CN106675276A - Environment-friendly interior wall coating material - Google Patents

Environment-friendly interior wall coating material Download PDF

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Publication number
CN106675276A
CN106675276A CN201611055262.3A CN201611055262A CN106675276A CN 106675276 A CN106675276 A CN 106675276A CN 201611055262 A CN201611055262 A CN 201611055262A CN 106675276 A CN106675276 A CN 106675276A
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China
Prior art keywords
parts
imidazoles
environment
interior wall
silver
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Granted
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CN201611055262.3A
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Chinese (zh)
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CN106675276B (en
Inventor
张启明
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Male (shanghai) New Mstar Technology Ltd
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Male (shanghai) New Mstar Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses an environment-friendly interior wall coating material which is prepared from the following raw materials in parts by weight: 55-65 parts of acrylate emulsion, 1-3 parts of sodium hexametaphosphate, 1-10 parts of texanol, 0.5-2.5 parts of simethicone, 1-3 parts of stannic oxide, 1-5 parts of iron powder, 1-5 parts of aluminum powder, 1-3 parts of 1,3-propylene glycol, 1-3 parts of carboxymethyl starch, 25-35 parts of silicon dioxide, 20-30 parts of calcium carbonate, 1-10 parts of an inorganic antibacterial agent, 0.5-5 parts of a formaldehyde capturing agent and 35-45 parts of water. The environment-friendly interior wall coating material disclosed by the invention optimizes the types and dosage of the inorganic antibacterial agent and the formaldehyde capturing agent suitable for a waterproof coating through a reasonable proportion and has excellent antibacterial and formaldehyde-removal properties; and meanwhile, by adding stannic oxide and metal powder, the wall face is relatively low in thermal radiation absorption and high in coefficient of thermal storage, and the temperature of the wall face is raised, so that the indoor temperature is raised, the hot comfort level of a living room is greatly improved, and the indoor insulting effect is improved.

