CN106676505A - Environment-friendly normal-temperature copper alloy blackening agent - Google Patents

Environment-friendly normal-temperature copper alloy blackening agent Download PDF

Info

Publication number
CN106676505A
CN106676505A CN201510758575.4A CN201510758575A CN106676505A CN 106676505 A CN106676505 A CN 106676505A CN 201510758575 A CN201510758575 A CN 201510758575A CN 106676505 A CN106676505 A CN 106676505A
Authority
CN
China
Prior art keywords
copper alloy
blackening agent
parts
environment
temperature copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510758575.4A
Other languages
Chinese (zh)
Inventor
宋振兴
谢玉娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Ruisaike New Material Technology Co Ltd
Original Assignee
Tianjin Ruisaike New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Ruisaike New Material Technology Co Ltd filed Critical Tianjin Ruisaike New Material Technology Co Ltd
Priority to CN201510758575.4A priority Critical patent/CN106676505A/en
Publication of CN106676505A publication Critical patent/CN106676505A/en
Pending legal-status Critical Current

Links

Landscapes

  • Chemical Treatment Of Metals (AREA)

Abstract

The invention provides an environment-friendly normal-temperature copper alloy blackening agent. The environment-friendly normal-temperature copper alloy blackening agent is composed of, by mass, 6-10 parts of water, 0.1-0.5 part of selenium oxide, 0.1-0.6 part of urotropine, 0.1-0.5 part of OP-10, 0.1-0.5 part of NNO, 0.1-1 part of copper nitrate and 0.1-1 part of nickel nitrate. According to the environment-friendly normal-temperature copper alloy blackening agent, the content of heavy metal is low, reaction is sufficient and occurs at normal temperature, and the environment-friendly normal-temperature copper alloy blackening agent has the characteristics of being environmentally friendly, saving energy and being easy and convenient to operate.

Description

A kind of environmentally friendly normal temperature copper alloy blackening agent for surface
Technical field
The present invention relates to a kind of environmentally friendly normal temperature copper alloy blackening agent for surface.
Background technology
To meet requirement of the decorations industry for copper alloy surface color and decay resistance, at present conventional high temperature blackening agent for surface processes copper alloy surface, so as to obtain black or browned surface.This high temperature blackening agent for surface needs to can be only achieved preferably decoration and anticorrosion effect under 90 degrees Celsius of conditions above, and heavy metal environmental pollution contained therein is very big.The present invention can carry out surface blackening process under normal temperature condition to copper alloy, and the present invention is applied in into copper alloy surface, after surface color is changed into black or brown, that is, completes blackening and improve alloy corrosion resistance energy simultaneously.Because content of beary metal is low contained by the present invention, and consume completely during the course of the reaction.Therefore the characteristics of copper alloy blackening agent for surface that the present invention is provided has environmental protection and energy saving.
The content of the invention
For the deficiencies in the prior art, the technical problem to be solved is to provide a kind of environmentally friendly normal temperature copper alloy blackening agent for surface, and content of beary metal is low, and reaction is complete, normal-temperature reaction, with environmental protection and energy saving and it is easy to operate the characteristics of.
To solve above-mentioned technical problem, the present invention adopts the technical scheme that a kind of environmentally friendly normal temperature copper alloy blackening agent for surface is made up of the raw material of following mass fraction:Water 6-10 parts, the sub- selenium 0.1-0.5 parts of oxidation, methenamine 0.1-0.6 parts, OP-10 0.1-0.5 parts, NNO 0.1-0.5 parts, copper nitrate 0.1-1 parts, nickel nitrate 0.1-1 parts.
The technical scheme of present invention optimization is that a kind of environmentally friendly normal temperature copper alloy blackening agent for surface is made up of the raw material of following mass fraction:6 parts of water, sub- 0.1 part of the selenium of oxidation, 0.1 part of methenamine, 0.1 part of OP-10,0.1 part of NNO, 0.1 part of copper nitrate, 0.1 part of nickel nitrate.
The technical scheme of present invention optimization is that a kind of environmentally friendly normal temperature copper alloy blackening agent for surface is made up of the raw material of following mass fraction:10 parts of water, sub- 0.5 part of the selenium of oxidation, 0.6 part of methenamine, 0.5 part of OP-10,0.5 part of NNO, 1 part of copper nitrate, 1 part of nickel nitrate.
The technical scheme of present invention optimization is that a kind of environmentally friendly normal temperature copper alloy blackening agent for surface is made up of the raw material of following mass fraction:8 parts of water, sub- 0.2 part of the selenium of oxidation, 0.5 part of methenamine, 0.2 part of OP-10,0.2 part of NNO, 0.4 part of copper nitrate, 0.3 part of nickel nitrate.
The invention has the beneficial effects as follows, the environmentally friendly normal temperature copper alloy blackening agent for surface of the present invention, content of beary metal is low, and reaction is complete, normal-temperature reaction, with environmental protection and energy saving and it is easy to operate the characteristics of.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are only illustrative of the invention and is not intended to limit the scope of the invention.In addition, it is to be understood that after present disclosure has been read, those skilled in the art can make various changes or modifications to the present invention, these equivalent form of values equally fall within scope defined herein.
Embodiment 1,
A kind of environmentally friendly normal temperature copper alloy blackening agent for surface, is made up of the raw material of following mass fraction:
6 parts of water, sub- 0.1 part of the selenium of oxidation, 0.1 part of methenamine, 0.1 part of OP-10,0.1 part of NNO, 0.1 part of copper nitrate, 0.1 part of nickel nitrate.
Embodiment 2,
A kind of environmentally friendly normal temperature copper alloy blackening agent for surface, is made up of the raw material of following mass fraction:
10 parts of water, sub- 0.5 part of the selenium of oxidation, 0.6 part of methenamine, 0.5 part of OP-10,0.5 part of NNO, 1 part of copper nitrate, 1 part of nickel nitrate.
Embodiment 3,
A kind of environmentally friendly normal temperature copper alloy blackening agent for surface, is made up of the raw material of following mass fraction:
8 parts of water, sub- 0.2 part of the selenium of oxidation, 0.5 part of methenamine, 0.2 part of OP-10,0.2 part of NNO, 0.4 part of copper nitrate, 0.3 part of nickel nitrate.
Although the present invention is disclosed as above with preferred embodiment, so it is not limited to the present invention, and any person of ordinary skill in the field, in the change done without departing from the spirit and scope of the present invention and improvement, falls within protection scope of the present invention.

Claims (4)

1. a kind of environmentally friendly normal temperature copper alloy blackening agent for surface, it is characterised in that:It is made up of the raw material of following mass fraction:Water 6-10 parts, the sub- selenium 0.1-0.5 parts of oxidation, methenamine 0.1-0.6 parts, OP-10 0.1-0.5 parts, NNO 0.1-0.5 parts, copper nitrate 0.1-1 parts, nickel nitrate 0.1-1 parts.
2. environmentally friendly normal temperature copper alloy blackening agent for surface according to claim 1, it is characterised in that:It is made up of the raw material of following mass fraction:6 parts of water, sub- 0.1 part of the selenium of oxidation, 0.1 part of methenamine, OP-10 0.1 part, 0.1 part of NNO, 0.1 part of copper nitrate, 0.1 part of nickel nitrate.
3. environmentally friendly normal temperature copper alloy blackening agent for surface according to claim 1, it is characterised in that:It is made up of the raw material of following mass fraction:10 parts of water, sub- 0.5 part of the selenium of oxidation, 0.6 part of methenamine, OP-10 0.5 part, 0.5 part of NNO, 1 part of copper nitrate, 1 part of nickel nitrate.
4. environmentally friendly normal temperature copper alloy blackening agent for surface according to claim 1, it is characterised in that:It is made up of the raw material of following mass fraction:8 parts of water, sub- 0.2 part of the selenium of oxidation, 0.5 part of methenamine, OP-10 0.2 part, 0.2 part of NNO, 0.4 part of copper nitrate, 0.3 part of nickel nitrate.
CN201510758575.4A 2015-11-10 2015-11-10 Environment-friendly normal-temperature copper alloy blackening agent Pending CN106676505A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510758575.4A CN106676505A (en) 2015-11-10 2015-11-10 Environment-friendly normal-temperature copper alloy blackening agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510758575.4A CN106676505A (en) 2015-11-10 2015-11-10 Environment-friendly normal-temperature copper alloy blackening agent

Publications (1)

Publication Number Publication Date
CN106676505A true CN106676505A (en) 2017-05-17

Family

ID=58864410

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510758575.4A Pending CN106676505A (en) 2015-11-10 2015-11-10 Environment-friendly normal-temperature copper alloy blackening agent

Country Status (1)

Country Link
CN (1) CN106676505A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110042379A (en) * 2019-03-27 2019-07-23 祝亚琴 Copper blackening agent for surface
CN111748810A (en) * 2020-06-30 2020-10-09 广东天承科技有限公司 Blackening solution and preparation method and use method thereof
CN112626508A (en) * 2020-11-19 2021-04-09 广州三孚新材料科技股份有限公司 Surface treatment liquid for copper or copper alloy plate and preparation method and application thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110042379A (en) * 2019-03-27 2019-07-23 祝亚琴 Copper blackening agent for surface
CN111748810A (en) * 2020-06-30 2020-10-09 广东天承科技有限公司 Blackening solution and preparation method and use method thereof
CN111748810B (en) * 2020-06-30 2021-03-26 广东天承科技股份有限公司 Blackening solution and preparation method and use method thereof
CN112626508A (en) * 2020-11-19 2021-04-09 广州三孚新材料科技股份有限公司 Surface treatment liquid for copper or copper alloy plate and preparation method and application thereof
CN112626508B (en) * 2020-11-19 2022-11-11 广州三孚新材料科技股份有限公司 Surface treatment liquid for copper or copper alloy plate and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN106676505A (en) Environment-friendly normal-temperature copper alloy blackening agent
CN104962180A (en) Silver wear-resisting powder coating and manufacturing and using methods thereof
CN204358275U (en) A kind of refractory metal pipeline
CN100554525C (en) A kind of passivation-free, non-oxygen washing-plate drying plate manganese electrolyzation
CN202960049U (en) Liner applied to electric cookers and electric pressure cookers
CN207316209U (en) One kind is by stainless steel and the molding faucet handle of plastic composition
CN204344926U (en) A kind of finishing mill seal ring
CN202893844U (en) Rolled steel billet with surface coated with heat-resistant anti-oxidation layer
CN205807832U (en) A kind of air energy thermal water machine using foamed material shell
CN204787791U (en) Electromagnetic heating aluminium metallurgy stove
CN203174161U (en) Novel electrical steel high-temperature bell furnace production system
CN107987629A (en) A kind of steel pipe anticorrosion paint
CN204151437U (en) A kind of electrophoresis hanging tool
CN203982974U (en) A kind of transformer core
CN205245814U (en) Smelting furnace
CN202954509U (en) Inner wall decorative plate
CN206151224U (en) Heat -insulation electric kettle
CN204607908U (en) A kind of green adhesive tape
CN202984856U (en) Welding nozzle applied to electromagnetic induction type unleaded welding table
CN202246088U (en) Reduction electrode bar for producing polycrystalline silicon by siemens process
CN202804075U (en) Evanescent mould with protective layer
CN203190005U (en) Antioxidant seamless steel pipe for gas cylinder
CN205064429U (en) Feed hydro -cylinder flange who uses in pipe cutting machine
CN204394224U (en) A kind of energy-conservation metal kettle
CN202945279U (en) Annealing hearth

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170517

WD01 Invention patent application deemed withdrawn after publication