CN106684261B - Transparency adjusts unit and display device - Google Patents

Transparency adjusts unit and display device Download PDF

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Publication number
CN106684261B
CN106684261B CN201710054221.0A CN201710054221A CN106684261B CN 106684261 B CN106684261 B CN 106684261B CN 201710054221 A CN201710054221 A CN 201710054221A CN 106684261 B CN106684261 B CN 106684261B
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China
Prior art keywords
electrode
metal ion
transparency
metal
reducing electrode
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CN201710054221.0A
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CN106684261A (en
Inventor
刘金强
闵超
罗志忠
敖伟
顾伟杰
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Chengdu Vistar Optoelectronics Co Ltd
Original Assignee
Kunshan New Flat Panel Display Technology Center Co Ltd
Kunshan Guoxian Photoelectric Co Ltd
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Priority to CN201710054221.0A priority Critical patent/CN106684261B/en
Publication of CN106684261A publication Critical patent/CN106684261A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09GARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G3/00Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
    • G09G3/20Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
    • G09G3/22Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
    • G09G3/30Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels
    • G09G3/32Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED]
    • G09G3/3208Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/81Anodes
    • H10K50/818Reflective anodes, e.g. ITO combined with thick metallic layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/82Cathodes
    • H10K50/828Transparent cathodes, e.g. comprising thin metal layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

The invention discloses a kind of transparencies to adjust unit and display device, and it includes: reducing electrode that the transparency, which adjusts unit, and the reducing electrode includes metal;Metal ion, positioned at the side of the reducing electrode;Permselective membrane deviates from the side of the reducing electrode positioned at the metal ion;First transparency electrode deviates from the side of the reducing electrode positioned at the permselective membrane.When adding positive pressure to the reducing electrode, when the first transparency electrode adds negative pressure, the metal of the reducing electrode is oxidized to metal ion, and the metal ion enters the metal ion, since the metal thickness in the reducing electrode reduces so that light transmittance improves;When adding negative pressure to the reducing electrode, when the first transparency electrode adds positive pressure, the metal ion in the metal ion is reduced to the metal, and metal thickness of the metal deposit in the reducing electrode, the reducing electrode increases so that light transmittance improves.

