CN106701352A - Environment-friendly type efficient lens cleanser and preparation method thereof - Google Patents

Environment-friendly type efficient lens cleanser and preparation method thereof Download PDF

Info

Publication number
CN106701352A
CN106701352A CN201611095000.XA CN201611095000A CN106701352A CN 106701352 A CN106701352 A CN 106701352A CN 201611095000 A CN201611095000 A CN 201611095000A CN 106701352 A CN106701352 A CN 106701352A
Authority
CN
China
Prior art keywords
parts
environment
cleaning agent
rice bran
efficient lens
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611095000.XA
Other languages
Chinese (zh)
Inventor
张小华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Original Assignee
ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd filed Critical ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Priority to CN201611095000.XA priority Critical patent/CN106701352A/en
Publication of CN106701352A publication Critical patent/CN106701352A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an environment-friendly type efficient lens cleanser and a preparation method thereof, and relates to the technical field of lens maintenance. The environment-friendly type efficient lens cleanser is prepared from the following raw materials in parts by weight: 10 to 15 parts of modified polyethylene oxide, 2 to 3 parts of polyvinyl alcohol resin, 2 to 3 parts of carbomer resin, 1 to 2 parts of hydrogenated castor oil, 1 to 2 parts of pregelatinized starch, 0.5 to 1 part of rice bran wax, 0.5 to 1 part of sodium bicarbonate powder, 0.5 to 1 part of pentanediol, 0.3 to 0.5 part of nano zinc oxide, 0.2 to 0.3 part of maleic anhydride grafted compatilizer, 0.1 to 0.2 part of polyaspartic acid and 100 to 150 parts of water. The environment-friendly type efficient lens cleanser disclosed by the invention has the advantages that the cleaning effect is good, the cleaning efficiency is high, dirt attached to a lens can be effectively cleaned away, and the cleaning rate can reach 99.5 percent; water is used as a solvent, so that the content of VOC (Volatile Organic Compounds) during a cleaning process is low than 0.05 percent, and the using safety of the environment-friendly type efficient lens cleanser is increased.

