CN106698959A - Manufacturing method of anticorrosive glass - Google Patents
Manufacturing method of anticorrosive glass Download PDFInfo
- Publication number
- CN106698959A CN106698959A CN201611217206.5A CN201611217206A CN106698959A CN 106698959 A CN106698959 A CN 106698959A CN 201611217206 A CN201611217206 A CN 201611217206A CN 106698959 A CN106698959 A CN 106698959A
- Authority
- CN
- China
- Prior art keywords
- glass
- anticorrosion
- manufacture method
- antioxidant
- annealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/235—Heating the glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a manufacturing method of anticorrosive glass. The method comprises a glass substrate manufacturing process and an anticorrosive film. The glass substrate manufacturing process comprises the following steps: proportioning, melting, forming and annealing. The anticorrosive film is composed of the following components in percentage by volume: 30-36% of boron oxide, 16-25% of sodium oxide, 12-18% of aluminum oxide, 10-15% of polycarbonate and 15-20% of antioxidant. The glass substrate manufacturing method comprises the following step: (1) proportioning: weighing various raw materials according to the designed formula, and uniformly mixing in a mixer according to a certain proportion. The complete glass production mechanism is adopted to ensure the completion of the glass substrate. The mixed components of the anticorrosive film ensure the anticorrosive effect of the glass, thereby reducing the possibility of damage to glass due to outside chemical substances, acidic substances or the like.
Description
Technical field
The present invention relates to glass technology technical field, specially a kind of manufacture method of anticorrosion glass.
Background technology
Glass be fused together by silica and other chemical substances formed (main production raw material is：Soda ash, stone
Lime stone, quartz).Melting when formed contiguous network structure, in cooling procedure viscosity gradually increase and harden cause its crystallize
Silicates nonmetallic materials, be widely used in now building, science and technology and electronic product among, but simple glass easily with outward
Some chemical substances or acidic materials reaction on boundary, influence the use of glass, so needing a kind of anticorrosion on the market now
Glass.
The content of the invention
It is an object of the invention to provide it is a kind of can be with the manufacture method of etch-proof anticorrosion glass, to solve background skill
The problem proposed in art.
To achieve the above object, the present invention provides following technical scheme：A kind of manufacture method of anticorrosion glass, including glass
Glass basic unit manufacture method and anticorrosion film, the glass-base manufacture method include dispensing, molten system, shaping and annealing, described
The composition material of anticorrosion film includes boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant, the boron oxide
Percent by volume be 30%-36%, the percent by volume of sodium oxide molybdena be 16%-25%, it is alundum (Al2O3) 12%-18%, poly-
Carbonic ester 10%-15% and antioxidant 15%-20%.
Preferably, the glass-base manufacture method is comprised the following steps：
(1) dispensing：According to the material Fang Dan for designing, will mix in batch mixer according to a certain percentage after various raw material weighings
Uniformly；
(2) molten system：In the dispensing input tank furnace that will be mixed, the tank furnace internal temperature is set to 1300 DEG C -1600 DEG C,
The raw material that will be prepared forms the glass metal of uniform bubble-free by high-temperature heating；
(3) it is molded：Glass metal after the completion of molten system is put among mould a kind of form for forming needs, the glass into
Temperature is about between 900 DEG C -1250 DEG C during type, thermal coefficient of expansion 5.0X10-7；
(4) anneal：The glass-base that will be molded is put into by the entrance of annealing furnace, is taken out by annealing outlet of still, described
Annealing process persistently carries out 3-5min, and the annealing furnace temperature control is between 550 DEG C -570 DEG C.
Preferably, the composition material of the anticorrosion film includes boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon
And antioxidant, the boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant are proportionally put and dissolves mixing shape
Into liquid substance, anticorrosion film compounding substances are sprayed at glass by the anticorrosion film by way of planar magnetic control sputtering
The surface of basic unit forms anticorrosion film, and the anticorrosion film sprinkling number of plies is 5 layers, the thickness of every layer of the anticorrosion film
Should be less than 0.2nm.
The present invention ensure that the complete of glass-base using complete glass production mechanism, and the anti-corrosion film of various mixing
Layer blending constituent ensure that the effect of anticorrosion glass erosion, reduce because extraneous chemical substance or acidic materials etc. are made to glass
Into the possibility damaged.
Specific embodiment
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only
It is a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill people
The every other embodiment that member is obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
Embodiment one：
A kind of manufacture method of anticorrosion glass, including glass-base manufacture method and anticorrosion film, glass-base system
Making method includes dispensing, molten system, shaping and annealing, and the composition material of anticorrosion film includes boron oxide, sodium oxide molybdena, three oxidations two
Aluminium, makrolon and antioxidant, the percent by volume of boron oxide are that the percent by volume of 34%, sodium oxide molybdena is 20%, three oxidations
Two aluminium 17%, makrolon 13% and antioxidant 16%.
Glass-base manufacture method is comprised the following steps：
(1) dispensing：According to the material Fang Dan for designing, will mix in batch mixer according to a certain percentage after various raw material weighings
Uniformly；
(2) molten system：In the dispensing input tank furnace that will be mixed, tank furnace internal temperature is set to 1500 DEG C, the original that will be prepared
Material forms the glass metal of uniform bubble-free by high-temperature heating；
(3) it is molded：Glass metal after the completion of molten system is put among mould a kind of form for forming needs, glass was molded
Temperature setting is 1100 DEG C, thermal coefficient of expansion 5.0X10-7 in journey；
(4) anneal：The glass-base that will be molded is put into by the entrance of annealing furnace, is taken out by annealing outlet of still, annealing
Process persistently carries out 4min, and annealing furnace temperature control is at 560 DEG C.