Description

Transparency adjusts unit and display device
Technical field
The present invention relates to field of display technology, adjust unit and display device more particularly to a kind of transparency.
Background technique
Transparence display device refers to the display that can form transparence display state so that its rear scene can be seen in viewer Part, more typically can be applied to need to be presented display picture such as show window before showing physical item is used.Transparence display is The development trend of next-generation display technology, it is widely used, and can be used in mobile phone, notebook, display, show window etc..
But due to the penetrability of transparence display device itself, can clearly illustrate the scene after device, privacy It is bad, it is often desired to can automatically control display device whether need it is transparent.
Summary of the invention
The present invention provides a kind of transparency adjusting unit, can present transparent, translucent and impermeable from main regulation transmitance Bright various states, the transparency adjust unit and include:
Reducing electrode, the reducing electrode include metal;
Metal ion, positioned at the side of the reducing electrode, the metal ion includes metal ion;
Permselective membrane deviates from the side positioned at the metal ion;And
First transparency electrode deviates from the side of the reducing electrode positioned at the permselective membrane;
When adding positive pressure to the reducing electrode, when the first transparency electrode adds negative pressure, the metal of the reducing electrode exists Metal ion is oxidized at the metal ion, the metal ion enters the metal ion;When electric to the reduction Pole adds negative pressure, and when the first transparency electrode adds positive pressure, the metal ion in the metal ion is in the reduction electricity The metal is reduced at pole, the metal deposit is in one side of the reducing electrode towards the metal ion.
Further, adjusted in unit in the transparency, the material of the metal ion include free metal from Son.
Further, it is adjusted in unit in the transparency, the metal is silver.
Further, it is adjusted in unit in the transparency, the reducing electrode further includes transparency conducting layer, described transparent Conductive layer is located at the side that the metal deviates from the metal ion.
Another side according to the present invention also provides a kind of display device, and the transparency including stacking gradually adjusts single Member, luminescent device and second electrode, it is that transparency described in any one as above adjusts unit that the transparency, which adjusts unit,.
Further, in the display device, the transparency is adjusted in unit, and the reducing electrode is towards the hair Optical device setting.
Further, in the display device, the second electrode is described as the cathode for driving the luminescent device Reducing electrode is as the anode for driving the luminescent device;Or, anode of the second electrode as the driving luminescent device, The reducing electrode is as the cathode for driving the luminescent device.
Further, in the display device, the transparency is adjusted in unit, and the first transparency electrode is towards institute State luminescent device setting.
Further, in the display device, cathode of the first transparency electrode as the driving luminescent device, The second electrode is as the anode for driving the luminescent device;Or, the first transparency electrode is as the driving photophore The anode of part, the second electrode is as the cathode for driving the luminescent device.
Further, in the display device, the display device further includes third transparent electrode, and the third is transparent Electrode is located at the transparency and adjusts between unit and luminescent device.
It provides a kind of transparency in the present invention to adjust in unit, it includes: reducing electrode that the transparency, which adjusts unit, described Reducing electrode includes metal;Metal ion, positioned at the side of the reducing electrode, the metal ion includes the metal Ion;Permselective membrane deviates from the side positioned at the metal ion;First transparency electrode is located at the metal Sheath deviates from the side of the reducing electrode.When adding positive pressure to the reducing electrode, when the first transparency electrode adds negative pressure, The metal of the reducing electrode is oxidized to metal ion at the metal ion, the metal ion enter the metal from Sublayer, since the metal thickness in the reducing electrode reduces so that light transmittance improves;When adding negative pressure to the reducing electrode, institute When stating first transparency electrode and adding positive pressure, the metal ion in the metal ion is reduced to institute at the reducing electrode State metal, gold of the metal deposit in one side of the reducing electrode towards the metal ion, the reducing electrode Belong to thickness to increase so that light transmittance improves.
There is provided in a kind of display device in the present invention, the display device include the transparency stacked gradually adjust it is single Member, luminescent device and second electrode, wherein the reducing electrode or first transparency electrode can be with to drive the photophore The cathode or anode of part.
Detailed description of the invention
Fig. 1 is the diagrammatic cross-section of the display device of one embodiment of the invention;
Fig. 2 is the diagrammatic cross-section of the display device of another embodiment of the present invention;
Fig. 3 is the diagrammatic cross-section of the display device of further embodiment of this invention;
Fig. 4 is the diagrammatic cross-section of the display device of yet another embodiment of the invention.
Specific embodiment
It adjusts unit to transparency of the invention below in conjunction with schematic diagram to be described in more detail, which show this The preferred embodiment of invention, it should be appreciated that those skilled in the art can modify invention described herein, and still realize this The advantageous effects of invention.Therefore, following description should be understood as the widely known of those skilled in the art, and not make For limitation of the present invention.
