CN106699110A - Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof - Google Patents
Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof Download PDFInfo
- Publication number
- CN106699110A CN106699110A CN201611060244.4A CN201611060244A CN106699110A CN 106699110 A CN106699110 A CN 106699110A CN 201611060244 A CN201611060244 A CN 201611060244A CN 106699110 A CN106699110 A CN 106699110A
- Authority
- CN
- China
- Prior art keywords
- preparation
- boron nitride
- weight portions
- consumption
- ceramic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/6261—Milling
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3256—Molybdenum oxides, molybdates or oxide forming salts thereof, e.g. cadmium molybdate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
- C04B2235/386—Boron nitrides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/40—Metallic constituents or additives not added as binding phase
- C04B2235/402—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
Abstract
The invention discloses a boron nitride ceramic material for 3D (Three Dimensional) printing and a preparation method thereof. The preparation method comprises the following steps: 1) mixing kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano-aluminum, glass fibers and water, and calcining to obtain a calcined product; 2) mixing polyvinylidene fluoride, methyl cellulose, a silane coupling agent and the calcined product to obtain a base material; and 3) grinding the base material to obtain the boron nitride ceramic material for the 3D printing. The boron nitride ceramic material for the 3D printing, disclosed by the invention, has small liquid-phase surface tension so that a few of cracks are formed on the surface of a ceramic product; and meanwhile, the preparation method has the advantages of easiness of obtaining raw materials and simple process.
Description
Technical field
The present invention relates to 3D printing material, in particular it relates to 3D printing boron nitride ceramic material and preparation method thereof.
Background technology
3D printing material is the important substance basis of 3D printing technique development, and to a certain extent, the development of material is to determine
Can 3D printing be determined the deciding factor being more widely used.At present, 3D printing material mainly include engineering plastics,
Photosensitive resin, rubber type of material, metal material and ceramic material.
3D printing ceramic material is the mixture of ceramic powders and adhesive powder composition.Due to the fusing point of adhesive powder
It is relatively low, adhesive powder will be melted when laser sintered and then cause that ceramic powders are bonded together.After laser sintered, need
Ceramic is placed in carries out High Temperature Curing in temperature controlling stove.Existing ceramic material in laser direct sintering, liquid phase surface
Tension force is big, larger thermal stress can be produced in rapid solidification, so as to form more crackle.
The content of the invention
It is an object of the invention to provide a kind of 3D printing boron nitride ceramic material and preparation method thereof, the 3D printing boron nitride
The liquid phase surface tension of ceramic material is small and then causes that the crackle on the surface of ceramic is few；The preparation method raw material is easy simultaneously
, operation it is simple.
To achieve these goals, the invention provides a kind of preparation method of 3D printing boron nitride ceramic material, including：
1) kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum, glass fibre and water are entered
Row mixing, is then calcined that calcined product is obtained；
2) Kynoar, methylcellulose, silane coupler are mixed base-material is obtained with calcined product；
3) base-material is ground that 3D printing boron nitride ceramic material is obtained.
Present invention also offers a kind of 3D printing boron nitride ceramic material, the 3D printing boron nitride ceramic material is by above-mentioned
Preparation method be prepared.
In the above-mentioned technical solutions, the present invention causes obtained 3D by the synergy of above-mentioned each raw material and each step
The liquid phase surface tension of printing boron nitride ceramic material is small and then causes that the crackle on the surface of ceramic is few；While the preparation side
Method raw material is easy to get, operation is simple.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Specific embodiment of the invention is described in detail below.It should be appreciated that described herein specific
Implementation method is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The invention provides a kind of preparation method of 3D printing boron nitride ceramic material, including：
1) kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum, glass fibre and water are entered
Row mixing, is then calcined that calcined product is obtained；
2) Kynoar, methylcellulose, silane coupler are mixed base-material is obtained with calcined product；
3) base-material is ground that 3D printing boron nitride ceramic material is obtained.
In step 1 of the invention) in, the consumption of each material can be selected in scope wide, but in order to further drop
The liquid phase surface tension of low obtained 3D printing boron nitride ceramic material, and then cause that the crackle on the surface of ceramic is reduced,
Preferably, in step 1) in, relative to the kaolin of 100 weight portions, the consumption of attapulgite is 44-52 weight portions, boron nitride
Consumption be 42-53 weight portions, the consumption of boric acid is 14-18 weight portions, and salicylic consumption is 27-36 weight portions, three oxidations
The consumption of molybdenum is 5-9 weight portions, and the consumption of nano aluminum is 11-14 weight portions, and the consumption of glass fibre is 17-24 weight portions, water
Consumption be 140-180 weight portions.
