CN106700533A - Textile material and preparation method thereof - Google Patents
Textile material and preparation method thereof Download PDFInfo
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- CN106700533A CN106700533A CN201611031091.0A CN201611031091A CN106700533A CN 106700533 A CN106700533 A CN 106700533A CN 201611031091 A CN201611031091 A CN 201611031091A CN 106700533 A CN106700533 A CN 106700533A
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- Prior art keywords
- parts
- fiber
- nylon
- nylon66 fiber
- antioxidant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
Abstract
The invention provides nylon 66 capable of being used for spinning a glass-fiber-free shuttle. The nylon 66 is mainly prepared from the following raw materials in parts by weight: 50-60 parts of nylon 66 slices, 20-28 parts of nylon 6 slices, 2-6 parts of ultra-high molecular weight polyethylene, 1-5 parts of high density polyethylene, 10-20 parts of a compatilizer, 0.1-0.5 part of an antioxidant and 2-8 parts of a lubricant. The nylon 66 provided by the invention takes nylon 66 resin as a base material; the problem that the mechanical properties of the nylon 66 are not good is solved very well by utilizing synergistic effects of the ultra-high molecular weight polyethylene and the high density polyethylene; and the obtained nylon 66 has the advantages of high flowability, impact resistance, high strength, wearing resistance, stable size, smooth appearance, no exposure of glass fibers and static resistance.
Description
Technical field
The present invention relates to a kind of textile material and preparation method thereof, and in particular to can be used for the nylon of weaving glass-fiber-free shuttle
66 and preparation method thereof.
Background technology
Polyamide is commonly called as nylon (Nylon), and English name Polyamide (abbreviation PA) is to contain repetition on molecular backbone
Amide group-[NHCO]-thermoplastic resin general name.Including aliphatic PA, aliphatic-aromatic race PA and aromatic series PA.Wherein, fat
PA is wide in variety for fat race, and yield is big, is widely used, depending on its name is by the specific carbon number of synthon.
Nylon is most important engineering plastics, and yield ranks first in five big general engineering plastics, can be made into length fine or short
It is fine.
Nylon is a computer MSR Information system development under the outstanding scientist's Tomas Carothers (Carothers) in the U.S. and its leader
Out, it is the first synthetic fibers for occurring in the world.The appearance of nylon makes assuming an entirely new aspect for textile, its synthesis
It is the important breakthrough of synthetic fiber industry, while being also an important milestone of polymer chemistry.
Principal item in nylon is nylon 6 and nylon66 fiber, accounts for absolute leading position, and nylon66 fiber is that a kind of macromolecule is included
6 uniform thermoplastic polyesters of symmetrical methylene, with high-strength, wear-resisting, solvent resistant, self lubricity is good and uses temperature
The advantages of degree scope is wide, is one of most wide engineering plastics of purposes, due to be used for weaving cotton cloth, so wanting high temperature resistant, impact resistance, resistance to
Mill, it is antistatic, it is therefore desirable to material used have combination property very high.All it is to use glass fibre currently used for Textile shuttle
Strengthen, be modified, there is glass emergence on the surface on poor mobile performance, injection-molded item surface, not antistatic, have a strong impact on spinning cloth quality.
CN 101760021A are related to polyamide composition field, more particularly to a kind of weaving glass-fiber-free shuttle that can be used for
Nylon 66 composition, it is made up of the raw material of following quality proportioning：Nylon 66 slice 40~67%, nylon 6 slice 15~30%,
Ultra-high molecular weight polyethylene 1~5%, compatilizer 15~30%, antioxidant 0.1~0.5%, lubricant 1~10%, its preparation side
Method is comprised the following steps：1st, raw material described above is weighed；2nd, all raw materials are put into high-speed mixer and mixing；3 then by mix
Raw material is put into double screw extruder, extruding pelletization.It is base-material that the invention uses nylon 66 resin, uses superhigh molecular weight polyethylene
The raw materials such as alkene, do not use glass fibre, advantage be with high fluidity, shock resistance, high intensity, wear-resisting, dimensionally stable,
Smooth appearance, without glass emergence on the surface, antistatic.But, the mechanical property and cannot meeting of the nylon66 fiber that the invention is provided increasingly increases
Plus the performance to shuttle requirement.
The content of the invention
For the problem of prior art, it is an object of the invention to provide a kind of good fluidity, have high impact property,
High intensity, product surface it is bright and clean can be used for the textile material nylon66 fiber of weaving glass-fiber-free shuttle, solve existing weaving material
The problem of the poor mechanical property of material.
To achieve these goals, present invention employs following technical scheme：
A kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
The parts by weight of the nylon66 fiber be 50-60, such as 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58
Part or 59 parts.