The present invention is more specifically described by way of example referring to attached drawing in the following passage.According to following explanation, the present invention The advantages of and feature will become apparent from.It should be noted that attached drawing is all made of very simplified form and uses non-accurate ratio, Only for the purpose of facilitating and clarifying the purpose of the embodiments of the invention.
Core of the invention thought is, provides a kind of transparency and adjusts in unit, the transparency adjusts unit and includes: Reducing electrode, the reducing electrode include metal;Metal ion, positioned at the side of the reducing electrode;Permselective membrane, position Deviate from the side of the reducing electrode in the metal ion;First transparency electrode is located at the permselective membrane and deviates from institute State the side of reducing electrode.When adding positive pressure to the reducing electrode, when the first transparency electrode adds negative pressure, the reducing electrode Metal be oxidized to metal ion at the metal ion, the metal ion enters the metal ion, by institute Stating the metal thickness in reducing electrode reduces so that light transmittance improves;When adding negative pressure to the reducing electrode, described first is transparent When electrode adds positive pressure, the metal ion in the metal ion is reduced to the metal, institute at the reducing electrode Metal thickness of the metal deposit in one side of the reducing electrode towards the metal ion, the reducing electrode is stated to increase So that light transmittance improves.
Further, the present invention also provides a kind of display device, the display device include stack gradually it is described Lightness adjusts unit, luminescent device and second electrode, and the transparency of unit is adjusted by adjusting the transparency, adjustable The transparency of the display device.
Below referring to FIG. 1, illustrating one embodiment of the invention.
As shown in Figure 1, in one embodiment of this invention, the transparency adjust unit 100 include reducing electrode 110, Metal ion 120, permselective membrane 130 and first transparency electrode 140, the reducing electrode 110, metal ion 120, Permselective membrane 130 and first transparency electrode 140 stack gradually.
Wherein, the reducing electrode 110 includes metal, and the metal is opaque state in solid-state, the metal The metal of electrochemical redox can occur for silver, copper etc. for material, and oxidation can occur under the electric field and make for the metal With formation metal ion.It for example, in one embodiment, the material of the metal is silver, and silver-colored conducts electricity very well, and is low work content Metal, in addition, the metals such as aluminium, tin also may be used.Thickness of the metal in the reducing electrode 110 can be subtracted by oxidation It is thin.
It include metal ion in the metal ion 120, the metal ion in the metal ion 120 is in electric field Reduction reaction can occur under effect and generate metal solid.Preferably, the material of the metal ion 120 includes selected from alkali gold Belong at least one of ion, alkaline-earth metal ions and rare earth ion metal ion, as long as the metal ion is in electric field Under the action of can occur reduction reaction generate metal solid.Preferably, the material of the metal ion 120 includes trip From metal ion, in the metal ion 120, metal exists with the state of metal ion, in the extraneous electric field that applies In the case of, metal ion can restore and precipitating metal.In one embodiment, the material of the metal ion 120 is conduction Glue, such as conductive silver glue, silver therein is with silver ion (Ag+) state exist.The metal is in the reducing electrode 110 Thickness can be thickened by reduction.
The permselective membrane 130 prevents between the metal ion 120 and the first transparency electrode 140 The metal ion passes through the permselective membrane 130 and is precipitated at the first transparency electrode 140, prevents the metal in institute The deposition of first transparency electrode 140 is stated, so that the first transparency electrode 140 is constantly in pellucidity.The permselective membrane 130 can be amberplex etc..
When adding positive pressure, the first transparency electrode 140 plus negative pressure to the reducing electrode 110, the reducing electrode 110 Metal (Ag) be oxidized at the metal ion 120 (Ag loses electronics) be metal ion (Ag+), the metal ion Into the metal ion 120, the metal thickness of the reducing electrode 110 is gradually thinned, the reducing electrode 110 it is transparent Degree gradually increases, when the metal thickness of the reducing electrode 110 is thinned to certain thickness (such as when being thinned to 2 microns or less), Metal in the reducing electrode 110 is essentially transparence, and it is transparence that the transparency, which adjusts unit 100,;
When adding negative pressure, the first transparency electrode 140 plus positive pressure to the reducing electrode 110, the metal ion Metal ion (the Ag in 120+) at the reducing electrode 110 it is reduced (Ag+Obtain electronics) it is the metal (Ag), The metal deposit is in one side of the reducing electrode 110 towards the metal ion 120, the gold of the reducing electrode 110 Belong to thickness progressive additive, the transparency of the reducing electrode 110 gradually decreases, when the metal thickness of the reducing electrode 110 increases For thickness to another certain thickness (such as when being thinned to 10 microns or more), the metal in the reducing electrode 110 is opaque shape, described It is opaque shape that transparency, which adjusts unit 100,.
In one embodiment, the reducing electrode 110 only includes one layer of metal, and one layer of metal is directly as electricity Pole uses, and the metal can be formed in one that the luminescent device 220 deviates from the second electrode 210 by modes such as vapor depositions Side, the second electrode 210 can be transparent electrode.
