CN106695170B - Stainless steel welded gas-shielded flux-cored wire - Google Patents

Stainless steel welded gas-shielded flux-cored wire Download PDF

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Publication number
CN106695170B
CN106695170B CN201611152859.XA CN201611152859A CN106695170B CN 106695170 B CN106695170 B CN 106695170B CN 201611152859 A CN201611152859 A CN 201611152859A CN 106695170 B CN106695170 B CN 106695170B
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Prior art keywords
stainless steel
iron
cored wire
medicine core
steel welded
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CN106695170A (en
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曹立兵
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Anhui Huazhong Welding Material Manufacturing Co Ltd
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Anhui Huazhong Welding Material Manufacturing Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/3066Fe as the principal constituent with Ni as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • B23K35/406Filled tubular wire or rods

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The invention proposes a kind of stainless steel welded gas-shielded flux-cored wires; including stainless steel crust and medicine core; it is calculated according to weight percent; the constituent of the medicine core are as follows: manganese-silicon 3~9%, silica 1~5%, Cr 5~20%, Ni 10~20%, potassium titanate 0.5~2.5%, bismuth oxide 10~15%, di-iron trioxide 2~8%, fluoride 0.2~2.2% and graphite 0.5~3.5%, surplus is iron.The welding wire has the advantages of arc stability, splashing is small, appearance of weld is beautiful, and vertical downward welding may be implemented using short circuiting transfer.

