CN106676522A - Multi-principal-element alloy material coating and preparation method thereof - Google Patents
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
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Abstract
The invention discloses a multi-principal-element alloy material coating and a preparation method thereof, and belongs to the fields of metal materials and metal material preparation. The chemical formula of the multi-principal-element alloy material coating is AlxCoCuFeyMnzNiRep, and Re is the rare earth element Ce or Y. The preparation method comprises the specific steps that metal powder and rare earth oxide are weighed according to the chemical formula and placed into a ball milling tank, an appropriate number of stainless steel balls are added, and the ball milling tank is sealed under inert gas; the sealed ball milling tank is put on a planetary ball mill for material mixing; organic glue is added into the uniformly-mixed powder to be blended into a pasty mixture, and the mixture is prefabricated on a base body to be dried; and plasma cladding is conducted on the base body material with the prefabricated raw material, and then the multi-principal-element alloy coating is obtained. According to the multi-principal-element alloy material coating and the preparation method thereof, the multi-principal-element alloy material coating uniform in component can be obtained, and forming of intermetallic compounds is effectively inhibited; and the method process is simple, the equipment cost is low, operation is controllable, the production efficiency is high, and the suitable material range is wide.
Description
Technical field
The invention belongs to metal material and its preparation field, and in particular to a kind of multi-principal elements alloy material coating and its preparation
Method.
Background technology
In order to improve the wearability of instrument, by anti abrasive material（Such as：Carbonization base, nitridation base, boronation base, silication base and
Oxidation base superhard material etc.）Coating is applied on the matrix of all kinds of instruments, and one or more layers may be included on these coating structures.
Such as：The superhard material coating of titanium aluminium nickel (TiAlN) base is widely used in the polishing machine for improving cutter, different Al contents pair
In improve it is wear-resistant and it is anti-oxidant generate influence, and other elements also have an impact to wear-resistant in titanium nitride coating, especially
It is the titanium nitride coating using PVD production.The alloy of traditional coating leads to generally using one or two elements as pivot
Cross and add specific a small amount of alloying element improvement performance, but alloying element species can excessively cause intermetallic compound especially crisp
Property intermetallic compound appearance, so as to cause alloy overall performance reduction.Multi-principal elements alloy has been jumped out based on single-element
The design philosophy of conventional alloys, alloy is mixed to form by nearly equimolar than various metals atom.Such alloy is possible to logical
New microstructure is formed after crossing alloying and processing and with excellent properties, so as to break through traditional metal materials performance boundary,
Meet higher demand of the industrial technology development to material.Therefore exploitation novel alloy coating can not only improve the resistance to of all kinds of instruments
Mill property, can also be such that its combination property is further optimized, and exploitation new coating is significant with multi-principal elements alloy.
The content of the invention
The present invention is regarding to the issue above, there is provided a kind of multi-principal elements alloy material coating and preparation method thereof.
Realize the technical scheme is that：A kind of multi-principal elements alloy material coating, the multi-principal elements alloy of prepares coating
Including metal dust and rare earth oxide, the chemical formula of multi-principal elements alloy is AlxCoCuFeyMnzNiRep, wherein 0.1≤x≤
1.2；0.1≤y≤1.2；0.1≤z≤1.2；0≤p≤0.5；And 0.02≤x/ (x+y+z+p+3)≤0.20；0.02≤y/(x+
y+z+p+3)≤0.20；0.02≤z/(x+y+z+p+3)≤0.20；0≤p/(x+y+z+p+3)≤0.10；Re is Ce or Y.
The purity of the metal dust is higher than 99.5%, and the purity of the rare earth oxide is higher than 99.9%.
The preparation method of described multi-principal elements alloy material coating, step is as follows：
（1）Metal dust and rare earth oxide are placed in ball grinder, stainless steel ball is added, then in an inert atmosphere will
Ball grinder is sealed；
（2）By step（1）The ball grinder of good seal is placed in and batch mixing is carried out on planetary ball mill, and batch mixing rotating speed is 50 ~ 250rpm,
Time is 0.5-6h；
（3）With step（2）On the basis of powder after batch mixing, in the powder after batch mixing add 97wt% the saturating alcohol of turpentine oil and
The ethyl cellulose of 3wt% is modulated into pasty state, pasty state batch mixing is applied and is formed on matrix, is dried at 80 ~ 120 DEG C；
（4）In step（3）In to coat and carry out plasma cladding, cladding 120 ~ 137A of electric current, cladding voltage on the matrix of batch mixing
34V, plasma arc translational speed is 120 ~ 180mm/min, and cladding completes to obtain multi-principal elements alloy coating.
