CN106700360A - Environmentally-friendly plastic film - Google Patents

Environmentally-friendly plastic film Download PDF

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Publication number
CN106700360A
CN106700360A CN201611143332.0A CN201611143332A CN106700360A CN 106700360 A CN106700360 A CN 106700360A CN 201611143332 A CN201611143332 A CN 201611143332A CN 106700360 A CN106700360 A CN 106700360A
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CN
China
Prior art keywords
parts
plastic film
environmentally
polyvinyl alcohol
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611143332.0A
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Chinese (zh)
Inventor
王举
孙益民
芮定文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Original Assignee
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
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Publication date
Application filed by ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd filed Critical ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority to CN201611143332.0A priority Critical patent/CN106700360A/en
Publication of CN106700360A publication Critical patent/CN106700360A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2429/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2489/00Characterised by the use of proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention provides an environmentally-friendly plastic film. The plastic film consists of the following components in parts by weight: 50 to 60 parts of polyvinyl alcohol, 20 to 30 parts of polyvinyl alcohol resin, 30 to 40 parts of polyurethane, 20 to 30 parts of an ethylene-vinyl acetate copolymer, 10 to 20 parts of a styrene-ethylene/butylenes-styrene copolymer, 10 to 20 parts of sodium alginate, 10 to 20 parts of hydroxypropyl methyl cellulose, 30 to 40 parts of zein and 3 to 10 parts of a plasticizer. The plastic film is prepared by utilizing degradable materials such as the zein, aloe gel and the polyvinyl alcohol resin and adding the plasticizer and a stabilizer, so that the tensile-resistant strength, the flowability, the tensile strength, the rigidity, the hardness, the degradability and the environment-protecting performance of the plastic film are greatly improved.

Description

A kind of environmentally-friendly plastic film
Technical field
The present invention relates to plastics arts, and in particular to a kind of environmentally-friendly plastic film.
Background technology
With the extensive use of China's plastic products, the demand of plastic foil also gradually increases.At present, many enterprises utilize Waste polyethylene plastics produce plastic foil, are then made the packaging bag of all size.Produced using waste polyethylene plastics Plastic foil tensile strength that plastic foil is produced is small, anti-impact force is weak, mobility is poor, so as to influence to use.Also, this modeling Material film is not degradable, and serious " white pollution " is had resulted in environment.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of environmentally-friendly plastic film, using zein, aloe gel, The degradation materials such as polyvinyl alcohol resin addition plasticizer, stabilizer are made plastic foil, make tensile strength, the flowing of plastic foil Property, tensile strength, rigidity and hardness, degradable and environmental-protecting performance improve a lot.
To realize object above, the present invention is achieved by the following technical programs:
A kind of environmentally-friendly plastic film, described plastic sheeting is made up of following parts by weight:Including polyvinyl alcohol 50-60 parts, it is poly- Vinyl alcohol resin 20-30 parts, polyurethane 30-40 parts, ethylene-vinyl acetate copolymer 20-30 parts, styrene-ethylene/butylene- Styrol copolymer 10-20 parts, sodium alginate 10-20 parts, hydroxypropyl methyl cellulose 10-20 parts, zein 30-40 parts, increasing 3-10 parts of agent of modeling.
Described 55 parts of polyvinyl alcohol, 25 parts of polyvinyl alcohol resin, 35 parts of polyurethane, ethylene-vinyl acetate copolymer 25 Part, 5 parts of styrene-ethylene/butylene-styrene copolymer 1,15 parts of sodium alginate, 15 parts of hydroxypropyl methyl cellulose, zein 35 parts, 5 parts of plasticizer.
Described plastic sheeting is additionally provided with aloe gel 1:1 5-20 parts and stabilizer 5-8 parts.
6 parts of 8 parts of described aloe gel 1:1 and stabilizer.
Beneficial effect of the present invention:The present invention is using the addition of the degradation materials such as zein, aloe gel, polyvinyl alcohol resin Plasticizer, stabilizer are made plastic foil, make the tensile strength of plastic foil, mobility, tensile strength, rigidity and hardness, can drop Solution and environmental-protecting performance improve a lot;The packaging bag of all size being made, stretching is not easy to break, and flexibility is good.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, to this Technical scheme in inventive embodiments is clearly and completely described, it is clear that described embodiment is that a part of the invention is real Example is applied, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation Property work under the premise of the every other embodiment that is obtained, belong to the scope of protection of the invention.
A kind of environmentally-friendly plastic film, described plastic sheeting is made up of following parts by weight:Including described polyvinyl alcohol 55 parts, 25 parts of polyvinyl alcohol resin, 35 parts of polyurethane, 25 parts of ethylene-vinyl acetate copolymer, styrene-ethylene/butylene-benzene 15 parts of ethylene copolymer, 15 parts of sodium alginate, 15 parts of hydroxypropyl methyl cellulose, 35 parts of zein, 8 parts of aloe gel 1:1, plasticising 5 parts of agent, 6 parts of stabilizer, described plastic sheeting outer surface are provided with the bionic pattern in rolling, described decorative pattern is scalelike mark, Fin line, dried small shrimp line or insect wing line;The present invention is added using degradation materials such as zein, aloe gel, polyvinyl alcohol resins Plus plasticizer, stabilizer are made plastic foil, make the tensile strength of plastic foil, mobility, tensile strength, rigidity and hardness, can Degraded and environmental-protecting performance improve a lot.The packaging bag of all size being made, stretching is not easy to break, and flexibility is good;Generation For conventional plastic film, can natural degradation, environmental protection.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating In any this actual relation or order.And, term " including ", "comprising" or its any other variant be intended to Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention has been described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.

