CN1067043A - Powder ammonium nitrate explosive and preparation method thereof - Google Patents
Powder ammonium nitrate explosive and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to a kind of powder ammonium nitrate explosive and manufacture method thereof that is used for engineering explosion.Explosive of the present invention is mixed by the bulk ammonium nitrate of lightweight, wood powder and compound oil phase material and forms or be made up of the bulk ammonium nitrate of lightweight, wood powder, compound oil phase material and a small amount of TNT mixing.Though do not contain TNT in this powder charge or only contain a small amount of TNT, the every performance index of product reach homemade No. 2, new No. 2 and surpass No. 1, No. 2, the index of new No. 2 rock explosives respectively.The manufacture method of explosive of the present invention is easy, is suitable for suitability for industrialized production.
Description
The present invention relates to a kind of powdery pyrotechnic composition and manufacture method thereof that is used for engineering explosion, particularly a kind of powder ammonium nitrate explosive and manufacture method thereof.
Commonly used homemade No. 1 and No. 2 powdery rock dynamites, it contains 14(quality % respectively in filling a prescription) and 11(quality %) tritonal (hereinafter to be referred as TNT, referring to former five WJ299-65 of machine portion and WJ299-73).Though this class explosive is used widely in engineering explosion, also has following problem: contain the TNT of larger proportion in (1) this explosive, its toxicity is very big, both is detrimental to health in manufacturing and the use, again contaminate environment; (2) because the TNT price rises steadily, increased the cost of this explosive; (3) this explosive in storing and using easily moisture absorption, caking, influence blast performance, even lost efficacy.
In order to overcome the shortcoming of above-mentioned explosive, Chinese patent application CN85100399 discloses a kind of " manufacture method of powder nitramon and technology ".No. 2 ammonium nitrate-fuel oils (hereinafter to be referred as " new No. 2 ") rock explosive that makes according to this processing method, it is by (quality %): 87.5 ammonium nitrate, 4.0 wood powders, 7.0TNT and 1.5 compound oil phase materials mix forms (referring to the regulation of " technical qualification of new No. 2 rock powdery an-tnt explosives " (trying)), the characteristics of this explosive are to adopt compound oil phase material instead of part TNT, reduced the TNT content in the explosive on the one hand, TNT dust pollution degree is alleviated to some extent; The shortcoming, the storage that makes product and the use properties that have overcome the easy moisture absorption caking of existing powder ammonium nitrate explosive have on the other hand preferably obtained certain improvement.But still there are following problem in this explosive and producing and manufacturing technique: the blast performance of (1) this explosive is on the low side, and stable inadequately; (2) this processing method is strict to the explosive production process, and suitability for industrialized production is difficult to reach the product performance design objective; (3) still have the TNT of high level in this explosive, problems such as cost and pollution remain further to be reduced.How to solve the existing in prior technology problem, become the higher scientific research task of difficulty anxious to be solved in the current powder ammonium nitrate explosive technical field.
A kind of powder nitramon and the manufacture method thereof that provide for the shortcoming that overcomes prior art is provided.Do not contain TNT in the explosive of the present invention or only contain a small amount of TNT, and the every performance index of product reach respectively No. 2, new No. 2 and surpass homemade No. 1, No. 2, the index of new No. 2 rock explosives; Manufacture method of the present invention is easy, is suitable for suitability for industrialized production.
The powder nitramon that designs according to the present invention is characterized in that by (quality %): the bulk ammonium nitrate of 90～93 lightweights, 3.5～5.5 wood powders and 3.5～4.5 compound oil phase materials mix and form; Or by (quality %): the bulk ammonium nitrate of 87～92 lightweights, 2.5～4.5 wood powders, 2.0～4.0 compound oil phase materials and 2.0～6.0TNT mix and form.Above-mentioned compound oil phase material is by (quality %): 53～78 diesel oil or (with) compound wax, 20～40 rosin, 1.0～4.0 stearic acid and 0～3.0 dehydrating sorbitol monooleate (hereinafter to be referred as span-80) mix and form.