Description

A kind of environment-friendly highly efficient lens cleaning agent and preparation method thereof
Technical field：
The present invention relates to camera lens maintenance technical field, and in particular to a kind of agent of environment-friendly highly efficient lens cleaning and its preparation side Method.
Background technology：
Camera lens, belongs to the important component of camera and video camera, it is necessary to careful maintenance.And camera lens is easily infected with dust and dirt Dirt, is such as cleaned not in time, it will the normal of influence camera lens is used.At present, commercial detergent is not specialty cleaning camera lens, But mixed using alcohol and ether, although cleaning effect is good, but high volatility, is easily quickly waved after being sprayed at camera lens Hair；In addition, ether can be oxidized to peroxide, aldehyde and acetic acid under air effect, there is destructiveness to lens protection film, shorten The service life of diaphragm.
The content of the invention：
The technical problems to be solved by the invention be provide a kind of cleaning effect it is good, safe to use, beneficial to extension Environment-friendly highly efficient lens cleaning agent of camera lens service life and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of environment-friendly highly efficient lens cleaning agent, is made up of the raw material of following parts by weight：
Modified 10-15 parts of polyethylene glycol oxide, polyvinyl alcohol resin 2-3 parts, carbomer 2-3 parts, rilanit special 1-2 Part, pre-gelatinized starch 1-2 parts, rice bran wax 0.5-1 parts, saleratus power 0.5-1 parts, pentanediol 0.5-1 parts, nano zine oxide 0.3- 0.5 part, maleic anhydride 0.2-0.3 parts, poly-aspartate 0.1-0.2 parts, water 100-150 parts of compatilizer of grafting；
The modified polyethylene glycol oxide is formed by the modified treatment of polyethylene glycol oxide, and its processing method is：To polyoxyethylene Polyquaternium and HPMA are added in alkene, microwave treater microwave treatment 5min is utilized after being sufficiently mixed, stood After 30min continue microwave treatment 5min, add HEMC and isomeric alcohol polyethenoxy ether, be well mixed after with The cooling rate of 10 DEG C/min is cooled to -5~5 DEG C of insulation mixing 15min, is subsequently adding 60~70 DEG C of hot water, and with 5 DEG C/min Programming rate be warming up to reflux state insulation mixing 15min, gained mixture is down to room with the cooling rate of 5 DEG C/min again Temperature, finally sends into spray dryer, dries gained particulate abrasive into powder, obtains final product modified polyethylene glycol oxide.
The polyethylene glycol oxide, polyquaternium, HPMA, HEMC, isomery alcohol polyoxy second The quality amount ratio of alkene ether and hot water is 15-20:1-2:0.5-1:0.5-1:0.2-0.5:50-60.
The condition of work of the microwave treater is microwave frequency 2450MHz, power 700W.
Polyethylene glycol oxide strengthens its thickening property by modification, it is dissolved in the solution formed after water and moistens well Dirt on wet and emulsification camera lens, so as to play the effect of cleaning.
The carbomer is selected from the one kind in carbomer 940, carbomer 934, carbomer 941.
Using preceding by pretreatment, its processing method is the rice bran wax：By rice bran wax with the programming rate liter of 5 DEG C/min Temperature is warming up to molten condition insulation mixing 5min to 45-50 DEG C of insulation mixing 5min, then with the programming rate of 10 DEG C/min, and adds Enter N hydroxymethyl acrylamide, pentaerythrite and allyl glycidyl ether, continue to be incubated mixing 15min, gained mixture is with 5 DEG C/cooling rate of min is down to room temperature, obtains final product rice bran wax after pretreatment.
The quality amount ratio of the rice bran wax, N hydroxymethyl acrylamide, pentaerythrite and allyl glycidyl ether is 10-15:0.5-1:0.3-0.5:0.1-0.2。
Rice bran wax also strengthens its water solubility by above-mentioned pretreatment, while reducing its fusing point, adds as thickening aids It is added in cleaning agent.
