CN106689204A - Composition for preventing and treating crop diseases and pests - Google Patents

Abstract

The invention provides a composition for preventing and treating crop diseases and pests. The composition comprises an active component (A) and an active component (B), wherein (A) is a compound as shown in a formula (A) which is described in the specification, (B) is selected from a group consisting of copper hydroxide and calcium copper sulfate, and a weight ratio of the compound (A) to the compound (B) is 1: 50 to 50: 1. Through compounding of the compound (A) and the compound (B), agricultural bactericidal and pesticidal effects are organically combined; and when the composition is used for soil treatment, the composition is capable of preventing fungal and bactericidal diseases and harm caused by soil insects and root nematodes.

Description

A kind of crop disease and insect prevents and kill off composition

Technical field

Composition is prevented and kill off the present invention relates to a kind of crop disease and insect, a kind of method for preventing and kill off crop disease and insect pest is further related to.

Background technology

In recent years, because various plant pathogenic fungis and bacterial plant disease are on the rise, from last century the eighties, agricultural chemicals company of various countries develops various efficient chemical bactericide successively, such as triazole type, strobilurin fungicide, the prevention effect of plant disease is substantially increased.But the continuing of chemical pesticide uses, the resistance to the action of a drug of disease is accelerated, and residual is high, and environment is polluted.

Biological pesticide refers to the preparation killed or suppressed for agricultural pest using biological living (fungi, bacterium, insect viruses, genetically modified organism, natural enemy etc.) or its metabolite (pheromones, auxin, methyl α-naphthyl acetate, 2,4-D etc.).Mainly including plant insecticide, botanical fungicide, botanical herbicides and the plant mould poison of photoactivation etc..Biological pesticide has the advantages that low toxicity, low-residual, and simultaneous can control numerous plant pathogenic fungi and bacterial diseases, is widely used in the preventing and treating of organic and green agricultural product disease.But it is slow that most biological pesticides all have drug effect, the dissatisfactory shortcoming of preventive effect, seriously perplex its application and promote.

Fosthiazate (Fosthiazate), chemical name is (RS)-S- sec-butyls-O- ethyl-2-oxos -1,3-thiazoles alkane -3- base Thiophosphonates；(RS) -3- (s-butylthio (ethyoxyl) phosphonic acids) -1,3-thiazoles alkane -2- ketone, its molecular structure is as follows：

Fosthiazate is insecticide and nematicide, and with good absorbability, main effect model is the activity of the acetylcholinesterase of suppression target insect, influences growing for larva.Can be used for vegetables, potato, banana and many crops of cotton, preventing and treating ground Thysanoptera, Lepidoptera, coleoptera, many insects of Diptera, it can also be used to which underground prevents and treats root-feeding insect are also effective to many evil mites, have good killing activity to various nematodes.When lythidathion is used to prevent and treat soil pests, root nematode, should be mixed in soil immediately after, expression effect more preferably, can directly impose on native table before crop-planting, can also be used in crop sowing, transplanting.Recommend 1~5kg of consumption active ingredients/hectare.

Lythidathion is that a kind of wide spectrum kills nematode, acaricide and soil insecticide, with strong contact toxicity, has to various nematodes, insect and mite class and toxic action is inhaled in obvious, and conventional pesticides have been produced with some insects of resistance, also there is activity very high.The nematode that can be prevented and treated is about 20 kinds etc. ground cauline leaf needle nematode, underground plant root endoparasitism nematode, half endoparasitism nematode, needle nematode.The agricultural and sanitary insect pest that can be prevented and treated more than 30 kind such as including Thysanoptera, Semiptera, Lepidoptera, coleoptera, Diptera, Orthoptera.Mite class has two-spotted spider mite, citrus red mite etc..Nematode has turned into one of the important pests that harm the crops and refractory insect, it is different from conventional nematicide, the kind is non-fumigation type and has Uptake and translocation effect in plant, the biological and physicochemical property of its uniqueness is adapted for soil, cauline leaf dispenser, there is broad spectrum of activity to plant nematode, be a kind of preferable nematicide for preventing and treating plant nematode.

Kocide SD (Copper Hydroxide), chemical name：Cu(OH)₂, its structural formula is：

Kocide SD is a kind of widely used compound, agriculturally used as bactericide and can be used for the preventing and treating of crop fungi, bacterial disease, its mechanism of action is mainly by pharmacy application in the release of copper ion after crop, play the oxidation of copper ion and work, meanwhile, growth of the copper to some crops has adjustment effect.Mainly by copper ion, the spore that copper ion is sprouted absorbs for Kocide SD bactericidal action, and when finite concentration is reached, it is possible to kill spore cell, so as to play bactericidal action, but this effect is only limitted to prevent spore germination, namely only protective effect.Kocide SD can be used for oranges and tangerines, paddy rice, peanut, brassicaceous vegetable, carrot, tomato, potato, green onion class, capsicum, tea tree, grape, the crops such as watermelon prevent and treat citrus scab, resin disease, routed tuberculosis, foot rot, bacterial blight of rice, bacterial stripe, rice blast, banded sclerotial blight, target, late blight, brassicaceous vegetable black spot, black rot, carrot leaf pinta, celery bacterial speck, early epidemic scrofula, spot blight, eggplant early blight, anthracnose, brown spot, common bacterial blight of bean, green onion class purple spot, downy mildew, pepper bacterial leaf spot, cucumber bacterial angular leaf spot, muskmelon downy mildew, reticulate pattern disease, grapevine anthracnose, powdery mildew, downy mildew, leaf spot of peanut, tea tree anthracnose, net cake disease etc..

Copper calcium sulfate (Copper Calcium Sulphate), trade name is called more peaceful, is non-selective copper ions protective fungicide, low toxicity, does not have medicine spot to pollute on blade face equivalent to " Bordeaux's powder " of industrialized production, but after spraying.Its bactericidal mechanism is combined with the various biological groups in disease fungus or bacterial body by the copper ion for discharging, and forms the materials such as the complex compound of copper, makes protein denaturation, so as to hinder and suppress metabolism, causes germ dead.Unique copper calcium compound slowly releases the copper ion of sterilization when meeting water, sprouting with germ, infect it is synchronous, sterilized, diseases prevention in time thoroughly, and to fungoid and bacterial disease effectively simultaneously.Copper calcium sulfate is different from common Bordeaux mixture, liquid be in subacidity, can with the non-alkaline pharmacy mix of not metal ion, it is easy to use.Copper calcium sulfate fine particles, in down-like structure, can be uniformly distributed and be adhered tightly to the blade surface of crop after spraying, resistance of rainwater washing against ability is strong.In addition, copper calcium sulfate is containing 12% calcium sulfate, while controlling disease, also with suitable effect of replenishing the calcium.

Copper calcium sulfate wide sterilization spectrum, is difficult induction pathogen and develops immunity to drugs.There is good result to all fungoids and bacterial disease.The many planting fruit-trees insensitive to copper ion, various vegetables and diversified economy crop be can be widely applied in case controlling various fungoids and bacterial disease, such as the trunk disease of various deciduous fruit trees；Apple marssonina leaf spot, the canker of oranges and tangerines, shot hole, anthracnose；The wildfire sincere heart disease of tobacco；The downy mildew of grape, anthracnose, brown spot, anthrachose of grape；The rust of jujube tree, ring spot, anthracnose, brown spot；The scab of pear tree, brown spot；The rotten neck disease of ginger（Rotten mould base rot disease）, bacterial wilt of ginger；The root rot of garlic, soft rot；Epidemic disease, samping off, damping-off, downy mildew, late blight, fungal leaf spot, bacterial leaf spot of the late blight of potato and other various gourd, fruit and vegetables etc..

Crop pathogenic bacteria and/or insect easily mix occur or to currently known product and produce resistance or have produce resistance risk in the case of, it is necessary to seek it is a kind of it is more efficient control or prevention composition or method.

The content of the invention

The object of the invention is directed to a kind of crop disease and insect of above-mentioned weak point offer and prevents and kill off composition, said composition can provide such as biological nature such as synergism characteristic of improvement, and fungi and/or insect are especially controlled in the useful plant that the plant propagation material through processing grows.

It is to take following technical scheme to realize that a kind of crop disease and insect of the present invention prevents and kill off composition：

A kind of crop disease and insect prevents and kill off composition, and active component is made up of compound (A) and (B), wherein (A) represents the compound fosthiazate (Fosthiazate) described by formula (A)：

And (B) is selected from Kocide SD or copper calcium sulfate；The weight ratio of compound (A) and compound (B) is 1: 50-50: 1, preferably 1: 25-25: 1, more preferably 1: 10-10: 1 in the composition, further preferably 1: 5-5: 1.

A kind of crop disease and insect prevents and kill off composition, also comprising filler and/or surfactant.

The formulation that described pest and disease damage prevents and kill off composition is suspending agent, seed coat agent, wettable powder, water dispersible granules, microcapsule suspending agent, coated granule, granule, water-soluble granule, water solube powder, aqua missible oil, microemulsion, aqueous emulsion, effervescent tablet, Seed Treatment dispersible granula.

Described pest and disease damage is prevented and kill off in composition, and wherein compound (A) accounts for the 5%-90% that crop disease and insect prevents and kill off composition with the content of compound (B).

Described pest and disease damage is prevented and kill off in composition, and wherein compound (A) accounts for the 10%-80% of composition with the content of compound (B).

Described pest and disease damage is prevented and kill off in composition, and wherein compound (A) accounts for the 10%-60% of composition with the content of compound (B).

The present invention also provides a kind of method for preventing and treating crop disease and insect pest, and described composition is applied into crop, crop propagating materials, fungi and insect and/or their environment.

The crop includes fruit tree kind, vegetables, cotton, flowers, tea tree, cereal crops.

The present invention is also provided, and described composition is used to prevent and treat the purposes of crop disease and insect pest.

Described composition is used to prevent and treat on fruit tree, vegetables, cotton, flowers, tea tree, cereal crops by fungi and the purposes of bacterial disease.

Described composition is used to prevent and treat the purposes of the insect pest caused by Thysanoptera, Lepidoptera, coleoptera, Diptera, Semiptera, Orthoptera, evil mite, nematode on fruit tree, vegetables, cotton, flowers, tea tree, cereal crops.

The present invention also provides a kind of cover crop from disease and the method for insect pest, and described composition is applied into crop, crop propagating materials, fungi and insect and/or/their environment.

The present invention also provides a kind of method for preventing and treating crop disease and insect pest, by described compound（A）And compound（B）It is administered simultaneously or applies respectively or sequential application.

Composition of the invention, said composition has the effect of insect prevention diseases prevention simultaneously；And reactive compound of the invention has synergistic function.This acts through the infringement of reduction insect and reduces wound, so as to reduce the intrusion probability of disease, so that the drug effect of composition is more longlasting.In agricultural, the combination of this collaboration prevention and elimination of disease and pests, can make the growth characteristics of plant improves, such as the control higher to fungal infection and/or pest infestation can be obtained, advantageously in arable farming.

The regulation of composition of the invention solves current needs, and such as biological nature such as synergism characteristic of improvement especially controls fungi and/or insect in the useful plant that the plant propagation material through processing grows or in soil.

Specific embodiment

The combination of active principles of different agricultural chemicals is made agricultural chemicals, be exploitation at present and develop novel pesticide and preventing and treating agriculturally resistance germ and insect one kind effectively and quick way.After the pestsides synthesis of different cultivars, three kinds of type of action are typically exhibited：Summation action, synergistic effect and antagonism.But which kind of effect be specially, it is impossible to predict.Due to significantly improving actual prevention effect, the usage amount of agricultural chemicals is reduced, be a kind of integrated control disease, the important means of insect pest so as to greatly increase the prevention effect of germ and insect.

The pest and disease damage that the present invention is provided prevents and kill off composition and includes compound (A) and compound (B), the effect with insect prevention disease-control simultaneously.Particularly said composition can provide synergism characteristic, especially control fungi and/or insect in the useful plant that the plant propagation material through processing grows or in soil.Wherein (A) represents the compound described by formula (A)：

And (B) is selected from Kocide SD or copper calcium sulfate；

Inventor is by substantial amounts of screening test, experiment and effectiveness analysis are carried out a large amount of to the different ratio of compound (A) and compound (B), it was found that in certain ratio range, resulting composition has a gain effect, and the not exclusively two kinds simple additions of medicament.

The present invention provides a kind of pest and disease damage and prevents and kill off composition, active component is made up of compound (A) and (B), compound (A) and the weight ratio of compound (B) are 1: 50-50: 1 in the composition, it is preferred that 1: 25-25: 1, more preferably 1: 10-10: 1, further preferably 1: 5-5: 1.

A kind of crop disease and insect of the invention prevents and kill off composition, also comprising filler and/or surfactant.