First kind of technical scheme according to the present invention and the manufacture method of the powder ammonium nitrate explosive that designs are: the first step is to carry out fragmentation, mixing by bulk ammonium nitrate of ready-formed lightweight and wood powder, and temperature is that 20～60 ℃, time are 15～20min; Second step by diesel oil or (with) compound wax, rosin, stearic acid, span-80 compound oil phase material and the first step blended material formed grind mixed, temperature is that 60～65 ℃, time are 10～20min; The 3rd step is with the second mixed material cooling of step (its temperature of charge is reduced to below 40 ℃); The 4th step was carried out finished product packing with cooled material of the 3rd step, made non-TNT powder ammoniumnitrate explosives product.Second kind of technical scheme according to the present invention and the manufacture method of the powder ammonium nitrate explosive that designs are: the first step is to carry out fragmentation, mixing by bulk ammonium nitrate of ready-formed lightweight and wood powder, and temperature is that 20～60 ℃, time are 15～20min; Second step by diesel oil or (with) compound oil phase material formed of compound wax, rosin, stearic acid, span-80 mixes with the first step blended material, temperature is that 40～55 ℃, time are 4～6min; The 3rd step was to go on foot mixed material by powdery TNT and second to grind mixed, and temperature is that 60～65 ℃, time are 10～20min; The 4th step is with the 3rd mixed material cooling of step (its temperature of charge is reduced to below 40 ℃); The 5th step was carried out finished product packing with cooled material of the 4th step, made few terraced powder ammonium nitrate explosive product.The common trait of above-mentioned two kinds of manufacture method is that the first method of the bulk ammonium nitrate of prefabricated lightweight is: at first that common ammonium nitrate is soluble in water, and add positively charged ion or anion surfactant (add-on be ammonium nitrate total mass 0.05～0.3%) simultaneously, obtaining concentration is 88～93(quality %), temperature is 110～130 ℃ ammonium nitrate solution; Crystallization under vacuum condition then, vacuum tightness is 0.085～0.095MPa during crystallization, the time is 10～15min, promptly makes moisture content≤0.3(quality %) the bulk ammonium nitrate of lightweight.The second method of the bulk ammonium nitrate of prefabricated lightweight is: at first that common ammonium nitrate is soluble in water, and add positively charged ion or anion surfactant (add-on be ammonium nitrate total mass 0.03～0.2%) simultaneously, obtaining concentration is 75～90(quality %), temperature is 70～90 ℃ ammonium nitrate solution; The crystallization of lowering the temperature then, temperature reduce to≤and 45 ℃; Material through solid-liquid separation to water content≤5(quality %), drying is to water content≤0.3(quality % again), promptly make the bulk ammonium nitrate of lightweight.
The principle of design of explosive of the present invention is: do not contain or only contain a small amount of TNT sensitizing agent in the explosive of the present invention, require to have higher blast performance again, the Sensitivity to Primary Explosion and the explosive reaction speed that therefore improve this explosive are key problem in technology.Powder ammonium nitrate explosive belongs to non-homogeneous explosive, from its mechanism of detonation and initiation mechanism analysis, each component particles of the ammoniumnitrate explosives of design is thin more, specific surface is big more, it is even more to mix, help the increase in space more, be easy to detonate more and explosive reaction rapid more, complete more.Therefore the present invention proposes the main component ammonium nitrate of this explosive is carried out modification, promptly changes its crystalline structure, improves fineness and specific surface.Adopt the bulk ammonium nitrate of lightweight of this modification to replace traditional common ammonium nitrate, be aided with preferred high heating value oil phase material again, both be easy on the bulk ammonium nitrate granule of lightweight auxilliary exhibition and along micropore permeation, suitable denseness and sticking power are arranged again, guarantee to mix full and uniform property and enough stability; Make the blended explosive that makes have competent space, defective and bigger reaction interface, reach and when not containing TNT or only contain a small amount of TNT sensitizing agent, have excellent blast performance.The principle of design of the manufacture method of explosive of the present invention: mainly propose at the bulk ammonium nitrate of prefabricated lightweight.Utilize ammonium nitrate in the aqueous solution during crystallization, because the effect of tensio-active agent, disturb the growth of nucleus, vacuum crystallization method and decrease temperature crystalline that the present invention is proposed can legal system get the bulk ammonium nitrate crystal of the fine needle-like lightweight of multiple cracks, porous feeler shape and many defectives, it has the advantages that very easily pulverize, and can obtain the bulk particle of lightweight of high fineness, high-ratio surface through simple crushing.Adopt above-mentioned principle of design can improve Sensitivity to Primary Explosion, explosion velocity and the power of ammoniumnitrate explosives of the present invention, to reach the purpose that overcomes the prior art shortcoming.