In step 1 of the invention) in, the actual conditions of mixing can be selected in scope wide, but in order to further
The liquid phase surface tension of obtained 3D printing boron nitride ceramic material is reduced, and then causes that the crackle on the surface of ceramic subtracts
It is few, it is preferable that in step 1) in, mixing at least meets following condition：Mixing temperature is 15-35 DEG C, and incorporation time is 40-
60min。
In step 1 of the invention) in, the actual conditions of calcining can be selected in scope wide, but in order to further
The liquid phase surface tension of obtained 3D printing boron nitride ceramic material is reduced, and then causes that the crackle on the surface of ceramic subtracts
It is few, it is preferable that in step 1) in, calcining at least meets following condition：Calcining heat is 470-520 DEG C, and calcination time is 7-
10h。
Meanwhile, in the present invention, in order to further reduce the liquid phase surface of obtained 3D printing boron nitride ceramic material
Power, so cause ceramic surface crackle reduce, it is preferable that in step 1) calcining before, preparation method also includes
Heating process, specially：From the 15-35 DEG C of speed with 0.5-0.8 DEG C/min 150-200 DEG C is warming up to first by mixture and protect
Warm 20-40min, is then warming up to 300-380 DEG C and is incubated 30-40min, finally with 0.8-1 with the speed of 1.5-2.5 DEG C/min
DEG C/speed of min is warming up to 470-520 DEG C and is incubated.
In step 1 of the invention) in, the particle diameter of nano aluminum can be selected in scope wide, but in order to further drop
The liquid phase surface tension of low obtained 3D printing boron nitride ceramic material, and then cause that the crackle on the surface of ceramic is reduced,
Preferably, in step 1) in, the particle diameter of nano aluminum is 30-40nm.
In step 2 of the invention) in, the consumption of each material can be selected in scope wide, but in order to further drop
The liquid phase surface tension of low obtained 3D printing boron nitride ceramic material, and then cause that the crackle on the surface of ceramic is reduced,
Preferably, in step 2) in, relative to the calcined product of 100 weight portions, the consumption of Kynoar is 75-90 weight portions, first
The consumption of base cellulose is 25-33 weight portions, and the consumption of silane coupler is 9-16 weight portions.
In step 2 of the invention) in, the actual conditions of mixing can be selected in scope wide, but in order to further
The liquid phase surface tension of obtained 3D printing boron nitride ceramic material is reduced, and then causes that the crackle on the surface of ceramic subtracts
It is few, it is preferable that in step 2) in, mixing at least meets following condition：Mixing temperature is 15-35 DEG C, and incorporation time is 20-
40min。
In step 2 of the invention) in, the actual conditions of grinding can be selected in scope wide, but in order to further
The liquid phase surface tension of obtained 3D printing boron nitride ceramic material is reduced, and then causes that the crackle on the surface of ceramic subtracts
It is few, it is preferable that in step 3) in, grinding is carried out by the way of ball milling, and ball milling at least meets following condition：Big ball and bead
Mass ratio be 2：1.3-1.5, abrading-ball is 10 with the mass ratio of material：0.8-1.2, rotating speed is 600-1200rpm, Ball-milling Time
It is 25-35min.
Present invention also offers a kind of 3D printing boron nitride ceramic material, the 3D printing boron nitride ceramic material is by above-mentioned
Preparation method be prepared.
Below will the present invention will be described in detail by embodiment.
Embodiment 1
1) by kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum (particle diameter is 35nm), glass
Glass fiber and water are according to 100：49：48：16：33：7：12：19：160 weight ratio in 50min is mixed at 25 DEG C, then from 25 DEG C
180 DEG C are warming up to the speed of 0.7 DEG C/min and are incubated 30min, be then warming up to 360 DEG C with the speed of 2 DEG C/min and be incubated
35min, is finally warming up to 490 DEG C and is incubated 8h so that calcined product is obtained with the speed of 0.9 DEG C/min；
2) by calcined product, Kynoar, methylcellulose, silane coupler (KH550) according to 100：80：28：14
Weight ratio at 25 DEG C mix 30min be obtained base-material；
3) base-material is carried out into ball milling (mass ratio of big ball and bead is 2：1.4, abrading-ball is 10 with the mass ratio of material：
1.0, rotating speed is 900rpm, and Ball-milling Time is 30min) with prepared 3D printing boron nitride ceramic material A1.