The preparation is prepared in a known way, for example, mix reactive compound with filler, i.e., mix with liquid flux, pressurized liquefied gas and/or solid carrier, optionally employs surfactant, i.e. emulsifying agent and/or dispersant and/or foaming agent.If filler used is water, such as organic solvent is it is also possible to use as secondary solvent.Suitable liquid flux mainly has：Aromatic compound, such as dimethylbenzene, toluene or alkylnaphthalene；Chlorinated aromatic compounds of group or chlorinated aliphatic, such as chlorobenzene, vinyl chloride or dichloromethane；Aliphatic hydrocarbon, such as hexamethylene or paraffin, such as petroleum distillate；Alcohol, such as butanol or ethylene glycol and their ether and ester；Ketone, such as acetone, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone；Intensive polar solvent, such as dimethylformamide or dimethyl sulfoxide (DMSO)；Or water.The implication of liquefied gas filler or carrier is interpreted as under normal temperature and atmospheric pressure being gaseous liquid, such as such as aerosol spray, halogenated hydrocarbons, or butane, propane, nitrogen and carbon dioxide.Suitable solid carrier has：The natural minerals of such as crushing, such as kaolin, clay, talcum powder, chalk, quartz, attapulgite, montmorillonite or diatomite；And the synthetic mineral crushed, such as finely divided silica, aluminum oxide and silicate.Solid carrier suitable for granule has：The natural rock for example crushed and be classified, such as calcite, float stone, marble, sepiolite and dolomite；Or the inorganic and organic powder particles of synthesis, and organic particle, such as wood sawdust, coconut husk, corncob and tobacco stem.Suitable emulsifying agent and/or foaming agent has：Such as nonionic and anion emulsifier, described emulsifying agent are selected from：Agriculture breast 500# (alkyl benzene calcium sulfonate),OP series phosphate (thermally coupled distillation columns),600# phosphates (phenyl phenol polyoxyethanyl ether phosphate),Styrene polyoxyethylene ether ammonium sulfate salt,Alkyl biphenyl ether disulfonic acid magnesium salts,Triethanolamine salt,Agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether),Agriculture breast 600# (phenyl phenol polyoxyethyl ether),Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether),Agriculture breast 36# (phenethyl phenol formaldehyde resin polyoxyethyl ether),Agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether),Ethylene oxide-propylene oxide block copolymer,OP series (NPE),By series (castor oil polyoxyethylene ether),Agriculture breast 33# (alkylaryl polyoxyethylene polyoxypropylene ether again),Agriculture breast 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether),Span series (sorbitan monostearate),TWEEN Series (sorbitan fatty acid ester APEO),One or more in AEO series (AEO).

Suitable dispersant is selected from alkylnaphthalene sulfonate, double (alkyl) naphthalenesulfonate formaldehyde condensation compounds, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, APES formaldehyde condensation products sulfat, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, one or more in APEO.Tackifier, such as carboxymethylcellulose calcium, such as natural and synthetic polymer of powder, particle or latex form, gum arabic, polyvinyl alcohol and polyvinyl acetate, or natural phospholipid, such as cephalin and lecithin and synthetic phospholipid can be used in preparation.Other additives can be mineral oil and vegetable oil.

Colouring agent, such as such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue, and organic dyestuff, alizarin dyes, azo dyes and metallized phthalocyanine dye, and micronutrient, such as molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt can be used.

Described composition, wherein compound (A) account for the 5%-90%, more preferably preferably 10%-80%, 10%-60% of composition with the content of compound (B).

Composition of the invention can be used in any commonly employed form.The blade face Exemplary dosage forms of premix composition are：

GR:Granule

WP:Wettable powder

WG:Water dispersibles granula

SG:Soluble granule

SL:Soluble concentrate

EC:Missible oil

EW:Emulsion, aqueous emulsion

ME:Microemulsion

SC:Suspending agent

CS:Microcapsule suspending agent

OD:Oil-based suspension

SE:Suspension emulsion

Meanwhile, the seed treatment Exemplary dosage forms of premix composition are：

WS:Seed Treatment thin pulp wettable powder

LS:Seed Treatment solution

ES:Seed Treatment emulsion

FS:Seed Treatment suspending agent

WG:Water dispersible granules

CS:Microcapsule suspending agent.

The Exemplary dosage forms for being adapted to bucket mixing composition are solution, dilution emulsion, suspending agent or its mixing and pulvis.

According to formulation properties, can with it is anticipated that object and popular environment are selected from application process, such as blade face, be impregnated with, spray, dust, scatter, be coated or irrigate and selected.

Generally, bucket mixing composition is to use solvent（Such as water）Dilution containing different agricultural chemicals, and optionally further auxiliary agent one or more premix composition.

In a way known, using the present composition and diluent in suitable seed coat agent type, such as have the aqueous suspension agent or dry powder doses of preferable seed adhesiveness, seed coat agent is applied to seed.These seed coat agent types are known in the art.

Typically, the bucket mixture of blade face or soil application comprising 0.1%-20%, particularly 0.1%-15% reactive compound, and 99.9%-80%, particularly 99.9%-85% solid-state or liquid flux（Comprising solvent such as water）, wherein auxiliary agent can be the surfactant of content 0-20%, particularly 0.1%-15% based on bucket mixture.

Active compound component of the pre-mixing agent of usual foliage applying comprising 0.1%-99.9%, particularly 1%-95%, and 99.9%-0.1%, particularly 99%-5% solid-state or liquid flux（Comprising such as solvent such as water）, wherein auxiliary agent can be the surfactant of content 0-50%, particularly 0.5%-40% based on pre-mixing agent.

Active compound component of the bucket mixture that general Seed Treatment is applied comprising 0.25%-80%, particularly 1%-75%, and 99.75%-20%, particularly 99%-25% solid-state or liquid flux（Comprising such as solvent such as water）, wherein auxiliary agent can be the surfactant of content 0-40%, particularly 0.5%-30% based on bucket mixture.

Generally, Seed Treatment apply pre-mixing agent comprising 0.5%-99.9%, particularly 1%-95% active compound component, and 99.5%-0.1%, particularly 99%-5% solid-state or liquid assistant agent（Comprising newborn solvent such as water）, wherein auxiliary agent can be that based on pre-mixing agent, content is 0-50%, particularly the surfactant of 0.5%-40%.

Generally, formulated composition of the invention includes 0.5%-99.9%, particularly 1%-95%, it is advantageously that the solid or liquid adjuvants of the active compound component of 1%-50%, and 99.5%-0.1%, particularly 99%-5% mass（Comprising such as solvent such as water）, wherein the auxiliary agent（Or assistant agent）Can be the 0-50% based on pre-mixing agent quality, the particularly surfactant of 0.5%-40%.

Composition of the invention can also itself or be used in mixed way with known fungicide, bactericide, acaricide, nematicide or insecticide with its dosage form, with the generation widened its action spectrum or prevent resistance.

Fungicide：

1. nucleic acid synthetic inhibitor

M 9834 (benalaxyl), smart M 9834 (benalaxyl-M), phonetic bacterium spirit (bupirimate) of sulphur, chiralaxyl, clozylacon, Milcurb (dimethirimol), Milstem (ethirimol), Furalaxyl (furalaxyl), hydroxyisoxazole (hymexazole), Metalaxyl-M (metalaxyl-M), fenfuram (ofurace), Evil frosts spirit (oxadixyl), oxolinic acide (oxolinic acid)

2. mitosis and cell division inhibitor

Benomyl (benomyl), carbendazim (carbendazim), diethofencarb (diethofencarb), furidazol (fuberidazole), Pencycuron (pencycuron), Apl-Luster (thiabendazole), thiophanate methyl (thiophanate-methyl), zoxamide (zoxamide)

3. respiratory chain inhibitor

3.1 composite Is

Fluorine mepanipyrim (diflumetorim)

3.2 Complex IIs

Boscalid (boscalid), carboxin (carboxin), first furan drink aniline (fenfuram), flutolanil (flutolanil), furan pyrazoles spirit (furametpyr), the third oxygen mebenil (mepronil), oxycarboxin (oxycarboxin), pyrrole metsulfovax (penthiopyrad), thifluzamide (thifluzamide)

3.3 Complex II I

Nitrile Fluoxastrobin (azoxystrobin), cyazofamid (cyazofamid), dimoxystrobin (dimoxystrobin), enestrobin, famoxadone (famoxadone), Fenamidone (fenamidone), fluoxastrobin (fluoxastrobin), imines bacterium (kresoxim-methyl), fork phenalgin acid amides (metominostrobin), orysastrobin (orysastrobin), fosthiazate (pyraclostrobin), ZEN 90160 (picoxystrobin)

The even agent of 3.4 solutions

Dinocap (dinocap), fluazinam (fluazinam)

3.5ATP produces inhibitor

Fentinacetate (fentin acetate), Fentin chloride (fentin chloride), fentin hydroxide (fentin Hydroxide), Silthiopham (silthiofam)

4. amino acid and protein biosynthesis inhibitor

Amine puts out (andoprim), blasticidin-S (blasticidin-S), cyprodinil (cyprodinil), kasugarnycin (kasugamycin), the hydrochloride hydrate of kasugarnycin one (kasugamycin hydrochloride hydrate), mepanipyrim (mepanipyrim), pyrimethanil (pyrimethanil)

5. signal transduction inhibitor

Fenpiclonil (fenpiclonil), Fu Evil bacterium (fludioxonil), quinoxyfen (quinoxyfen)

6. lipid and film synthetic inhibitor

Chlozolinate (chlozolinate), isopropyl fixed (iprodione), sterilized profit (procymidone), vinclozolin (vinclozolin)

Ppyrazophos (pyrazophos), Hinosan (edifenphos), IBP (iprobenfos) (IBP), Isoprothiolane (isoprothiolane)

Tolelofos-methyl (tolclofos-methyl), biphenyl

Iodocarb, hundred dimensions clever (propamocarb), the clever mono-hydrochloric salts (propamocarbhydrochloride) of hundred dimensions

7. ergosterol biosynthesis inhibitor

Fenhexamid (fenhexamid)

Penta ring azoles (azaconazole),Bitertanol (bitertanol),Bromuconazole (bromuconazole),Cyproconazole (cyproconazole),Diclobutrazol (diclobutrazole),Difenoconazole (difenoconazole),Olefin conversion (duniconazole),Olefin conversion-M (diniconazole-M),Oxole bacterium (epoxiconazole),Etaconazole (etaconazole),RH-7592 (fenbuconazole),Fluquinconazole (fluquinconazole),Flusilazole (flusilazole),Flutriafol (flutriafol),Furconazole (furconazole),Furconazole_cis (furconazole-cis),Hexaconazole (hexaconazole),Acid amides azoles (imibenconazole),Cycltebuconazole (ipconazole),The azoles bacterium (metconazole) of ring penta,Nitrile bacterium azoles (myclobutanil),Paclobutrazol (paclobutrazol),Penconazole (penconazole),Propiconazole (propiconazole),Prothioconazoles (prothioconazole),Simeconazoles (simeconazole),Tebuconazole (tebuconazole),Fluorine ether azoles (tetraconazole),Triazolone (triadimefon),Triadimenol (triadimenol),Triticonazole (triticonazole),Uniconazole P (uniconazole),Voriconazole (voriconazole),Imazalil (imazalil),IMAZALIL (imazalil Sulphate), dislike imidazoles (oxpoconazole), fenarimol (fenarimol), flurprimidol (flurprimidol), nuarimol (nuarimol), pyrifenox (pyrifenox), triforine (triforine), pefurazoate (pefurazoate), Prochloraz (prochloraz), fluorine bacterium azoles (triflumizole), alkene frost benzene azoles (viniconazole), aldimorph, dodemorph (dodemorph), dodemorph acetate (dodemorph Acetate), butadiene morpholine (fenpropimorph), tridemorph (tridemorph), fenpropidin (fenpropidin), spiroxamines (spiroxamine), Naftifine (naftifine), pyributicarb (pyributicarb), Terbinafine (terbinafine)

8. Cell wall synthesis inhibitor

Benzene metsulfovax (benthiavalicarb), bialaphos (bialaphos), dimethomorph (dimethomorph), flumorph (flumorph), iprovalicarb (iprovalicarb), polyoxin (polyoxins), Polyoxin (polyoxorim), Validacin (Takeda) (validamycin A)

9. melanin biosynthesis inhibitor

Ring propionyl bacterium amine (capropamid), double chlorine zarilamid (diclocymet), fenoxanil (fenoxanil), Rabcide (phthalide), pyroquilon (pyroquilon), compound (A) (tricyclazole)

10. resistance inductors

Diazosulfide (acibenzolar-S-methyl), probenazole (probenazole), tiadinil (tiadinil)

11. compounds with many site activities

Difoltan (captafol), Bravo (chlorothalonil), mantoquita are for example：Kocide SD,Copper naphthenate,COPPER OXYCHLORIDE 37,5 (copper oxychloride),Copper sulphate,Copper monoxide,Copper 8-hydroxyquinolinate (oxine copper) and Bordeaux mixture,Euparen (dichlofluanid),Dithianon (dithianon),Dodine (dodine),Dodine free alkali (dodine free base),Fervam (ferbam),Fluorine folpet (fluorofolpet),Folpet (folpet),Fosetyl (fosetyl-Al),The pungent salt of biguanides (guazatine),Guazatine acetate (guazatine acetate),Iminoctadine (iminoctadine),Double eight guanidinesalts (iminoctadine albesilate),Iminoctadine triacetate (iminoctadine Triacetate), mancopper (mancopper), Mancozeb (mancozeb), maneb (maneb), Carbatene (metiram), Carbatene zinc (metiram-zinc), Propineb (propineb), sulphur and sulphur preparation include calcium polysulfide, thiram (thiram), tolyfluanid (tolylfluanid), zineb (zineb), ziram (ziram)