The present invention compared with prior art, its distinguishing feature is: do not contain TNT in (1) explosive of the present invention or only contain a small amount of TNT, thereby the problem of eliminating or having alleviated the TNT contaminate environment and be detrimental to health.(2) formulating of recipe of explosive is reasonable, particularly adopt the main body composition of the bulk ammonium nitrate of lightweight as explosive, can improve the Sensitivity to Primary Explosion and the explosive reaction speed of explosive effectively, make TNT-free explosive reach homemade No. 2, the blast performance index of new No. 2 explosives, few terraced explosive reaches and surpasses homemade No. 1, No. 2, explosion velocity, brisance and the power of the blast performance index, particularly explosive of new No. 2 explosives and reaches the best level of current powder ammonium nitrate explosive; Its anti-caking effect, anti-moisture absorption and shelf characteric all are better than new No. 2 explosives.(3) material cost of product has decline by a relatively large margin than currently available products, and TNT-free explosive descends 360 yuan/ton and 250 yuan/ton than No. 2 respectively with new No. 2 explosives; Few terraced explosive descends 270 yuan/ton and 150 yuan/ton than No. 2 respectively with new No. 2 rock dynamites.(4) manufacture method of explosive of the present invention is reasonable in design, is easy to industrializing implementation, and production efficiency is higher, helps producing in enormous quantities, having the industrialization promotion using value.The present invention is through repetition test and checking, and product performance are excellent, process stabilizing is reliable.
Specific embodiments of the present invention is provided by drawings and Examples.
Fig. 1 be non-TNT powder ammoniumnitrate explosives manufacture method (one of) process flow diagram.
Fig. 2 is the process flow diagram of non-TNT powder ammoniumnitrate explosives manufacture method (two).
Fig. 3 be few terraced powder ammonium nitrate explosive manufacture method (one of) process flow diagram.
Fig. 4 is the process flow diagram of few terraced powder ammonium nitrate explosive manufacture method (two).
Below in conjunction with accompanying drawing the present invention is described in further detail.
The various starting material that adopted in the manufacturing process of the powder ammonium nitrate explosive that the present invention proposes all meet the Ministry of Chemical Industry's ministerial standard or company standard.
Embodiment 1(is an example to produce the 220kg powder ammonium nitrate explosive):
Select the mass ratio of powder ammonium nitrate explosive: lightweight is bulk ammonium nitrate 92%, wood powder 4% and compound oil phase material 4%; The quality proportioning of compound oil phase material is: diesel oil 50%, rosin 25%, compound wax 22.5%, stearic acid 1.25% and (span-80) 1.25%.
According to said ratio, implementation step is as follows:
The first step takes by weighing 202.4kg ammonium nitrate, adds in the 300kg ammonium nitrate mother liquor of the concentration about 66% that recycles repeatedly, under agitation is warming up to 80 ℃, and ammonium nitrate is all dissolved; Add cats product octadecane amine acetate 600g then; After treating surfactant dissolves, under agitation be cooled to about 35 ℃; Again this suspension being carried out centrifugation, cake moisture is controlled at≤and 4%, filtrate is the still recyclable circulation of the ammonium nitrate mother liquor of concentration 66%, recycles; Filter cake to water content≤0.3%, makes the bulk ammonium nitrate of lightweight through heating, drying thus, and is standby.
Second step took by weighing compound wax 1.98kg and rosin 2.2kg earlier, under 130 ℃ temperature condition, and molten mixing in melting tank; All moltenly mix the back, add diesel oil 4.4kg, hard ester acid 0.11kg and (span-80) 0.11kg again, under 90 ± 5 ℃ temperature condition, continue molten mixed; All insulations about 70 ℃ behind the consolute, standby.