A kind of preparation method of environment-friendly highly efficient lens cleaning agent, comprises the following steps：
(1) to addition polyvinyl alcohol resin and rice bran wax in water, and reflux state is warming up to the programming rate of 5 DEG C/min Insulation mixing 10-15min, adds modified polyethylene glycol oxide and maleic anhydride grafting compatilizer, continues the insulation mixing 15- that flows back 30min, is then cooled to 0-5 DEG C of insulation mixing 15-30min with the cooling rate of 5 DEG C/min, obtains final product material I；
(2) to addition pentanediol and nano zine oxide in rilanit special, and it is warming up to the programming rate of 5 DEG C/min 75-80 DEG C of insulation mixing 5-10min, adds carbomer and saleratus power, continues to be incubated mixing 3-5min, then with 5 DEG C/ The cooling rate of min is cooled to room temperature, obtains final product material II；
(3) to addition material II, pre-gelatinized starch and poly-aspartate in material I, and with the programming rate of 10 DEG C/min Reflux state insulation mixing 5-10min is warming up to, room temperature is then cooled to the cooling rate of 5 DEG C/min, gained mixture turns Enter in ball mill, 400 mesh sieves are crossed after ball milling, obtain final product target cleaning agent.
The beneficial effects of the invention are as follows：The present invention is raw material with modified polyethylene glycol oxide, is aided with various auxiliary agents and camera lens is obtained Cleaning agent, the cleaning effect of made cleaning agent is good, cleaning efficiency is high, can effectively remove the dirt adhered on camera lens, its clearance rate Reach 99.5%；And using water as solvent, make the VOC content during cleaning less than 0.05%, improve the use of cleaning agent Security；The cleaning agent does not possess corrosivity simultaneously, lens protection film will not be caused to damage, so as to be used beneficial to extension camera lens Life-span.
Specific embodiment：
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) to addition 3 parts of polyvinyl alcohol resins and 0.5 part of rice bran wax in 150 parts of water, and with the programming rate of 5 DEG C/min Reflux state insulation mixing 10min is warming up to, 15 parts of modified polyethylene glycol oxides is added and 0.2 part of maleic anhydride grafting is compatible Agent, continues the insulation mixing 30min that flows back, and is then cooled to 0-5 DEG C of insulation mixing 30min with the cooling rate of 5 DEG C/min, obtains final product Material I；
(2) to addition 0.5 part of pentanediol and 0.3 part of nano zine oxide in 1 part of rilanit special, and with the liter of 5 DEG C/min Warm speed is warming up to 75-80 DEG C of insulation mixing 10min, adds 3 parts of carbomers 940 and 0.5 part of saleratus power, continues to be incubated Mixing 5min, is then cooled to room temperature with the cooling rate of 5 DEG C/min, obtains final product material II；
(3) to addition material II, 2 parts of pre-gelatinized starches and 0.2 part of poly-aspartate in material I, and with 10 DEG C/min's Programming rate is warming up to reflux state insulation mixing 10min, is then cooled to room temperature with the cooling rate of 5 DEG C/min, and gained is mixed Compound is transferred in ball mill, and 400 mesh sieves are crossed after ball milling, obtains final product target cleaning agent.
The preparation of modified polyethylene glycol oxide：To 1 part of polyquaternium of addition in 20 parts of polyethylene glycol oxides and 0.5 part of poly- horse of hydrolysis Carry out acid anhydrides, microwave frequency 2450MHz, the microwave treater microwave treatment 5min of power 700W are utilized after being sufficiently mixed, stand Continue microwave treatment 5min after 30min, add 0.5 part of HEMC and 0.3 part of isomeric alcohol polyethenoxy ether, mix - 5~5 DEG C of insulation mixing 15min are cooled to the cooling rate of 10 DEG C/min after closing uniformly, 60 parts of 60~70 DEG C of heat are subsequently adding Water, and reflux state insulation mixing 15min is warming up to the programming rate of 5 DEG C/min, gained mixture is again with the drop of 5 DEG C/min Warm speed is down to room temperature, finally sends into spray dryer, dries gained particulate abrasive into powder, obtains final product modified polyoxyethylene Alkene.