Description

Environment-friendly interior wall coating
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of environment-friendly interior wall coating.
Background technology
Paint finishing can very well bond with matrix material in body surface and form the material of complete and tough and tensile diaphragm, claim For coating.Coating and paint are identical concepts.Paint is people's custom title used for a long time, just sharp always after introducing China Used in building trade.The effect of coating may be summarized to be three aspects:Protective effect, decoration function, specific function effect.Coating General composition:Comprising film forming matter, color stuffing, solvent, auxiliary agent.
There is building coating decoration functions, defencive function and livability to improve function.Proportion shared by various functions is because making It is not quite similar with purpose difference.Decoration functions are the beautifications by building improving the function of its appearance value.Mainly Design design and the design of three-dimensional pattern design in terms of including plane color, pattern and gloss.But will be with building itself The size and shape of moulding and base material itself is engaged, and just can fully play out.
Defencive function refers to the function of protecting building not protected from environmental and destroy.It is different types of by protective pair The content that defencive function is required is also different.It is very big if interior with the index difference reached required by outdoor application.Have Building has particular/special requirement to mould proof, fire prevention, insulation, corrosion-resistant etc..
The invention provides a kind of environment-friendly interior wall coating, with excellent heat insulation effect.
The content of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide in a kind of environmental protection Wall coating.
The present invention seeks to be achieved through the following technical solutions:
A kind of environment-friendly interior wall coating, is prepared from by the raw material of following weight parts:
Acrylic acid ester emulsion 55-65 parts, calgon 1-3 parts, the 1-10 parts of alcohol ester 12, dimethicone 0.5-2.5 Part, tin ash 1-3 parts, iron powder 1-5 parts, aluminium powder 1-5 parts, 1,3- propane diols 1-3 parts, CMS 1-3 parts, silica 25-35 parts, calcium carbonate 20-30 parts, inorganic antiseptic 1-10 parts, methanal trapping agent 0.5-5 parts, water 35-45 parts.
Preferably, described inorganic antiseptic is one or more in silver orthophosphate, wolframic acid silver, silver bromide of mixture.
It is highly preferred that described inorganic antiseptic is mixed by silver orthophosphate, wolframic acid silver, silver bromide, the silver orthophosphate, tungsten Sour silver, the mass ratio of silver bromide are (1-3):(1-3):(1-3).
Preferably, described methanal trapping agent is 1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (the 2- chloro- 1H- of bromo- 4,5- bis- Imidazoles -1- bases) acethydrazide, one or more of mixture in 1- (1H- indoles -3- carbonyls) -1H- imidazoles.
It is highly preferred that described methanal trapping agent by 1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, (bromo- 4, the 5- bis- of 2- are chloro- for 2- 1H- imidazoles -1- bases) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles mix, the 1- methyl isophthalic acids H- imidazoles -5- Formylhydrazine, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide, the quality of 1- (1H- indoles -3- carbonyls) -1H- imidazoles Than for (1-3):(1-3):(1-3).
The present invention provide environment-friendly interior wall coating, by rational proportioning, preferably go out suitable water-repellent paint inorganic antiseptic, The species and consumption of methanal trapping agent, with excellent antibacterial and except formaldehyde performance;Add tin ash, metal powder simultaneously to cause Metope has relatively low thermal radiation absorption and high heat storage coefficient, raises can body of wall face temperature, so as to increased indoor temperature, The hot comfort in room is substantially increased, the heat insulation effect of interior is improve.
Specific embodiment
With reference to embodiment, the present invention is described further, described below, is only the preferable enforcement to the present invention Example, not does the restriction of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above Technology contents be changed to the Equivalent embodiments of equal change.It is every without departing from the present invention program content, according to the present invention Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Each raw material introduction in embodiment:
Acrylic acid ester emulsion, using application number:In 201010504851.1 prepared by embodiment 1.
Calgon, No. CAS:10124-56-8.
Alcohol ester 12, No. CAS:25265-77-4.
Dimethicone, No. CAS:63148-62-9, the dimethyl-silicon of the model 201 provided using Dow Corning Corporation Oil.
Tin ash, No. CAS:18282-10-5, particle diameter 50nm.
Iron powder, No. CAS:7439-89-6, particle diameter 50nm.
Aluminium powder, No. CAS:7429-90-5, particle diameter 50nm.
1,3-PD, No. CAS:504-63-2.
CMS, No. CAS:9063-38-1, the carboxymethyl provided using Hebei Heng Jintai Environmental Protection Technology Co., Ltd Starch.
Silica, No. CAS:7631-86-9, model TSP- provided using Nanjing Tian Hang new materials Co., Ltd The silica of K05, particle diameter is 20nm.
Calcium carbonate, No. CAS:471-34-1, the ultra-fine white carbonic acid of 1250 mesh produced using Changxing Qun Fenggai industry Co., Ltd Calcium.
Silver orthophosphate, No. CAS:7784-09-0,10 μm of particle diameter.
Silver bromide, No. CAS:7785-23-1,10 μm of particle diameter.
Wolframic acid silver, No. CAS:13465-93-5,10 μm of particle diameter.
1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, No. CAS:23585-00-4.
2- (the chloro- 1H- imidazoles -1- bases of bromo- 4, the 5- bis- of 2-) acethydrazide, No. CAS:175202-83-2.
1- (1H- indoles -3- carbonyls) -1H- imidazoles, No. CAS:99445-26-8.
Embodiment 1
Environment-friendly interior wall coating raw material (weight portion):
60 parts of acrylic acid ester emulsion, 2 parts of calgon, 12 parts of alcohol ester, 1.5 parts of dimethicone, tin ash 2 It is part, 4 parts of iron powder, 3 parts of aluminium powder, 2 parts of 1,3- propane diols, 2 parts of CMS, 30 parts of silica, 25 parts of calcium carbonate, inorganic anti- 4.5 parts of microbial inoculum, 1.2 parts of methanal trapping agent, 36 parts of water.
Described inorganic antiseptic is 1 by silver orthophosphate, wolframic acid silver, silver bromide in mass ratio:1:1 is uniformly mixed Arrive.