Embodiment 2
1) by kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum (particle diameter is 30nm), glass
Glass fiber and water are according to 100：44：42：14：27：5：11：17：140 weight ratio in 40min is mixed at 15 DEG C, then from 15 DEG C
150 DEG C are warming up to the speed of 0.5 DEG C/min and are incubated 20min, be then warming up to 300 DEG C with the speed of 1.5 DEG C/min and protect
Warm 30min, is finally warming up to 470 DEG C and is incubated 7h so that calcined product is obtained with the speed of 0.8 DEG C/min；
2) by calcined product, Kynoar, methylcellulose, silane coupler (KH560) according to 100：75：25：9
Weight ratio is in mixing 20min at 15 DEG C with prepared base-material；
3) base-material is carried out into ball milling (mass ratio of big ball and bead is 2：1.3, abrading-ball is 10 with the mass ratio of material：
0.8, rotating speed is 600rpm, and Ball-milling Time is 25min) with prepared 3D printing boron nitride ceramic material A2.
Embodiment 3
1) by kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum (particle diameter is 40nm), glass
Glass fiber and water are according to 100：52：53：18：36：9：14：24：180 weight ratio in 60min is mixed at 35 DEG C, then from 35 DEG C
200 DEG C are warming up to the speed of 0.8 DEG C/min and are incubated 40min, be then warming up to 380 DEG C with the speed of 2.5 DEG C/min and protect
Warm 40min, is finally warming up to 520 DEG C and is incubated 10h so that calcined product is obtained with the speed of 1 DEG C/min；
2) by calcined product, Kynoar, methylcellulose, silane coupler (KH570) according to 100：90：33：16
Weight ratio at 35 DEG C mix 40min be obtained base-material；
3) base-material is carried out into ball milling (mass ratio of big ball and bead is 2：1.5, abrading-ball is 10 with the mass ratio of material：
1.2, rotating speed is 1200rpm, and Ball-milling Time is 35min) with prepared 3D printing boron nitride ceramic material A3.
Comparative example 1
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B1 is obtained, except that, step 1) in
Boric acid is not used.
Comparative example 2
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B2 is obtained, except that, step 1) in
Salicylic acid is not used.
Comparative example 3
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B3 is obtained, except that, step 1) in
Molybdenum trioxide is not used.
Comparative example 4
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B4 is obtained, except that, step 1) in
Nano aluminum is not used.
Comparative example 5
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B5 is obtained, except that, step 1) in
Glass fibre is not used.
Comparative example 6
Method according to embodiment 1 is carried out so that 3D printing boron nitride ceramic material B6 is obtained, except that, step 2) in
Silane coupler is not used.
Detection example 1
Above-mentioned 3D printing boron nitride ceramic material is carried out into 3D printing so that printing product is obtained, then detection prints product
The crackle on surface, counts every square of crackle number (bar/dm of cubic meter2) and average crack length (μm/bar), concrete outcome is shown in Table
1。
Table 1
| Crackle number (bar/dm2) | Average crack length (μm/bar) | |
| A1 | 2 | 0.2 |
| A2 | 3 | 0.2 |
| A3 | 2 | 0.3 |
| B1 | 7 | 0.4 |
| B2 | 6 | 0.6 |
| B3 | 8 | 0.5 |
| B4 | 9 | 0.4 |
| B5 | 10 | 0.3 |
| B6 | 9 | 0.5 |
By above-described embodiment, comparative example and detection example, the obtained 3D printing boron nitride ceramics that the present invention is provided
Material has relatively low liquid phase surface tension, and then reduces the crackle on the surface of ceramic.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned implementation method
Detail, in range of the technology design of the invention, various simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of implementation methods of the invention, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (10)
1. a kind of preparation method of 3D printing boron nitride ceramic material, it is characterised in that including：
1) kaolin, attapulgite, boron nitride, boric acid, salicylic acid, molybdenum trioxide, nano aluminum, glass fibre and water are mixed
Close, then calcined that calcined product is obtained；
2) Kynoar, methylcellulose, silane coupler are mixed base-material is obtained with the calcined product；
3) base-material is ground that the 3D printing boron nitride ceramic material is obtained.