The pretreatment of rice bran wax：15 parts of rice bran waxs are warming up to 45-50 DEG C of insulation mixing with the programming rate of 5 DEG C/min 5min, then molten condition insulation mixing 5min is warming up to the programming rate of 10 DEG C/min, and add 0.5 part of N- methylol propylene Acid amides, 0.3 part of pentaerythrite and 0.2 part of allyl glycidyl ether, continue be incubated mixing 15min, gained mixture with 5 DEG C/ The cooling rate of min is down to room temperature, obtains final product rice bran wax after pretreatment.
Embodiment 2
(1) to addition 3 parts of polyvinyl alcohol resins and 1 part of rice bran wax in 150 parts of water, and with the programming rate liter of 5 DEG C/min Temperature adds 12 parts of modified polyethylene glycol oxides and 0.2 part of maleic anhydride grafting compatilizer to reflux state insulation mixing 15min, Continue the insulation mixing 20min that flows back, 0-5 DEG C of insulation mixing 30min is then cooled to the cooling rate of 5 DEG C/min, obtain final product thing Material I；
(2) to addition 0.5 part of pentanediol and 0.3 part of nano zine oxide in 1.5 parts of rilanit specials, and with 5 DEG C/min's Programming rate is warming up to 75-80 DEG C of insulation mixing 5min, adds 2 parts of carbomers 934 and 0.5 part of saleratus power, continues to protect Temperature mixing 5min, is then cooled to room temperature with the cooling rate of 5 DEG C/min, obtains final product material II；
(3) to addition material II, 1 part of pre-gelatinized starch and 0.2 part of poly-aspartate in material I, and with 10 DEG C/min's Programming rate is warming up to reflux state insulation mixing 10min, is then cooled to room temperature with the cooling rate of 5 DEG C/min, and gained is mixed Compound is transferred in ball mill, and 400 mesh sieves are crossed after ball milling, obtains final product target cleaning agent.
The preparation of modified polyethylene glycol oxide：To 1 part of polyquaternium of addition in 20 parts of polyethylene glycol oxides and 1 part of poly- Malaysia of hydrolysis Acid anhydrides, utilizes microwave frequency 2450MHz, the microwave treater microwave treatment 5min of power 700W after being sufficiently mixed, stand 30min Continue microwave treatment 5min afterwards, add 0.5 part of HEMC and 0.5 part of isomeric alcohol polyethenoxy ether, mixing is equal - 5~5 DEG C of insulation mixing 15min are cooled to the cooling rate of 10 DEG C/min after even, 60 parts of 60~70 DEG C of hot water are subsequently adding, And reflux state insulation mixing 15min is warming up to the programming rate of 5 DEG C/min, gained mixture is again with the cooling of 5 DEG C/min Speed is down to room temperature, finally sends into spray dryer, dries gained particulate abrasive into powder, obtains final product modified polyethylene glycol oxide.
The pretreatment of rice bran wax：15 parts of rice bran waxs are warming up to 45-50 DEG C of insulation mixing with the programming rate of 5 DEG C/min 5min, then molten condition insulation mixing 5min is warming up to the programming rate of 10 DEG C/min, and add 0.5 part of N- methylol propylene Acid amides, 0.5 part of pentaerythrite and 0.2 part of allyl glycidyl ether, continue be incubated mixing 15min, gained mixture with 5 DEG C/ The cooling rate of min is down to room temperature, obtains final product rice bran wax after pretreatment.
Embodiment 3
Embodiment 1 and the made cleaning agent of embodiment 2 are used to wipe camera lens, and cleaning effect is measured.
Measurement result shows that embodiment 1 and the made cleaning agent of embodiment 2 are respectively 99.5% to the clearance rate of camera lens dirt It is 0.03% and 0.05% with the VOC content during 99.6%, and cleaning.
General principle of the invention and principal character and advantages of the present invention has been shown and described above.The technology of the industry Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (7)