Claims (4)

1. a kind of environmentally-friendly plastic film, it is characterised in that:Described plastic sheeting is made up of following parts by weight:Including polyethylene Alcohol 50-60 parts, polyvinyl alcohol resin 20-30 parts, polyurethane 30-40 parts, ethylene-vinyl acetate copolymer 20-30 parts, benzene second Alkene-ethylene/butylene-styrol copolymer 10-20 parts, sodium alginate 10-20 parts, hydroxypropyl methyl cellulose 10-20 parts, corn Protein 30-40 parts, plasticizer 3-10 parts.
2. environmentally-friendly plastic film as claimed in claim 1, it is characterised in that described 55 parts of polyvinyl alcohol, polyvinyl alcohol tree 25 parts of fat, 35 parts of polyurethane, 25 parts of ethylene-vinyl acetate copolymer, 5 parts of styrene-ethylene/butylene-styrene copolymer 1, 15 parts of sodium alginate, 15 parts of hydroxypropyl methyl cellulose, 35 parts of zein, 5 parts of plasticizer.
3. environmentally-friendly plastic film as claimed in claim 1, it is characterised in that described plastic sheeting is additionally provided with aloe gel 15-20 parts and stabilizer 5-8 parts.
4. environmentally-friendly plastic film as claimed in claim 3, it is characterised in that 6 parts of 8 parts of described aloe gel 1:1 and stabilizer.
CN201611143332.0A 2016-12-13 2016-12-13 Environmentally-friendly plastic film Pending CN106700360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611143332.0A CN106700360A (en) 2016-12-13 2016-12-13 Environmentally-friendly plastic film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611143332.0A CN106700360A (en) 2016-12-13 2016-12-13 Environmentally-friendly plastic film

Publications (1)

Publication Number Publication Date
CN106700360A true CN106700360A (en) 2017-05-24

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CN201611143332.0A Pending CN106700360A (en) 2016-12-13 2016-12-13 Environmentally-friendly plastic film

Country Status (1)

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CN (1) CN106700360A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266775A (en) * 2017-06-12 2017-10-20 太仓雅奥塑业有限公司 A kind of environment-protection food package bag
CN107540926A (en) * 2017-10-13 2018-01-05 安徽嘉美包装有限公司 A kind of inexpensive toughened plastics bag material and preparation method thereof
CN108384265A (en) * 2018-02-07 2018-08-10 陕西科技大学 A kind of method that Cortex Bulbus Allii prepares degradation material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051010A (en) * 2010-12-03 2011-05-11 世源科技(嘉兴)医疗电子有限公司 Disposable polyvinyl alcohol thin-film material for cooling protection and production process thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051010A (en) * 2010-12-03 2011-05-11 世源科技(嘉兴)医疗电子有限公司 Disposable polyvinyl alcohol thin-film material for cooling protection and production process thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266775A (en) * 2017-06-12 2017-10-20 太仓雅奥塑业有限公司 A kind of environment-protection food package bag
CN107540926A (en) * 2017-10-13 2018-01-05 安徽嘉美包装有限公司 A kind of inexpensive toughened plastics bag material and preparation method thereof
CN108384265A (en) * 2018-02-07 2018-08-10 陕西科技大学 A kind of method that Cortex Bulbus Allii prepares degradation material

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