CN106675436B - A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof - Google Patents

A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof Download PDF

Info

Publication number
CN106675436B
CN106675436B CN201710002810.4A CN201710002810A CN106675436B CN 106675436 B CN106675436 B CN 106675436B CN 201710002810 A CN201710002810 A CN 201710002810A CN 106675436 B CN106675436 B CN 106675436B
Authority
CN
China
Prior art keywords
sealant
liquid crystal
absorption agent
ions absorption
main body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710002810.4A
Other languages
Chinese (zh)
Other versions
CN106675436A (en
Inventor
武晓娟
郑琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BOE Technology Group Co Ltd
Beijing BOE Optoelectronics Technology Co Ltd
Original Assignee
BOE Technology Group Co Ltd
Beijing BOE Optoelectronics Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BOE Technology Group Co Ltd, Beijing BOE Optoelectronics Technology Co Ltd filed Critical BOE Technology Group Co Ltd
Priority to CN201710002810.4A priority Critical patent/CN106675436B/en
Publication of CN106675436A publication Critical patent/CN106675436A/en
Application granted granted Critical
Publication of CN106675436B publication Critical patent/CN106675436B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • G02F1/13398Spacer materials; Spacer properties

Landscapes

  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mathematical Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Organic Chemistry (AREA)
  • Liquid Crystal (AREA)
  • Sealing Material Composition (AREA)

Abstract

The embodiment of the present invention provides a kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof, is related to field of display technology, it is possible to reduce the activity substance content of liquid crystal region, and then improve angle nigrescence bad phenomenon.The sealant includes main body glue material, further includes the Ions Absorption agent being dispersed in the main body glue material.