12. unknown mechanism compounds

amibromdol,Benthiozole (benthiazole),bethoxazin,Capsimycin (capsimycin),Carvol (carvone),Chinomethionat (chinomethionat),Chloropicrin (chloropicrin),Cufraneb (cufraneb),Cyflufenamid (cyflufenamid),Cymoxanil (cymoxanil),Dazomet (dazomet),Debacarb (debacarb),Diclomezin (diclomezine),Antiphen (dichlorophen),Botran (dicloran),Difenzoquat (difenzoquat),Difenzoquat methylsulfuric acid ester (difenzoquat methyl sulphate),Diphenylamines (diphenylamine),Han Lening (ethaboxam),Ferimzone (ferimzone),Fluorine acyl bacterium amine (flumetover),Flusulfamide (flusulfamide),Fluopicolide (fluopicolide),Fluoromide (fluoroimide),Hexachloro-benzene (hexachlorobenzene),8-hydroxyquinoline,People's metamycin (irumamycin),Methasulfocarb (methasulfocarb),Metrafenone (metrafenone),Methyl-isorhodanate (methyl isothiocyanate),Midolthromycin (mildiomycin),Myprozine (natamycin),Sankel (nickeldimethyldithiocarbamate),Nitrothalisopropyl (nitrothal-isopropyl),Different thiophene bacterium ketone (octhilinone),oxamocarb,oxyfenthiin,Pentachlorophenol (pentachlorophenol) and its salt,2- phenylphenols and its salt,Pipron (piperalin),propanosine-sodium,The third oxygen quinoline (proquinazid),Pyrroles's rhzomorph (pyrrolnitrin),Pentachloronitrobenzene (quintozene),Tecloftalam (tecloftalam),Tecnazene (tecnazene),Azoles bacterium piperazine (triazoxide),Trichlamide (trichlamide),Zarilamid (zarilamid) and 2,3,5,6- tetra- chloro- 4- (methyl sulphonyl) pyridine,N- (the chloro- 2- nitrobenzophenones of 4-)-N- ethyl -4- methyl benzenesulfonamides,2- amino -4- Methyl-N-phenyl -5- thiazole carboxamides,The chloro- N- (2 of 2-,3- dihydros -1,1,3- trimethyl -1H- indenes -4- bases)-Niacinamide,3- [5- (4- chlorphenyls) -2,3- dimethyl isoxazole alkane -3- bases] pyridine,Cis- 1- (4- chlorphenyls) -2- (1H-1,2,4- triazol-1-yls) suberol,2,4- dihydro -5- methoxyl group -2- methyl -4- [[[[1- [3- (trifluoromethyl) phenyl] ethylidene] amino] epoxide] methyl] phenyl] -3H-1,2,3- triazole -3- ketone (185336-79-2),1-(2,3- dihydros -2,2- dimethyl -1H- indenes -1- bases) -1H- imidazole-5-carboxylic acid methyl esters,3,4,5- tri- chloro- 2,6- pyridine dintrile,2- [[[cyclopropyl-[(4- methoxyphenyls) imino group] methyl] sulfenyl] methyl]-α-(methoxymethylene) methyl benzylacetate,The chloro- α of 4--propargyl alcoholate-N- [2- [3- methoxyl groups -4- (2- propargyl alcoholates) phenyl] ethyl] phenyl acetamide,(2S)-N- [2- [4- [[3- (4- chlorphenyls) -2-propynyl] oxygen] -3- methoxyphenyls] ethyl] -3- methyl -2- [(methyl sulphonyl) amino] butyramide,The chloro- 7- of 5- (4- methyl piperidine -1- bases) -6- (2,4,6- trifluorophenyls) [1,2,4] triazol [1,5-a] pyrimidine,The chloro- 6- (2 of 5-,4,6- trifluorophenyls)-N- [(1R) -1,2,2- thmethylpropyls] [1,2,4] triazol [1,5-a] pyrimidine -7- amine,The chloro- N- of 5- [(1R) -1,2- dimethyl propyls] -6- (2,4,6- trifluorophenyls) [1,2,4] triazol [1,5-a] pyrimidine -7- amine,N- [1- (the bromo- 3- chloro-pyridines -2- bases of 5-) ethyl] -2,The chloro-nicotinamides of 4- bis-,N- (the bromo- 3- chloro-pyridines -2- bases of 5-) methyl -2,The chloro-nicotinamides of 4- bis-,The iodo- 3- propyl group chromene -4- ketone of 2- butoxy -6-,N- { (Z)-[(cyclo propyl methoxy) imino group] [6- (difluoro-methoxy) -2,3- difluorophenyls] methyl } -2- phenyl acetamides,N- (3- ethyls -3,5,5- trimethylcyclohexyls) -3- Formylaminos -2-Hydroxylbenzamide,2- [[[[1- [3- (the fluoro- 2- phenylethyls of 1-) epoxide] phenyl] ethylidene] amino] epoxide] methyl]-α-(methoxyimino)-N- methyl-α E- phenyl acetamides,N- { 2- [3- chloro- 5- (trifluoromethyl) pyridine -2- bases] ethyl } -2- (trifluoromethyl) benzamide,N-(3′,4 '-two chloro- 5- fluorine xenyl -2- bases) -3- (difluoromethyl) -1- methyl isophthalic acid H- pyrazole-4-carboxamides,N- (6- methoxyl group -3- pyridine radicals) cyclopropane carboxamide,1- [(4- methoxyphenoxies) methyl] -2,2- dimethyl propyl -1H- imidazoles -1- carboxylic acids,O- [1- [(4- methoxyphenoxies) methyl] -2,2- dimethyl propyls] -1H- imidazoles -1- carbothioic acids,2- (2- { [6- (3- chloro-2-methyls phenoxy group) -5-FU -4- bases] epoxide } phenyl) -2- (methoxyimino)-N- methylacetamides

Bactericide：

Bronopol (bronopol), antiphen, trichloromethyl pyridine (nitrapyrin), good fortune magnesium nickel (nickel dimethyldithiocarbamate), kasugarnycin, different thiophene bacterium ketone (octhilinone), carboxylic acid furans (furancarboxylic Acid), terramycin (oxytetracyclin), probenazole, streptomysin (streptomycin), tecloftalam, copper sulphate and other copper agents.

Insecticide / Acaricide / Nematicide：

1. acetylcholinesterase (AChE) inhibitor

1.1 carbamates are (for example,Alanycarb (alanycarb),Aldicarb (aldicarb),Sulfone goes out prestige (aldoxycarb),Allyxycarb (allyxycarb),Aminocarb (aminocarb),Azamethiphos (azamethiphos),Evil worms prestige (bendiocarb),Benfuracard micro (benfuracarb),Must gram lice (bufencarb),Butacarb (butacarb),Fourth pitches prestige (butocarboxim),Oxygen fourth pitches prestige (butoxycarboxim),Sevin (carbaryl),Furadan (carbofuran),Carbosulfan (carbosulfan),Cloethocarb (chloethocarb),Resistox (coumaphos),Surecide (cyanofenphos),Cynock (cyanophos),Dimetilan (dimetilan),Benzene worm prestige (ethiofencarb),Osbac (fenobucarb),Fenothiocarb (fenothiocarb),Carzol (formetanate),Furathiocarb (furathiocarb),Mobucin (isoprocarb),Metham-sodium (metam-sodium),Mercaptodimethur (methiocarb),Methomyl (methomyl),MTMC (metolcarb),Methomyl (oxamyl),Aphox (pirimicarb),Carbamult (promecarb),Arprocarb (propoxur),UC-51762 (thiodicarb),Special ammonia pitches prestige (thiofanox),Triaguron (triazamate),Landrin (trimethacarb),XMC,Meobal (xylylcarb))

1.2 organophosphorus compoundses are (for example,Accephate (acephate),Azoles pyridine phosphorus (azamethiphos),Azinphos-methyl (azinphos-methyl),Triazotion (azinphos-ethyl),Rilariol (bromophos-ethyl),Bromobenzene alkene phosphorus (bromfenvinfos (- methyl)),Special Pyrimitate (butathiofos),Cadusafos (cadusafos),Carbophenothion (carbophenothion),Earth worm chlorine phosphorus (chlorethoxyfos),Chlorfenviphos (chlorfenvinphos),Chlormephos (chlormephos),Chlorpyrifos-methyl (chlorpyrifos-methyl),Ethyl chlopyrifos,Resistox (coumaphos),Surecide (cyanofenphos),Cynock (cyanophos),Chlorfenviphos (chlorfenvinphos),The O nine (demeton-s-methyl) of methyl one,Dioxydemeton-s-methyl (demeton-s-methylsulphon),Torak (dialifos),Basudin (diazinon),Dichlofenthion (dichlofenthion),DDVP (dichlorvos)/DDVP,Carbicron (dicrotophos),Rogor (dimethoate),Dimethylvinphos (dimethylvinphos),Salithion (dioxabenzofos),Disulfoton (disulfoton),EPN,Ethodan (ethion),Ethoprop (ethoprophos),Oxygen Diothyl (etrimfos),Dovip (famphur),Nemacur (fenamiphos),Folithion (fenitrothion),Fensulfothion (fensulfothion),Entex (fenthion),Flupyrazofos-containpesticide (flupyrazofos),Dyfonate (fonofos),Peace fruit (formothion),Fosmethilan (fosmethilan),Thiazolone phosphorus (fosthiazate),Worm phosphorus in heptan (heptenophos),Iodfenphos (iodofenphos),IBP (iprobenfos),Fluorine azoles phosphorus (isazofos),Propylamine phosphorus (isofenphos),O- isopropyl salicylates,Isoxazoline (isoxathion),Marathon (malathion),Afos (mecarbam),Methacrifos (methacrifos),Acephatemet (methamidophos),Methidathion (methidathion),Menite (mevinphos),Azodrin (monocrotophos),2-dichloroethylk dimethyl phosphate (naled),Flolimat (omethoate),Metilomerkaptofosoksid (oxydemeton-methyl),Parathion-methyl (parathionmethyl),Parathion (parathion-ethyl),Phenthoate dimephenthoate cidial (phenthoate),Phorate (phorate),Zolone (phosalone),Phosmet (phosmet),Phosphamidon (phosphamidon),Second the third phosphorus prestige (phosphocarb),Phoxim (phoxim),Actellic (pirimiphos methyl),Pirimiphos ethyl (pirimiphos ethyl),Profenofos (profenofos),Kayaphos (propaphos),Propetamphos (propetamphos),Toyodan (prothiofos),Fac (prothoate),Pyraclofos (pyraclofos),Ofunack (pyridaphenthion),pyridathion,Quinalphos (quinalphos),Cadusafos (sebufos),Thiotep (sulfotep),Second Toyodan (sulprofos),Tebupirimphos (tebupirimphos),Swebate (temephos),Terbufos (terbufos),Ravap (tetrachlorvinphos),Thiometon (thiometon),Hostathion (triazophos),Metrifonate (triclorfon),Kilval (vamidothion))

2. sodium channel modulators/potential gate (voltage-gated) sodium channel blockers

2.1 pyrethroids are (for example,Fluorine ester chrysanthemum ester (acrinathrin),(d- is cis- anti-for Pynamin,D- is anti-) (allethrin (d-cis-trans,d-trans)),β-cyfloxylate (beta-cyfluthrin),Bifenthrin (bifenthrin),Dtrans allethrin (bioallethrin),Dtrans allethrin-S- cyclopenta-isomers,bioethanomethrin,Biopermethrin (biopermethrin),Bioresmethrin (bioresmethrin),chlovaporthrin,Cis- cypermethrin,Cis- Chryson (cis-resmethrin),Cis- Permethrin (cis-permethrin),Cyhalothrin (clocythrin),Cycloprothrin (cycloprothrin),Cyfloxylate (cyfluthrin),Lambda-cyhalothrin (cyhalothrin),Cypermethrin (α-,β-,θ-,ζ-)(cypermethrin(alpha-,beta-,theta-,zeta-)),Phenylate Permethrin (cyphenothrin),DDT,Decis (deltamethrin),Prallethrin (1R- isomers) (empenthrin (1R-isomer)),Esfenvalerate (esfenvalerate),Ethofenprox (etofenprox),Fenfluthrin (fenfluthrin),Fenpropathrin (fenpropathrin),Fenpirithrin (fenpyrithrin),Kill chrysanthemum ester (fenvalerate),Brofluthrinate (flubrocythrinate),Flucythrinate (flucythrinate),The benzyl oxide of fluorine third (flufenprox),Flumethrin (flumethrin),Taufluvalinate (fluvalinate),fubfenprox,Gamma-cyhalothrin (gamma-cyhalothrin),Imiprothrin (imiprothrin),Kadethrin (kadethrin),λ-lambda-cyhalothrin (lambda-cyhalothrin),Metofluthrin (metofluthrin),Permethrin is (cis-,It is trans-),Phenothrin (1R- transisomers) (phenothrin (1R-trans isomer),Prallethrin (prallethrin),Third Flumethrin (profluthrin),protrifenbute,Anti- Chryson (pyresmethrin),Chryson,RU-15525,Deinsectization silicon ether (silafluofen),Taufluvalinate (tau-fluvalinate),Tefluthrin (tefluthrin),Terallethrin (terallethrin),Tetramethrin (1R- isomers) (tetramethrin (1R-isomer)),Tralomethrin (tralomethrin),Transfluthrin (transfluthrin),ZXI 8901st, pyrethrin (pyrethrins) (Dalmatian chrysanthemum (pyrethrum)))