The step（1）Middle inert gas is argon gas or nitrogen.
The step（3）In matrix be any in aluminium, aluminium alloy, copper, copper alloy, nickel, nickel alloy, iron and ferroalloy
Kind.
The beneficial effects of the invention are as follows：The inventive method is obtained in that the uniform multi-principal elements alloy material coating of composition, has
Effect suppresses the formation of intermetallic compound；The method process is simple, equipment cost is low, and the controllable, production efficiency of operation is high, be applicable material
Material scope is wide.
Brief description of the drawings
Fig. 1 is multi-principal elements alloy AlCoCuFeMnNiCe prepared by embodiment 10.01X ray diffracting spectrum.
Specific embodiment
Technical solution of the present invention is not limited to the specific embodiment of act set forth below, also including each specific embodiment it
Between any combination.
Embodiment 1
By chemical formula AlCoCuFeMnNiCe0.01Aluminium powder, cobalt powder, copper powder, iron powder, manganese powder and the nickel powder of 0.43mol are weighed respectively
With the cerium oxide of 0.0043mol, the purity of various simple metal powder is above 99.5%, and the purity of cerium oxide is higher than 99.9%；To claim
Measured above-mentioned pure metal powder and cerium oxide are placed in ball grinder, add appropriate stainless steel ball, then in a nitrogen environment
The ball grinder that raw material will be placed with is sealed；The ball grinder of above-mentioned good seal is placed in carries out batch mixing on planetary ball mill, mix
Material rotating speed is 150rpm, and the time is 2h；The saturating alcohol of 97wt% turpentine oil and 3wt% ethyls are added in powder after above-mentioned uniform batch mixing
Cellulose is modulated into pasty state, is formed on matrix in advance, is dried at 90 DEG C；Carried out on the matrix material aluminium for be prefabricated with raw material etc. from
Sub- cladding, cladding electric current 130A, cladding voltage 34V, plasma arc translational speed are 160mm/min, and cladding is completed i.e. in matrix
On prepare required multi-principal elements alloy coating.
Embodiment 2
By chemical formula Al0.1CoCuFeMnNiCe0.01Weigh respectively the aluminium powder of 0.043mol, the cobalt powder of 0.43mol, copper powder iron powder,
The cerium oxide of manganese powder and nickel powder and 0.0043mol, the purity of various simple metal powder is above 99.5%, and the purity of cerium oxide is higher than
99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball, Ran Hou is added
The ball grinder that raw material will be placed with nitrogen environment is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill enterprising
Row batch mixing, batch mixing rotating speed is 100rpm, and the time is 4h；The saturating alcohol of 97wt% turpentine oil is added in powder after above-mentioned uniform batch mixing
Pasty state is modulated into 3wt% ethyl celluloses, is formed on matrix in advance, dried at 100 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 125A, cladding voltage 34V are carried out on aluminium alloy, plasma arc translational speed is 140mm/min,
Cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 3
By chemical formula AlCoCuFe0.1MnNiCe0.01Weigh respectively the aluminium powder of 0.43mol, cobalt powder, copper powder, manganese powder and nickel powder,
The iron powder of 0.043mol and the cerium oxide of 0.0043mol, the purity of various simple metal powder are above 99.5%, the purity of cerium oxide
Higher than 99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball is added, so
The ball grinder that raw material will be placed with a nitrogen environment afterwards is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill
On carry out batch mixing, batch mixing rotating speed is 50rpm, and the time is 6h；Add 97wt% turpentine oil saturating in powder after above-mentioned uniform batch mixing
Alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 120 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 120A, cladding voltage 34V are carried out on material copper, plasma arc translational speed is 120mm/min, is melted
Cover and complete to prepare required multi-principal elements alloy coating on matrix.