Description

A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof
Technical field
The present invention relates to field of display technology more particularly to a kind of sealant and preparation method thereof, liquid crystal display panel and Preparation method.
Background technique
Liquid crystal monomer in the synthesis process, irradiates, high temperature action, Yi Jigao at ultraviolet light (ultraviolet, abbreviation UV) Under wet environment, it is all easy to produce active material.
Currently, in liquid crystal display panel manufacturing process, array substrate and to box substrate to box after, need to carry out sealant Thermal polymerization processing and UV polymerization processing.However since liquid crystal monomer is under the action of UV illumination, high temperature, it is easier to generate active matter Matter causes to generate active matter in liquid crystal monomer synthesis process when carrying out thermal polymerization processing and UV polymerization processing to sealant On the basis of matter, more active materials are generated.
Wherein, in UV polymerisation process, as shown in Figure 1, liquid crystal 10 is generally used UV by UV illumination in order to prevent Mask plate 40 covers liquid crystal region, and in order to ensure sealant 30 polymerize completely, UV mask plate 40 is at four angles of liquid crystal region Position is designed using radian, and the position at such four angles of liquid crystal region is easier to be caused by UV illumination compared to liquid crystal region Other positions, the active material 20 that the position at four angles of liquid crystal region generates are more.
When the liquid crystal display of normally black mode, when long-term lighting or high temperature and humidity trust test, due to oxygen etc. into Enter, so that the position at four angles of liquid crystal region is generated more active materials 20, upset the arrangement of liquid crystal 10 at this position, make its rotation Turn not in place or do not rotate, cannot pass through so as to cause light, generates angle nigrescence bad phenomenon.
Summary of the invention
The embodiment of the present invention provides a kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof, can To reduce the activity substance content of liquid crystal region, and then improve angle nigrescence bad phenomenon.
In order to achieve the above objectives, the embodiment of the present invention adopts the following technical scheme that
It further include the ion being dispersed in the main body glue material in a first aspect, providing a kind of sealant, including main body glue material Absorbent.
Preferably, the mass fraction of main body glue material described in the sealant is 95~99.5%, institute in the sealant The mass fraction for stating Ions Absorption agent is 0.5~5%.
Preferably, the Ions Absorption agent includes cyclic annular hydrogen bound to nitrogen.
It is further preferred that the Ions Absorption agent includes that structural formula isOne Kind Ions Absorption agent;Wherein, R is alkyl.
Second aspect provides a kind of preparation method of sealant, comprising: by main body glue material and Ions Absorption agent mixture It is even, form the mixture of the main body glue material and the Ions Absorption agent;By the main body glue material and the Ions Absorption agent Mixture, which is put into deaerator, be protected from light deaeration processing, forms sealant.
Preferably, the mass fraction of main body glue material described in the sealant is 95~99.5%, institute in the sealant The mass fraction for stating Ions Absorption agent is 0.5~5%.
Preferably, the Ions Absorption agent includes cyclic annular hydrogen bound to nitrogen.
The third aspect provides a kind of liquid crystal display panel, including first substrate, the second substrate and liquid crystal layer, the liquid crystal Layer is fixed between the first substrate and the second substrate by sealant, and the sealant is envelope described in first aspect Frame glue.
Preferably, the liquid crystal monomer in the liquid crystal layer is negativity liquid crystal monomer.
Fourth aspect provides a kind of preparation method of liquid crystal display panel, comprising: by what is be prepared by second aspect Sealant is protected from light, is uniformly coated on first substrate;The second substrate for having liquid crystal and described first coated with sealant will be dripped Substrate forms liquid crystal display panel to box;The liquid crystal display panel is heated, and UV illumination is carried out to the sealant It penetrates.
The embodiment of the present invention provides a kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof, passes through Ions Absorption agent is spilt into the main body glue material of sealant, sealant is made to have the function of absorbing active material, when sealant is used When liquid crystal display panel, the active material in liquid crystal layer is absorbed, is made more easily by four angles of the liquid crystal region of UV illumination The activity substance content of position is reduced, so as to improve angle nigrescence bad phenomenon.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is a kind of top view for liquid crystal display panel that the prior art provides;
Fig. 2 is a kind of schematic diagram of sealant provided in an embodiment of the present invention;
Fig. 3 is a kind of flow diagram for preparing sealant provided in an embodiment of the present invention;
Fig. 4 is a kind of structural schematic diagram of liquid crystal display panel provided in an embodiment of the present invention;
Fig. 5 is a kind of flow diagram for preparing liquid crystal display panel provided in an embodiment of the present invention.
Appended drawing reference:
01- first substrate;02- the second substrate;03- liquid crystal layer;10- liquid crystal;20- active material;30- sealant;301- Main body glue material;302- Ions Absorption agent;40-UV mask plate.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The embodiment of the present invention provides a kind of sealant 30, further includes being dispersed in master as shown in Fig. 2, including main body glue material 301 Ions Absorption agent 302 in body glue material 301.
It should be noted that first, main body glue material 301 refers to the substance with adhesivity, can include but is not limited to by Resin material is constituted.There are many selections of resin material, such as can be epoxy resin, acrylic resin, bisphenol-A-type epoxy Resin, polyvinyl butyral resin, diethylene glycol monobutyl ether acetate, polyurethane resin containing carboxyl etc..Wherein, not to main body The model of glue material 301 is defined, such as can be SWB-73, is also possible to SUR-66.
In addition to above-mentioned main body glue material 301, Ions Absorption agent 302, may also include has curing agent (such as light is poly- sealant 30 Mixture) etc. the components such as additives and filler, can specifically continue to use the prior art.Wherein, with main body glue material 301 by epoxy resin For being constituted with the mixture of acrylic resin, the quality of epoxy resin and acrylic resin than range be 80%:20%~ 50%:50%, i.e. quality can be 4:1 than maximum value, and quality can be 1:1 than minimum value.
It is exemplary, epoxy resin: acrylic resin=3:1.
Here, since epoxy resin is Thermocurable, ratio can be more compared with acrylic resin, to guarantee sealant 30 is whole with enough cohesivenesses.
Second, Ions Absorption agent 302 has stronger adsorption capacity to active material 20, and changes with active material 20 Reaction is learned, active material 20 is converted to stable substance.
Herein, Ions Absorption agent 302 does not influence the cohesiveness of main body glue material 301.
Third, the embodiment of the present invention are not limited to sealant 30 and include a kind of Ions Absorption agent 302.
The embodiment of the present invention provides a kind of sealant 30, is inhaled by spilling into ion in the main body glue material 301 of sealant 30 Agent 302 is received, sealant 30 is made to have the function of absorbing active material 20, when sealant 30 is used for liquid crystal display panel, is absorbed Active material 20 in liquid crystal layer, make more easily by four angles of liquid crystal region of UV illumination position 20 content of active material It reduces, so as to improve angle nigrescence bad phenomenon.
In view of spilling into excessive Ions Absorption agent 302 in the main body glue material 301 of sealant 30, cause main in sealant 30 The mass fraction of body glue material 301 is too low, the cohesiveness of sealant 30 can be made to decline, therefore in order to guarantee cohering for sealant 30 Property, and do not influence the effect of Ions Absorption agent 302, it is preferred that in sealant 30 mass fraction of main body glue material 301 be 95~ 99.5%, the mass fraction of 30 intermediate ion absorbent 302 of sealant is 0.5~5%.
