CN106674841A - Wear-resistant silicone rubber material for heavy-duty vehicle - Google Patents
Wear-resistant silicone rubber material for heavy-duty vehicle Download PDFInfo
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- CN106674841A CN106674841A CN201611139504.7A CN201611139504A CN106674841A CN 106674841 A CN106674841 A CN 106674841A CN 201611139504 A CN201611139504 A CN 201611139504A CN 106674841 A CN106674841 A CN 106674841A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a wear-resistant silicone rubber material for a heavy-duty vehicle. The material comprises the following raw materials in parts by weight: 30-50 parts of acrylic rubber, 10-30 parts of silicone rubber, 20-40 parts of polyurethane rubber, 2-4 parts of a silane coupling agent KH-551, 10-20 parts of nano-silicon dioxide, 20-40 parts of silicon nitride, 10-20 parts of aluminum borate whiskers, 16-20 parts of ceramic microspheres, 25-45 parts of modified peanut shell fibers, 2-4 parts of an antioxidant 264, 2-4 parts of an antioxidant 1076, 2-3 parts of sorbitol, 1-3 parts of triallyl cyanurate, 2-5 parts of trimethyl phosphate, 0.5-0.8 part of tricresyl phosphate, 1.5-2.5 parts of microcrystalline wax, 0.4-1.2 parts of dibutyltin dilaurate, 1.5-2.5 parts of magnesium stearate, 1.5-2.5 parts of sulfur and 1-2 parts of dicumyl peroxide.
Description
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of wear-resisting silastic material of heavy-duty car.
Background technology
Existing automobile rubber bearing is unreasonable because formula is designed, and it is easily aging to there is the rubber support produced, easy to wear,
The short defect of service life.For heavy-duty car vibrates in the process of moving the moment impact to bending plate, rear axle, back axle, also not
Can play a very good protection.Therefore a kind of not easy to wear, ageing-resistant rubber of invention is needed, to meet people's productive life
Need.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of wear-resisting silastic material of heavy-duty car,
Oil resistance is good, high temperature resistant, excellent anti-corrosion performance, can effectively meet the needs in productive life, ageing-resistant, wear resistance
Can be excellent, service life is greatly prolonged.
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
Rubber 30-50 parts, silicone rubber 10-30 parts, polyurethane rubber 20-40 parts, silane coupler KH-551 2-4 parts, nanometer titanium dioxide
Silicon 10-20 parts, silicon nitride 20-40 parts, aluminium borate whisker 10-20 parts, ceramic microsphere 16-20 parts, modified peanut fiber 25-45
Part, antioxidant 264 2-4 parts, antioxidant 1076 2-4 parts, Sorbitol 2-3 parts, triallyl cyanurate 1-3 part, phosphoric acid
Trimethyl 2-5 parts, tricresyl phosphate 0.5-0.8 parts, microcrystalline wax 1.5-2.5 parts, dibutyl tin laurate 0.4-1.2
Part, magnesium stearate 1.5-2.5 part, sulfur 1.5-2.5 parts, cumyl peroxide 1-2 parts.
Preferably, silane coupler KH-551, nano silicon, silicon nitride, aluminium borate whisker, ceramic microsphere, modified
The weight ratio of Semen arachidis hypogaeae case fibre is 2.5-3.5：12-18：25-35：12-18：17-19：30-40.
Preferably, antioxidant 264, antioxidant 1076, the weight ratio of Sorbitol are 2.5-3.5：2.5-3.5：2.2-
2.8。
Preferably, its raw material includes by weight：Acrylate rubber 35-45 part, silicone rubber 15-25 parts, polyurethane rubber
Glue 25-35 parts, silane coupler KH-551 2.5-3.5 parts, nano silicon 12-18 parts, silicon nitride 25-35 parts, Alborex M 12
Whisker 12-18 parts, ceramic microsphere 17-19 parts, modified peanut fiber 30-40 parts, antioxidant 264 2.5-3.5 parts, antioxidant
1076 2.5-3.5 parts, Sorbitol 2.2-2.8 parts, triallyl cyanurate 1.5-2.5 part, trimethyl phosphate 3-4 parts, phosphorus
Sour front three phenolic ester 0.6-0.7 parts, microcrystalline wax 1.8-2.2 parts, dibutyl tin laurate 0.8-1 parts, magnesium stearate 1.8-2.2
Part, sulfur 1.8-2.2 parts, cumyl peroxide 1.3-1.7 parts.
Preferably, modified peanut fiber is prepared using following technique：Semen arachidis hypogaeae case fibre is sent in dichloromethane and is soaked,
Filter, washing adds sodium hydrate aqueous solution, heat up stirring, filters, and successively with water, ethanol and washing with acetone, dry, pulverize,
Diethyl pentetic acid, Anhydrous potassium carbonate stirring are added, is filtered, washing, vacuum drying, it is fine that crushing obtains modified peanut
Dimension.