2.2 oxadiazine class (oxadiazines) (Li such as oxadiazole worm (indoxacarb))

3. acetyl choline receptor agonists/antagonist

3.1 chlorine nicotine base class (chloronicotinyls)/anabasine (neonicotinoids) (for example, acetamiprid (acetamiprid), clothianidin (clothianidin), MTI-446 (dinotefuran), imidacloprid (imidacloprid), nitenpyram (nitenpyram), Nithiazine (nithiazine), thiacloprid (thiacloprid), Diacloden (thiamethoxam))

3.2 nicotine (nicotine), bensultap (bensultap), Padan (cartap)

4. acetylcholine receptor modulators

4.1spinosyn classes (such as spinosad (spinosad))

5.GABA gates chloride channel antagonist

5.1 cyclopentadiene organochlorine class (for example, toxaphene (camphechlor), Niran (chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), lindane (gamma-HCH), HCH, heptachlor (heptachlor), lindane (lindane), methoxychlor (methoxychlor))

5.2fiprole classes (for example, second phthalein worm eyeball (acetoprole), ethiprole (ethiprole), Frontline (fipronil), fluorine pyrazoles worm (vaniliprole))

6. chloride channel activator class

6.1Mectin classes are (for example, AVM (abamectin, avermectin), emaricin (emamectin), emaricin benzoate (emamectin-benzoate), ivermectin (ivermectin), milbemectin (milbemectin), milbemycin (milbemycin))

7. juvenile hormone mimics (mimetic) class

(such as , Evil cyclopentadienyls ether (diofenolan), the young ether (epofenonane) of guarantor, ABG-6215 (fenoxycarb), Entocon ZR 512 (hydroprene), 7 (kinoprene) of illiteracy, Entocon ZR 515 (methoprene), pyriproxyfen (pyriproxifen), triprene (triprene))

8. ecdysone agonist/agent interfering class

8.1 diacyl hydrazines (for example, ring tebufenozide (chromafenozide), Benzoic acid N-tert-butyl-N-(4-chlorobenzoyl)hydrazide (halofenozide), Runner (methoxyfenozide), RH-5992 (tebufenozide))

9. benzoylurea derivertives

9.1 benzoyl area kinds are (for example, bistrifluron (bistrifluron), UC 62644 (chlofluazuron), TH-6040 (diflubenzuron), fluorine fluazuron (fluazuron), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), HEXAFLUMURON (hexaflumuron), fluorine the third oxygen urea (lufenuron), Rimon (novaluron), noviflumuron (noviflumuron), penfluron (penfluron), volt worm phosphorus (teflubenzuron), desinsection is grand (triflumuron))

9.2 Buprofezins (buprofezin)

9.3 cyromazines (cyromazine)

10. oxidative phosphorylation inhibitors class, ATP agent interfering classes

10.1 mite killing sulphur are grand (diafenthiuron)

10.2 organic tins (such as azoles ring tin (azocyclotin), plictran (cyhexatin), fenbutatin oxide (fenbutatin-oxide))

11. oxidative phosphorylations worked by being interrupted H- proton gradients are uncoupled agent class

11.1 pyroles (such as chlorfenapyr (chlorfenapyr))

11.2 dinitrophenolses (such as binapacryl (binapacryl), dinobuton (dinobuton), dinocap (dinocap), DNOC)

12. site-I electron transfer inhibitors classes

12.1METI classes (such as fenazaquin (fenazaquin), fenpyroximate (fenpyroximate), pyramine phenylate (pyrimidifen), pyridaben (pyridaben), tebufenpyrad (tebufenpyrad), Tolfenpyrad (tolfenpyrad))

12.2 amdros (hydramethylnone)

12.3 Mitigans (dicofol)

13. site-II electron transfer inhibitors classes

13.1 rotenone (rotenone)

14. site-III electron transfer inhibitors classes

14.1 acequinocyls (acequinocyl), fluacrypyrim (fluacrypyrim)

15. insect gut membrane micro agent interfering classes

Dipel (Bacillus thuringiensis) bacterial strain

16. Fatty synthesis inhibitor classes

16.1 tetronic acid classes (for example, Envidor (spirodiclofen), Spiromesifen (spiromesifen))

16.2 tetramates acids (tetramic acids) (for example, 3- (2,5- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1- azaspiro [4.5] decyl- 3- alkene -4- base ethyl carbonates ester (also known as：Carbonic acid 3- (2,5- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1- azaspiro [4.5] decyl- 3- alkene -4- base ethyl esters, CAS Registry Number：382608-10-8) and the cis- 3- of carbonic acid (2,5- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1- azaspiro [4.5] decyl- 3- alkene -4- base ethyl ester (CAS Registry Numbers：203313-25-1))

17. benzamide types

(such as flonicamid (flonicamid))

18. octopaminergic agonist classes

(such as amitraz (amitraz))

The atpase inhibitor class that 19. magnesium stimulate

(such as propargite (propargite))

20. phthalyl amines

(such as N2- [1,1- dimethyl -2- (methyl sulphonyl) ethyl] iodo- N1- of -3- [2- methyl -4- [1,2,2,2- tetra- fluoro- 1- (trifluoromethyl) ethyl] phenyl] -1,2- benzenedicarboxamide (CAS Registry Numbers：272451-65-7), Flubendiamide (flubendiamide))

21. nereistoxins are similar to thing

(for example sulphur grants peace (thiocyclam hydrogen oxalate), dimehypo (thiosultap-sodium))

22. biological agent classes, steroids or pheromones class

(for example, Ai Zhading (azadirachtin), Bacillus kind (Bacillus spec.), stiff Pseudomonas kind (Beauveria Spec.), Pherocon CM (Codlemone), Metarhizium Species (Metarrhizium spec.), paecilomyces kind (Paecilomyces Spec.), thuringiensin (Thuringiensin), Verticillium dahliae category kind (Verticillium spec.))

23. have unknown or pending activity mechanism active ingredient species

23.1 fumigant classes (for example, aluminum phosphate, a bromomethane, vikane)

23.2 selective anti-feedant class (for example, ice crystal, flonicamid (flonicamid), pymetrozine (pymetrozine))

23.3 mite growth inhibitor classes (for example, clofentezine (clofentezine), Te Ben oxazoles (etoxazole), Hexythiazox (hexythiazox))

23.4amidoflumet,benclothiaz,Citrazon (benzoximate),Bifenazate (bifenazate),Fenisobromolate (bromopropylate),Buprofezin (buprofezin),Quinomethionate (chinomethionat),Spanon (chlordimeform),Chlorobenzilate (chlorobenzilate),Chloropicrin (chloropicrin),clothiazoben,cycloprene,cyflumetofen,Dicyclanil (dicyclanil),fenoxacrim,Fluorine nitre diphenylamines (fentrifanil),Thiazole mite (flubenzimine),flufenerim,Flutiazin (flutenzin),Gossyplure (gossyplure),Amdro (hydramethylnone),japonilure,Metoxadiazone (metoxadiazone),Oil,Piperonyl butoxide (piperonyl Butoxide), potassium oleate, pyrafluprole, pyridalyl (pyridalyl), pyriprole, sulfluramid (sulfluramid), tetradiphon (tetradifon), Diphenylsulfide (tetrasul), benzene match mite (triarathene), verbutin (verbutin)

With the mixture of other known reactive compound such as herbicide, it is or also possible with the mixture of fertilizer and growth regulator, safener and/or semiochemical.

Crop disease and insect of the invention prevents and kill off composition for preventing and treating the purposes of fungi and bacterium.

Crop disease and insect of the invention prevents and kill off composition for preventing and treating the purposes of fruit tree kind, vegetables, cotton, flowers, tea tree, cereal crops fungi and bacterium.

Pest and disease damage of the invention prevents and kill off composition and kills microbial activity with effective, and can be used to prevent and treat undesired microorganism, such as fungi and bacterium in crop protection or material protection.

Crop disease and insect of the invention prevents and kill off composition has extraordinary fungicide performance, and can be used for preventing and treating phytopathogenic fungi, such as plasmodiophora brassicae (Plasmodiophoromycetes), oomycetes (Oomycetes), chytrid (Chytridiomycetes), zygomycete (Zygomycetes), sac fungus (Ascomycetes), basidiomycetes (Basidiomycetes) and Fungi Imperfecti (Deuteromycetes).

Crop disease and insect of the invention prevents and kill off composition has extraordinary bactericidal performance, and can be used for preventing and treating phytopathogenic bacteria.Such as prevent and treat pseudomonas (Pseudomonadaceae), rhizobium (Rhizobiaceae), enterobacteria (Enterobacteriaceae), bar bacterium (Corynebacteriaceae) and streptomycete (Streptomycetaceae).

It is as follows that crop disease and insect of the invention prevents and kill off some pathogen for causing fungal disease and bacteriosis for being included into generic name listed above of composition for that can be referred to as example but without limitation in crop protection：

The disease caused by powdery mildew pathogen, the pathogen is for example

Blumeria (Blumeria) strain, such as grass family dlumeria graminis (Blumeriagraminis)；

Podosphaera (Podosphaera) strain, such as white cross hair list softgel shell (Podosphaera leucotricha)；

Sphaerotheca (Sphaerotheca) strain, such as balsamine list softgel shell (Sphaerothecafuliginea)；

Uncinula (Uncinula) strain, such as grape snag shell (Uncinula necator)；

The disease caused by rust pathogen, the pathogen is for example

Glue Rust (Gymnosporangium) strain, such as Gymnosporangiumsabinae；

Hunchbacked spore rust category (Hemileia) strain, such as coffee rust (Hemileiavastatrix)；

Layer rest fungus (Phakopsora) strain, such as Phakopsora pachyrhizi (Phakopsorapachyrhizi) and mountain horseleech layer bacterium (Phakopsora meibomiae)；

Handle rest fungus (Puccinia) strain, such as Puccinia recondita (Pucciniarecondita)；

Uromyces (Uromyces) strain, such as wart top uromyce (Uromycesappendiculatus)；

The disease caused by Oomycete (Oomycetene) class pathogen, the pathogen is for example

Disk downy mildew (Bremia) strain, such as lettuce disk downy mildew (Bremia lactucae)；

Downy mildew (Peronospora) strain, such as pea downy mildew (Peronospora pisi) or Cruciferae downy mildew (P.brassicae)；

Phytophthora (Phytophthora) strain, such as phytophthora infestans (Phytophthorainfestans)；

Axle downy mildew (Plasmopara) strain, such as grape give birth to axle downy mildew (Plasmoparaviticola)；

False downy mildew (Pseudoperonospora) strain, such as grass vacation downy mildew (Pseudoperonospora humuli) or Pseudoperonospora cubensis (Pseudoperonosporacubensis)；

Rotten mould (Pythium) strain, such as Pythium ultimum (Pythium ultimum)；

Leaf spot blight and leaf withering the disease disease caused by for example following pathogen,

Alternaria (Alternaria) strain, such as early blight rod method (Alternariasolani)；

Cercospora (Cercospora) strain, Li such as Chard dishes give birth to tail spore (Cercosporabeticola)；

Cladiosporum strains, such as Cladiosporium cucumerinum；

Cochliobolus belongs to (Cochliobolus) strain, such as standing grain cochliobolus (Cochliobolussativus)

(conidial form：Drechslera, Syn：Helminthosporium)；

Colletotrichum (Colletotrichum) strain, such as Colletotrichumlindemuthanium；

Cycloconium strains, such as Cycloconium oleaginum；

Between seat shell category (Diaporthe) strain, such as seat shell (Diaporthe citri) between citrus；

Elsinoe (Elsinoe) strain, such as citrus Elsinochrome (Elsinoefawcettii)；

Disk spore category (Gloeosporium) strain long, for example, please colour disk spore long (Gloeosporiumlaeticolor)；

Small cluster shell belongs to (Glomerella) strain, such as GLOMERFLLA CINGULATA (Glomerellacingulata)；

Ball seat Pseudomonas (Guignardia) strain, such as grape Guignardia (Guignardiabidwelli)；

Leptosphaeria (Leptosphaeria) strain, such as Leptosphaeriamaculans；

Magnaporthe strains, such as Magnaporthe grisea；

Mycosphaerella (Mycosphaerella) strain, such as Fijian spherical cavity bacterium (Mycosphaerella fijiensis)；

Phaeosphaeria strains, such as Phaeosphaeria nodorum；

Nuclear cavity Pseudomonas (Pyrenophora) strain, for example, justify nuclear cavity bacteria (Pyrenophorateres)；

Ramularia (Ramularia) strain, such as Ramularia collo-cygni；

Beak genuss (Rhynchosporium) bacterium, such as rye beak spore (Rhynchosporiumsecalis)；

Pin spore belongs to (Septoria) strain, such as Septoria apii (Septoriaapii)；

Core coral Pseudomonas (Typhula) strain, such as meat spore core coral bacterium (Typhulaincarnata)；

Venturia (Venturia) strain, such as apple black star bacteria (Venturiainaequalis)；

The root and stem disease caused by for example following pathogen do harm to,

Corticium strains, such as Corticium graminearum；

Fusarium (Fusarium) strain, such as sharp fusarium (Fusarium oxysporum)；

Gaeumannomyces strains, such as Gaeumannomyces graminis；

Rhizoctonia (Rhizoctonia) strain, such as Rhizoctonia solani Kuhn (Rhizoctoniasolani).