Exemplary, the mass fraction of main body glue material 301 is 97% in sealant 30, the mass fraction of Ions Absorption agent 302 It is 3%.Alternatively, the mass fraction of main body glue material 301 is 99% in sealant 30, the mass fraction of Ions Absorption agent 302 is 1%.Alternatively, the mass fraction of main body glue material 301 is 97.5% in sealant 30, the mass fraction of Ions Absorption agent 302 is 2.5%;.
Preferably, Ions Absorption agent 302 includes cyclic annular hydrogen bound to nitrogen.
Herein, the structural formula of cyclic annular hydrogen bound to nitrogen is
It should be noted that Ions Absorption agent 302 further includes other components, herein other than cyclic annular hydrogen bound to nitrogen Without limitation, as long as it can be made to form stable chemical substance with cyclic annular hydrogen bound to nitrogen.
In the embodiment of the present invention, cyclic annular hydrogen bound to nitrogen can be by free radical, group, free ion and organic peroxide The oxygen radical isoreactivity substance 20 generated is decomposed, the stable material for not influencing the arrangement of liquid crystal 10 is converted into.
It is further preferred that Ions Absorption agent 302 is including structural formulaOne Kind Ions Absorption agent 302;Wherein, R is alkyl.
Herein, R can be methyl (CH3), ethyl (CH3CH2) etc. alkyl.
Exemplary, Ions Absorption agent 302 is made of cyclic annular hydrogen bound to nitrogen and acetate, and structural formula is
Wherein, the structural formula of acetate is
The embodiment of the present invention also provides a kind of preparation method of sealant 30, as shown in figure 3, specifically can be as follows It realizes:
S10, main body glue material 301 and 302 mixture of Ions Absorption agent is uniform, formation main body glue material 301 and Ions Absorption agent 302 mixture.
S20, it the mixture of main body glue material 301 and Ions Absorption agent 302 is put into carries out being protected from light at deaeration in deaerator Reason forms sealant 30.
Herein, the time that sealant 30 carries out being protected from light in deaerator deaeration processing can be 1~5 hour, such as can be with It is 2 hours, 2.5 hours, 3 hours etc..
The embodiment of the present invention provides a kind of preparation method of sealant 30, by by mixed uniform 301 He of main body glue material Ions Absorption agent 302 carries out deaeration processing, forms sealant 30, makes it have the effect for absorbing active material 20.Work as sealant 30 be used for liquid crystal display panel when, absorb liquid crystal layer in active material 20, make the liquid crystal region four more easily by UV illumination 20 content of active material of the position at a angle is reduced, so as to improve angle nigrescence bad phenomenon.
In view of spilling into excessive Ions Absorption agent 302, main gel in sealant 30 in the main body glue material 301 of sealant 30 The mass fraction of material 301 is too low, the cohesiveness of sealant 30 can be made to decline, therefore the cohesiveness in order to guarantee sealant 30, and The effect of Ions Absorption agent 302 is not influenced, it is preferred that the mass fraction of main body glue material 301 is 95~99.5% in sealant 30, The mass fraction of 30 intermediate ion absorbent 302 of sealant is 0.5~5%.
Preferably, Ions Absorption agent 302 includes cyclic annular hydrogen bound to nitrogen.
Herein, the structural formula of cyclic annular hydrogen bound to nitrogen is
In the embodiment of the present invention, cyclic annular hydrogen bound to nitrogen can be by free radical, group, free ion and organic peroxide The oxygen radical isoreactivity substance 20 generated is decomposed, the stable material for not influencing the arrangement of liquid crystal 10 is converted into.
The embodiment of the present invention also provides a kind of liquid crystal display panel, as shown in figure 4, including first substrate 01, the second substrate 02 and liquid crystal layer 03, liquid crystal layer 03 is fixed between first substrate 01 and the second substrate 02 by sealant 30, and sealant 30 is The sealant 30 of the aforementioned any embodiment of the present invention.
Working principle of the Ions Absorption agent 302 in liquid crystal display panel are as follows: Ions Absorption agent 302 first absorbs liquid crystal region The active material 20 of marginal position, after absorbing to a certain extent, the active material concentration in liquid crystal region middle position is greater than liquid crystal The active material concentration of edges of regions position, at this point, due to there is concentration difference therebetween, positioned at liquid crystal region middle position Active material 20 is moved to liquid crystal region marginal position, and Ions Absorption agent 302, which is absorbed, moves to liquid by liquid crystal region middle position The active material 20 of crystalline region domain marginal position.
Wherein, liquid crystal 10 is under UV illumination or heating condition, generates free radicals, group, free ion and organic mistake Oxide, wherein organic peroxide, which is easy to decompose, generates oxygen radical.
Specifically, the material of liquid crystal 10 includes alkane molecule, alkane (R'H) homolysis under UV illumination or heating condition is generated Alkyl diradical (R') and hydroperoxyl radical (H), that is,And R' and oxygen (O2) It can react and generate peroxy (R'OO), that is, R'+O2 → R'OO.
On this basis, by being added into sealant 30Ions Absorption agent 302, AndAsA kind of existence form, can be with liquid crystal layer 03 The R' of middle generation reacts, and generatesThis is stable material, that is,
Further,It can react, generate with the R'OO generated in liquid crystal layer 03With the substances such as stable alcohols or ketone, wherein generationIt can recycle.
On this basis, also other active matters can be absorbed by the way that other Ions Absorption agent 302 are added into sealant 30 Matter 20.
It should be noted that the second substrate 02 is color membrane substrates when first substrate 01 is array substrate;Work as first substrate 01 be color membrane substrates when, the second substrate 02 be array substrate.Certainly, color film may also be arranged in array substrate, be not provided at this time Having the substrate of color film can be described as to box substrate.
The embodiment of the present invention provides a kind of liquid crystal display panel, includes main body glue material by using in liquid crystal display panel 301 and Ions Absorption agent 302 sealant 30, make its absorb liquid crystal display panel liquid crystal layer 03 in active material 20, make more 20 content of active material for being easy the position at four angles of liquid crystal region by UV illumination is reduced, and is blacked so as to improve angle bad existing As.
Preferably, the liquid crystal monomer in liquid crystal layer 03 is negativity liquid crystal monomer.
In the embodiment of the present invention, liquid crystal is can be improved on the basis of improving liquid crystal display resolution ratio in negative liquid crystal monomer The aperture opening ratio and transmitance of display.
The embodiment of the present invention also provides a kind of preparation method of liquid crystal display panel, as shown in figure 5, specifically can be by as follows Step is realized:
S100, the sealant 30 that aforementioned any embodiment through the invention is prepared, are protected from light, are uniformly coated to first On substrate 01.
S200, drop there are the second substrate 02 of liquid crystal 10 and the first substrate 01 coated with sealant 30 to box, forms liquid LCD panel.
S300, liquid crystal display panel is heated, and the irradiation of UV light is carried out to sealant 30.
It should be noted that when carrying out thermal polymerization processing to sealant 30, due to being technically difficult to realize only to envelope frame Glue 30 heats, and therefore, heats to entire liquid crystal display panel.
And when carrying out UV polymerization processing to sealant 30, liquid crystal 10 is generally used UV mask by UV illumination in order to prevent Plate covers liquid crystal region, and the ultraviolet light for emitting UV lamp carries out the irradiation of UV light to sealant 30.
The embodiment of the present invention provides a kind of preparation method of liquid crystal display panel, has identical as foregoing liquid crystal display panel Technical effect, details are not described herein.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.