Described methanal trapping agent is by 1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- of the bromo- 4,5- bis- of 2- Base) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles in mass ratio be 1:1:1 is uniformly mixed and obtains.
The preparation method of environment-friendly interior wall coating:By water, calgon, alcohol ester 12, dimethicone, tin ash, Iron powder, aluminium powder, 1,3- propane diols, CMS, silica, calcium carbonate, inorganic antiseptic, methanal trapping agent with 100 turns/ Point stirring is well mixed for 5 minutes, then with 1000 revs/min of stirrings carries out high speed shear within 15 minutes again, obtains mixed liquor;By propylene Acid esters emulsion is added in mixed liquor and is well mixed within 10 minutes with 300 revs/min of stirrings.Obtain the environment-friendly interior wall coating of embodiment 1.
Embodiment 2
It is substantially the same manner as Example 1, differ only in:Described inorganic antiseptic by wolframic acid silver, silver bromide in mass ratio For 1:1 is uniformly mixed and obtains.Obtain the environment-friendly interior wall coating of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in:Described inorganic antiseptic by silver orthophosphate, silver bromide in mass ratio For 1:1 is uniformly mixed and obtains.Obtain the environment-friendly interior wall coating of embodiment 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in:Described inorganic antiseptic is silver-colored in mass ratio by silver orthophosphate, wolframic acid For 1:1 is uniformly mixed and obtains.Obtain the environment-friendly interior wall coating of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in:Described methanal trapping agent is by 2- (the chloro- 1H- miaows of the bromo- 4,5- bis- of 2- Azoles -1- bases) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles in mass ratio be 1:1 is uniformly mixed and obtains.Obtain reality Apply the environment-friendly interior wall coating of example 5.
Embodiment 6
It is substantially the same manner as Example 1, differ only in:Described methanal trapping agent is by 1- methyl isophthalic acid H- imidazoles -5- formyls Hydrazine, 1- (1H- indoles -3- carbonyls) -1H- imidazoles are 1 in mass ratio:1 is uniformly mixed and obtains.Obtain the environmental protection of embodiment 6 Interior wall coating.
Embodiment 7
It is substantially the same manner as Example 1, differ only in:Described methanal trapping agent is by 1- methyl isophthalic acid H- imidazoles -5- formyls Hydrazine, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide are 1 in mass ratio:1 is uniformly mixed and obtains.Implemented The environment-friendly interior wall coating of example 7.
Test case 1
The anti-microbial property of the environment-friendly interior wall coating prepared to embodiment 1-7 is tested, anti-microbial property test reference GB/T21866-2008《Antibiotic paint anti-microbial property assay method and antibacterial effect》.
Antibacterial test:Escherichia coli ATYCC 25922, staphylococcus aureus ATCC 6538.
Concrete test result is shown in Table 1.
Table 1:Anti-microbial property test data
Sample Escherichia coli sterilizing rate, % Staphylococcus aureus sterilizing rate, %
Embodiment 1 99.99 99.99
Embodiment 2 96.02 94.03
Embodiment 3 93.06 95.06
Embodiment 4 94.33 95.24
Embodiment 5 97.40 98.13
Embodiment 6 98.12 97.12
Embodiment 7 97.15 97.25
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (silver orthophosphate, wolframic acid silver, silver bromide compounding) anti-microbial property is obvious Better than embodiment 2-4 (arbitrarily the two compounding in silver orthophosphate, wolframic acid silver, silver bromide).
Comparing embodiment 1 and embodiment 5-7, embodiment 1 (1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (bromo- 4, the 5- bis- of 2- Chloro- 1H- imidazoles -1- bases) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles compounding) anti-microbial property is substantially better than embodiment 5-7 (1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide, 1- (1H- indoles - 3- carbonyls) any the two compounding in -1H- imidazoles).
Test case 2
The each 15g of environment-friendly interior wall coating that embodiment 1-7 is prepared is weighed, initial concentration is inserted for 40mg/m3Formaldehyde In 5L driers, concentration of formaldehyde rheological parameters' change with time in gas is then determined in drier.Detecting instrument:Assert for national standard metering The type formaldehyde monitor of the U.S. 4160, while detection display density value numeral.4160 type formaldehyde monitors determine numerical value with The deviation of laboratory chemical method detected value, typically within 5%.Test result is shown in Table 2.
Table 2:Concentration of formaldehyde tests table
Concentration of formaldehyde after 24 hours, mg/m3
Embodiment 1 1.3
Embodiment 2 4.2
Embodiment 3 5.7
Embodiment 4 3.4
Embodiment 5 7.5
Embodiment 6 5.9
Embodiment 7 8.2
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (silver orthophosphate, wolframic acid silver, silver bromide compounding) is bright except formaldehyde performance It is aobvious to be better than embodiment 2-4 (arbitrarily the two compounding in silver orthophosphate, wolframic acid silver, silver bromide).
Comparing embodiment 1 and embodiment 5-7, embodiment 1 (1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (bromo- 4, the 5- bis- of 2- Chloro- 1H- imidazoles -1- bases) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles compounding) be substantially better than enforcement except formaldehyde performance Example 5-7 (1- methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide, 1- (1H- Yin Diindyl -3- carbonyls) any the two compounding in -1H- imidazoles).
Test case 3
The environment-friendly interior wall coating that embodiment 1-4 is prepared carries out the test of mid and far infrared reflectivity, and test equipment is Albedometer.Test result is shown in Table 3.
Table 3:Mid and far infrared reflectance test table
Mid and far infrared reflectivity, %
Embodiment 1 38
Embodiment 2 33
Embodiment 3 35
Embodiment 4 31
As shown in Table 3, environment-friendly interior wall coating mid and far infrared reflectivity of the present invention can reach 38%, and this explanation, the present invention is carried For environment-friendly interior wall coating can reflect the mid and far infrared of larger proportion, it is possible to increase indoor heat insulating effect.Comparing embodiment 1 with Embodiment 2-4, embodiment 1 (silver orthophosphate, wolframic acid silver, silver bromide compounding) heat insulation effect be substantially better than embodiment 2-4 (silver orthophosphate, Arbitrarily the two is compounded in wolframic acid silver, silver bromide).