Tapesia strains, such as Tapesia acuformis；

Thiclaviopsis (Thielaviopsis) strain, such as thielaviopsis sp (Thielaviopsisbasicola)；

The spadix and panicled spike (including corncob) disease caused by for example following pathogen,

Alternaria strain, such as Alternaria kind (Alternaria spp.)；

Aspergillus (Aspergillus) strain, such as aspergillus flavus (Aspergillus flavus)；

Cladosporium strains, such as Cladosporium spp.；

Claviceps (Claviceps) strain, such as ergot (Claviceps purpurea)；

Fusarium strain, such as yellow fusarium (Fusarium culmorum)；

Gibberella (Gibberella) strain, such as Gibberella zeae (Gibberella zeae)；

Monographella strains, such as Monographella nivalis；

The disease caused by smut, the smut is for example

Sphacelotheca strains, such as Sphacelotheca reiliana；

Tilletia (Tilletia) strain, such as Tilletia caries (Tilletiacaries)；

Urocystis (Urocystis) strain, such as hidden bar smut (Urocystisocculta)；

Smut (Ustilago) strain, such as naked smut (Ustilago nuda)；

The fruit rot caused by for example following pathogen,

Aspergillus bacterium, such as aspergillus flavus；

Botrytis (Botrytis) strain, such as Botrytis cinerea (Botrytiscinerea)；

Penicillium (Penicillium) strain, such as penicillium expansum (Penicilliumexpansum)；

Sclerotinia (Sclerotinia) strain, such as sclerotinite (Sclerotiniasclerotiorum)；

Verticilium strains, such as Verticilium alboatrum；

It is that the kind caused by for example following pathogen is passed and that soil is passed to rot and wilting disease and seedling disease,

Fusarium strain, such as yellow fusarium；

Phytophthora strain, such as Phytophthora cactorum (Phytophthora cactorum)；

Pythium spp kind, such as Pythium ultimum；

Rhizoctonia strain, such as Rhizoctonia solani Kuhn；

Bulbil belongs to (Sclerotium) strain, such as Sclerotium rolfsii (Sclerotiumrolfsii)；

Carcinous disease, mycoceicidum and the witches' broom caused by for example following pathogen,

Nectria strains, such as Nectria galligena；

The wilting disease caused by for example following pathogen,

Chain sclerotinia sclerotiorum belong (Monilinia) strain, such as drupe chain sclerotinia sclerotiorum (Monilinialaxa)；

The deformity of the leaf, flower and the fruit that are caused by for example following pathogen,

Exoascus (Taphrina) strain, such as peach external capsule bacterium (Taphrina deformans)；

The degeneration disease of the xylophyta caused by for example following pathogen,

Esca strains, such as Phaemoniella clamydospora；

The flower and the disease of seed caused by for example following pathogen,

Botrytis strain, such as Botrytis cinerea；

The plant tuber disease caused by for example following pathogen,

Rhizoctonia strain, such as Rhizoctonia solani Kuhn；

The disease caused by for example following bacterial pathogens：

Xanthomonas (Xanthomonas) strain, such as rice leaf spot bacteria (Xanthomonas campestris pv.oryzae)；

Pseudomonad (Pseudomonas) strain, such as pseudomonas syringae (Pseudomonassyringae pv.lachrymans)；

Erwinia (Erwinia) strain, such as pears fire vaccine (Erwinia amylovora)；

By the fungal disease of leaf, stem, beanpod and seed caused by following pathogen, for example：

Wheel line leaf spot (alternaria leaf spot) (Alternaria Spec.atranstenuissima), anthracnose (anthracnose) (Colletotrichumgloeosporoides Dematium var.truncatum), brown spot (brown spot) (Soybean Brown Spot line septoria musiva (Septoria glycines)), peach leaf shothole disease and leaf blight (cercospora Leaf spot and blight) (Kikuchi tail spore (Cercosporakikuchii)), choanephora leaf blights (Choanephora Infundibuliferatrispora (syn.)), dactuliophora leaf spots (Dactuliophora glycines), downy mildew (downy Mildew) (northeast downy mildew (Peronospora manshurica)), drechslera blight (Drechslera glycini), frog eye (frogeye leafspot) (soybean tail spore (Cercospora Sojina)), Kidney bean leaf spot (leptosphaerulina leaf Spot) (Leptosphaerulina trifolii), phyllosticta leaf spot (phyllostica Leaf spot) (soybean give birth to phyllosticta (Phyllostictasojaecola)), powdery mildew (powdery mildew) (Microsphaera diffusa), pyrenochaeta leaf spots (Pyrenochaeta Glycines), sclerotium aerial part droop (aerial blight), leaf blight and damping-off (Rhizoctonia solani Kuhn), rust (Phakopsora pachyrhizi (Phakopsora Pachyrhizi)), scab (scab) (soybean scab circle spore (Sphaceloma Glycines)), stemphylium leaf blights (handle of crawling is mould (Stemphyliumbotryosum)), target (target spot) (Corynespora cassicola).

Crop disease and insect of the invention shows particularly advantageous effect when preventing and kill off composition for such as following plant：Cereal such as wheat,Oat,Barley,Spelt (spelt),Triticale and rye,And corn,Jowar and chestnut,Rice,Sugarcane,Soybean,Sunflower,Potato,Cotton,Rape (oil seed rape),Canola (canola),Tobacco,Beet,Fodder beet,Asparagus,Hops and fruit bearing plant (including the operatic circle such as apple and pears,Drupe such as peach,Honey peach,Cherry,Plum,Apricot,Cedra fruits such as orange,Grape cypress,Bitter orange,Cumquat,Oranges and tangerines and Sa Mo tangerines,Nut such as almond,Walnut and pecan,Tropical fruit (tree) such as mango,Papaya,Pineapple,Nipa palm and banana,And grape) and vegetables (including leaf vegetables such as hare's-lettuce,Corn salad,Fennel,Leaf lettuce,Celery lettuce,Swiss chard,Spinach and salad use witloof,Wild cabbage such as cauliflower,Broccoli,Chinese leaf,Brassica Oleracea (L.) convar. acephalavar. sabellicaL. (savoy, collard), kohlrabi, brussels sprout, red cabbage, white cabbage and savoy, fruit vegetables such as eggplant, cucumber, capsicum, edible squash, tomato, bush pumpkin and corn, root vegetables such as celeriac, rape, carrot include that yellow cultivars, wild radish class include Raphanus sativus var. niger and Raphanus Sativus var.radicula, beet, celery, legume such as pea and soybean, and allium vegetables such as leek and onion.

Crop disease and insect of the invention prevents and kill off composition and is particularly suitable for preventing and treating citrus scab, resin disease, routed tuberculosis, foot rot, bacterial blight of rice, bacterial stripe, rice blast, banded sclerotial blight, target, late blight, brassicaceous vegetable black spot, black rot, carrot leaf pinta, celery bacterial speck, early blight, spot blight, eggplant early blight, anthracnose, brown spot, common bacterial blight of bean, green onion class purple spot, downy mildew, pepper bacterial leaf spot, cucumber bacterial angular leaf spot, muskmelon downy mildew, reticulate pattern disease, grapevine anthracnose, powdery mildew, downy mildew, leaf spot of peanut, tea tree anthracnose, net cake disease, dish soft rot.

Crop disease and insect of the present invention prevents and kill off composition and is particularly suitable for preventing and treating pepper bacterial leaf spot, cucumber bacterial angular leaf spot, dish soft rot, Cucumber wilt.

Crop disease and insect of the present invention is prevented and kill off composition and is particularly well suited for use in vinegrowing, fruit cultivation, crop cultivation, vegetable growing and legume cultivation.

Crop disease and insect of the invention prevents and kill off composition with extremely excellent insecticidal properties.Composition of the invention is all effective generally for sensitive and resistant species and whole or single stage of development.The insect is included for example：

From Isopoda, such as damp worm（Oniscus aselluse）, pillworm（Armadillidium vulgare）, and spot pillworm（Porcellio scaber）.

From Diplopoda, such as Blaniuus guttulatus.

From chilopoda, such as centipede（Geophilus carpophagus）With common house centipede dragonfly（Scutigera spp.）.

From Symphyla, such as clean symphilid（Scutigerella immaculate）.

From Thysanoptera, such as silverfiss（Lepisma saccharina）.

From Collembola, such as Onychiurus arcticus（Onychiurus armatus）.

From Orthoptera, such as house cricket found in a kitchen（Acheta domesticus）, Gryllotalpa spp（Gryllotalpa spp.）, tropical migratory locusts（Locusta migratoria migratorioides）, the negative locust category of volume long（Melanoplus spp.）, and desert locust（Schistocerca gregaria）.

From Blattaria, such as oriental cockroach（Blatta orientalis）, American cockroach（Periplaneta Americana）, leucophaea maderae（Leucophaea maderae）, Groton bug（Blattella germanica）.

From Dermaptera, such as European earwig（Forficula auricularia）.

From Isoptera, such as Reticulitermes.

From Anoplura, such as body louse（Pediculus humanus corporis）, blind pediculus, and volume Pediculus long, Trichodectes, Damalinia.

From Thysanoptera, such as greenhouse Hercinothrips spp（Hercinothrips femoralis）, cotton thrips（Thrips tabaci）, Thrips palmi and Frankliniella accidentalis.

From Heteroptera, such as Eurygasterspp category, middle red cotton bug（Dysdercus intermedius）, beet plan lace bug（Piesma quadrata）, the smelly stinkbug in temperate zone（Cimex lectularius）, red abdomen hunts stinkbug（Rhodnius prolixus）And Triatoma.

From Homoptera, such as wild cabbage aleyrodid（Aleurodes brassicae）, Bemisia tabaci（Bemisia tabaci）, Trialeurodes vaporariorum Westwood（Trialeurodes vaporariorum）, cotten aphid（Aphis gossypii）, brevicoryne brassicae（Brevicoryne brassicae）, the hidden knurl volume aphid of tea deer（Cryptomyzus ribis）, black bean aphid（Brevicoryne brassicae）, apple aphid（Aphispomi）, apple aphid（ Eriosoma lanigerum）, mealy plum aphid（Hyalopterus arundinis）, grape phylloxera（Phylloxera vastatrix）, Pemphigus, grain aphid (Macrosiphum Avenae), knurl volume Aphis, hops knurl volume aphid (Phorodon humuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper category, Euscelisbilobatus, rice green leafhopper (Nephotettix Cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiel1a Aurantii), oleander justifies a red-spotted lizard (Aspidiotus hederae), mealybug category and Psylla spp.

From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus piniarius), winter geometrid moth (Chemimatobia ), brumata Lithoclletis blancardela, cherry ermine moth（Hyponomeuta padella）, diamondback moth (Plutella Xylostel1a), tent caterpillar (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix Thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, cutworm belongs to, brown Noctua, earias insulana (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid (Panolis Flammea), Noctua, cabbage looper (Trichoplusiani), carpocapsa pononella (Carpocapsa pomonella), Pier, snout moth's larva belongs to Pyrausta Nubilalis, Anagasta kuehniella (Ephestia kuehniella), rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineola Bisselliella), etting moth (Tineapell ionel1a), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), the slow-witted moth moth (Clysia of grape Ambiguel1a), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), volume snout moth's larva category, Oulema oryzae (Oulema oryzae)。

From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides Obtectus), house longhorn beetle (Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug (Leptinotarsadecemlineata) , horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, rape orchid flea beetle (Psylliodes chrysocephala), mexican bean ladybird (Epi1achna varivestis), hidden wing first category, saw-toothed grain beetle (Oryzaephilus Surinamensis), weevil category, Sitophilus, vine black ear is as (Otiorrhynchus Sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hypera Postica), khapra beetle category, spot khapra beetle category, Anthrenus, the moth-eaten category of hair, the moth-eaten category of powder, pollen beetle (Meligethes Aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebrio Molitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolontha Melolontha), June chafer (Amphimallon solstitialis), brown New Zealand's rib wing gill cockchafer (Costelytrazealandica) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus)

From Hymenoptera, such as Neodiprion spp category, tenthredinidae, field ant category, MonomoriumMayr (Monomorium ) and Vespa pharaonis

From Diptera, such as Aedes, Anopheles, Culex, drosophila yellow gorilla (Drosophila Melanogaster), Musca, male servant fly category, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata category, Carysomyia, cuterbrid belongs to, Gasterophilus, Hippobosca, chela fly belongs to, nose fly category, Hypoderma, Pituophis, Tannia belongs to, Bibio hortulanus, Sweden straw rope (Oscinella Frit), wheat fly category, beet fly (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), dacus oleae (Dacusoleae) With European daddy-longlegs (Tipula paludosa), Hylemyia, and Hippelates.