Preferably, modified peanut fiber is prepared using following technique：25-35 part Semen arachidis hypogaeaes case fibre is sent into by weight
Soak in 70-90 part dichloromethane, filter, washing adds the sodium hydrate aqueous solution that 70-90 parts concentration is 1-2mol/L, rises
Temperature stirring, filters, and successively with water, ethanol and washing with acetone, dry, pulverize, and adds 15-25 part diethyl pentetic acids, 80-
120 parts of Anhydrous potassium carbonate stirrings, filter, and washing, vacuum drying, crushing obtains modified peanut fiber.
Preferably, modified peanut fiber is prepared using following technique：25-35 part Semen arachidis hypogaeaes case fibre is sent into by weight
4-8h is soaked in 70-90 part dichloromethane, is filtered, washing adds 70-90 parts concentration water-soluble for the sodium hydroxide of 1-2mol/L
Liquid, is warming up to 70-80 DEG C of stirring 60-120min, filters, and successively with water, ethanol and washing with acetone, 80-90 DEG C dry, pulverize,
15-25 part diethyl pentetic acids, 80-120 parts Anhydrous potassium carbonate stirring 4-10h are added, whipping temp is 70-80 DEG C, mistake
Filter, washing, 95-105 DEG C of vacuum drying, crushing obtains modified peanut fiber.
The present invention is obtained using conventional fabrication process.
The oil resistance of the present invention is good, and high temperature resistant, excellent anti-corrosion performance can effectively meet the need in productive life
Will, ageing-resistant, abrasion resistance properties are significantly increased, and service life is greatly prolonged.The present invention adopts silicone rubber, polyurethane rubber
Glue, acrylate rubber make the resistance to ag(e)ing of the present invention good, mechanics as base material, sulfur, cumyl peroxide collaboration sulfuration
Performance is fabulous, and oil resistance is good, high temperature resistant, excellent anti-corrosion performance, and trimethyl phosphate, tricresyl phosphate, microcrystalline wax
The lubricity of material can not only be increased, the formation in internal flaw and cavity is reduced, make the abrasion resistance properties of the present invention extremely strong；This
In bright modified peanut fiber, Semen arachidis hypogaeae case fibre is alkalized, then in fiber after dichloromethane process using sodium hydroxide
Surface introduce diethyl pentetic acid, make modified peanut fiber can with nano silicon, ceramic microsphere complexation in raw material,
Each other combination degree is high, high mechanical strength, and silicon nitride, aluminium borate whisker are coordinated in the presence of silane coupler KH-551
Effect, hardness is high, and anti-wear performance is extremely excellent；Antioxidant 264, antioxidant 1076 and Sorbitol as composite antioxidant, no
Only can effectively slow down aging speed, and elongation at break of the invention, long service life can be ensured.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
30 parts of rubber, 30 parts of silicone rubber, 20 parts of polyurethane rubber, 4 parts of silane coupler KH-551,10 parts of nano silicon, nitridation
40 parts of silicon, 10 parts of aluminium borate whisker, 20 parts of ceramic microsphere, 25 parts of modified peanut fiber, 4 parts of antioxidant 264, antioxidant
1076 2 parts, 3 parts of Sorbitol, 1 part of triallyl cyanurate, 5 parts of trimethyl phosphate, 0.5 part of tricresyl phosphate, crystallite
2.5 parts of paraffin, 0.4 part of dibutyl tin laurate, 2.5 parts of magnesium stearate, 1.5 parts of sulfur, 2 parts of cumyl peroxide.
Embodiment 2
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
50 parts of rubber, 10 parts of silicone rubber, 40 parts of polyurethane rubber, 2 parts of silane coupler KH-551,20 parts of nano silicon, nitridation
20 parts of silicon, 20 parts of aluminium borate whisker, 16 parts of ceramic microsphere, 45 parts of modified peanut fiber, 2 parts of antioxidant 264, antioxidant
1076 4 parts, 2 parts of Sorbitol, 3 parts of triallyl cyanurate, 2 parts of trimethyl phosphate, 0.8 part of tricresyl phosphate, crystallite
1.5 parts of paraffin, 1.2 parts of dibutyl tin laurate, 1.5 parts of magnesium stearate, 2.5 parts of sulfur, 1 part of cumyl peroxide.
Modified peanut fiber is prepared using following technique：Semen arachidis hypogaeae case fibre is sent in dichloromethane and is soaked, filter, wash
Wash, add sodium hydrate aqueous solution, heat up stirring, filters, and successively with water, ethanol and washing with acetone, dry, pulverize, and adds two
Ethyl pentaacetic acid, Anhydrous potassium carbonate stirring, filter, and washing, vacuum drying, crushing obtains modified peanut fiber.