2. preparation method according to claim 1, wherein, in step 1) in, relative to the kaolinite of 100 weight portions
Soil, the consumption of the attapulgite is 44-52 weight portions, and the consumption of the boron nitride is 42-53 weight portions, the use of the boric acid
It is 14-18 weight portions to measure, and the salicylic consumption is 27-36 weight portions, and the consumption of the molybdenum trioxide is 5-9 weight portions,
The consumption of the nano aluminum is 11-14 weight portions, and the consumption of the glass fibre is 17-24 weight portions, and the consumption of the water is
140-180 weight portions.
3. preparation method according to claim 2, wherein, in step 1) in, the mixing at least meets following condition：It is mixed
It is 15-35 DEG C to close temperature, and incorporation time is 40-60min.
4. preparation method according to claim 2, wherein, in step 1) in, the calcining at least meets following condition：Forge
It is 470-520 DEG C to burn temperature, and calcination time is 7-10h.
5. preparation method according to claim 4, wherein, in step 1) the calcining before, the preparation method is also
Including heating process, specially：Mixture is warming up to 150-200 DEG C from the 15-35 DEG C of speed with 0.5-0.8 DEG C/min first
And be incubated 20-40min, be then warming up to 300-380 DEG C with the speed of 1.5-2.5 DEG C/min and be incubated 30-40min, finally with
The speed of 0.8-1 DEG C/min is warming up to 470-520 DEG C and is incubated.
6. preparation method according to claim 2, wherein, in step 1) in, the particle diameter of the nano aluminum is 30-40nm.
7. the preparation method according to any one in claim 1-6, wherein, in step 2) in, relative to 100 weight portions
The calcined product, the consumption of the Kynoar is 75-90 weight portions, and the consumption of the methylcellulose is 25-33
Weight portion, the consumption of the silane coupler is 9-16 weight portions.
8. preparation method according to claim 7, wherein, in step 2) in, the mixing at least meets following condition：It is mixed
It is 15-35 DEG C to close temperature, and incorporation time is 20-40min.
9. the preparation method stated according to any one in claim 1-6,8, wherein, in step 3) in, the grinding uses ball
The mode of mill is carried out, and the ball milling at least meets following condition：Big ball is 2 with the mass ratio of bead：1.3-1.5, abrading-ball with
The mass ratio of material is 10：0.8-1.2, rotating speed is 600-1200rpm, and Ball-milling Time is 25-35min.
10. a kind of 3D printing boron nitride ceramic material, it is characterised in that the 3D printing boron nitride ceramic material will by right
The preparation method in 1-9 described in any one is asked to be prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611060244.4A CN106699110A (en) | 2016-11-28 | 2016-11-28 | Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611060244.4A CN106699110A (en) | 2016-11-28 | 2016-11-28 | Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106699110A true CN106699110A (en) | 2017-05-24 |
Family
ID=58934974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611060244.4A Pending CN106699110A (en) | 2016-11-28 | 2016-11-28 | Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106699110A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104744050A (en) * | 2015-03-23 | 2015-07-01 | 济南大学 | Preparation of three-dimensional printing and rapid prototyping boron nitride powder material |
| CN105017734A (en) * | 2015-07-10 | 2015-11-04 | 清华大学 | Polymeric material for 3D printing and preparation method of polymeric material |
| WO2015188352A1 (en) * | 2014-06-12 | 2015-12-17 | 广东生益科技股份有限公司 | Thermosetting epoxy resin composition and uses thereof |
| CN105482365A (en) * | 2015-12-22 | 2016-04-13 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Attapulgite based 3D printer bracket and preparation method thereof |
| CN105541298A (en) * | 2015-12-24 | 2016-05-04 | 成都新柯力化工科技有限公司 | Continuous inorganic fiber reinforced ceramic and 3D (3-Dimensional) printing forming method for same |
| CN105566860A (en) * | 2015-12-11 | 2016-05-11 | 上海联泰科技股份有限公司 | Ceramic material for 3D (three-dimensional) light curing forming printing and preparation method thereof |
| CN105562677A (en) * | 2015-12-22 | 2016-05-11 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | High-strength ceramic material combination for printer and preparing method for high-strength ceramic |
| CN105623191A (en) * | 2015-12-22 | 2016-06-01 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Kaolin-based 3D printer bracket and preparation method thereof |