From Siphonaptera, such as Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf sage mouse.

From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectus Mactans), Acarus siro (Acarus siro), hidden category, Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite (Eriophyesribis) , citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato category, Amblyomma, Hyalommaspp, Isodesspp, Acarus tritici category, ginger mite category, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobia Praetiosa), red spider category, the compacted category of red autumnal leaves, sharp tenthredinidae, short whisker Acarapis.

Plant nematode includes plant nematode and the nematode lived in soil.Plant nematode includes but is not limited to ectoparasite, such as Xiphinema (Xiphinema spp.), minute hand Turbatrix (Longidorus spp.) and burr Turbatrix (Trichodorus spp.)；Partial parasite, such as pulvinulus sword Turbatrix (Tylenchulus spp.)；Mobility endoparasite (migratory endoparasites), such as Pratylenchus (Pratylenchus Spp.), perforation line Eimeria (Radopholus spp.) and Scutellonerna spp.；Sedentariae parasitic animal and plant (sedentary Parasites), such as Heterodera (Heterodera spp.), Globoderal spp. and Meloidogyne (Meloidogyne spp.)；And stem and leaf endoparasite, such as Ditylenchus (Ditylenchus Spp.), Aphelenchoides (Aphelenchoides spp.) and Hirshmaniella spp..

Compound described herein is especially characterized with its effectively harmful root parasitic soil nematode of preventing and treating, the nematode such as Heterodera (Heterodera) or ball cyst category (Globodera) formation SCN, and/or Meloidogyne root-knot nematode.The Harmful species of these category kind for example have, Meloidogyne incognita (Meloidogyne incognata), soybean cyst nematode Heterodera glycines (Heterodera glycines) (soybean cyst nematode Heterodera glycines), globus pallidus golden nematode (Globodera pallida) and globodera rostochiensis (Globodera Rostochiensis) (potato cyst nematode), the species can effectively be prevented and treated with compound specifically described herein.However, the use of compound specifically described herein is not in any way limited to these category kind or species, but other nematodes are extended in the same manner.

Compound specifically described herein can have the category kind of the various Nematas of resistance and/or the wide range activity of strain and/or species, the nematode includes but is not limited to, for example, Aglenchus agricola, Anguina tritici (Anguina tritici), peanut aphelenchoides (Aphelenchoides Arachidis), strawberry aphelenchoides (Aphelenchoides fragariae) and wide in range Aphelenchoides (Aphelenchoides spp.) stem and leaf endoparasite；Tiny fine rule worm (Belonolaimus Gracilis), anal spine nematode (Belonolaimus longicaudatus) long, Nuo Dunci nematodes (Belonolaimus nortoni), desert umbrella aphelenchoides (Bursaphelenchus Eremus), pine wood nematode (Burs aphelenchus xylophilus) and wide in range Bursaphelenchus (Bursaphelenchus spp)；Cacopaurus Pestis, the small loop wire worm (Criconemella curvata) of bending, the small loop wire worm of groove (Criconemella onoensis), the small loop wire worm (Criconemella of decoration Ornata), Criconemella rusium, slender lobule loop wire worm (Criconemella xenoplax (=Mesocriconema )) and wide in range small loop wire Eimeria (Criconemella spp.) xenoplax；Criconemoides ferniae、Criconemoides Onoense, Criconemoides ornatum and wide in range Criconemoides (Criconemoides spp.)；Potato Rot Nemotode (Ditylenchus Destructor), Ditylenchus dip saci (Ditylenchus dipsaci), D.myceliophagus (Ditylenchus myceliophagus) and wide in range Ditylenchus (Ditylenchus Spp.) class stem and leaf endoparasite；Different nose cone nematode (Dolichodorus heterocephalus), globus pallidus golden nematode (Globodera pallida (=Heterodera Pallida)), globodera rostochiensis (Globodera rostochiensis) (potato cyst nematode), eggplant ball golden nematode (Globodera Solanacearum), tobacco ball golden nematode (Globodera tabacum), Virginia ball golden nematode (Globodera virginiae) and wide in range ball cyst belong to class sedentariae cyst parasitic animal and plant；Double angle helicotylenchus (Helicotylenchus Digonicus), double angles helicotylenchus (Helicotylenchus dihystera) in double palaces, double angles helicotylenchus (Helicotylenchus erythrine) of erythrina indica, the double angle helicotylenchus (Helicotylenchus of many bands Multicinctus), short and small pair of angle helicotylenchus (Helicotylenchus nannus), false strong pair of angle helicotylenchus (Helicotylenchus pseudorobustus) and wide in range helix Eimeria (Helicotylenchus spp.)；Half wheel nematode (Hemicriconemoides), sandwort sheath nematode (Hemicycliophora Arenaria), Hemicycliophora nudata, fine sheath nematode (Hemicycliophora parvana), Heterodera Avenae, Cruciferae golden nematode (Heterodera cruciferae), soybean cyst nematode (Heterodera glycines) (soybean cyst nematode Heterodera glycines), paddy rice golden nematode (Heterodera oryzae), beet golden nematode (Heterodera Schachtii), corn golden nematode (Heterodera zeae) and wide in range Heterodera class sedentariae cyst parasitic animal and plant；Very thin latent root nematode (Hirschmaniella gracilis), Hirschmanniella Oryzae (Hirschmaniella oryzae), spine tail He Ximan nematodes (Hirschmaniella ) and wide in range Hirschmanniella (Hirschmaniella spp.) class stem and leaf endoparasite spinicaudata；Egyptian tie nematode (Hoplolaimus aegyptii), Hoplolaimus Californicus, Colombia's tie nematode (Hoplolaimus columbus), hat shape tie nematode (Hoplolaimus galeatus), India tie nematode (Hoplolaimus Indicus), large needle tie nematode (Hoplolaimus magnistylus), not strong tie nematode (Hoplolaimus pararobustus), African minute hand nematode (Longidorus Africanus), becate minute hand nematode (Longidorus Breviannulatus), ease removes minute hand nematode (Longidorus Elongatus), bare headed minute hand nematode (Longidorus laevicapitatus), tendril minute hand nematode (Longidorus vineacola) and wide in range minute hand Turbatrix ectoparasite；Sorghum root-knot nematode (Meloidogyne Acronea), African root-knot nematode (Meloidogyne africana), peanut root-knot nematode (Meloidogyne arenaria), Meloidogyne Arenaria thamesi, broccoli root-knot nematode (Meloidogyne Artiella), Qi Shi root-knot nematodes (Meloidogyne chitwoodi), Meloidogyne coffeicola, Ethiopia root-knot nematode (Meloidogyne Ethiopica), short and small root-knot nematode (Meloidogyne exigua), dogstail root-knot nematode (Meloidogyne graminicola), grass family root-knot nematode (Meloidogyne Graminis), M hapla (Meloidogyne hapla), Meloidogyne incognita (Meloidogyne incognita), Meloidogyne Incognita acrita, javanese root knot nematode (Meloidogyne Javanica), Ji Kuyou root-knot nematodes (Meloidogyne kikuyensis), Nahsi root-knot nematode (Meloidogyne naasi), Parana root-knot nematode (Meloidogyne Paranaensis), Times root-knot nematode (Meloidogyne thamesi) and wide in range Meloidogyne class sedentariae parasitic animal and plant；Wooden dipper Turbatrix (Meloinema spp.), abnormal section's cloth nematode (Nacobbus aberrans), Neotylenchus Vigissi, Paraphelenchus pseudoparietinus, green onion pair burr nematode (Paratrichodorus allius), sliver pair burr nematode (Paratrichodorus Lobatus), Paratrichodorus minor, Paratrichodorus nanus, callosity pair burr nematode (Paratrichodorus Porosus), smooth secondary burr nematode (Paratrichodorus ) and wide in range secondary burr Turbatrix (Paratrichodorus spp.) teres；Crotch needlework worm (Paratylenchus hamatus), Paratylenchus minutus, prominent needlework worm (Paratylenchus ) and wide in range needlework Eimeria (Paratylenchus spp.) projectus；Quick Pratylenchidae (Pratylenchus agilis), Emhorn Pratylenchidae (Pratylenchus Alleni), Andean Pratylenchidae (Pratylenchus andinus), most short-tail Pratylenchidae (Pratylenchus brachyurus), cereal Pratylenchidae (Pratylenchus Cerealis), coffee pot handle (Pratylenchus coffeae), indentation Pratylenchidae (Pratylenchus crenatus), German-style Pratylenchidae (Pratylenchus Delattrei), rounded tail Pratylenchidae (Pratylenchus giibbicaudatus), Gooch Pratylenchidae (Pratylenchus goodeyi), Pratylenchus Hamatus, six line Pratylenchidaes (Pratylenchus hexincisus), Lu Si Pratylenchidaes (Pratylenchus loosi), unsuccessful Pratylenchidae (Pratylenchus Neglectus), Cobb root (Pratylenchus penetrans), Pratylenchus pratensis (Pratylenchus pratensis), Pratylenchus Scribneri, exquisite Pratylenchidae (Pratylenchus teres), Soxhlet Pratylenchidae (Pratylenchus thornei), disability Pratylenchidae (Pratylenchus Vulnus), corn lesion nematode (Pratylenchus zeae) and wide in range Pratylenchus class mobility endoparasite；Pseudohalenchus minutus、Psilenchus magnidens、Psilenchus Tumidus, Cha Er spot rubber-insulated wire (Punctodera chalcoensis), sharp keen five ditches nematode (Quinisulcius acutus), oranges and tangerines similes thorne (Radopholus Citrophilus), Radopholus similis Throne (Radopholus similis), wide in range perforation line Eimeria class movement endoparasite；Northern shallow bid spin line worm (Rotylenchulus borealis), small shallow bid spin line worm (Rotylenchulus parvu), kidney shape shallow bid spin line worm (Rotylenchulus ) and wide in range shallow bid spin line Eimeria (Rotylenchulus spp.) reniformis；Straight flute spirals nematode (Rotylenchus laurentinus), Rotylenchus Macrodoratus, the strong nematode that spirals (Rotylenchus robustus), monotype are spiraled nematode (Rotylenchus uniformis) and the wide in range Turbatrix (Rotylenchus that spirals spp.)；Bottom class's shield nematode (Scutellonema brachyurum), slow shield nematode (Scutellonema bradys), lattice tail shield nematode (Scutellonema ) and wide in range shield Turbatrix (Scutellonema clathricaudatum Spp.) class movement endoparasite；Root galls Ya Man nematodes (Subanguina radiciola), Tetylenchus nicotianae, cylinder burr nematode (Trichodorus Cylindricus), Trichodorus minor, original burr nematode (Trichodorus primitivus), nearest burr nematode (Trichodorus Proximus), similar burr nematode (Trichodorus similis), rare burr nematode (Trichodorus sparsus) and wide in range burr Turbatrix ectoparasite；Farmland species of Tylenchorhynchus Nematodes (Tylenchorhynchus Agri), vegetables species of Tylenchorhynchus Nematodes (Tylenchorhynchus brassicae), limpid species of Tylenchorhynchus Nematodes (Tylenchorhynchus clarus), Clayton's species of Tylenchorhynchus Nematodes (Tylenchorhynchus Claytoni), finger-like species of Tylenchorhynchus Nematodes (Tylenchorhynchus digitatus), Yi Buli species of Tylenchorhynchus Nematodes (Tylenchorhynchus ebriensis), maximum species of Tylenchorhynchus Nematodes (Tylenchorhynchus maximus), naked species of Tylenchorhynchus Nematodes (Tylenchorhynchus Nudus), common species of Tylenchorhynchus Nematodes (Tylenchorhynchus vulgaris) and wide in range Tylenchorhynchus (Tylenchorhynchus spp.) class partial parasite；Tylenchulus Semipenetrans (Tylenchulus ) and wide in range pulvinulus sword Turbatrix class partial parasite semipenetrans；X. radicicola (Xiphinema Americanum), Xiphinama brevicolle (Xiphinema brevicolle), Xiphinema.

Composition of the invention is suitable for preventing and treating various Thysanopteras, Lepidoptera, coleoptera, Diptera, Semiptera, Orthoptera, root-feeding insect, evil mite, nematode.

The present invention also provides a kind of cover crop from disease and the method for insect pest, and Fungicidal insecticidal composition of the invention is applied into crop, crop propagating materials, fungi and insect and/or/their environment.

A kind of crop disease and insect prevents and kill off ground position, propagating materials and seed and the soil that the fact that composition has good plant tolerance under concentration needed for controlling plant diseases makes it possible to process plant.A kind of plant disease control composition of the present invention can be used for foliar spray or seed dressing.

Composition of the present invention is used for the purposes of cover crop propagating materials and the crop organ for then growing.