In other embodiments, the reducing electrode 110 can also include layer of transparent conductive layer (not shown), institute It states transparency conducting layer and is located at the side that the metal deviates from the metal ion, the metal is towards the metal ion 120 settings.When the transparency described in initial preparation adjusts unit 100, the metal can be prepared directly in the transparency tune It saves in unit 100, then 110 original state of reducing electrode is translucent or opaque state;In an other embodiment, In the preparation, 110 preparation layer of transparent conductive layers of the reducing electrode, the metal can not also be prepared in the transparency It adjusts in unit 100, then 110 original state of reducing electrode is that transparent state can pass through institute when adjusting transparency The metal ion stated in metal ion 120 is precipitated in the transparency conducting layer towards the side of the metal ion 120, from And the metal is deposited between the transparency conducting layer and the metal ion 120, the reducing electrode 110 becomes impermeable It is bright.
The transparency adjusts unit 100 and is displayed in device, to adjust the transparency of the display device, institute Stating display device can be electro-luminescence display device, in the examples below, by taking the display device is OLED device as an example It is illustrated.
As shown in Figure 1, the display device 1 includes that the transparency stacked gradually adjusts unit 100, luminescent device 220 and second electrode 210, in one embodiment, the transparency is adjusted in unit 100, and the reducing electrode 110 is towards institute State the setting of luminescent device 220.Preferably, the reducing electrode 110 can be multiplexed with the electrode of the driving luminescent device 220, The multiplexing is that the reducing electrode 110 is also used as driving the electrode of the luminescent device 220, to simplify structure, is reduced Cost.For example, the second electrode 210 is as the cathode for driving the luminescent device 220, the reducing electrode 110 is as drive Move the anode of the luminescent device 220;Or, the second electrode 210 is as the anode for driving the luminescent device 220, it is described Reducing electrode 110 is as the cathode for driving the luminescent device 220.The luminescent device 220 can be OLED luminescent device etc. Deng.
In addition, can also be formed with metal-doped layer between the reducing electrode 110 and the luminescent device 220, this is It will be understood by those skilled in the art that, this will not be repeated here.
In one embodiment, by adjusting the thickness of the metal in the reducing electrode 110, the adjustable display The transparency or transmitance of device 1.
As shown in Fig. 2, in another embodiment, the transparency of the display device 2 is adjusted in unit 100, described First transparency electrode 140 is arranged towards the luminescent device 220.Preferably, the first transparency electrode 140 can be with driving institute The electrode multiplexing of luminescent device 220 is stated, the multiplexing is that the first transparency electrode 140 is also used as driving the photophore The electrode of part 220 reduces cost to simplify structure.For example, the second electrode 210 is as the driving luminescent device 220 Cathode, the first transparency electrode 140 is as the anode for driving the luminescent device 220;Or, 210 conduct of second electrode The anode of the luminescent device 220 is driven, the first transparency electrode 140 is as the cathode for driving the luminescent device 220.? In another embodiment, by adjusting the thickness of the metal in the reducing electrode 110, the adjustable display device 2 Transparency or transmitance.
As shown in figure 3, in another embodiment, the transparency of the display device 3 is adjusted in unit 100, described Reducing electrode 110 is arranged towards the luminescent device 220.The reducing electrode 110 and the electrode for driving the luminescent device 220 It is not multiplexed, the display device 3 further includes third transparent electrode 230, and the third transparent electrode 230 is located at the transparency tune It saves between unit 100 and luminescent device 220, the third transparent electrode 230 can be used as the yin for driving the luminescent device 220 Pole, the second electrode 210 is as the anode for driving the luminescent device 220;It can be with the third transparent electrode 230 As the anode for driving the luminescent device 220, the second electrode 210 is as the cathode for driving the luminescent device 220.This Insulating layer 240 can also be set to the transparent electricity of the third between the outer third transparent electrode 230 and the reducing electrode 110 Pole 230 and the reducing electrode 110 are electrically isolated.In another embodiment, by adjusting institute in the reducing electrode 110 State the thickness of metal, the transparency or transmitance of the adjustable display device 3.
As shown in figure 4, the transparency of the display device 4 is adjusted in unit 100, described in another embodiment First transparency electrode 140 is arranged towards the luminescent device 220.The first transparency electrode 140 and the driving luminescent device 220 electrode is not multiplexed, and the display device 4 further includes third transparent electrode 230, and the third transparent electrode 230 is located at institute It states transparency to adjust between unit 100 and luminescent device 220, it is described luminous that the third transparent electrode 230 can be used as driving The cathode of device 220, the second electrode 210 is as the anode for driving the luminescent device 220;It can be transparent with the third Electrode 230 can be used as the anode for driving the luminescent device 220, and the second electrode 210 is as the driving luminescent device 220 cathode.Furthermore insulating layer 240 can also be set between the third transparent electrode 230 and the first transparency electrode 140 The third transparent electrode 230 and the first transparency electrode 140 are electrically isolated.In another embodiment, pass through tune Save the thickness of the metal in the reducing electrode 110, the transparency or transmitance of the adjustable display device 3.
It not merely can be used for showing it will be understood by those skilled in the art that the transparency adjusts unit 100 To show in device, the transparency adjusts unit 100 and can be also used in other structures, such as can be used on the glass of show window, To change the transparency of glass, foregoing description through the invention, the those of ordinary skill in this field that bases on practicality can be with Understand and predictable, this will not be repeated here.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art Mind and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies Within, then the present invention is also intended to include these modifications and variations.