The content of the nylon 6 slice is, for example, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts or 27 parts.
The content of the ultra-high molecular weight polyethylene is, for example, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts or 5.5 parts.
The content of the high density polyethylene (HDPE) is, for example, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts or 4.5 parts.
The content of the compatilizer is, for example, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts or 19 parts.
The content of the antioxidant is, for example, 0.15 part, 0.2 part, 0.25 part, 0.3 part, 0.35 part, 0.4 part, 0.45 part.
The content of the lubricant is, for example, 3 parts, 4 parts, 5 parts, 6 parts or 7 parts.
The present invention is significantly carried using the ultra-high molecular weight polyethylene of certain content and the conspiracy relation of high density polyethylene (HDPE)
The mechanical property of the high nylon66 fiber for obtaining.
Preferably, a kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is by weight mainly by the following raw material system
It is standby to obtain：
Preferably, the relative viscosity of described nylon 66 slice is 2.5~2.7.
Preferably, compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
Preferably, described antioxidant is that Hinered phenols antioxidant is compounded with phosphorous lipid antioxidant.
Preferably, described Hinered phenols antioxidant is 1010 or 1098；Described phosphorous lipid antioxidant is 168.
Preferably, lubricant is metallic stearic soaps or fatty acid acyl amine.
Preferably, described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate, described fat
Sour amide-type is TAF or EBS.
The second object of the present invention is that offer is a kind of can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described above
Preparation method the described method comprises the following steps：
The raw material of formula ratio is mixed, extrusion, granulation obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
Preferably, described being blended in high mixer is carried out, and incorporation time is 1-5 minutes.
Preferably, described to be extruded through double screw extruder realization, processing temperature is 200-300 DEG C, and screw speed is
200-360 revs/min.
Compared with the prior art, the present invention has the advantages that：
It is base-material that the present invention uses nylon 66 resin, is imitated using the collaboration of ultra-high molecular weight polyethylene and high density polyethylene (HDPE)
Should, solve the problems, such as that nylon66 fiber mechanical property is not good well, so as to get nylon66 fiber there is high fluidity, impact resistance
Energy, high intensity, wear-resisting, dimensionally stable, smooth appearance, without glass emergence on the surface, anlistatig advantage.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
The relative viscosity of described nylon 66 slice is 2.5.
Compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
Described antioxidant is that Hinered phenols antioxidant is compounded with phosphorous lipid antioxidant.
Described Hinered phenols antioxidant is 1010；Described phosphorous lipid antioxidant is 168.
Lubricant is metallic stearic soaps.
Described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate.
The preparation method that can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described above the described method comprises the following steps：
By the raw material of formula ratio at high-speed mixer and mixing 1-5 minutes, double screw extruder is subsequently adding, processing temperature is
200-300 DEG C, screw speed is 200-360 revs/min, and extruding pelletization obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
Embodiment 2
A kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
The relative viscosity of described nylon 66 slice is 2.5~2.7.
Compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
Described antioxidant is that Hinered phenols antioxidant is compounded with phosphorous lipid antioxidant.
Described Hinered phenols antioxidant is 1010 or 1098；Described phosphorous lipid antioxidant is 168.
Lubricant is metallic stearic soaps or fatty acid acyl amine.
Described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate, described fatty acid acyl amine
It is TAF or EBS.
The preparation method that can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described above the described method comprises the following steps：
By the raw material of formula ratio at high-speed mixer and mixing 1-5 minutes, double screw extruder is subsequently adding, processing temperature is
200-300 DEG C, screw speed is 200-360 revs/min, and extruding pelletization obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
Embodiment 3
A kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
The relative viscosity of described nylon 66 slice is 2.5~2.7.
Compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
Described antioxidant is that Hinered phenols antioxidant is compounded with phosphorous lipid antioxidant.
Described Hinered phenols antioxidant is 1010 or 1098；Described phosphorous lipid antioxidant is 168.
Lubricant is metallic stearic soaps or fatty acid acyl amine.
Described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate, described fatty acid acyl amine
It is TAF or EBS.
The preparation method that can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described above the described method comprises the following steps：
By the raw material of formula ratio at high-speed mixer and mixing 1-5 minutes, double screw extruder is subsequently adding, processing temperature is
200-300 DEG C, screw speed is 200-360 revs/min, and extruding pelletization obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
Embodiment 4
A kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
The relative viscosity of described nylon 66 slice is 2.5~2.7.
Compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
Described antioxidant is that Hinered phenols antioxidant is compounded with phosphorous lipid antioxidant.