Embodiment 4
By chemical formula AlCoCuFeMn0.1NiCe0.01Weigh respectively the aluminium powder of 0.43mol, cobalt powder, copper powder, iron powder and nickel powder,
The manganese powder of 0.043mol and the cerium oxide of 0.0043mol, the purity of various simple metal powder are above 99.5%, the purity of cerium oxide
Higher than 99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball is added, so
The ball grinder that raw material will be placed with a nitrogen environment afterwards is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill
On carry out batch mixing, batch mixing rotating speed is 250rpm, and the time is 0.5h；97wt% turpentines are added in powder after above-mentioned uniform batch mixing
Oily alcohol and 3wt% ethyl celluloses thoroughly are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix of raw material
Plasma cladding, cladding electric current 137A, cladding voltage 34V are carried out on material copper alloy, plasma arc translational speed is 180mm/
Min, cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 4
Weigh aluminium powder, cobalt powder, copper powder, iron powder, manganese powder and the nickel powder of 0.43mol respectively by chemical formula AlCoCuFeMnNi, it is various
The purity of simple metal powder is above 99.5%；Load weighted above-mentioned pure metal powder is placed in ball grinder, is added appropriate stainless
Steel ball, the ball grinder that raw material then will be placed with a nitrogen environment is sealed；The ball grinder of above-mentioned good seal is placed in planet
Batch mixing is carried out on formula ball mill, batch mixing rotating speed is 250rpm, and the time is 2h；Added in powder after above-mentioned uniform batch mixing
The saturating alcohol of 97wt% turpentine oil and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 100 DEG C；It is being prefabricated with
Plasma cladding, cladding electric current 125A, cladding voltage 34V are carried out on the matrix material nickel of raw material, plasma arc translational speed is
120mm/min, cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 5
By chemical formula Al0.5CoCuFeMnNiY0.023The aluminium powder of 0.215mol and the cobalt powder of 0.43mol, copper powder, iron are weighed respectively
The yittrium oxide of powder, manganese powder and nickel powder and 0.01mol, the purity of various simple metal powder is above 99.5%, and the purity of yittrium oxide is higher than
99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball, Ran Hou is added
The ball grinder that raw material will be placed with ar gas environment is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill enterprising
Row batch mixing, batch mixing rotating speed is 200rpm, and the time is 2.5h；Add 97wt% turpentine oil saturating in powder after above-mentioned uniform batch mixing
Alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 130A, cladding voltage 34V are carried out on nickel alloy, plasma arc translational speed is 160mm/min,
Cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 6
By chemical formula Al0.5CoCuFeMn0.5NiY0.023Weigh respectively aluminium powder, manganese powder and the 0.43mol of 0.215mol cobalt powder,
The yittrium oxide of copper powder, iron powder and nickel powder and 0.01mol, the purity of various simple metal powder is above 99.5%, and the purity of yittrium oxide is high
In 99.9%；Load weighted above-mentioned pure metal powder and yittrium oxide are placed in ball grinder, appropriate stainless steel ball is added, then
The ball grinder that raw material will be placed with ar gas environment is sealed；The ball grinder of above-mentioned good seal is placed on planetary ball mill
Batch mixing is carried out, batch mixing rotating speed is 100rpm, and the time is 4h；Add 97wt% turpentine oil saturating in powder after above-mentioned uniform batch mixing
Alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 125A, cladding voltage 34V are carried out on iron, plasma arc translational speed is 120mm/min, cladding
Complete to prepare required multi-principal elements alloy coating on matrix.
