CN106675042A - Metallized film capacitor encapsulation wax - Google Patents

Metallized film capacitor encapsulation wax Download PDF

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Publication number
CN106675042A
CN106675042A CN201611133803.XA CN201611133803A CN106675042A CN 106675042 A CN106675042 A CN 106675042A CN 201611133803 A CN201611133803 A CN 201611133803A CN 106675042 A CN106675042 A CN 106675042A
Authority
CN
China
Prior art keywords
wax
embedding
membrane capacitance
powder
metallized membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611133803.XA
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Chinese (zh)
Inventor
周继平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NINGGUO DARONG ELECTRICS Co Ltd
Original Assignee
NINGGUO DARONG ELECTRICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NINGGUO DARONG ELECTRICS Co Ltd filed Critical NINGGUO DARONG ELECTRICS Co Ltd
Priority to CN201611133803.XA priority Critical patent/CN106675042A/en
Publication of CN106675042A publication Critical patent/CN106675042A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

The invention discloses metallized film capacitor encapsulation wax which is prepared from the following components: modified petroleum wax, nano-zinc oxide, polytrifluorochloroethylene, polyvinyl alcohol, coconut oil monoethanolamide, rosin, methylcellulose, mica powder and medical stone powder. The encapsulation wax is excellent in electrical property, high in moisture resistance, flowability, heat resistance and cold resistance, and good in usability, and can guarantee the stability of the electrical property of a metallized film capacitor.