Described Hinered phenols antioxidant is 1010 or 1098；Described phosphorous lipid antioxidant is 168.
Lubricant is metallic stearic soaps or fatty acid acyl amine.
Described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate, described fatty acid acyl amine
It is TAF or EBS.
The preparation method that can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described above the described method comprises the following steps：
By the raw material of formula ratio at high-speed mixer and mixing 1-5 minutes, double screw extruder is subsequently adding, processing temperature is
200-300 DEG C, screw speed is 200-360 revs/min, and extruding pelletization obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
Comparative example 1
Remaining is same as Example 3, except not containing ultra-high molecular weight polyethylene.
Comparative example 2
Remaining is same as Example 3, except not containing high density polyethylene (HDPE).
Comparative example 3
Comparative example 3 is CN 101760021A disclosed embodiments 2.
Performance test is as shown in the table：
Applicant states that the present invention illustrates method detailed of the invention by above-described embodiment, but the present invention not office
It is limited to above-mentioned method detailed, that is, does not mean that the present invention has to rely on above-mentioned method detailed and could implement.Art
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention
Addition, selection of concrete mode etc., within the scope of all falling within protection scope of the present invention and disclosing.
Claims (10)
1. a kind of to can be used for the nylon66 fiber of weaving glass-fiber-free shuttle, it is mainly prepared by the following raw material by weight：
2. nylon66 fiber as claimed in claim 1, it is mainly prepared by the following raw material by weight：
3. nylon66 fiber as claimed in claim 1 or 2, it is characterised in that the relative viscosity of described nylon 66 slice is 2.5~
2.7。
4. the nylon66 fiber as described in one of claim 1-3, it is characterised in that compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene.
5. the nylon66 fiber as described in one of claim 1-4, it is characterised in that described antioxidant be Hinered phenols antioxidant with
Phosphorous lipid antioxidant is compounded.
6. the nylon66 fiber as described in one of claim 1-5, it is characterised in that described Hinered phenols antioxidant be 1010 or
1098；Described phosphorous lipid antioxidant is 168.
7. the nylon66 fiber as described in one of claim 1-6, it is characterised in that lubricant is metallic stearic soaps or aliphatic acid
Amide-type；
Preferably, described metallic stearic soaps are barium stearate or calcium stearate or zinc stearate, described fatty acid acyl
Amine is TAF or EBS.
8. square as described in a kind of preparation method that can be used for the nylon66 fiber of weaving glass-fiber-free shuttle as described in one of claim 1-7
Method is comprised the following steps：
The raw material of formula ratio is mixed, extrusion, granulation obtains can be used for the nylon66 fiber of weaving glass-fiber-free shuttle.
9. method as claimed in claim 8, it is characterised in that described being blended in high mixer is carried out, and incorporation time is 1-5 points
Clock.
10. method as claimed in claim 8 or 9, it is characterised in that described to be extruded through double screw extruder realization, processing
Temperature is 200-300 DEG C, and screw speed is 200-360 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611031091.0A CN106700533A (en) | 2016-11-17 | 2016-11-17 | Textile material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611031091.0A CN106700533A (en) | 2016-11-17 | 2016-11-17 | Textile material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106700533A true CN106700533A (en) | 2017-05-24 |
Family
ID=58941229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611031091.0A Pending CN106700533A (en) | 2016-11-17 | 2016-11-17 | Textile material and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106700533A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416704B1 (en) * | 1999-08-26 | 2002-07-09 | Alliedsignal Inc. | Nylon molding compositions having improved surface appearance |
| CN101760021A (en) * | 2009-11-27 | 2010-06-30 | 平顶山华邦工程塑料有限公司 | Nylon 66 compound capable of use for weaving glass-fiber-free shuttle |
| CN105062061A (en) * | 2015-09-11 | 2015-11-18 | 无锡市长安曙光手套厂 | Textile material and preparation method thereof |
| CN105086439A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Textile material and preparation method thereof |
-
2016
- 2016-11-17 CN CN201611031091.0A patent/CN106700533A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416704B1 (en) * | 1999-08-26 | 2002-07-09 | Alliedsignal Inc. | Nylon molding compositions having improved surface appearance |
| CN101760021A (en) * | 2009-11-27 | 2010-06-30 | 平顶山华邦工程塑料有限公司 | Nylon 66 compound capable of use for weaving glass-fiber-free shuttle |
| CN105086439A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Textile material and preparation method thereof |
| CN105062061A (en) * | 2015-09-11 | 2015-11-18 | 无锡市长安曙光手套厂 | Textile material and preparation method thereof |
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Application publication date: 20170524 |