Embodiment 7
By chemical formula Al0.5CoCuFe0.5MnNiY0.023Weigh respectively aluminium powder, iron powder and the 0.43mol of 0.215mol cobalt powder,
The yittrium oxide of copper powder, manganese powder and nickel powder and 0.01mol, the purity of various simple metal powder is above 99.5%, and the purity of yittrium oxide is high
In 99.9%；Load weighted above-mentioned pure metal powder and yittrium oxide are placed in ball grinder, appropriate stainless steel ball is added, then
The ball grinder that raw material will be placed with ar gas environment is sealed；The ball grinder of above-mentioned good seal is placed on planetary ball mill
Batch mixing is carried out, batch mixing rotating speed is 250rpm, and the time is 0.5h；97wt% turpentine oil is added in powder after above-mentioned uniform batch mixing
Saturating alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 137A, cladding voltage 34V are carried out on material ferroalloy, plasma arc translational speed is 180mm/
Min, cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 8
By chemical formula Al0.1CoCuFeMnNiY0.5Weigh respectively the aluminium powder of 0.043mol, the cobalt powder of 0.43mol, copper powder, iron powder,
The yittrium oxide of manganese powder and nickel powder and 0.215mol, the purity of various simple metal powder is above 99.5%, and the purity of yittrium oxide is higher than
99.9%；Load weighted above-mentioned pure metal powder and yittrium oxide are placed in ball grinder, appropriate stainless steel ball, Ran Hou is added
The ball grinder that raw material will be placed with ar gas environment is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill enterprising
Row batch mixing, batch mixing rotating speed is 250rpm, and the time is 0.5h；Add 97wt% turpentine oil saturating in powder after above-mentioned uniform batch mixing
Alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix material of raw material
Upper ferroalloy carries out plasma cladding, cladding electric current 137A, cladding voltage 34V, and plasma arc translational speed is 180mm/min,
Cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 9
By chemical formula Al1.2CoCuFeMnNiCe0.01Weigh respectively the aluminium powder of 0.516mol, the cobalt powder of 0.43mol, copper powder iron powder,
The cerium oxide of manganese powder and nickel powder and 0.0043mol, the purity of various simple metal powder is above 99.5%, and the purity of cerium oxide is higher than
99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball, Ran Hou is added
The ball grinder that raw material will be placed with nitrogen environment is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill enterprising
Row batch mixing, batch mixing rotating speed is 100rpm, and the time is 4h；The saturating alcohol of 97wt% turpentine oil is added in powder after above-mentioned uniform batch mixing
Pasty state is modulated into 3wt% ethyl celluloses, is formed on matrix in advance, dried at 100 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 125A, cladding voltage 34V are carried out on aluminium alloy, plasma arc translational speed is 140mm/min,
Cladding completes to prepare required multi-principal elements alloy coating on matrix.
Embodiment 10
By chemical formula AlCoCuFe1.2MnNiCe0.01Weigh respectively the aluminium powder of 0.43mol, cobalt powder, copper powder, manganese powder and nickel powder,
The iron powder of 0.516mol and the cerium oxide of 0.0043mol, the purity of various simple metal powder are above 99.5%, the purity of cerium oxide
Higher than 99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball is added, so
The ball grinder that raw material will be placed with a nitrogen environment afterwards is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill
On carry out batch mixing, batch mixing rotating speed is 50rpm, and the time is 6h；Add 97wt% turpentine oil saturating in powder after above-mentioned uniform batch mixing
Alcohol and 3wt% ethyl celluloses are modulated into pasty state, are formed on matrix in advance, are dried at 120 DEG C；It is being prefabricated with the matrix material of raw material
Plasma cladding, cladding electric current 120A, cladding voltage 34V are carried out on material copper, plasma arc translational speed is 120mm/min, is melted
Cover and complete to prepare required multi-principal elements alloy coating on matrix.
Embodiment 10
By chemical formula AlCoCuFeMn1.2NiCe0.01Weigh respectively the aluminium powder of 0.43mol, cobalt powder, copper powder, iron powder and nickel powder,
The manganese powder of 0.516mol and the cerium oxide of 0.0043mol, the purity of various simple metal powder are above 99.5%, the purity of cerium oxide
Higher than 99.9%；Load weighted above-mentioned pure metal powder and cerium oxide are placed in ball grinder, appropriate stainless steel ball is added, so
The ball grinder that raw material will be placed with a nitrogen environment afterwards is sealed；The ball grinder of above-mentioned good seal is placed in planetary ball mill
On carry out batch mixing, batch mixing rotating speed is 250rpm, and the time is 0.5h；97wt% turpentines are added in powder after above-mentioned uniform batch mixing
Oily alcohol and 3wt% ethyl celluloses thoroughly are modulated into pasty state, are formed on matrix in advance, are dried at 80 DEG C；It is being prefabricated with the matrix of raw material
Plasma cladding, cladding electric current 137A, cladding voltage 34V are carried out on material copper alloy, plasma arc translational speed is 180mm/
Min, cladding completes to prepare required multi-principal elements alloy coating on matrix.