The 3rd step, the bulk ammonium nitrate 202.4kg of lightweight that the first step is made is warming up to 60 ℃ in wheel roller, roll and add after 15 minutes through pulverizing, exsiccant wood powder 8.8kg, ground down mixed 10 minutes in 60 ℃, the compound oil phase material 8.8kg that last second step of evenly adding has prepared, discharging after continuing to puddle 15 minutes under 60 ℃.
In the 4th step, with below the mixed material medicine of a cold nature to 40 ℃, powder charge in spiral medicine charge machine through packing and vanning, is product again.
Product performance: as charge diameter 32mm, charge density 0.95～1.08gcm
-3The time, explosion velocity of explosive 3210ms
-1, power 356ml, brisance 14.5mm, induced detonation 6cm.
Embodiment 2(is an example to produce the 220kg powder ammonium nitrate explosive):
Select the quality proportioning of powder ammonium nitrate explosive to be: lightweight is bulk ammonium nitrate 90.5%, wood powder 3.25%, compound oil phase material 3.5% and TNT2.75%.The mass ratio of compound oil phase material is: diesel oil 50%, rosin 25%, compound wax 20%, stearic acid 2.5% and (span-80) 2.5%.
According to said ratio, implementation step is as follows:
The first step takes by weighing 199.1kg ammonium nitrate and 390g octadecane amine acetate, is dissolved in the 20kg water; Be warming up to 120 ℃ and all after the dissolving, this solution put into the vacuum crystallization machine, under vacuum tightness 0.09 ± 0.005MPa condition, vacuumize 15min, promptly make water content≤0.3(quality %) the bulk ammonium nitrate of lightweight, standby.
Second step took by weighing compound wax 1.54kg and rosin 1.93kg earlier, and is molten mixed in dissolution boiler under 120 ℃ of temperature; The all molten back of mixing adds diesel oil 3.85kg, stearic acid 0.19kg and (span-80) 0.19kg, and consolute evenly is incubated under 80 ± 5 ℃ of conditions, and is standby.
The 3rd step, the bulk ammonium nitrate 199kg of lightweight that the first step is obtained and through pulverize, exsiccant wood powder 7.15kg pulverizes together, mix 15min after, under 50 ± 5 ℃ of conditions, evenly add ready compound oil phase material 7.7kg of second step, mixed grind 5min; Evenly add again and pulverize qualified powdery TNT6kg, discharging after continuing mixed grind 15min under 60 ℃.
The 4th step is with the 4th step of embodiment 1.
Product performance: as charge diameter 32mm, charge density 0.95～1.0gcm
-3The time, explosion velocity 3560m8
-1, power 406ml, brisance 16.2mm, induced detonation 6cm, impact sensitivity and friction sensitivity are zero.
Embodiment 3(is an example to produce the 1kg powder ammonium nitrate explosive):
Select the quality proportioning of powder ammonium nitrate explosive to be: lightweight is bulk ammonium nitrate 89%, wood powder 3%, TNT5% and compound oil phase material 3%.The quality proportioning of compound oil phase material is: diesel oil 50%, rosin 25%, compound wax 22.5% and stearic acid 2.5%.
According to said ratio, implementation step is as follows:
The first step takes by weighing 890g ammonium nitrate and 1.5g octadecane nitrate, is dissolved in the 90g water; Be warming up to 125 ℃ and all after the dissolving, this solution put into vacuum cyrsytalliser, under vacuum tightness 0.095MPa condition, vacuumize 10min, promptly make water content≤0.3(quality %) the bulk ammonium nitrate of lightweight, standby.
Second step took by weighing compound wax 6.75g and rosin 7.5g earlier, under 120 ℃ temperature condition, and molten mixing in beaker; After all molten the mixing, add diesel oil 15g and stearic acid 0.75g again, under 90 ± 5 ℃ temperature condition, continue consolute; All behind the consolute, under 80 ℃ of left and right sides conditions, be incubated, standby.
The 3rd step is with the bulk ammonium nitrate 890g of the lightweight of the first step and dry wood powder 30g ball milling 20min in small grinder in small, broken bits; Again this mixture is poured on the mixed batch pan of preheating and heats; To the medicine temperature rise to about 50 ℃ the time, add the compound oil phase material 30g of second step preparation, add powdery TNT50g again, discharging, the medicine of a cold nature, powder charge then after continuing to puddle 15min under 60 ℃ of left and right sides conditions after puddling evenly.