Claims (9)

1. a kind of display device, which is characterized in that the transparency including stacking gradually adjusts unit, luminescent device and the second electricity Pole, the transparency adjust unit and include:
Reducing electrode, the reducing electrode include metal;
Metal ion, positioned at the side of the reducing electrode, the metal ion includes metal ion, the metal ion The material of layer is conducting resinl;
Permselective membrane deviates from the side of the reducing electrode positioned at the metal ion;And
First transparency electrode deviates from the side of the reducing electrode positioned at the permselective membrane;
When adding positive pressure to the reducing electrode, when the first transparency electrode adds negative pressure, the metal of the reducing electrode is described Metal ion is oxidized at metal ion, the metal ion enters the metal ion;Add when to the reducing electrode Negative pressure, when the first transparency electrode adds positive pressure, the metal ion in the metal ion is at the reducing electrode It is reduced to the metal, the metal deposit is in one side of the reducing electrode towards the metal ion;The selection is saturating Film is crossed to be precipitated at the first transparency electrode to prevent the metal ion from passing through the permselective membrane.
2. display device as described in claim 1, which is characterized in that the material of the metal ion includes free metal Ion.
3. display device as described in claim 1, which is characterized in that the metal is silver.
4. the display device as described in any one of claim 1-3, which is characterized in that the reducing electrode further includes transparent Conductive layer, the transparency conducting layer are located at the side that the metal deviates from the metal ion.
5. display device as described in claim 1, which is characterized in that the transparency is adjusted in unit, the reducing electrode It is arranged towards the luminescent device.
6. display device as claimed in claim 5, which is characterized in that the second electrode is as the driving luminescent device Cathode, the reducing electrode is as the anode for driving the luminescent device;Or, the second electrode is as the driving photophore The anode of part, the reducing electrode is as the cathode for driving the luminescent device.
7. display device as described in claim 1, which is characterized in that the transparency is adjusted in unit, and described first is transparent Electrode is arranged towards the luminescent device.
8. display device as claimed in claim 7, which is characterized in that the first transparency electrode is as the driving photophore The cathode of part, the second electrode is as the anode for driving the luminescent device;Or, the first transparency electrode is as driving institute The anode of luminescent device is stated, the second electrode is as the cathode for driving the luminescent device.
9. the display device as described in claim 1 or 5 or 7, which is characterized in that the display device further includes the transparent electricity of third Pole, the third transparent electrode are located at the transparency and adjust between unit and luminescent device.
CN201710054221.0A 2017-01-22 2017-01-22 Transparency adjusts unit and display device Active CN106684261B (en)

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Publication number Priority date Publication date Assignee Title
CN109560106A (en) * 2017-09-26 2019-04-02 上海和辉光电有限公司 A kind of transparence display device and its transmitance adjusting method
CN112596293A (en) * 2020-12-18 2021-04-02 天津宝兴威科技股份有限公司 Transparent liquid crystal display and method for improving transmittance of transparent display

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CN103869569A (en) * 2012-12-18 2014-06-18 株式会社日本显示器 Display device
CN105807526A (en) * 2016-04-18 2016-07-27 京东方科技集团股份有限公司 Display device capable of being switched between display state and mirror surface state

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Publication number Priority date Publication date Assignee Title
CN1466704A (en) * 2001-07-26 2004-01-07 ������������ʽ���� Antiglare anticlouding device and antomotive outer mirror
CN102830490A (en) * 2011-06-16 2012-12-19 索尼公司 Display apparatus
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Effective date of registration: 20201210

Address after: No.146 Tianying Road, high tech Zone, Chengdu, Sichuan Province

Patentee after: Chengdu CHENXIAN photoelectric Co.,Ltd.

Address before: No. 215300, Kunshan, Jiangsu Province

Patentee before: Kunshan New Flat Panel Display Technology Center Co.,Ltd.

Patentee before: KunShan Go-Visionox Opto-Electronics Co.,Ltd.