Claims (5)

1. a kind of environment-friendly interior wall coating, it is characterised in that be prepared from by the raw material of following weight parts:Acrylic acid ester emulsion 55- 65 parts, calgon 1-3 parts, the 1-10 parts of alcohol ester 12, dimethicone 0.5-2.5 parts, tin ash 1-3 parts, iron powder 1-5 Part, aluminium powder 1-5 parts, 1,3- propane diols 1-3 parts, CMS 1-3 parts, silica 25-35 parts, calcium carbonate 20-30 parts, nothing Machine antiseptic 1-10 parts, methanal trapping agent 0.5-5 parts, water 35-45 parts.
2. environment-friendly interior wall coating as claimed in claim 1, it is characterised in that:Described inorganic antiseptic is silver orthophosphate, wolframic acid One or more of mixture in silver, silver bromide.
3. environment-friendly interior wall coating as claimed in claim 2, it is characterised in that:Described inorganic antiseptic is by silver orthophosphate, wolframic acid Silver, silver bromide are mixed, and the silver orthophosphate, wolframic acid silver, the mass ratio of silver bromide are (1-3):(1-3):(1-3).
4. the environment-friendly interior wall coating as any one of claim 1-3, it is characterised in that:Described methanal trapping agent is 1- Methyl isophthalic acid H- imidazoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide, 1- (1H- indoles -3- carbonyls Base) one or more of mixture in -1H- imidazoles.
5. environment-friendly interior wall coating as claimed in claim 4, it is characterised in that:Described methanal trapping agent is by 1- methyl isophthalic acid H- miaows Azoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- bases of the bromo- 4,5- bis- of 2-) acethydrazide, 1- (1H- indoles -3- carbonyls) -1H- imidazoles are mixed Conjunction is formed, the 1- methyl isophthalic acids H- imidazoles -5- formylhydrazines, 2- (the chloro- 1H- imidazoles -1- bases of bromo- 4, the 5- bis- of 2-) acethydrazide, 1- The mass ratio of (1H- indoles -3- carbonyls) -1H- imidazoles is (1-3):(1-3):(1-3).
CN201611055262.3A 2016-11-25 2016-11-25 Environment-friendly interior wall coating Expired - Fee Related CN106675276B (en)

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CN107118649A (en) * 2017-07-07 2017-09-01 佛山领新信息科技有限公司 A kind of antibacterial and ageing-resistant interior wall coating and preparation method thereof
CN114250004A (en) * 2021-12-28 2022-03-29 沈阳康亿环保科技有限公司 Environment-friendly antibacterial antiviral mildew-proof integrated interior wall coating and preparation method thereof

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CN105505076A (en) * 2016-01-21 2016-04-20 上海馨来建筑装饰设计有限公司 Environment-friendly external wall paint and preparation method thereof
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118649A (en) * 2017-07-07 2017-09-01 佛山领新信息科技有限公司 A kind of antibacterial and ageing-resistant interior wall coating and preparation method thereof
CN114250004A (en) * 2021-12-28 2022-03-29 沈阳康亿环保科技有限公司 Environment-friendly antibacterial antiviral mildew-proof integrated interior wall coating and preparation method thereof

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