1. a kind of environment-friendly highly efficient lens cleaning agent, it is characterised in that be made up of the raw material of following parts by weight：Modified polyoxygenated Ethene 10-15 parts, polyvinyl alcohol resin 2-3 parts, carbomer 2-3 parts, rilanit special 1-2 parts, pre-gelatinized starch 1-2 parts, Rice bran wax 0.5-1 parts, saleratus power 0.5-1 parts, pentanediol 0.5-1 parts, nano zine oxide 0.3-0.5 parts, maleic anhydride grafting Compatilizer 0.2-0.3 parts, poly-aspartate 0.1-0.2 parts, water 100-150 parts；
The modified polyethylene glycol oxide is formed by the modified treatment of polyethylene glycol oxide, and its processing method is：To in polyethylene glycol oxide Polyquaternium and HPMA are added, microwave treater microwave treatment 5min is utilized after being sufficiently mixed, after standing 30min Continue microwave treatment 5min, add HEMC and isomeric alcohol polyethenoxy ether, be well mixed after with 10 DEG C/ The cooling rate of min is cooled to -5~5 DEG C of insulation mixing 15min, is subsequently adding 60~70 DEG C of hot water, and with the liter of 5 DEG C/min Warm speed is warming up to reflux state insulation mixing 15min, and gained mixture is down to room temperature with the cooling rate of 5 DEG C/min again, most Afterwards in feeding spray dryer, gained particulate abrasive is dried into powder, obtain final product modified polyethylene glycol oxide.
2. environment-friendly highly efficient lens cleaning agent according to claim 1, it is characterised in that：The polyethylene glycol oxide, poly- season The quality amount ratio of ammonium salt, HPMA, HEMC, isomeric alcohol polyethenoxy ether and hot water is 15- 20:1-2:0.5-1:0.5-1:0.2-0.5:50-60。
3. environment-friendly highly efficient lens cleaning agent according to claim 1, it is characterised in that：The work of the microwave treater Condition is microwave frequency 2450MHz, power 700W.
4. environment-friendly highly efficient lens cleaning agent according to claim 1, it is characterised in that：The carbomer is selected from card ripple One kind in resin 940, carbomer 934, carbomer 941.
5. environment-friendly highly efficient lens cleaning agent according to claim 1, it is characterised in that：The rice bran wax uses preceding process Pre-process, its processing method is：Rice bran wax is warming up to 45-50 DEG C and is incubated with the programming rate of 5 DEG C/min and mixes 5min, then with The programming rate of 10 DEG C/min is warming up to molten condition insulation mixing 5min, and adds N hydroxymethyl acrylamide, pentaerythrite And allyl glycidyl ether, continuing to be incubated mixing 15min, gained mixture is down to room temperature with the cooling rate of 5 DEG C/min, i.e., Obtain rice bran wax after pretreatment.
6. environment-friendly highly efficient lens cleaning agent according to claim 5, it is characterised in that：The rice bran wax, N- methylols The quality amount ratio of acrylamide, pentaerythrite and allyl glycidyl ether is 10-15:0.5-1:0.3-0.5:0.1-0.2.
7. a kind of preparation method of environment-friendly highly efficient lens cleaning agent, it is characterised in that comprise the following steps：
(1) to addition polyvinyl alcohol resin and rice bran wax in water, and reflux state insulation is warming up to the programming rate of 5 DEG C/min Mixing 10-15min, adds modified polyethylene glycol oxide and maleic anhydride grafting compatilizer, continues the insulation mixing 15- that flows back 30min, is then cooled to 0-5 DEG C of insulation mixing 15-30min with the cooling rate of 5 DEG C/min, obtains final product material I；
(2) to addition pentanediol and nano zine oxide in rilanit special, and 75-80 is warming up to the programming rate of 5 DEG C/min DEG C insulation mixing 5-10min, adds carbomer and saleratus power, continues to be incubated mixing 3-5min, then with 5 DEG C/min's Cooling rate is cooled to room temperature, obtains final product material II；
(3) to addition material II, pre-gelatinized starch and poly-aspartate in material I, and heated up with the programming rate of 10 DEG C/min To reflux state insulation mixing 5-10min, room temperature is then cooled to the cooling rate of 5 DEG C/min, gained mixture is transferred to ball In grinding machine, 400 mesh sieves are crossed after ball milling, obtain final product target cleaning agent.
CN201611095000.XA 2016-12-02 2016-12-02 Environment-friendly type efficient lens cleanser and preparation method thereof Pending CN106701352A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611095000.XA CN106701352A (en) 2016-12-02 2016-12-02 Environment-friendly type efficient lens cleanser and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611095000.XA CN106701352A (en) 2016-12-02 2016-12-02 Environment-friendly type efficient lens cleanser and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106701352A true CN106701352A (en) 2017-05-24