Product performance: as charge diameter 32mm, charge density 0.95～1.0gcm
-3The time, explosion velocity 3714ms
-1, brisance 16.5mm, induced detonation 8cm, power 418ml.
Embodiment 4(is an example to produce the 1kg powder ammonium nitrate explosive):
Select the quality proportioning of powder ammonium nitrate explosive: lightweight is bulk ammonium nitrate 89%, wood powder 3%, composite oil material 3% and TNT5%.The quality proportioning of compound oil phase material is: compound wax 22.5%, rosin 25%, diesel oil 50% and stearic acid 2.5%.
According to said ratio, implementation step is as follows:
The first step, used tensio-active agent are Sodium dodecylbenzene sulfonate, and consumption is 1.2g, and all the other are all with the first step of implementing 3.
In second step, all go on foot with second of embodiment 3.
In the 3rd step, all go on foot with the 3rd of embodiment 3.
Product performance: as charge diameter 32mm, charge density 0.95～1.0gcm
-3The time, explosion velocity 3670ms
-1, brisance 16.4mm, induced detonation 7cm.
Embodiment 5(is an example to produce the 1kg powder ammonium nitrate explosive):
Select the quality proportioning of powder ammonium nitrate explosive: lightweight is bulk ammonium nitrate 88.5%, wood powder 3%, TNT6% and compound oil phase material 2.5%.The quality proportioning of compound oil phase material is: compound wax 20%, rosin 25%, diesel oil 51% and stearic acid 4%.
According to said ratio, implementation step is as follows:
The first step, used ammonium nitrate are 885g, and anion surfactant is an alkyl sodium sulfonate, consumption 1.5g, and all the other are all with the first step of embodiment 3.
In second step, except that the quality of each compound oil phase material is compound wax 5g, rosin 6.25g, diesel oil 12.75g and the stearic acid 1g, all the other operations all go on foot with second of embodiment 3.
In the 3rd step, except that the quality of each material is the bulk ammonium nitrate 885g of lightweight, compound oil phase material 25g and the powdery TNT60g, all the other are all with the 3rd step of example 3.
Product performance: as charge diameter 32mm, charge density 0.95～1.0gcm
-3The time, explosion velocity 3590ms
-1, brisance 16mm, induced detonation 8cm, power 403ml.
Embodiment 6(is an example to produce 1kg powdery ammonium nitrate fried):
Select the quality proportioning of powder ammonium nitrate explosive: lightweight is bulk ammonium nitrate 90.8%, wood powder 3.6%, compound oil phase material 3.6% and TNT2%.Compound oil phase quality proportioning is: compound wax 26%, rosin 30%, diesel oil 40% and stearic acid 4%.
By said ratio, implementation step is as follows:
The first step, used ammonium nitrate 908g, tensio-active agent octadecane amine acetate 1g, all the other are all with the first step of example 3.
In second step, except that used compound oil phase material was compound wax 9.36g, rosin 10.8g, diesel oil 14.4g, stearic acid 1.44g, all the other all went on foot with second of example 3.
In the 3rd step, the quality of removing each material is: bulk ammonium nitrate 908g, wood powder 36g, compound oil phase 36g and the TNT20g, all the other all go on foot with the 3rd of example 3.
Product performance: as charge diameter 32mm, charge density 0.95～1.0g/cm
3The time, explosion velocity 3540m/s, brisance 15.7mm, power 395ml, induced detonation 6cm.
In the foregoing description 1～3, except that selecting octadecane amine acetate and nitrate cats product for use, if select for use other salt of octadecane amine also to have same effect.
Claims (10)
1, a kind of powder ammonium nitrate explosive that is used for engineering explosion is characterized in that by (quality %): the bulk ammonium nitrate of 90～93 lightweights, 3.5～5.5 wood powders and 3.5～4.5 compound oil phase materials mix and form.
2, a kind of powder ammonium nitrate explosive that is used for engineering explosion is characterized in that by (quality %): the bulk ammonium nitrate of 87～92 lightweights, 2.5～4.5 wood powders, 2.0～4.0 compound oil phase materials and 2.0～6.0TNT mix and form.
