CN106674985A - Novel degradable high molecular material - Google Patents
Novel degradable high molecular material Download PDFInfo
- Publication number
- CN106674985A CN106674985A CN201611145789.5A CN201611145789A CN106674985A CN 106674985 A CN106674985 A CN 106674985A CN 201611145789 A CN201611145789 A CN 201611145789A CN 106674985 A CN106674985 A CN 106674985A
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- CN
- China
- Prior art keywords
- parts
- novel degradable
- tert
- polyurethane resin
- sodium citrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a novel degradable high molecular material. The novel degradable high molecular material is prepared from the following components in parts by weight: 80-90 parts of polyurethane resin, 4-8 parts of corn starch, 3-6 parts of pentamethyldiethylenetriamine, 1-3 parts of methylene bisstearamide, 1-3 parts of ferrous sulfate, 1-2 parts of aluminum hydroxy distearate, 1-3 parts of PDMS (Polydimethylsiloxane), 3-4 parts of triisopropyl tert-butylphenol phosphate, 2-4 parts of tourmaline negative-ion powder, 1-3 parts of MES (Methyl Ester Sulfonate), 1-3 parts of sodium citrate, 3-5 parts of cyanoethyl cellulose and 1-3 parts of calcium lactobionate. With the adoption of the manner, the novel degradable high molecular material belongs to an environment-friendly material, is easy to degrade and has no pollution.
Description
Technical field
The present invention relates to polymeric material field, more particularly to a kind of novel degradable macromolecular material.
Background technology
Modern industrial society develops rapidly, and the utilization of macromolecular material is more and more extensive, and Ge great colleges and universities, research institution etc. are all
It is provided with macromolecular material research center.Macromolecular material is also referred to as polymeric material, be based on macromolecular compound, then
It is furnished with other additives（Auxiliary agent）The material for being constituted, macromolecular material is divided into rubber, fiber, plastics, macromolecule glue by characteristic
Stick, high-molecular coating and polymer-based composite etc..Macromolecular material electric and electronic industry, aerospace industry, building industry,
All it is widely used in all trades and professions such as medical apparatus and instruments, medical packaging, transportation, household electrical appliance, agricultural.At present, exist
The high molecular products garbage environmental pollution that the industries such as food and drink, medical treatment are used is larger.
The content of the invention
The invention mainly solves the technical problem of providing a kind of novel degradable macromolecular material, belong to environmentally friendly
Material, it is degradable, it is pollution-free.
To solve above-mentioned technical problem, one aspect of the present invention is：A kind of novel degradable high score is provided
Sub- material, including the component of following weight portion：80 ~ 90 parts of polyurethane resin, 4 ~ 8 parts of corn starch, pentamethyl divinyl three
3 ~ 6 parts of amine, 1 ~ 3 part of methylene bis stearic amide, 1 ~ 3 part of ferrous sulfate, 1 ~ 2 part of aluminium hydroxy distearate, PDMS1 ~ 3 part, phosphorus
3 ~ 4 parts of sour triisopropyl tert-butyl phenol, 2 ~ 4 parts of tourmaline anion powder, MES1 ~ 3 part, 1 ~ 3 part of sodium citrate, cyanoethyl are fine
1 ~ 3 part of 3 ~ 5 parts of dimension element and calcium lactobionate..
In a preferred embodiment of the present invention, including the component of following weight portion：80 parts of polyurethane resin, corn starch
4 parts, 3 parts of PMDETA, 1 part of methylene bis stearic amide, 1 part of ferrous sulfate, 1 part of aluminium hydroxy distearate,
PDMS1 parts, 3 parts of phosphoric acid triisopropyl tert-butyl phenol, 2 parts of tourmaline anion powder, MES1 parts, 1 part of sodium citrate, cyanoethyl
1 part of 3 parts of cellulose and calcium lactobionate..
In a preferred embodiment of the present invention, including the component of following weight portion：88 parts of polyurethane resin, corn starch
6 parts, 5 parts of PMDETA, 2 parts of methylene bis stearic amide, 1.8 parts of ferrous sulfate, aluminium hydroxy distearate 1.3
Part, PDMS2 parts, 3.6 parts of phosphoric acid triisopropyl tert-butyl phenol, 3 parts of tourmaline anion powder, MES2 parts, 2 parts of sodium citrate,
2 parts of 4 parts of cyanethyl cellulose and calcium lactobionate..
In a preferred embodiment of the present invention, including the component of following weight portion：90 parts of polyurethane resin, corn starch
8 parts, 6 parts of PMDETA, 3 parts of methylene bis stearic amide, 3 parts of ferrous sulfate, 2 parts of aluminium hydroxy distearate,
PDMS3 parts, 4 parts of phosphoric acid triisopropyl tert-butyl phenol, 4 parts of tourmaline anion powder, MES3 parts, 3 parts of sodium citrate, cyanoethyl
3 parts of 5 parts of cellulose and calcium lactobionate..
The invention has the beneficial effects as follows：Novel degradable macromolecular material of the present invention, belongs to environmentally friendly material, easily drop
Solution, it is pollution-free.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement
Example is only a part of embodiment of the present invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
The embodiment of the present invention includes：
Embodiment one：
A kind of novel degradable macromolecular material, including the component of following weight portion：80 parts of polyurethane resin, 4 parts of corn starch,
3 parts of PMDETA, 1 part of methylene bis stearic amide, 1 part of ferrous sulfate, 1 part of aluminium hydroxy distearate, PDMS1
Part, 3 parts of phosphoric acid triisopropyl tert-butyl phenol, 2 parts of tourmaline anion powder, MES1 parts, 1 part of sodium citrate, cyanoethyl fiber
1 part of 3 parts of element and calcium lactobionate..