Description

Stainless steel welded gas-shielded flux-cored wire
Technical field
The invention belongs to technical field of welding materials, and in particular to a kind of stainless steel welded gas-shielded flux-cored wire.
Background technique
In recent years, with the rapid development of economy, stainless steel industry is also developed faster.Stainless steel consumption figure it is strong Strength increases, and will drive the rapid growth in welding market: on the one hand, the quality progress of steel promotes stainless steel welding material more It is new to regenerate;On the other hand, stainless steel welded efficiently (automation) process obviously raises speed, and promotes the breed structure readjustment of welding material Paces are accelerated.
Compared with traditional stick electrode, copper plating solid core welding wire, submerged arc welding flux, welded using stainless flux-cored wire With apparent advantage, first, welding process is more continuous, and may be implemented automatic welding, thus reduce welding point, Greatly improve production efficiency, be 3-4 times of manual electric arc welding, welding quality is good, has saved the energy, reduce it is comprehensive at This;Second, there is no fever and redness phenomenons for stainless flux-cored wire, and it is minimum to splash, and weld seam light is silvery white in color, postwelding one As do not need pickling, grinding and buffing;Third, the medicinal powder in flux-cored wire all passes through high temperature baking, moisture is few, before welding It does not need to dry, stomata sensitivity is lower.So stainless flux-cored wire is widely used in shipbuilding, petrochemical industry, pressure vessel, steel knot The industries such as structure and engineering machinery.
Therefore, with economic quick, stable, sustainable development, demand rapid growth of the market to stainless steel material, to not The demand of rust steel flux-cored wire is also increasing, develops, develops a kind of flux core welding wire matched with stainless steel, keeps it full In the case where foot low cost, also has the characteristics that welding technological properties is good, arc stability, splashing is small, appearance of weld is beautiful, be Highly important research topic.
Summary of the invention
The present invention proposes a kind of stainless steel welded gas-shielded flux-cored wire, the welding wire have arc stability, splash it is small, The advantages of appearance of weld is beautiful, and vertical downward welding may be implemented using short circuiting transfer.
The technical scheme of the present invention is realized as follows:
A kind of stainless steel welded gas-shielded flux-cored wire, including stainless steel crust and medicine core, according to weight percent It calculates, the constituent of the medicine core are as follows:
Manganese-silicon 3~9%, silica 1~5%, Cr 5~20%, Ni 10~20%, potassium titanate 0.5~ 2.5%, bismuth oxide 10~15%, di-iron trioxide 2~8%, fluoride 0.2~2.2% and graphite 0.5~3.5%, surplus are Iron.
Further, the fluoride is one of calcirm-fluoride, prodan, potassium fluosilicate and cryolite or more Kind.
Further, the constituent of the medicine core are as follows:
Manganese-silicon 5%, silica 3%, Cr 12%, Ni 16%, potassium titanate 1.2%, bismuth oxide 12%, three aoxidize Two iron 6%, fluoride 1.2% and graphite 2%, surplus is iron.
Further, the constituent of the medicine core are as follows:
Manganese-silicon 9%, silica 5%, Cr 20%, Ni 10%, potassium titanate 0.5%, bismuth oxide 10%, three aoxidize Two iron 2%, fluoride 2.2% and graphite 0.5%, surplus is iron.
Further, the diameter of the gas-shielded flux-cored wire is 1.2~1.8mm.
Manganese-silicon: the content of its silicon is 20%~25%, and suitable element silicon is added in formula to be helped to improve weld seam Molding.
Potassium titanate and bismuth oxide can refine crystal grain, improve low-temperature impact toughness, and can improve welding pool surface tension, Improve the molding of weld seam.
Graphite: deoxidation provides C element into molten bath.
Stainless steel welded gas-shielded flux-cored wire preparation method of the invention uses the prior art, including following step It is rapid:
1, medicinal powder of the present invention is prepared by formula rate;
2, steel band is rolled into U-shaped, then 16%~20% medicine of the present invention for accounting for welding wire gross weight of the present invention is added into U-lag Core powder;
3, U-lag is healed up with forming machine, makes medicine core powder package wherein, by wire drawing machine, by road by wire drawing machine drawing, Tube reducing finally makes its diameter reach 1.2~1.8mm, obtains final products.
Beneficial effects of the present invention:
Deposited metal after being welded with gas-shielded flux-cored wire provided by the invention: tensile strength >=650Mpa, elongation percentage >=46%;And welding technological properties is good, and arc stability, splashing is small, appearance of weld is beautiful, may be implemented using short circuiting transfer Vertical downward welding.
Specific embodiment
Embodiment 1
Select the steel band of 10mm × 0.4mm, carbon, the 0.5- of chemical component (by weight percentage) 0.01-0.1% 1.5% manganese, the silicon of 0.1-1%, the sulphur of 0.005-0.015%, the phosphorus of 0.005-0.035%, the chromium of 15-25%, 5-15% Nickel, surplus be iron.
Medicine core forms percentage, and medicine core accounts for the 16% of welding wire weight, the weight percent of medicine core composition therein Number are as follows:
Manganese-silicon 5%, silica 3%, Cr 12%, Ni 16%, potassium titanate 1.2%, bismuth oxide 12%, three aoxidize Two iron 6%, calcirm-fluoride 1.2% and graphite 2%, surplus is iron.
Welding parameter: I=200-220A, U=30-32V, gas flow 20L/min, pure CO2 gas.
Deposited metal composition (count by weight percentage) are as follows: C 0.025%, Mn1.33, Si 0.5, S0.002%, P0.012, Cr 18.78, Ni9.67, surplus Fe.
Deposited metal mechanical performance (pure CO2Gas) are as follows: tensile strength 680MPa, elongation percentage 48%.
Embodiment 2
Select the steel band of 10mm × 0.4mm, carbon, the 0.5- of chemical component (by weight percentage) 0.01-0.1% 1.5% manganese, the silicon of 0.1-1%, the sulphur of 0.005-0.015%, the phosphorus of 0.005-0.035%, the chromium of 15-25%, 5-15% Nickel, surplus be iron.
Medicine core forms percentage, and medicine core accounts for the 18% of welding wire weight, the weight percent of medicine core composition therein Number are as follows:
Manganese-silicon 9%, silica 5%, Cr 20%, Ni 10%, potassium titanate 0.5%, bismuth oxide 10%, three aoxidize Two iron 2%, potassium fluosilicate 2.2% and graphite 0.5%, surplus is iron.
Deposited metal composition (count by weight percentage) are as follows: C 0.025%, Mn1.33, Si 0.5, S0.002%, P0.012, Cr 18.78, Ni9.67, surplus Fe.
Deposited metal mechanical performance (pure CO2Gas) are as follows: tensile strength 650MPa, elongation percentage 46%.
Embodiment 3
Select the steel band of 10mm × 0.4mm, carbon, the 0.5- of chemical component (by weight percentage) 0.01-0.1% 1.5% manganese, the silicon of 0.1-1%, the sulphur of 0.005-0.015%, the phosphorus of 0.005-0.035%, the chromium of 15-25%, 5-15% Nickel, surplus be iron.
Medicine core forms percentage, and medicine core accounts for the 20% of welding wire weight, the weight percent of medicine core composition therein Number are as follows:
Medicine core forms percentage, and medicine core accounts for the 18% of welding wire weight, the weight percent of medicine core composition therein Number are as follows:
Manganese-silicon 3%, silica 1 %, Cr 5%, Ni20%, potassium titanate 2.5%, the oxidation of bismuth oxide 15%, three two Iron 8%, prodan 0.2% and graphite 3.5%, surplus is iron.
Deposited metal composition (count by weight percentage) are as follows: C 0.025%, Mn1.33, Si 0.5, S0.002%, P0.012, Cr 18.78, Ni9.67, surplus Fe.
Deposited metal mechanical performance (pure CO2Gas) are as follows: tensile strength 670MPa, elongation percentage 46.8%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (5)