Claims (5)

1. a kind of sealant, including main body glue material, which is characterized in that further include the Ions Absorption being dispersed in the main body glue material Agent makes the liquid more easily by UV Light so that the sealant has the function of the absorption active material in liquid crystal layer The activity substance content of the position at four angles in crystalline region domain is reduced, and improves angle nigrescence bad phenomenon;
The mass fraction of main body glue material described in the sealant is 95~99.5%, Ions Absorption agent described in the sealant Mass fraction be 0.5~5%;
The Ions Absorption agent includes cyclic annular hydrogen bound to nitrogen;
The Ions Absorption agent includes that structural formula isA kind of Ions Absorption agent;
Wherein, R is alkyl.
2. a kind of preparation method of sealant characterized by comprising
Uniformly by main body glue material and Ions Absorption agent mixture, the mixture of the main body glue material and the Ions Absorption agent is formed;
The mixture of the main body glue material and the Ions Absorption agent is put into deaerator and be protected from light deaeration processing, is formed Sealant;
The mass fraction of main body glue material described in the sealant is 95~99.5%, Ions Absorption agent described in the sealant Mass fraction be 0.5~5%;
The Ions Absorption agent includes cyclic annular hydrogen bound to nitrogen;
The Ions Absorption agent includes that structural formula isA kind of Ions Absorption agent;
Wherein, R is alkyl.
3. a kind of liquid crystal display panel, including first substrate, the second substrate and liquid crystal layer, the liquid crystal layer are fixed by sealant Between the first substrate and the second substrate, which is characterized in that the sealant is envelope frame described in claim 1 Glue.
4. liquid crystal display panel according to claim 3, which is characterized in that the liquid crystal monomer in the liquid crystal layer is negativity Liquid crystal monomer.
5. a kind of preparation method of liquid crystal display panel characterized by comprising
The sealant that will be prepared by claim 2, is protected from light, is uniformly coated on first substrate;
The second substrate that drop is had liquid crystal and the first substrate coated with sealant form liquid crystal display panel to box;
The liquid crystal display panel is heated, and the irradiation of UV light is carried out to the sealant.
CN201710002810.4A 2017-01-03 2017-01-03 A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof Active CN106675436B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710002810.4A CN106675436B (en) 2017-01-03 2017-01-03 A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710002810.4A CN106675436B (en) 2017-01-03 2017-01-03 A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106675436A CN106675436A (en) 2017-05-17
CN106675436B true CN106675436B (en) 2019-03-15