3, explosive according to claim 1 and 2 is characterized in that compound oil phase material is by (quality %): 53～78 diesel oil or (with) compound wax, 20～40 rosin, 1.0～4.0 stearic acid and 0～3.0span-80 mix and form.
4, a kind of method of making the described powder ammonium nitrate explosive of claim 1, the first step are to carry out fragmentation, mixing by bulk ammonium nitrate of ready-formed lightweight and wood powder, and temperature is that 20～60 ℃, time are 15～20min; Second step by diesel oil or (with) compound wax, rosin, stearic acid, span-80 compound oil phase material and the first step blended material formed grind mixed, temperature is that 60～65 ℃, time are 10～20min; The 3rd step is with the second mixed material cooling of step (its temperature of charge is reduced to below 40 ℃); The 4th step was carried out finished product packing with cooled material of the 3rd step, made the powder ammonium nitrate explosive product; The method that it is characterized in that the bulk ammonium nitrate of prefabricated lightweight, at first that common ammonium nitrate is soluble in water, and add positively charged ion or anion surfactant (add-on be ammonium nitrate total mass 0.05～0.3%) simultaneously, obtaining concentration is 88～93(quality %), temperature is 110～130 ℃ ammonium nitrate solution; Crystallization under vacuum condition then, vacuum tightness is that 0.085～0.095MPa, time are 10～15min during crystallization, makes moisture content≤0.3(quality % thus) the bulk ammonium nitrate of lightweight.
5, a kind of method of making the described powder ammonium nitrate explosive of claim 2, the first step are to carry out fragmentation, mixing by bulk ammonium nitrate of ready-formed lightweight and wood powder, and temperature is that 20～60 ℃, time are 15～20min; Second step by diesel oil or (with) compound oil phase material formed of compound wax, rosin, stearic acid, span-80 mixes with the first step blended material, temperature is that 40～55 ℃, time are 4～6min; The 3rd step was to go on foot the blended material by powdery TNT and second to grind mixed, and temperature is that 60～65 ℃, time are 10～20min; The 4th step is with the 3rd mixed material cooling of step (its temperature of charge is reduced to below 40 ℃); The 5th step carried out cooled material of the 4th step finished product packing, makes the powder ammonium nitrate explosive product; The method that it is characterized in that the bulk ammonium nitrate of prefabricated lightweight, at first that common ammonium nitrate is soluble in water, and add positively charged ion or anion surfactant (add-on be ammonium nitrate total mass 0.05～0.3%) simultaneously, obtaining concentration is 88～93(quality %), temperature is 110～130 ℃ ammonium nitrate solution; Crystallization under vacuum condition then, vacuum tightness is that 0.085～0.095MPa, time are 10～15min during crystallization, makes water content≤0.3(quality % thus) the bulk ammonium nitrate of lightweight.
6, manufacture method according to claim 4 or 5 described powder ammonium nitrate explosives, the method that it is characterized in that the bulk ammonium nitrate of prefabricated lightweight, at first that common ammonium nitrate is soluble in water, and add positively charged ion or anion surfactant simultaneously, (add-on be ammonium nitrate total mass 0.03～0.2%), obtaining concentration is 75～90(quality %), temperature is 70～90 ℃ a ammonium nitrate solution, the crystallization of lowering the temperature then, temperature reduces to≤and 45 ℃, material carries out solid-liquid separation to moisture content≤5(quality %), drying is to moisture content≤0.3(quality % again), promptly make the bulk ammonium nitrate of lightweight.
7,, it is characterized in that cats product is the octadecane amine salt according to the manufacture method of claim 4 or 5 described powder ammonium nitrate explosives.
8,, it is characterized in that anion surfactant is Sodium dodecylbenzene sulfonate or alkyl sodium sulfonate according to the manufacture method of claim 4 or 5 described powder ammonium nitrate explosives.
9, the manufacture method of powder ammonium nitrate explosive according to claim 6 is characterized in that cats product is the octadecane amine salt.