| CN105665697A (en) * | 2016-03-11 | 2016-06-15 | 中山大学惠州研究院 | Metal or ceramic consumable item for FDM 3D printing, preparation method for metal or ceramic consumable item and finished product printing method |
-
2016
- 2016-11-28 CN CN201611060244.4A patent/CN106699110A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015188352A1 (en) * | 2014-06-12 | 2015-12-17 | 广东生益科技股份有限公司 | Thermosetting epoxy resin composition and uses thereof |
| CN104744050A (en) * | 2015-03-23 | 2015-07-01 | 济南大学 | Preparation of three-dimensional printing and rapid prototyping boron nitride powder material |
| CN105017734A (en) * | 2015-07-10 | 2015-11-04 | 清华大学 | Polymeric material for 3D printing and preparation method of polymeric material |
| CN105566860A (en) * | 2015-12-11 | 2016-05-11 | 上海联泰科技股份有限公司 | Ceramic material for 3D (three-dimensional) light curing forming printing and preparation method thereof |
| CN105482365A (en) * | 2015-12-22 | 2016-04-13 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Attapulgite based 3D printer bracket and preparation method thereof |
| CN105562677A (en) * | 2015-12-22 | 2016-05-11 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | High-strength ceramic material combination for printer and preparing method for high-strength ceramic |
| CN105623191A (en) * | 2015-12-22 | 2016-06-01 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Kaolin-based 3D printer bracket and preparation method thereof |
| CN105541298A (en) * | 2015-12-24 | 2016-05-04 | 成都新柯力化工科技有限公司 | Continuous inorganic fiber reinforced ceramic and 3D (3-Dimensional) printing forming method for same |
| CN105665697A (en) * | 2016-03-11 | 2016-06-15 | 中山大学惠州研究院 | Metal or ceramic consumable item for FDM 3D printing, preparation method for metal or ceramic consumable item and finished product printing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105130410B (en) | A kind of preparation method of Fast back-projection algorithm CBN grinding tool vitrified bonds | |
| CN105150122B (en) | A kind of vitrified bond and preparation method thereof | |
| CN103029048B (en) | A kind of manufacture method of large size ceramic high speed grinding wheel | |
| CN105860612A (en) | Energy-saving paint resistant to high temperature and high infrared radiation and preparation method thereof | |
| CN105084877B (en) | A kind of preparation method of microwave method Fast back-projection algorithm CBN grinding tool vitrified bonds | |
| CN104086150A (en) | Heat-insulated aerogel material for building and preparation method of heat-insulated aerogel material | |
| CN106270366A (en) | A kind of high temperature resistant moulding sand for casting | |
| CN108059354A (en) | It is a kind of to prepare unleaded alkali metal-free low-temperature co-fired ceramics using traditional glass melting technology（LTCC）The method of powder | |
| CN103465186A (en) | Vitrified bonded grinding wheel manufacturing method | |
| EP3677548A1 (en) | Method for manufacturing ultra-porous nano-sio2 | |
| CN106674828A (en) | 3d printing silicon nitride ceramic material and preparation method thereof | |
| CN104761286A (en) | Sintered color sand | |
| CN106699110A (en) | Boron nitride ceramic material for 3D (Three Dimensional) printing and preparation method thereof | |
| CN107042475A (en) | A kind of universal joint alley mill nano-grade ceramic binding agent cBN emery wheels and preparation method thereof | |
| CN106699111A (en) | 3d printing titanium oxide ceramic material and preparation method thereof | |
| CN106631081A (en) | Three-dimensional printed magnesium nitride ceramic material and preparation method thereof | |
| CN106084902A (en) | A kind of high infrared radiation powder and preparation method thereof | |
| CN106630960A (en) | 3d printing tantalum nitride ceramic material and preparation method thereof | |
| CN106854075A (en) | 3D printing aluminium nitride ceramics material and preparation method thereof | |
| CN110981456B (en) | Nano microporous heat insulation plate and preparation method thereof | |
| CN104341145B (en) | Based on the alumina-silicate ceramic fibre and preparation method thereof of cyanite tailing | |
| CN105330269B (en) | A kind of high-ductility wear-resistant ceramic material and preparation method thereof | |
| CN104418577A (en) | Method for preparing silicon dioxide aerogel modified glass wool board for external thermal insulation | |
| CN103396685A (en) | Preparation method of energy-saving paint | |
| CN107815148A (en) | A kind of high temperature resistant infrared radiative energy-saving coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170524 |