Family

ID=58850310

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710002810.4A Active CN106675436B (en) 2017-01-03 2017-01-03 A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106675436B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108535920B (en) * 2018-04-24 2020-01-21 京东方科技集团股份有限公司 Frame sealing glue, display panel, manufacturing method of display panel and display device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344125A (en) * 2000-06-29 2002-04-10 松下电器产业株式会社 Electroluminescence element
CN1621479A (en) * 2003-11-26 2005-06-01 江苏中电华威电子股份有限公司 Epoxy resin composition for semiconductor packaging and its preparation
CN105802559A (en) * 2016-04-14 2016-07-27 京东方科技集团股份有限公司 Frame sealing glue, preparing method thereof and liquid crystal display device

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010132535A1 (en) * 2009-05-12 2010-11-18 E. I. Du Pont De Nemours And Company Uv stabilized polyester compositions for long-term outdoor exposure

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344125A (en) * 2000-06-29 2002-04-10 松下电器产业株式会社 Electroluminescence element
CN1621479A (en) * 2003-11-26 2005-06-01 江苏中电华威电子股份有限公司 Epoxy resin composition for semiconductor packaging and its preparation
CN105802559A (en) * 2016-04-14 2016-07-27 京东方科技集团股份有限公司 Frame sealing glue, preparing method thereof and liquid crystal display device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
stabilization of polypropylene by esters of 2,2,6,6-tetramethyl 4-piperidinole;Marta Povazancova,et al.;《Macromolecular Matericals & Engineerign》;19901231;第176卷(第1期);第291-301页

Also Published As

Publication number Publication date
CN106675436A (en) 2017-05-17

Similar Documents

Publication Publication Date Title
TWI472590B (en) Cationic polymerizable adhesive and polarizing plate obtained by using the same
EP2829584B1 (en) Frame sealing glue composition, method for preventing liquid crystal pollution, liquid crystal panel and display device
JP6623505B2 (en) Method for producing inorganic fine particle dispersion, inorganic fine particle dispersion, coating film, and laminate
KR101611005B1 (en) Adhesive composition for polarizing plate, polarizing plate using the same and optical member comprising the same
JP2009086291A (en) Liquid crystal sealing material, method for manufacturing liquid crystal display panel using the same, and liquid crystal display panel
US9904118B2 (en) Frame sealant, process for preparing same, and liquid crystal display panel and liquid crystal display containing same
KR20150125879A (en) Adhesive film for polarizing plate, adhesive composition for the same, polarizing plate comprising the same and optical display apparatus comprising the same
JP5044326B2 (en) Epoxy resin composition and resin sealing device
TWI675080B (en) Adhesive composition
CN105158990B (en) A kind of sealant and preparation method thereof, display device
TWI715714B (en) Curable resin composition
CN106675436B (en) A kind of sealant and preparation method thereof, liquid crystal display panel and preparation method thereof
JP5138405B2 (en) Liquid crystal sealant and liquid crystal display panel manufacturing method using the same
JP2012151109A (en) Sealant for organic electroluminescent display element
JP4937410B2 (en) Sealant for dye-sensitized solar cell and dye-sensitized solar cell
CN105182623A (en) Frame sealing glue, method for preparing frame sealing glue and display device
CN105802559B (en) A kind of sealant and preparation method thereof, liquid crystal display device
TW201816041A (en) Polarizing film with adhesive layer and method for producing said polarizing film with adhesive layer
JP2013157204A (en) Sealant for organic electroluminescent display element
CN105838129B (en) A kind of ultraviolet absorber and its preparation method and application
CN112375529A (en) Adhesive for membrane electrode and membrane electrode
CN103992445A (en) Elastomer material, and color film substrate and liquid crystal panel prepared from same
JP2010032766A (en) Cationic polymerizable adhesive for bonding polarizer and protective film together, and polarizing plate obtained by using the same
TW201730231A (en) Polarizing plate
KR20100013775A (en) Cross-linking agents incorporating a light diffusion agent of spherical silica bead and methods for making same

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant