurry, it is characterised in that: include the low viscosity organic phase preparation successively carried out Step, nano-powder dispersion steps, slurry tune glue filtration step;
The low viscosity organic phase preparation step are as follows: the 10% ~ 60% of resin, auxiliary agent and solvent will be measured and mixed, under certain temperature Stirring to resin is completely dissolved, and whipping temp is 50 ± 5 DEG C, to complete the low viscosity organic phase preparation of clear homogeneous;
The nano-powder dispersion steps are as follows: by the nano-powder of metering with low viscosity is organic is added to size barrel, will starch Charging basket is placed in ultrasonic equipment ultrasonic disperse while stirring, and dispersion machine mixing speed is 200 ~ 1000r/min, and the processing time 5 ~ 15h completes nano-powder dispersion steps and uniform and stable nano dispersion fluid is made;Wherein, the nano-powder includes metal The partial size three-dimensional at least one dimension of powder, oxide powder or glass powder, nano-powder is less than 100nm;
The slurry tune glues filtration step are as follows: will measure remaining 40% ~ 90% resin and be added into nano dispersion fluid, and use dispersion machine It stirs at low speed to resin and is completely dissolved, the speed that dispersion machine stirs at low speed is 100 ~ 800r/min, and slurry is then used pressure Filtration method is filtered, to complete the preparation of nanoelectronic slurry.
2. a kind of preparation method of nanoelectronic slurry according to claim 1, it is characterised in that: the auxiliary agent includes Dispersing agent, defoaming agent, levelling agent.
CN201611174795.3A 2016-12-19 2016-12-19 A kind of preparation method of nanoelectronic slurry Active CN106710716B (en)

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CN109166671B (en) * 2018-08-22 2021-01-26 深圳市璞瑞达薄膜开关技术有限公司 Preparation method of quick-drying low-temperature silver paste
CN110600162B (en) * 2019-10-23 2021-04-02 河南农业大学 Solar cell conductive paste and preparation method thereof
CN111117371B (en) * 2020-01-20 2022-05-06 浙江纳美新材料股份有限公司 Special color paste for bamboo and wood dyeing and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101710497A (en) * 2009-12-08 2010-05-19 华中科技大学 Nano-silver conductive slurry
CN104282356A (en) * 2013-07-03 2015-01-14 肖淑勇 Low-silver-content composite conductive silver paste and preparation method thereof
CN105702320A (en) * 2014-11-28 2016-06-22 湖南利德电子浆料股份有限公司 Silver conductive paste for radio frequency identification tag and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101710497A (en) * 2009-12-08 2010-05-19 华中科技大学 Nano-silver conductive slurry
CN104282356A (en) * 2013-07-03 2015-01-14 肖淑勇 Low-silver-content composite conductive silver paste and preparation method thereof
CN105702320A (en) * 2014-11-28 2016-06-22 湖南利德电子浆料股份有限公司 Silver conductive paste for radio frequency identification tag and preparation method thereof

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