The composition material of anticorrosion film includes boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant, will
Boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant are proportionally put to dissolve and are mixed to form liquid substance, anti-corrosion
The surface that anticorrosion film compounding substances are sprayed at glass-base is formed anti-corrosion by erosion film layer by way of planar magnetic control sputtering
Erosion film layer, the anticorrosion film sprinkling number of plies is 5 layers, and the thickness of every layer of anticorrosion film should be less than 0.15nm.
The anticorrosion glass that will be processed uses digital ultrasonic flaw detector after being placed on 12h in acidic materials, experiment
Tested, the damage such as sand holes will not be cracked, met standard.
Embodiment two：
A kind of manufacture method of anticorrosion glass, including glass-base manufacture method and anticorrosion film, glass-base system
Making method includes dispensing, molten system, shaping and annealing, and the composition material of anticorrosion film includes boron oxide, sodium oxide molybdena, three oxidations two
Aluminium, makrolon and antioxidant, the percent by volume of boron oxide are that the percent by volume of 32%, sodium oxide molybdena is 21%, three oxidations
Two aluminium 14%, makrolon 15% and antioxidant 18%.
Glass-base manufacture method is comprised the following steps：
(1) dispensing：According to the material Fang Dan for designing, will mix in batch mixer according to a certain percentage after various raw material weighings
Uniformly；
(2) molten system：In the dispensing input tank furnace that will be mixed, tank furnace internal temperature is set to 1550 DEG C, the original that will be prepared
Material forms the glass metal of uniform bubble-free by high-temperature heating；
(3) it is molded：Glass metal after the completion of molten system is put among mould a kind of form for forming needs, glass was molded
Temperature setting is 1050 DEG C, thermal coefficient of expansion 5.0X10-7 in journey；
(4) anneal：The glass-base that will be molded is put into by the entrance of annealing furnace, is taken out by annealing outlet of still, annealing
Process persistently carries out 3.5min, and annealing furnace temperature control is at 550 DEG C.
The composition material of anticorrosion film includes boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant, will
Boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant are proportionally put to dissolve and are mixed to form liquid substance, anti-corrosion
The surface that anticorrosion film compounding substances are sprayed at glass-base is formed anti-corrosion by erosion film layer by way of planar magnetic control sputtering
Erosion film layer, the anticorrosion film sprinkling number of plies is 5 layers, and the thickness of every layer of anticorrosion film should be less than 0.18nm.
The anticorrosion glass that will be processed uses digital ultrasonic flaw detector after being placed on 12h in acidic materials, experiment
Tested, the damage such as sand holes will not be cracked, met standard.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (3)
1. a kind of manufacture method of anticorrosion glass, including glass-base manufacture method and anticorrosion film, it is characterised in that institute
Stating glass-base manufacture method includes dispensing, molten system, shaping and annealing, and the composition material of the anticorrosion film includes oxidation
Boron, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant, the percent by volume of the boron oxide are 30%-36%, aoxidize
The percent by volume of sodium is 16%-25%, alundum (Al2O3) 12%-18%, makrolon 10%-15% and antioxidant 15%-
20%.
2. a kind of anticorrosion glass according to claim 1, it is characterised in that：The glass-base manufacture method include with
Lower step：
(1) dispensing：According to the material Fang Dan for designing, will mix equal in batch mixer according to a certain percentage after various raw material weighings
It is even；
(2) molten system：In the dispensing input tank furnace that will be mixed, the tank furnace internal temperature is set to 1300 DEG C -1600 DEG C, will match somebody with somebody
Good raw material forms the glass metal of uniform bubble-free by high-temperature heating；
(3) it is molded：Glass metal after the completion of molten system is put among mould a kind of form for forming needs, the glass was molded
Temperature is about between 900 DEG C -1250 DEG C in journey, thermal coefficient of expansion 5.0X10-7；
(4) anneal：The glass-base that will be molded is put into by the entrance of annealing furnace, is taken out by annealing outlet of still, the annealing
Process persistently carries out 3-5min, and the annealing furnace temperature control is between 550 DEG C -570 DEG C.
3. the manufacture method of a kind of anticorrosion glass according to claim 1, it is characterised in that：The anticorrosion film
Composition material includes boron oxide, sodium oxide molybdena, alundum (Al2O3), makrolon and antioxidant, by the boron oxide, sodium oxide molybdena, three
Al 2 O, makrolon and antioxidant are proportionally put to dissolve and are mixed to form liquid substance, and the anticorrosion film is by flat
The surface that anticorrosion film compounding substances are sprayed at glass-base is formed anticorrosion film by the mode of face magnetron sputtering, described anti-
The corrosion film layer sprinkling number of plies is 5 layers, and the thickness of every layer of the anticorrosion film should be less than 0.2nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611217206.5A CN106698959A (en) | 2016-12-26 | 2016-12-26 | Manufacturing method of anticorrosive glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611217206.5A CN106698959A (en) | 2016-12-26 | 2016-12-26 | Manufacturing method of anticorrosive glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106698959A true CN106698959A (en) | 2017-05-24 |
Family
ID=58903332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611217206.5A Withdrawn CN106698959A (en) | 2016-12-26 | 2016-12-26 | Manufacturing method of anticorrosive glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106698959A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108994108A (en) * | 2018-07-02 | 2018-12-14 | 安徽省佳隆汽车配件有限公司 | A kind of production technology of ceramics anti-corrosion exhaust pipe |
-
2016
- 2016-12-26 CN CN201611217206.5A patent/CN106698959A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108994108A (en) * | 2018-07-02 | 2018-12-14 | 安徽省佳隆汽车配件有限公司 | A kind of production technology of ceramics anti-corrosion exhaust pipe |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170524 |
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| WW01 | Invention patent application withdrawn after publication |