10, the manufacture method of powder ammonium nitrate explosive according to claim 6 is characterized in that anion surfactant is Sodium dodecylbenzene sulfonate or alkyl sodium sulfonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107051 CN1028862C (en) | 1991-05-17 | 1991-05-17 | Powdered ammonium nitrate explosive and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107051 CN1028862C (en) | 1991-05-17 | 1991-05-17 | Powdered ammonium nitrate explosive and its preparation method |
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| CN1067043A true CN1067043A (en) | 1992-12-16 |
| CN1028862C CN1028862C (en) | 1995-06-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 91107051 Expired - Fee Related CN1028862C (en) | 1991-05-17 | 1991-05-17 | Powdered ammonium nitrate explosive and its preparation method |
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| CN (1) | CN1028862C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035759C (en) * | 1992-12-29 | 1997-09-03 | 南京理工大学 | Powdered ammonium nitrate fuel explosive and its preparing process |
| CN1069093C (en) * | 1997-11-21 | 2001-08-01 | 南京理工大学 | Ammonium nitrate explosive without TNT for coal mine and production thereof |
| CN1086685C (en) * | 1997-09-02 | 2002-06-26 | 南京理工大学 | Explosive columns for earthquake sources and manufacture thereof |
| CN1099400C (en) * | 1999-05-28 | 2003-01-22 | 兴宁市华威化工实业有限公司 | Method for preparing low TNT-equivalent ammonium nitrate-fuel oil explosive |
| CN1321949C (en) * | 2004-07-29 | 2007-06-20 | 国营云南包装厂 | Rocky powdery ammonium nitrate explosive with no stibium, and preparation method |
| CN100425580C (en) * | 2006-12-04 | 2008-10-15 | 唐秋明 | Method and equipment for preparing powder explosive |
| CN101723767B (en) * | 2009-12-08 | 2011-07-27 | 新时代(济南)民爆科技产业有限公司 | Powdery explosive |
| CN102557845A (en) * | 2010-12-31 | 2012-07-11 | 新时代(济南)民爆科技产业有限公司 | Expanded ammonium nitrate explosive and preparation process thereof |
| CN102795950A (en) * | 2012-07-10 | 2012-11-28 | 贵州巨能化工有限公司 | Composite oil phase for expanded explosive and preparation method of composite oil phase |
| CN104163744A (en) * | 2014-08-18 | 2014-11-26 | 南京理工大学 | Powdery expanded ammonium nitrate explosive and preparation method for same |
-
1991
- 1991-05-17 CN CN 91107051 patent/CN1028862C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035759C (en) * | 1992-12-29 | 1997-09-03 | 南京理工大学 | Powdered ammonium nitrate fuel explosive and its preparing process |
| CN1086685C (en) * | 1997-09-02 | 2002-06-26 | 南京理工大学 | Explosive columns for earthquake sources and manufacture thereof |
| CN1069093C (en) * | 1997-11-21 | 2001-08-01 | 南京理工大学 | Ammonium nitrate explosive without TNT for coal mine and production thereof |
| CN1099400C (en) * | 1999-05-28 | 2003-01-22 | 兴宁市华威化工实业有限公司 | Method for preparing low TNT-equivalent ammonium nitrate-fuel oil explosive |
| CN1321949C (en) * | 2004-07-29 | 2007-06-20 | 国营云南包装厂 | Rocky powdery ammonium nitrate explosive with no stibium, and preparation method |
| CN100425580C (en) * | 2006-12-04 | 2008-10-15 | 唐秋明 | Method and equipment for preparing powder explosive |
| CN101723767B (en) * | 2009-12-08 | 2011-07-27 | 新时代(济南)民爆科技产业有限公司 | Powdery explosive |
| CN102557845A (en) * | 2010-12-31 | 2012-07-11 | 新时代(济南)民爆科技产业有限公司 | Expanded ammonium nitrate explosive and preparation process thereof |
| CN102795950A (en) * | 2012-07-10 | 2012-11-28 | 贵州巨能化工有限公司 | Composite oil phase for expanded explosive and preparation method of composite oil phase |
| CN102795950B (en) * | 2012-07-10 | 2015-01-21 | 贵州巨能化工有限公司 | Composite oil phase for expanded explosive and preparation method of composite oil phase |
| CN104163744A (en) * | 2014-08-18 | 2014-11-26 | 南京理工大学 | Powdery expanded ammonium nitrate explosive and preparation method for same |
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| CN1028862C (en) | 1995-06-14 |
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