1. a kind of stainless steel welded gas-shielded flux-cored wire, including stainless steel crust and medicine core, which is characterized in that according to weight It measures percentage to calculate, the constituent of the medicine core are as follows:
Manganese-silicon 3~9%, silica 1~5%, Cr 5~20%, Ni 10~20%, potassium titanate 0.5~2.5%, oxygen Change bismuth 10~15%, di-iron trioxide 2~8%, fluoride 0.2~2.2% and graphite 0.5~3.5%, surplus is iron.
2. stainless steel welded gas-shielded flux-cored wire according to claim 1, which is characterized in that the fluoride is One or more of calcirm-fluoride, prodan, potassium fluosilicate and cryolite.
3. stainless steel welded gas-shielded flux-cored wire according to claim 1 or 2, which is characterized in that the medicine core Constituent are as follows:
Manganese-silicon 5%, silica 3%, Cr 12%, Ni 16%, potassium titanate 1.2%, bismuth oxide 12%, di-iron trioxide 6%, fluoride 1.2% and graphite 2%, surplus is iron.
4. stainless steel welded gas-shielded flux-cored wire according to claim 1 or 2, which is characterized in that the medicine core Constituent are as follows:
Manganese-silicon 9%, silica 5%, Cr 20%, Ni 10%, potassium titanate 0.5%, bismuth oxide 10%, di-iron trioxide 2%, fluoride 2.2% and graphite 0.5%, surplus is iron.
5. stainless steel welded gas-shielded flux-cored wire according to claim 1, which is characterized in that the gas shielded medicine The diameter of core welding wire is 1.2~1.8mm.
CN201611152859.XA 2016-12-14 2016-12-14 Stainless steel welded gas-shielded flux-cored wire Active CN106695170B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108941974A (en) * 2018-09-11 2018-12-07 江苏思迪彼特新材料科技有限公司 A kind of corrosion-resistant stainless steel arc welding flux cored wire and preparation method thereof
CN110153586B (en) * 2019-05-27 2021-07-02 中国船舶重工集团公司第七二五研究所 Ultralow-hydrogen moisture-absorption-resistant welding electrode with seamless flux-cored wire as core wire and preparation method thereof
CN111203673B (en) * 2020-01-13 2021-12-28 武汉铁锚焊接材料股份有限公司 High-toughness metal powder flux-cored welding wire for argon-rich shielded welding
CN112643243B (en) * 2020-11-30 2022-04-19 山东聚力焊接材料有限公司 Stainless steel flux-cored wire

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101259574A (en) * 2008-04-22 2008-09-10 武汉铁锚焊接材料股份有限公司 Stainless steel welding stick
CN101497152A (en) * 2009-02-26 2009-08-05 山东大学 Large-diameter flux-cored wire for revolving body or wear-resistant composite board overlaying welding
JP2011125904A (en) * 2009-12-18 2011-06-30 Nippon Steel & Sumikin Welding Co Ltd Flux cored wire for gas shielded arc welding for weather resistant steel
CN102229029A (en) * 2011-05-30 2011-11-02 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel all-position welding
CN103042321A (en) * 2012-12-21 2013-04-17 中国兵器工业第五二研究所 Metal powder-cored type nitrogen austenite stainless steel flux-cored wire and method for manufacturing same
CN105215580A (en) * 2015-11-16 2016-01-06 洛阳双瑞特种合金材料有限公司 A kind of E309L stainless steel that can be used for big current welding adds Long Welding rod
CN105269177A (en) * 2015-11-24 2016-01-27 天津市金桥焊材集团有限公司 Stainless steel flux-cored wire achieving purpose that surface of welding joint is free of oxidation tint
CN105880867A (en) * 2014-08-29 2016-08-24 伊利诺斯工具制品有限公司 Flux cored wire, and production method and application thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101259574A (en) * 2008-04-22 2008-09-10 武汉铁锚焊接材料股份有限公司 Stainless steel welding stick
CN101497152A (en) * 2009-02-26 2009-08-05 山东大学 Large-diameter flux-cored wire for revolving body or wear-resistant composite board overlaying welding
JP2011125904A (en) * 2009-12-18 2011-06-30 Nippon Steel & Sumikin Welding Co Ltd Flux cored wire for gas shielded arc welding for weather resistant steel
CN102229029A (en) * 2011-05-30 2011-11-02 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel all-position welding
CN103042321A (en) * 2012-12-21 2013-04-17 中国兵器工业第五二研究所 Metal powder-cored type nitrogen austenite stainless steel flux-cored wire and method for manufacturing same
CN105880867A (en) * 2014-08-29 2016-08-24 伊利诺斯工具制品有限公司 Flux cored wire, and production method and application thereof
CN105215580A (en) * 2015-11-16 2016-01-06 洛阳双瑞特种合金材料有限公司 A kind of E309L stainless steel that can be used for big current welding adds Long Welding rod
CN105269177A (en) * 2015-11-24 2016-01-27 天津市金桥焊材集团有限公司 Stainless steel flux-cored wire achieving purpose that surface of welding joint is free of oxidation tint

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