Family

ID=58935470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611095000.XA Pending CN106701352A (en) 2016-12-02 2016-12-02 Environment-friendly type efficient lens cleanser and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106701352A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1125463A (en) * 1993-06-18 1996-06-26 聚合物技术公司 Composition for cleaning and wetting contact lenses
CN1279710A (en) * 1997-11-26 2001-01-10 阿勒根销售公司 Contact lens cleaning compsitions
CN1418942A (en) * 2001-11-14 2003-05-21 金元振 Detergent for high molecular synthetic resin spectacle lens and moulding die
CN102796625A (en) * 2012-07-13 2012-11-28 湖北海力化工科技有限公司 Water-based cleaning agent used before coating of optical glass
CN102965214A (en) * 2011-08-31 2013-03-13 东友Fine-Chem股份有限公司 Cleaning composition
CN103571650A (en) * 2012-08-01 2014-02-12 周宇 Detergent for lens
CN104403813A (en) * 2014-12-22 2015-03-11 广东富行洗涤剂科技有限公司 Cleaning agent
CN104593166A (en) * 2014-12-31 2015-05-06 苏州禾川化学技术服务有限公司 Efficient dust-removal optical glass cleaning agent

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1125463A (en) * 1993-06-18 1996-06-26 聚合物技术公司 Composition for cleaning and wetting contact lenses
CN1279710A (en) * 1997-11-26 2001-01-10 阿勒根销售公司 Contact lens cleaning compsitions
CN1418942A (en) * 2001-11-14 2003-05-21 金元振 Detergent for high molecular synthetic resin spectacle lens and moulding die
CN102965214A (en) * 2011-08-31 2013-03-13 东友Fine-Chem股份有限公司 Cleaning composition
CN102796625A (en) * 2012-07-13 2012-11-28 湖北海力化工科技有限公司 Water-based cleaning agent used before coating of optical glass
CN103571650A (en) * 2012-08-01 2014-02-12 周宇 Detergent for lens
CN104403813A (en) * 2014-12-22 2015-03-11 广东富行洗涤剂科技有限公司 Cleaning agent
CN104593166A (en) * 2014-12-31 2015-05-06 苏州禾川化学技术服务有限公司 Efficient dust-removal optical glass cleaning agent

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
化学工业出版社: "《中国化工产品大全（下卷）》", 31 January 2005, 化学工业出版社 *
李广宇 等: "《胶黏剂原材料手册》", 31 August 2004, 国防工业出版社 *
陈宁: "《氨基酸工艺学》", 31 January 2007, 中国轻工业出版社 *
黄可龙: "《精细化学品技术手册》", 30 June 1994, 中南工业大学出版社 *

Similar Documents

Publication Publication Date Title
CN106832729A (en) A kind of aqueous antitack agent suitable for synthetic leather
CN106381096A (en) Water-based plastic product label adhesive
CN107177895A (en) A kind of moistureproof eider down of antibacterial is processed the preparation method with modified down fiber
CN108690336B (en) Biodegradable polylactic acid agricultural mulching film and processing technology thereof
CN107675489A (en) A kind of processing method of outdoor nylon fabric ultraviolet-proof
CN106758532B (en) Release paper coating material for manufacturing heat-storage thermal-insulation synthetic leather suitable for clothes
CN106758246A (en) A kind of starching is uniform and purified cotton yarns sizing agent of easy desizing
CN106675026A (en) Heat-insulating anti-freezing electric vehicle battery shell material and preparation method thereof
CN107082991A (en) A kind of environmentally friendly anti-soiling aging-resisting high-intensity wood plastic composite material and preparation method thereof
CN106398530A (en) Antibacterial and softening leather surface treatment agent
CN106701352A (en) Environment-friendly type efficient lens cleanser and preparation method thereof
CN105694668A (en) Lost foam casting sand box interior wall paint
CN106752208A (en) A kind of open type electric tricycle seat processing outside leather substance
TW201730388A (en) Method to manufacture composite fibers of rice husk and charcoal
CN106939102A (en) A kind of aqueous fire retardant suitable for synthetic leather
CN106752750A (en) A kind of cylinder body of hydraulic oil cylinder inwall proprietary powder coatingses
CN106637977A (en) Polyester fiber treating agent prepared from hydroxyethyl methylacrylate
CN106190521A (en) A kind of building template waterborne organic silicon releasing agent
CN102690557A (en) Multifunctional plastic coated material and preparation method thereof
CN106905753A (en) A kind of aqueous anti-pinhole agent suitable for synthetic leather
CN107118608B (en) Leveling agent for preparing ultrathin coating of alkyd resin powder coating
CN106758188A (en) A kind of environmentally friendly sticky dedusting cloth preparation maceration extract
CN106928846A (en) It is a kind of to peel off auxiliary agent suitable for the aqueous high of synthetic leather
CN107034698A (en) A kind of aqueous wet method color fixing agent suitable for synthetic leather
CN106519977A (en) Composite finishing agent used for leather care, and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170524