The present invention also provides a kind of cover crop from disease and the method for insect pest, and any desired serially or simultaneously treatment crop of composition, crop propagating materials or crop growth environment cover crop are prevented and kill off from disease and insect pest by by crop disease and insect of the present invention.

The present invention provides a kind of crop organ or the composition of the environment of plant growth for processing crop propagating materials and then growing.Can be used as seed dressing treatment plant propagation material, particularly seed（Fruit, stem tuber, cereal）With plant cutting（Such as rice）To resist the germ on seed and pestinfestation and appear in infecting for crop pathogenic in soil and insect.Crop disease and insect of the present invention prevents and kill off composition and is distinguished by and can admirably be tolerated and environmentally friendly by plant.

Term " crop propagating materials " is interpreted as referring to all parts with fertility of crop, for example, can be used for the seed of breeding plant, and asexually propagated plant material such as cutting or stem tuber.Here it may be mentioned that such as seed, root, fruit, stem tuber, bulb, rhizome and plant part.The germination plant and effective plant transplanted after being germinateed from soil or after emerging are also what be can be mentioned that.The young plant can also be protected by whole or local impregnation process plant propagation material before transplantation.

Most of infringement to crop caused by noxious plant pathogenic bacteria and insect, after memory period and seed are sown into soil and during plant germination or after germination, just there occurs early in seed by invading and harassing.This stage is particularly critical, because just especially sensitive in the root of growing plant and tender shoots, even small infringement may also lead to the death of whole plant.Noxious plant pathogenic bacteria and insect are prevented and treated by processing vegetable seeds to be known for a long time and is the theme updated.Accordingly, it would be desirable to the method for developing protection seed and germination plant, it can exempt after planting or additionally be applied again after plant germination crop protection products.In addition, in addition it is also necessary to the amount of optimization reactive compound used, so that best protection can be provided to seed and germination plant, to prevent the infringement of plant pathogen and insect, and reactive compound used will not damage plant in itself.

In crop propagating materials processing procedure, should be uniformly distributed active component and be attached to seed.Treatment can be recognizable by the seed dressing of the thin layer preparation containing active component on crop propagating materials such as seed, its original size and/or shape, is changed into intermediateness（As being coated）, then it is changed into thick-layer（As and multiple layers of different materials（For example load agent such as clay；Different preparations such as other active components；Polymer；And colouring agent）Pelletized together, its seed original-shape and/or size cannot be recognized again.

Seed Treatment can be that unseeded seed is carried out, and unseeded seed refers to for the purpose of being to make plant germination and growth, seed whenever between carrying out seed sowing in the results of seed and in field.

Unseeded seed to be processed do not include active component is applied to the behavior of soil, but be included in planting process all administration behaviors with seed as target.

It is preferred that processed before seed sowing, so as to be pre-processed to the seed for broadcasting sowing with composition.Specifically, preferably by seed pelleting or by seed-pelleting in compositions-treated of the invention.Treatment as a result, the active component in said composition is attached on seed, so as to can be used for disease and/or insect pest control.

Composition of the present invention is applied to seed with itself or suitable formulation.It is preferred that, seed is processed at steady state, so that treatment does not cause any infringement.Treatment to seed generally can be between harvesting and sowing any time carry out.

It has to be noticed that the amount selection for being applied to the amount and/or other additives of the present composition of seed is not interfere with the germination of seed or will not damage gained plant generally during Seed Treatment.

Composition of the present invention is particularly advantageous for the seed for the treatment of plant propagation material, particularly paddy rice, rape, cotton, wheat, barley, soybean, corn, peanut, cucumber.

Preventing and treating to the plant pathogen of after seedling infringement plant is mainly carried out by with crop protection compositions-treated soil and aboveground vegetation part.It is contemplated that the influence that crop production compositions may bring to environment and human and animal's health, so making great efforts to reduce the amount for applying reactive compound.

Crop disease and insect of the present invention can be prevented and kill off composition for the environment of plant growth.

The environment of plant growth refers to the supporter for making crops take root, growing, for example：Soil, water etc., specific raw material can use such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc..It is preferred that soil.

The example of the aquacultural fungal pathogen of soil-borne includes Alternaria（Alternaria spp.）, Ascochyta (Ascochyta ), spp. Botrytis cinerea（Botrytis cinerea）, Cercospora（Cercospora spp. , ergot（Claviceps purpurea）, standing grain cochliobolus（Cochliobolus sativus）, Colletotrichum（colletotrichum spp.）, Epicoccum（Epicoccum spp.）, F.graminearum schw（Fusarium graminearum）, rice evil seedling chain spore（Fusarium moniliforme）, fusarium oxysporum（Fusarium oxysporum）, fusarium moniliforme（Fusarium proliferatum）, fusariun solani (Fusarium Solani), dimension glue chain spore (Fusarium Subglitinans), Helminthosporium (Helminthosporium Spp), rotten microtorr bacterium (Microdochium is avenged Nivale), Penicillium (Pencillium spp), Phoma (Phoma spp.), wheat class nuclear cavity bacteria (Pyrenophora graminea), rice blast Pyricularia Sacc. (Pyricularia Oryzae), Rhizoctonia solani Kuhn (Rhizoctonia Solani), Rhizoctonia cerealis (Rhizoctonia Cerealis), Sclerotinia (Sclerotinia spp.), Septoria (Septoria spp.), silk axle smut (Sphacelotheca Reilliana), Tilletia (Tilletia spp.), meat spore core coral bacterium (Typhula incarnate), hidden bar smut (Urocystis Occulta), Ustilago (Ustilago spp.) or Verticillium (Verticillium spp.).

Soil germ has rhizoctonia solani, sickle-like bacteria, pythium spp, phytophthora, bacterium of dampinging off, root rot, pythium spp, botrytis cinerea, soft-rot fungi etc..In general, soil germ can produce a large amount of thalline, as long as condition is favourable to pathogen growth development and host is susceptible, germ just with amount reproduction and can infect host, in the presence of susceptible host, these germs can just enter the lasting pathogenic phase, the amount reproduction diffusion with the continuous cropping of crop, but nutrient is depleted or when edaphic condition such as temperature, humidity etc. is unfavorable to germ that germ can enter rest period afterwards again.When susceptible host does not exist, soil-borne disease bacterium can also survive in soil, in addition to soil germ has extensive host range, moreover it is possible to survived on the root surface of non-host or the broken branches and fallen leaves, with it there is saprophytic competitiveness to be undivided.But different germs are discrepant, as pythium spp can almost be survived in soil with indefinite duration.

The present invention is applied to preventing and treating nematode, the especially nematode in the field soil of fruit tree, vegetables, other crops and ornamental plant.

" preventing and treating nematode " used means to kill nematode or prevents elegans development or growth in the present invention.Preventing and treating nematode used herein also includes control nematode offspring (developments of viable cyst and/or pieces of an egg).Composition specifically described herein can be used to maintaining body health and can be used for therapeutic, preventative or systematically prevent and treat nematode.

The example of the nematode that composition of the invention can be applied is included but is not limited to, nematodes of meloidogyne genus, such as Meloidogyne incognita (Meloidogyne incognita), javanese root knot nematode (javanese root knot nematode), M hapla (M hapla) and peanut root-knot nematode (peanut root-knot nematode)；The nematode of Ditylenchus, such as potato rot nematode (Potato Rot Nemotode) and Ditylenchus dip saci (Ditylenchus dip saci)；Pratylenchus nematode, such as northern root belongs to nematode (Cobb root), chrysanthemum pratylenchus (pseudo- Pratylenchidae (Pratylenchus fallax)), coffee pratylenchus (coffee pot handle), tealeaves pratylenchus (Lu Si Pratylenchidaes) and English walnut pratylenchus (disability Pratylenchidae)；Ball cyst belongs to nematode, such as hairworm (globodera rostochiensis) and potato cyst nematode (globus pallidus golden nematode)；Heterodera nematode, such as soybean cyst nematode Heterodera glycines (soybean cyst nematode) and beet SCN (beet golden nematode)；Aphelenchoides nematode, such as aphelenchoides besseyi (aphelenchoides besseyi (Aphelenchoides besseyi)), chrysanthemum leaf bud aphelenchoides (chrysanthemum aphelenchoides (Aphelenchoides ritzemabosi)) and strawberry nematode (strawberry aphelenchoides)；True Aphelenchoides nematode, such as Fungal-feeding nematode (Aphelenchus avenae (Aphelenchus avenae))；Perforation line Eimeria nematode, such as similes thorne (Radopholus similis Throne)；Pulvinulus sword Turbatrix nematode, such as phase tangerine nematode (Tylenchulus Semipenetrans)；Shallow bid spin line Eimeria nematode, such as kidney shape shallow bid spin line worm (kidney shape shallow bid spin line worm)；Appear in woodsy nematode, such as pine wood nematode (pine wood nematode) etc..Additionally, composition of the invention can also be reasonably resistant to animal parasitic nematodes, such as roundworm, pinworm, Anisakid nematode (anisakis), filaria (filaria), bancroft's filaria (Wuchereria Bancrofti), filaria volvulus (Onchocerca volvulus) and gnathostoma siamense (Gnathostoma).

To the method in soil using medicament, for example liquid preparation is diluted in water or not diluted the medium method in the rice seedling bed of root or seedling for being directly applied to plant, the method that granule is disseminated in the rice seedling bed of the root of plant or seedling is had the method that pulvis, water dispersible granules etc. are sprayed in soil and are integrally mixed with soil prior to seeding, in implantation hole, seed furrow being sprayed on before sowing or before serike body after pulvis, water-dispersible grain dilution agent, then the method sowed etc..Crop disease and insect is preferably prevented and kill off composition and is made granule and spread fertilizer over the fields by the present invention, or is made after wettable powder is watered or mixes fine sand and is carried out soil treatment.

Crop disease and insect of the present invention prevents and kill off the invasion and attack of pathogen described in protection plant resistant in certain time that composition can be used for after treatment.The time of the protective effect for being obtained usually be from plant be activated compound processed continuity 1 to 10 day, preferably 1 to 7 day.Or for up to 200 days after seed is processed.

When the composition of the invention is used, depending on the type applied, application dosage can change in relatively wide scope.When plant part is processed, the application dosage of active compound combinations is generally between 0.1 to 10,000g/ha, preferably 10 to 1000g/ha.When seed is processed, the application dosage of reactive compound is usual in 0.001 to 50g/kg seeds, preferably between 0.01 to 10g/kg seeds.When soil is processed, the application dosage of reactive compound is usual in 0.1 to 10,000g/ha, preferably between 1 to 5000g/ha.

Composition of the invention can be additionally used in protection Stored Product from germ and/or insect pest infringement field.The suitable example of the product include stem, leaf, seed, fruit or cereal, it can be protected under fresh harvesting state or when process, as it is predrying, be humidified, crush, grind, extrude or toast.

Composition of the invention shows good bactericidal activity and insecticidal activity, and the antifungal or insecticidal activity of single reactive compound is weaker, the activity of the present composition exceed the simple of each single compound activity plus and.

A kind of plant disease control composition of the present invention is further adapted for increasing harvested material yield.Additionally, they show the toxicity of reduction and have good plant tolerance.

According to the present invention it is possible to process all plants and plant parts.Plant is understood to mean that all of plant and plant population herein, such as need and unwanted wild plant or crop plants (including crop plants of naturally occurring).Crop plants can be the plant that can be obtained by conventional breeding and optimum seeking method or by biotechnology and gene engineering research or by the combination of methods described, including genetically modified plants, also including that can receive or by the plant cultivars of plant seedling power protection.The implication of plant parts is interpreted as all of position above and below the ground of plant and plant organ, such as bud, leaf, Hua Jigen, and the example that can be mentioned that has leaf, needle, stem, dry, flower, fructification, fruit and seed, Yi Jigen, stem tuber and rhizome.Plant parts also include harvested material and asexual and generative propagation thing, such as seedling, stem tuber, rhizome, cutting (cutting) and seed.

According to plant species or plant cultivars, its plantation place and growth conditions (soil, weather, growth period, nutrition), treatment of the invention can also produce superadditivity (superadditive) (" collaboration ") effect.Thus the effect more than actual desired can be obtained, for example, it is possible to decrease the rate of application of the material that uses of the present invention and conjugate and/or widen its action spectrum and/or improve its activity, improve plant growth, improve high temperature or cold tolerance, improve arid or water or soil salt content tolerance, improve Flowering quality, make harvesting simpler, hasting of maturity, improve harvesting yield, improve the quality of harvested products and/or improve its nutritive value, improve the bin stability and/or its processing characteristics of harvested products.

A kind of good bactericidal insecticidal activity of plant disease control composition of the present invention can be confirmed by the following examples.Although single reactive compound shows weak bactericidal insecticidal activity, the activity that composition of the invention shows exceed the simple of each activity plus and.

When the bactericidal insecticidal activity of the plant disease control composition is more than the activity of the combination that each reactive compound is administered alone, the composition certainly exists cooperative effect.

