CN106700378A - Optical rupture membrane - Google Patents
Optical rupture membrane Download PDFInfo
- Publication number
- CN106700378A CN106700378A CN201611141233.9A CN201611141233A CN106700378A CN 106700378 A CN106700378 A CN 106700378A CN 201611141233 A CN201611141233 A CN 201611141233A CN 106700378 A CN106700378 A CN 106700378A
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- Prior art keywords
- parts
- ultra
- violet
- rupture pressure
- antioxidant
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/08—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses an optical rupture membrane. The optical rupture membrane is prepared from raw materials in parts by weight as follows: 10-80 parts of polycarbonate, 1-25 parts of a UV (ultraviolet) luminescent material, 3-20 parts of a UV stabilizer, 0.1-18 parts of a UV absorber, 0.01-2 parts of an antioxidant, 5-85 parts of acrylic ester, 0.1-5 parts of a binder, 20-250 parts of a diluent and 0.1-5 parts of lithium hydroxide. The optical rupture membrane is good in optical transparency and high in impact strength, has excellent rupture preventing performance and functions of UV excited luminescence and blue light reflection, can absorb invisible UV light and convert invisible UV light into larger-wavelength blue light or purple visible light and can be widely used for preparing various blue light isolating LCD screen protection membranes, UV isolating solar heat-insulating membranes and other products. The optical rupture membrane adopts direct membrane-drawing molding, reduces gluing procedures and saves a large quantity of production cost, thereby having broad market application prospect.
Description
Technical field
The present invention relates to thin film technique field, specifically a kind of optics rupture pressure disc.
Background technology
With continuing to develop for electronics techniques, smart mobile phone technology is even more prominent, with the intelligence for constantly updating the replacement
Energy product, protection pad pasting also arises at the historic moment, and demand is huge.At present, conventional pad pasting cannot effective buffering collision of closed, it is anti-
Only screen explosion, has an effect on attractive in appearance, it is impossible to prevents product from clashing into accidentally and causes the broken of glass panel to disperse, it is impossible to reduces glass
The covert harm of panel, ensures user security;So it is in need to design a kind of rupture pressure disc, and also strengthened glass can be maintained
Distinctive gloss, texture and raising case hardness.Additionally, many film products every ultraviolet are needed by rear road gluing work
Sequence, can be only achieved the function of absorbing and convert ultraviolet light and shortwave blue light after multiple deep processing, and in per pass coating process by
The reason such as the cleanliness factor of imperfection, production environment in coating process is below standard, can cause different degrees of waste of material.
The content of the invention
It is an object of the invention to provide a kind of good, excellent in cushion effect, the excellent explosion-proof of optical transparence and purple
Outer excited light-emitting simultaneously reflects the optics rupture pressure disc of blue light, to solve the problems, such as to be proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of optics rupture pressure disc, includes according to the raw material of weight portion:Makrolon 10-80 parts, ultra-violet light-emitting material 1-25
Part, ultra-violet stabilizer 3-20 part, ultra-violet absorber 0.1-18 parts, antioxidant 0.01-2 parts, acrylate 5-85 parts, glue
0.1-5 parts, diluent 20-250 parts, lithium hydroxide 0.1-5 parts of agent of knot.
As further scheme of the invention:The optics rupture pressure disc, includes according to the raw material of weight portion:Makrolon
15-75 parts, 1-20 parts of ultra-violet light-emitting material, ultra-violet stabilizer 4-15 parts, ultra-violet absorber 0.2-15 parts, antioxidant
0.05-1.5 parts, acrylate 10-80 parts, binding agent 0.3-4 parts, diluent 30-220 parts, lithium hydroxide 0.2-4 parts.
As further scheme of the invention:The optics rupture pressure disc, includes according to the raw material of weight portion:Makrolon
20-30 parts, 1-15 parts of ultra-violet light-emitting material, ultra-violet stabilizer 5-10 parts, ultra-violet absorber 0.5-12 parts, antioxidant
0.1-0.5 parts, acrylate 15-75 parts, binding agent 0.5-2 parts, diluent 40-200 parts, lithium hydroxide 0.5-2 parts.