Description

A kind of metallized membrane capacitance embedding wax
Technical field
The present invention relates to capacitor encapsulation technology field, more particularly to a kind of metallized membrane capacitance embedding wax.
Background technology
Capacitor is quite varied in electric field application, in metallization film capacitor production, main medium and pole plate with Hole between main medium is typically to carry out embedding with a kind of material, to improve capacitance and insulating properties, and improves local putting Electricity and heat resistance., there is under toughness plasticity difference low temperature easily embrittlement and have larger contraction in simple commodity in use paraffin or microwax Etc. defect, there is loss greatly using oils and be easy to seepage, be not suitable with the requirement of current factory.
The content of the invention
It is an object of the invention to provide a kind of metallized membrane capacitance embedding wax, it is achieved through the following technical solutions:
A kind of metallized membrane capacitance embedding wax, is made up of following component by weight:Modified petroleum wax 80-100, nano oxygen Change zinc 2-4, polytrifluorochloroethylene 10-16, polyvinyl alcohol 8-10, Coconut Fatty Acid Monoethanolamide 23-25, rosin 2-5, Methyl cellulose Plain 4-7, mica powder powder 12-14, medical stone powder 12-14.
Further, the modified petroleum wax is made up of following component by weight:Pertroleum wax 40, Tissuemat E 2, horse Carry out sour glycosides 0.4, its preparation method is:Tissuemat E, pertroleum wax are added in reactor and fusing is heated to, horse is slowly added into Carry out sour glycosides, heat while stirring, untill well mixed, start compressor, oxygen is passed through in reactor, after 3 hours, close Compressor is closed, stops being passed through for oxygen, reactant is taken out from reactor, be dried, obtain final product required modified petroleum wax.
Further, the particle diameter of the nano zine oxide is 28nm.
Further, the mica powder Powder Particle Size is 400 mesh, and the medical stone powder granularity is 600 mesh.
Further, the application method of the metallized membrane capacitance embedding wax is:By metallized membrane capacitance embedding wax First it is placed at subzero 2 DEG C, is incubated 30min, be then warming up to 70 DEG C with 2 DEG C/min speed, after is incubated 2 hours, you can carry out Embedding to metallization film capacitor is used, application method of the present invention, can greatly improve the use of the capacitor after embedding Life-span.
Preparation method:
Metallized membrane capacitance embedding wax of the present invention is at a temperature of 115 DEG C, by each weight portion by modified petroleum wax, nano oxygen Change zinc, polytrifluorochloroethylene, polyvinyl alcohol, Coconut Fatty Acid Monoethanolamide, rosin, methylcellulose, mica powder powder, medical stone powder Uniform mixed melting is into uniform liquid, then is molded, you can.
Beneficial effect of the present invention:Embedding wax of the present invention has an excellent electrical properties, moisture resistance, mobility, heat resistance and cold-resistant Property is good, with good performance, ensure that the stabilization of metallization film capacitor electrical property, can abundant added metal Membrane capacitance gap, will not produce harmful effect to metallization film capacitor service behaviour;By using the modified petroleum wax can be with The electrical property of embedding wax is improved, and the resistance to elevated temperatures of embedding wax can be improved, greatly improve the toughness plasticity of embedding wax;Pass through The mica powder powder of certain mesh number of addition and the synergy of medical stone powder so that embedding wax has good heat resistance and resists cold Property, do not trickle at the working temperature, do not shelled during cooling;By adding cooperateing with for methylcellulose and Coconut Fatty Acid Monoethanolamide Effect, enables to embedding wax stability to be greatly improved, by the synergy between each composition of the invention so that this Invention embedding wax can not only be applied to the dipping embedding of metallization film capacitor, be also applied for inductance coil and other electronics unit The dipping embedding of part coils special.
Specific embodiment
Embodiment 1
A kind of metallized membrane capacitance embedding wax, is made up of following component by weight:Modified petroleum wax 80, nano zine oxide 2nd, polytrifluorochloroethylene 10, polyvinyl alcohol 8, Coconut Fatty Acid Monoethanolamide 23, rosin 2, methylcellulose 4, mica powder powder 12, wheat Meal stone flour 12.
Embodiment 2
A kind of metallized membrane capacitance embedding wax, is made up of following component by weight:It is modified petroleum wax 100, nano oxidized Zinc 4, polytrifluorochloroethylene 16, polyvinyl alcohol 10, Coconut Fatty Acid Monoethanolamide 25, rosin 5, methylcellulose 7, mica powder powder 14th, medical stone powder 14.
Embodiment 3
A kind of metallized membrane capacitance embedding wax, is made up of following component by weight:Modified petroleum wax 90, nano zine oxide 3rd, polytrifluorochloroethylene 14, polyvinyl alcohol 9, Coconut Fatty Acid Monoethanolamide 24, rosin 3, methylcellulose 5, mica powder powder 13, wheat Meal stone flour 13.
In above-described embodiment:
The modified petroleum wax is made up of following component by weight:Pertroleum wax 40, Tissuemat E 2, maleic acid glycosides 0.4, its Preparation method is:Tissuemat E, pertroleum wax are added in reactor and fusing is heated to, maleic acid glycosides, Bian Jia is slowly added into Hot side stirring, untill well mixed, starts compressor, and oxygen is passed through in reactor, and after 3 hours, close compressor is stopped Being passed through for block gas, takes out reactant from reactor, is dried, and obtains final product required modified petroleum wax.
The particle diameter of the nano zine oxide is 28nm.
The mica powder Powder Particle Size is 400 mesh, and the medical stone powder granularity is 600 mesh.
The application method of the metallized membrane capacitance embedding wax is:Metallized membrane capacitance embedding wax is first placed on zero At lower 2 DEG C, 30min is incubated, is then warming up to 70 DEG C with 2 DEG C/min speed, after being incubated 2 hours, you can carry out to metalized film The embedding of capacitor is used.
Preparation method:
Metallized membrane capacitance embedding wax of the present invention is at a temperature of 115 DEG C, by each weight portion by modified petroleum wax, nano oxygen Change zinc, polytrifluorochloroethylene, polyvinyl alcohol, Coconut Fatty Acid Monoethanolamide, rosin, methylcellulose, mica powder powder, medical stone powder Uniform mixed melting is into uniform liquid, then is molded, you can.
Embedding wax of the present invention can be brought into close contact with capacitor body all the time, keep good insulating properties, in addition, make 22.3% can be about improved with the capacitor life-span of embedding wax embedding obtained in above-described embodiment 1, is obtained using above-described embodiment 2 Embedding wax perfusion capacitor life-span can about improve 22.5%, use obtained in above-described embodiment 3 embedding wax irrigate electric capacity The device life-span can about improve 22.6%, effect is significant, when modified petroleum wax in embodiment 3 is substituted for into common petroleum wax, perfusion Capacitor life-span can about improve 12.5%, when mica powder powder in embodiment 3 and medical stone powder granularity are replaced with into 500 purposes, The capacitor life-span of perfusion can about improve 16.2%.
By detection, the main performance of gained electric capacity embedding wax is as follows in the present embodiment:
Table 1
Wherein, comparative example 1 is only that modified petroleum wax is replaced with into common unmodified pertroleum wax with the difference of the embodiment of the present invention 3;
Comparative example 2 is differed only in embodiment 3 and for mica powder powder and medical stone powder granularity to replace with 500 purposes;
As can be seen from Table 1, the embedding wax superior performance that prepared by the present invention.