Claims (5)
1. a kind of multi-principal elements alloy material coating, it is characterised in that：The multi-principal elements alloy of prepares coating include metal dust and
Rare earth oxide, the chemical formula of multi-principal elements alloy is AlxCoCuFeyMnzNiRep, wherein 0.1≤x≤1.2；0.1≤y≤1.2；
0.1≤z≤1.2；0≤p≤0.5；And 0.02≤x/ (x+y+z+p+3)≤0.20；0.02≤y/(x+y+z+p+3)≤0.20；
0.02≤z/(x+y+z+p+3)≤0.20；0≤p/(x+y+z+p+3)≤0.10；Re is Ce or Y.
2. multi-principal elements alloy material coating according to claim 1, it is characterised in that：The purity of the metal dust is high
In 99.5%, the purity of the rare earth oxide is higher than 99.9%.
3. the preparation method of the multi-principal elements alloy material coating described in claim 1, it is characterised in that step is as follows：
（1）Metal dust and rare earth oxide are placed in ball grinder, stainless steel ball is added, then in an inert atmosphere will
Ball grinder is sealed；
（2）By step（1）The ball grinder of good seal is placed in and batch mixing is carried out on planetary ball mill, and batch mixing rotating speed is 50 ~ 250rpm,
Time is 0.5-6h；
（3）With step（2）On the basis of powder after batch mixing, in the powder after batch mixing add 97wt% the saturating alcohol of turpentine oil and
The ethyl cellulose of 3wt% is modulated into pasty state, pasty state batch mixing is applied and is formed on matrix, is dried at 80 ~ 120 DEG C；
（4）In step（3）In to coat and carry out plasma cladding, cladding 120 ~ 137A of electric current, cladding voltage on the matrix of batch mixing
34V, plasma arc translational speed is 120 ~ 180mm/min, and cladding completes to obtain multi-principal elements alloy coating.
4. the preparation method of multi-principal elements alloy material coating according to claim 3, it is characterised in that：The step（1）
Middle inert gas is argon gas or nitrogen.
5. the preparation method of multi-principal elements alloy material coating according to claim 3, it is characterised in that：The step（3）
In matrix be any one in aluminium, aluminium alloy, copper, copper alloy, nickel, nickel alloy, iron and ferroalloy.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103060797A (en) * | 2013-01-14 | 2013-04-24 | 北京工业大学 | Preparation method of plasma cladding high-entropy alloy coating layer |
| CN104561878A (en) * | 2013-10-29 | 2015-04-29 | 比亚迪股份有限公司 | High-entropy alloy powder for spray coating and preparation method thereof, as well as composite material and preparation method thereof |
| CN106041031A (en) * | 2016-07-29 | 2016-10-26 | 河海大学常州校区 | Preparation method of high-entropy alloy coating layer on surface of casting |
-
2017
- 2017-03-02 CN CN201710120455.0A patent/CN106676522A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103060797A (en) * | 2013-01-14 | 2013-04-24 | 北京工业大学 | Preparation method of plasma cladding high-entropy alloy coating layer |
| CN104561878A (en) * | 2013-10-29 | 2015-04-29 | 比亚迪股份有限公司 | High-entropy alloy powder for spray coating and preparation method thereof, as well as composite material and preparation method thereof |
| CN106041031A (en) * | 2016-07-29 | 2016-10-26 | 河海大学常州校区 | Preparation method of high-entropy alloy coating layer on surface of casting |
Non-Patent Citations (1)
| Title |
|---|
| 卢金斌等: "Q235钢等离子熔覆CoCrCuFeMnNi高熵合金涂层", 《金属热处理》 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Address after: 451191 No. 1 Huaihe Road, Shuang Hu Economic and Technological Development Zone, Xinzheng, Zhengzhou, Henan Applicant after: Zhongyuan University of Technology Address before: 451191 No. 1 Huaihe Road, Shuanghu Town Economic and Technological Development Zone, Zhengzhou City, Henan Province Applicant before: Zhongyuan University of Technology |
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