As further scheme of the invention:The preparation process of the optics rupture pressure disc is:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, are entered in centrifugal thin-film reactor at 250-350 DEG C
Row centrifugation;Then polymerisation is carried out using double-shaft horizontal reactor;
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Compared with prior art, the beneficial effects of the invention are as follows:
Optics rupture pressure disc optical transparence of the invention is good, excellent in cushion effect, with excellent explosion-proof and ultraviolet
Excited light-emitting simultaneously reflects the function of blue light, can absorb sightless ultraviolet light, is converted into longer wavelengths of blue light or purple
Visible ray, can be widely applied to make it is all kinds of every blue light liquid crystal screen protection film, every products such as ultraviolet solar energy thermal isolation films.This
Invention reduces each road coating process using the shaping of direct membrane, saves substantial amounts of production cost, therefore have wide city
Field application prospect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 10 parts of makrolon, ultraviolet
1 part of luminescent material, 3 parts of ultra-violet stabilizer, 0.1 part of ultra-violet absorber, 0.01 part of antioxidant, 5 parts of acrylate, bonding
0.1 part of agent, 20 parts of diluent, 0.1 part of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 250 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Embodiment 2
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 80 parts of makrolon, ultraviolet
25 parts of luminescent material, 20 parts of ultra-violet stabilizer, 18 parts of ultra-violet absorber, 2 parts of antioxidant, 85 parts of acrylate, bonding
5 parts of agent, 250 parts of diluent, 5 parts of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 350 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Embodiment 3
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 15 parts of makrolon, ultraviolet
It is 1 part of luminescent material, 4 parts of ultra-violet stabilizer, 0.2 part of ultra-violet absorber, 0.05 part of antioxidant, 10 parts of acrylate, viscous
0.3 part of agent of knot, 30 parts of diluent, 0.2 part of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 270 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Embodiment 4
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 75 parts of makrolon, ultraviolet
It is 20 parts of luminescent material, 15 parts of ultra-violet stabilizer, 15 parts of ultra-violet absorber, 1.5 parts of antioxidant, 80 parts of acrylate, viscous
4 parts of agent of knot, 220 parts of diluent, 4 parts of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 320 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Embodiment 5
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 20 parts of makrolon, ultraviolet
1 part of luminescent material, 5 parts of ultra-violet stabilizer, 0.5 part of ultra-violet absorber, 0.1 part of antioxidant, 15 parts of acrylate, bonding
0.5 part of agent, 40 parts of diluent, 0.5 part of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 300 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
Embodiment 6
In the embodiment of the present invention, a kind of optics rupture pressure disc includes according to the raw material of weight portion:It is 30 parts of makrolon, ultraviolet
It is 15 parts of luminescent material, 10 parts of ultra-violet stabilizer, 12 parts of ultra-violet absorber, 0.5 part of antioxidant, 75 parts of acrylate, viscous
2 parts of agent of knot, 200 parts of diluent, 2 parts of lithium hydroxide.
The preparation process of the optics rupture pressure disc, comprises the following steps:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, third
Olefin(e) acid ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 310 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor.
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, so
After cool down, can just obtain optics rupture pressure disc.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (4)
1. a kind of optics rupture pressure disc, it is characterised in that the raw material according to weight portion includes:Makrolon 10-80 parts, ultra-violet light-emitting
Material 1-25 parts, ultra-violet stabilizer 3-20 parts, ultra-violet absorber 0.1-18 parts, antioxidant 0.01-2 parts, acrylate
5-85 parts, binding agent 0.1-5 parts, diluent 20-250 parts, lithium hydroxide 0.1-5 parts.
2. optics rupture pressure disc according to claim 1, it is characterised in that the raw material according to weight portion includes:Makrolon
15-75 parts, 1-20 parts of ultra-violet light-emitting material, ultra-violet stabilizer 4-15 parts, ultra-violet absorber 0.2-15 parts, antioxidant
0.05-1.5 parts, acrylate 10-80 parts, binding agent 0.3-4 parts, diluent 30-220 parts, lithium hydroxide 0.2-4 parts.
3. optics rupture pressure disc according to claim 2, it is characterised in that the raw material according to weight portion includes:Makrolon
20-30 parts, 1-15 parts of ultra-violet light-emitting material, ultra-violet stabilizer 5-10 parts, ultra-violet absorber 0.5-12 parts, antioxidant
0.1-0.5 parts, acrylate 15-75 parts, binding agent 0.5-2 parts, diluent 40-200 parts, lithium hydroxide 0.5-2 parts.
4. according to any described optics rupture pressure discs of claim 1-3, it is characterised in that its preparation process is:
Step 1), by makrolon, ultra-violet light-emitting material, ultra-violet stabilizer, ultra-violet absorber, antioxidant, acrylic acid
Ester, binding agent, diluent, lithium hydroxide are weighed according to weight portion, carried out in centrifugal thin-film reactor at 250-350 DEG C from
The heart;Then polymerisation is carried out using double-shaft horizontal reactor;
Step 2), by step 1) in the material that obtains add double screw extruder, in double screw extruder melting extrusion, Ran Houleng
But, optics rupture pressure disc can just be obtained.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611141233.9A CN106700378A (en) | 2016-12-12 | 2016-12-12 | Optical rupture membrane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611141233.9A CN106700378A (en) | 2016-12-12 | 2016-12-12 | Optical rupture membrane |
Publications (1)
Publication Number | Publication Date |
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CN106700378A true CN106700378A (en) | 2017-05-24 |
Family
ID=58936655
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201611141233.9A Pending CN106700378A (en) | 2016-12-12 | 2016-12-12 | Optical rupture membrane |
Country Status (1)
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CN (1) | CN106700378A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641258A (en) * | 2018-05-10 | 2018-10-12 | 重庆新康意安得达尔新材料有限公司 | A kind of optically functional film and its manufacturing method |
-
2016
- 2016-12-12 CN CN201611141233.9A patent/CN106700378A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641258A (en) * | 2018-05-10 | 2018-10-12 | 重庆新康意安得达尔新材料有限公司 | A kind of optically functional film and its manufacturing method |
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PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170524 |