Claims (5)

1. a kind of metallized membrane capacitance embedding wax, it is characterised in that be made up of following component by weight:Modified petroleum wax 80-100, nano zine oxide 2-4, polytrifluorochloroethylene 10-16, polyvinyl alcohol 8-10, Coconut Fatty Acid Monoethanolamide 23-25, pine Fragrant 2-5, methylcellulose 4-7, mica powder powder 12-14, medical stone powder 12-14.
2. a kind of metallized membrane capacitance embedding wax according to claim 1, it is characterised in that the modified petroleum wax is pressed Weight portion meter is made up of following component:Pertroleum wax 40, Tissuemat E 2, maleic acid glycosides 0.4, its preparation method is:By polyethylene Wax, pertroleum wax are added in reactor and are heated to fusing, are slowly added into maleic acid glycosides, heat while stirring, until mixing is equal Untill even, start compressor, oxygen is passed through in reactor, after 3 hours, close compressor stops being passed through for oxygen, from reaction Reactant is taken out in device, is dried, obtain final product required modified petroleum wax.
3. a kind of metallized membrane capacitance embedding wax according to claim 1, it is characterised in that the nano zine oxide Particle diameter is 28nm.
4. a kind of metallized membrane capacitance embedding wax according to claim 1, it is characterised in that the mica powder Powder Particle Size It is 400 mesh, the medical stone powder granularity is 600 mesh.
5. a kind of metallized membrane capacitance embedding wax according to claim 1, it is characterised in that the metalized film electric capacity The application method of device embedding wax is:Metallized membrane capacitance embedding wax is first placed at subzero 2 DEG C, be incubated 30min, then with 2 DEG C/min speed is warming up to 70 DEG C, after being incubated 2 hours, you can the embedding of metallization film capacitor is used.
CN201611133803.XA 2016-12-10 2016-12-10 Metallized film capacitor encapsulation wax Pending CN106675042A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201611133803.XA CN106675042A (en) 2016-12-10 2016-12-10 Metallized film capacitor encapsulation wax

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CN106675042A true CN106675042A (en) 2017-05-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804315A (en) * 2019-12-09 2020-02-18 安徽省睿斯达石油有限公司 Capacitor potting wax

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101082000A (en) * 2007-06-07 2007-12-05 上海焦耳蜡业有限公司 Polyethylene wax polypropylene wax and petroleum wax co-oxidation method
CN102382475A (en) * 2011-09-17 2012-03-21 安徽江威精密制造有限公司 Metalized film capacitor encapsulation wax
CN104292855A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Modifying agent for metallized film capacitor potting material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101082000A (en) * 2007-06-07 2007-12-05 上海焦耳蜡业有限公司 Polyethylene wax polypropylene wax and petroleum wax co-oxidation method
CN102382475A (en) * 2011-09-17 2012-03-21 安徽江威精密制造有限公司 Metalized film capacitor encapsulation wax
CN104292855A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Modifying agent for metallized film capacitor potting material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨明山: "《塑料改性实用技术与应用》", 30 June 2014, 印刷工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804315A (en) * 2019-12-09 2020-02-18 安徽省睿斯达石油有限公司 Capacitor potting wax

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Application publication date: 20170517