A kind of plant disease control composition of the invention has advantages below：

A kind of plant disease control composition of the invention, active component is made up of formula (A) reactive compound and formula (B) reactive compound.A kind of plant disease control composition of the invention is the combination of agricultural bactericidal and desinsection, can be used for soil dedicated processes, can simultaneous anti-fungal, bacteriosis and root nematode.

Example of formulations

The copper hydroxide wettable powder of 1 2% fosthiazate of embodiment+10%

Fosthiazate 2%

Kocide SD 10%

Lauryl sodium sulfate 10%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin Complement to 100%

By Fungicidal active compound, various auxiliary agents and filler etc. by formula proportional components mix, through ultra-fine pulverizer disintegrating after, that is, obtain the copper hydroxide wettable powder of 2% fosthiazate+10%.

The copper calcium sulfate wettable powder of 2 1% fosthiazate of embodiment+50%

Fosthiazate 1%

Copper calcium sulfate 50%

Calcium dodecyl benzene sulfonate 1%

Sodium lignin sulfonate 2%

Sucrose Complement to 100%

By Fungicidal active compound, various auxiliary agents and filler etc. by formula proportional components mix, through ultra-fine pulverizer disintegrating after, that is, obtain the copper hydroxide wettable powder of 1% fosthiazate+50%.

The Kocide SD missible oil of 3 1% fosthiazate of embodiment+4%

Fosthiazate 1%

Kocide SD 4%

Ethoxylated castor oil 5%

Calcium dodecyl benzene sulfonate 3%

Dimethyl sulfoxide (DMSO) Complement to 100%

Mentioned component is proportionally prepared, homogeneous phase is uniformly mixing to obtain.

The copper calcium sulfate wettable powder of 4 5% fosthiazate of embodiment+50%

Fosthiazate 5%

Kocide SD 50%

Lauryl sodium sulfate 10%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin Complement to 100%

Said components are mixed in proportion, and ground, crushed, be prepared into wettable powder.

The copper hydroxide water dispersible granule of 5 2% fosthiazate of embodiment+50%

Fosthiazate 2%

Kocide SD 50%

MODIFIED LIGNOSULPHONATE 5%

Lauryl sodium sulfate 5%

Urea 5%

Kaolin Complement to 100%

Fosthiazate, Kocide SD, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow crushing into wettable powder；Add a certain amount of water mixing extruding and make material.The copper hydroxide water dispersible granule of 2% fosthiazate+50% is obtained after drying screening.

The Kocide SD suspension emulsion of 6 0.5% fosthiazate of embodiment+50%

Oil phase：

Fosthiazate 0.5%

Methyl oleate 10%

Ethoxylated castor oil 5%

Water phase：

Kocide SD 50%

The sodium salt of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation 1%

Water Complement to 100%

Fosthiazate is dissolved in methyl oleate, adds ethoxylated castor oil to obtain oil phase；According to formula by Kocide SD, the sodium salt of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation, water is ground and/or high speed shear after obtain the suspending agent of water phase Kocide SD；Oil phase addition water is mutually obtained into suspension emulsion under agitation.

The copper calcium sulfate wettable powder of 7 10% fosthiazate of embodiment+10%

Fosthiazate 10%

Copper calcium sulfate 10%

Sodium lignin sulfonate 1%

NaLS 2%

The silicic acid of high degree of dispersion 1%

Kaolin Complement to 100%

Said components are mixed in proportion, and ground, crushed, be prepared into wettable powder.

The Kocide SD coated granule of 8 40% fosthiazate of embodiment+50%

Fosthiazate 40%

Kocide SD 50%

Polyethylene glycol 3%

The silicic acid of high degree of dispersion 1%

Calcium carbonate Complement to 100%

In a mixer, by levigate Fungicidal active compound even spread to the carrier soaked by polyethylene glycol.Dust-free coated granules agent can be obtained in this way.

The copper hydroxide wettable powder of 9 50% fosthiazate of embodiment+10%

Fosthiazate 50%

Kocide SD 10%

Lauryl sodium sulfate 1%

Sodium lignin sulfonate 1%

Kaolin Complement to 100%

Said components are mixed in proportion, and ground, crushed, be prepared into wettable powder.

The copper calcium sulfate granule of 10 20% fosthiazate of embodiment+60%

Fosthiazate 20%

Copper calcium sulfate 60%

Sodium lignin sulfonate 4%

Carboxymethylcellulose calcium 2%

Kaolin Complement to 100%

Reactive compound is mixed and ground with auxiliary agent, is soaked with water, then granulation dries in the air stream.

The Kocide SD seed coat agent of 11 50% fosthiazate of embodiment+2%

Fosthiazate 50%

Kocide SD 2%

AEO sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

PVP-K30 1%

Water Complement to 100%

Seed coat agent is obtained after above-mentioned each component is mixed into ground and/or high speed shear in proportion.

The copper calcium sulfate microcapsule suspension-suspendinagent agent of 12 5% fosthiazate of embodiment+50%

ATLOX^TM4913 4%

Citric acid 0.05%

Catalyst 0.1%

Water 13%

Copper calcium sulfate 50%

PAPI ^TM 1.35%

SOLVESSO^TM200 10%

ATLOX^TM4913 16%

Dispersant LFH 0.3%

Defoamer 0.16%

Urea 8.4%

Fosthiazate 5%

Water Complement to 100%

By PAPI^TM, fosthiazate, SOLVESSO^TM200 oil phases for being formed are added and contain ATLOX^TMIn 4913 aqueous solution, emulsion is formed.Then heat and be incubated 50^oCatalyst reaction is added under C 2 hours.The microcapsules of fosthiazate is obtained after cooling.

ATLOX^TM4913, Dispersant LFH, defoamer, urea, copper calcium sulfate and water mix in proportion, and suspending agent is obtained after ground and/or high speed shear.

The fosthiazate microcapsules that will be obtained is added in the suspending agent of copper calcium sulfate, is uniformly mixing to obtain the copper calcium sulfate microcapsule suspension-suspendinagent agent of 5% fosthiazate+50%

The sulfuric acid ketone calcium suspension emulsion of 13 50% fosthiazate of embodiment+1%

Fosthiazate 50%

Copper calcium sulfate 1%

SOLVESSO^TM200 10%

Ethoxylated castor oil 4%

AEO sulfosuccinic acid monoesters disodium 5%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water Complement to 100%

Fosthiazate is dissolved in SOLVESSO^TMIn 200, ethoxylated castor oil is added, obtain the oil phase of fosthiazate；

AEO sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, Kocide SD and water are mixed in proportion, the suspending agent of copper calcium sulfate is obtained after ground and/or high speed shear.

Oil phase containing fosthiazate is added in the suspending agent of sulfur acid copper calcium, suspension emulsion is obtained.

The Kocide SD missible oil of 14 50% fosthiazate of embodiment+0.5%

Fosthiazate 50%

Kocide SD 0.5%

Ethoxylated castor oil 5%

Calcium dodecyl benzene sulfonate 3%

SOLVESSO^TM100 Complement to 100%

Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.

The copper hydroxide water dispersible granule of 15 20% fosthiazate of embodiment+30%

Fosthiazate 20%

Kocide SD 30%

MODIFIED LIGNOSULPHONATE 5%

Lauryl sodium sulfate 5%

Urea 5%

Kaolin Complement to 100%

Fosthiazate, Kocide SD, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow crushing into wettable powder；Add a certain amount of water mixing extruding and make material.The copper hydroxide water dispersible granule of 20% fosthiazate+30% is obtained after drying screening.

The copper calcium sulfate wettable powder of 16 5% fosthiazate of embodiment+30%

Fosthiazate 5%

Copper calcium sulfate 30%

Lauryl sodium sulfate 1%

Sodium lignin sulfonate 1%

Kaolin Complement to 100%

Said components are mixed in proportion, and ground, crushed, be prepared into wettable powder.

The Kocide SD of 17 50% fosthiazate of embodiment+50%

Fosthiazate 50%

Kocide SD 50%

Fosthiazate, Kocide SD are proportionally well mixed.

The Kocide SD of 18 40% fosthiazate of embodiment+60%

Fosthiazate 40%

Kocide SD 60%

Fosthiazate, Kocide SD are proportionally well mixed.

Proportioning in above example is weight per distribution ratio.

Biological test example

Experimental technique

It is for examination soil sample：

Soil sample picks up from Fauna of Kunshan, Jiangsu vegetable field, and long-term nematode and disease occur serious, take topsoil in after the culture such as Verticillium dahliae, blue or green withered Raul Salmonella 2 weeks of indoor addition pure culture, cross 2mm sieves, mix standby.Through analysis, soil moisture content (water: dry ground) is 22.50%, pH6.37, soil organic matter content 32.0g/kg, NH4+-N3.2mg/kg, NO3--N53.6mg/kg, and available phosphorus 578.0mg/kg, available potassium 1069.0mg/kg belong to sandy loam.

Evaluation index and method are：

Meloidogyne Meloidogyne spp., using sucrose Centrifugal Flotation method；

Pratylenchus Pratylenchus Filipjev, using modified Baermann funnel method；

Heterodera Heterodera spp., using modified Baermann funnel method；

Phytophthora Phytophthora spp., are separated using Masago methods；

Verticillium dahliae belongs to Verticillium dahliae, is separated using Christen methods；

Blue or green withered Raul Salmonella Ralstonia solanacarum, are separated using Kelman methods.

Dose is set

Following 18 embodiments are separately designed by medicament (active ingredient) and soil quality ratio：

Process of the test

Ready soil sample before 1000g is weighed, is put into 3.5L driers.5d is fumigated at 25 DEG C.Gas 1d is opened after stifling end, nematode and soil-borne pathogen is then peeled off, and space management is set, each 3 repetition for the treatment of.30 days observation nemic death rates after medicine.

Computational methods

Nematode survival rate and corrected mortality are calculated with following formula：

Survival rate %=100 × living nematodes number/confession tries total borer population

Corrected mortality %=100 × (the treatment death rate-control death rate)/(1- compares the death rate)

Pathogen inhibiting rate is calculated with following formula：

Inhibiting rate %=100 × (check plot pathogen quantity-chemicals treatment district pathogen quantity)/check plot pathogen quantity

The predictive role of two kinds of particular combinations of reactive compound can be used so-called " Colby formula " (referring to S.R. Colby, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) it is calculated as below:If

X is the activity when the reactive compound A that consumption is mg/ha or concentration is mppm is used；It is expressed as accounting for the percentage of untreated control；

Y is the activity when the reactive compound B that consumption is ng/ha or concentration is nppm is used, and is expressed as accounting for the percentage of untreated control；

E is to work as to use consumption for m and n G/ha or concentration are m and n ppm Reactive compound A and B when activity,

So

If the activity of actual observation is more than expection activity, then said composition it is super plus and, i.e., with synergistic effect.

Measurement result

To the effect of nematode

The effect of the formula of table 1 (A) reactive compound and formula (B) reactive compound different proportion mixture to nematode

As it can be seen from table 1 formula (A) reactive compound shows synergistic effect with 9 kinds of mixtures of different proportion of formula (B) reactive compound to three kinds of nematodes.

To the effect of soil-borne pathogen

The effect of the formula of table 2 (A) reactive compound and formula (B) reactive compound different proportion mixture to soil-borne pathogen

From table 2 it can be seen that formula (A) reactive compound shows synergistic effect with 9 kinds of mixtures of different proportion of formula (B) reactive compound to phytophthora, Verticillium dahliae and ralstonia solanacearum.

Claims (9)

1. a kind of crop disease and insect prevents and kill off composition, and active component is made up of compound (A) and (B), wherein (A) represents the compound described by formula (A)：

And (B) is selected from Kocide SD or copper calcium sulfate；The weight ratio of compound (A) and compound (B) is 1: 50-50: 1, preferably 1: 25-25: 1, more preferably 1: 10-10: 1 in the composition, further preferably 1: 5-5: 1.

2. composition according to claim 1, also comprising filler and/or surfactant.

3. composition according to claim 1, the formulation of the composition is that suspending agent, seed coat agent, wettable powder, water dispersible granules, microcapsule suspending agent, coated granule, granule, water-soluble granule, water solube powder, aqua missible oil, microemulsion, aqueous emulsion, effervescent tablet, Seed Treatment dispersible granula.

4. composition according to claim 1, the compound (A) accounts for the 5%-90%, more preferably preferably 10%-80%, 10%-60% of composition with the content of compound (B).

5. composition according to claim 1 is used to prevent and treat the purposes of crop disease and insect pest.

6. composition according to claim 1 is used to prevent and treat on fruit tree, vegetables, cotton, flowers, tea tree, cereal crops by fungi and the purposes of bacterial disease.

7. composition according to claim 1 is used to prevent and treat the purposes of the insect pest caused by Thysanoptera, Lepidoptera, coleoptera, Diptera, Semiptera, Orthoptera, evil mite, nematode on fruit tree, vegetables, cotton, flowers, tea tree, cereal crops.

8. the composition of claim 1 is applied to crop, crop propagating materials, fungi and insect and/or/their environment by a kind of cover crop from disease and the method for insect pest.

9. a kind of method for preventing and treating crop disease and insect pest, the compound (A) and compound (B) described in claim 1 are administered simultaneously or applied respectively or sequential application.