Embodiment two：
A kind of novel degradable macromolecular material, including the component of following weight portion：88 parts of polyurethane resin, 6 parts of corn starch,
5 parts of PMDETA, 2 parts of methylene bis stearic amide, 1.8 parts of ferrous sulfate, 1.3 parts of aluminium hydroxy distearate,
PDMS2 parts, 3.6 parts of phosphoric acid triisopropyl tert-butyl phenol, 3 parts of tourmaline anion powder, MES2 parts, 2 parts of sodium citrate, cyanogen second
2 parts of 4 parts of base cellulose and calcium lactobionate..
Embodiment three：
A kind of novel degradable macromolecular material, including the component of following weight portion：90 parts of polyurethane resin, 8 parts of corn starch,
6 parts of PMDETA, 3 parts of methylene bis stearic amide, 3 parts of ferrous sulfate, 2 parts of aluminium hydroxy distearate, PDMS3
Part, 4 parts of phosphoric acid triisopropyl tert-butyl phenol, 4 parts of tourmaline anion powder, MES3 parts, 3 parts of sodium citrate, cyanoethyl fiber
3 parts of 5 parts of element and calcium lactobionate..
The invention has the beneficial effects as follows：Novel degradable macromolecular material of the present invention, belongs to environmentally friendly material, easily drop
Solution, it is pollution-free.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (4)
1. a kind of novel degradable macromolecular material, it is characterised in that including the component of following weight portion：Polyurethane resin 80 ~
90 parts, 4 ~ 8 parts of corn starch, 3 ~ 6 parts of PMDETA, 1 ~ 3 part of methylene bis stearic amide, ferrous sulfate 1 ~ 3
Part, 1 ~ 2 part of aluminium hydroxy distearate, PDMS1 ~ 3 part, 3 ~ 4 parts of phosphoric acid triisopropyl tert-butyl phenol, tourmaline anion powder 2 ~
1 ~ 3 part of 4 parts, MES1 ~ 3 part, 1 ~ 3 part of sodium citrate, 3 ~ 5 parts of cyanethyl cellulose and calcium lactobionate..
2. novel degradable macromolecular material according to claim 1, it is characterised in that including the group of following weight portion
Part：80 parts of polyurethane resin, 4 parts of corn starch, 3 parts of PMDETA, 1 part of methylene bis stearic amide, sulphuric acid
Ferrous 1 part, 1 part of aluminium hydroxy distearate, PDMS1 parts, 3 parts of phosphoric acid triisopropyl tert-butyl phenol, tourmaline anion powder 2
1 part of part, MES1 parts, 1 part of sodium citrate, 3 parts of cyanethyl cellulose and calcium lactobionate..
3. novel degradable macromolecular material according to claim 1, it is characterised in that including the group of following weight portion
Part：88 parts of polyurethane resin, 6 parts of corn starch, 5 parts of PMDETA, 2 parts of methylene bis stearic amide, sulphuric acid
Ferrous 1.8 parts, 1.3 parts of aluminium hydroxy distearate, PDMS2 parts, 3.6 parts of phosphoric acid triisopropyl tert-butyl phenol, tourmaline bear from
2 parts of 3 parts of sub- powder, MES2 parts, 2 parts of sodium citrate, 4 parts of cyanethyl cellulose and calcium lactobionate..
4. novel degradable macromolecular material according to claim 1, it is characterised in that including the group of following weight portion
Part：90 parts of polyurethane resin, 8 parts of corn starch, 6 parts of PMDETA, 3 parts of methylene bis stearic amide, sulphuric acid
Ferrous 3 parts, 2 parts of aluminium hydroxy distearate, PDMS3 parts, 4 parts of phosphoric acid triisopropyl tert-butyl phenol, tourmaline anion powder 4
3 parts of part, MES3 parts, 3 parts of sodium citrate, 5 parts of cyanethyl cellulose and calcium lactobionate..
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145789.5A CN106674985A (en) | 2016-12-13 | 2016-12-13 | Novel degradable high molecular material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145789.5A CN106674985A (en) | 2016-12-13 | 2016-12-13 | Novel degradable high molecular material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674985A true CN106674985A (en) | 2017-05-17 |
Family
ID=58868148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611145789.5A Pending CN106674985A (en) | 2016-12-13 | 2016-12-13 | Novel degradable high molecular material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674985A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698840A (en) * | 2019-08-22 | 2020-01-17 | 金群英 | TPU polyester health-care composite film and production method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792591A (en) * | 2009-12-30 | 2010-08-04 | 中国科学院广州化学研究所 | Full-biodegradable plastic film and preparation method thereof |
-
2016
- 2016-12-13 CN CN201611145789.5A patent/CN106674985A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792591A (en) * | 2009-12-30 | 2010-08-04 | 中国科学院广州化学研究所 | Full-biodegradable plastic film and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 俞志明主编: "《中国化工商品大全 第一卷 （1995年版）》", 31 January 1996, 中国物资出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698840A (en) * | 2019-08-22 | 2020-01-17 | 金群英 | TPU polyester health-care composite film and production method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170517 |
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| RJ01 | Rejection of invention patent application after publication |