Embodiment 3
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
35 parts of rubber, 25 parts of silicone rubber, 25 parts of polyurethane rubber, 3.5 parts of silane coupler KH-551,12 parts of nano silicon, nitrogen
35 parts of SiClx, 12 parts of aluminium borate whisker, 19 parts of ceramic microsphere, 30 parts of modified peanut fiber, 3.5 parts of antioxidant 264, antioxygen
1,076 2.5 parts of agent, 2.8 parts of Sorbitol, 1.5 parts of triallyl cyanurate, 4 parts of trimethyl phosphate, tricresyl phosphate
0.6 part, 2.2 parts of microcrystalline wax, 0.8 part of dibutyl tin laurate, 2.2 parts of magnesium stearate, 1.8 parts of sulfur, peroxidating two is different
1.7 parts of propyl benzene.
Modified peanut fiber is prepared using following technique：By weight 30 parts of Semen arachidis hypogaeae case fibres are sent into into 80 parts of dichloromethanes
Soak in alkane, filter, washing adds the sodium hydrate aqueous solution that 80 parts of concentration are 1.5mol/L, heat up stirring, filters, successively
With water, ethanol and washing with acetone, dry, pulverize, add 20 parts of diethyl pentetic acids, 100 parts of Anhydrous potassium carbonate stirrings, mistake
Filter, washing, vacuum drying, crushing obtains modified peanut fiber.
Embodiment 4
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
45 parts of rubber, 15 parts of silicone rubber, 35 parts of polyurethane rubber, 2.5 parts of silane coupler KH-551,18 parts of nano silicon, nitrogen
25 parts of SiClx, 18 parts of aluminium borate whisker, 17 parts of ceramic microsphere, 40 parts of modified peanut fiber, 2.5 parts of antioxidant 264, antioxygen
1,076 3.5 parts of agent, 2.2 parts of Sorbitol, 2.5 parts of triallyl cyanurate, 3 parts of trimethyl phosphate, tricresyl phosphate
0.7 part, 1.8 parts of microcrystalline wax, 1 part of dibutyl tin laurate, 1.8 parts of magnesium stearate, 2.2 parts of sulfur, peroxidating diisopropyl
1.3 parts of benzene.
Modified peanut fiber is prepared using following technique：By weight 25 parts of Semen arachidis hypogaeae case fibres are sent into into 90 parts of dichloromethanes
4h is soaked in alkane, is filtered, washing, the sodium hydrate aqueous solution for adding 90 parts of concentration to be 1mol/L is warming up to 80 DEG C of stirrings
60min, filters, and successively with water, ethanol and washing with acetone, 90 DEG C dry, pulverize, add 15 parts of diethyl pentetic acids, 120
Part Anhydrous potassium carbonate stirring 4h, whipping temp is 80 DEG C, is filtered, washing, and 95 DEG C are vacuum dried, and it is fine that crushing obtains modified peanut
Dimension.
Embodiment 5
A kind of wear-resisting silastic material of heavy-duty car proposed by the present invention, its raw material includes by weight：Acrylate
40 parts of rubber, 20 parts of silicone rubber, 30 parts of polyurethane rubber, 3 parts of silane coupler KH-551,15 parts of nano silicon, nitridation
30 parts of silicon, 15 parts of aluminium borate whisker, 18 parts of ceramic microsphere, 35 parts of modified peanut fiber, 3 parts of antioxidant 264, antioxidant
1076 3 parts, 2.5 parts of Sorbitol, 2 parts of triallyl cyanurate, 3.5 parts of trimethyl phosphate, tricresyl phosphate 0.65
Part, 2 parts of microcrystalline wax, 0.9 part of dibutyl tin laurate, 2 parts of magnesium stearate, 2 parts of sulfur, 1.5 parts of cumyl peroxide.
Modified peanut fiber is prepared using following technique：By weight 35 parts of Semen arachidis hypogaeae case fibres are sent into into 70 parts of dichloromethanes
8h is soaked in alkane, is filtered, washing, the sodium hydrate aqueous solution for adding 70 parts of concentration to be 2mol/L is warming up to 70 DEG C of stirrings
120min, filters, and successively with water, ethanol and washing with acetone, 80 DEG C dry, pulverize, add 25 parts of diethyl pentetic acids, 80
Part Anhydrous potassium carbonate stirring 10h, whipping temp is 70 DEG C, is filtered, washing, and 105 DEG C are vacuum dried, and crushing obtains modified peanut
Fiber.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. the wear-resisting silastic material of a kind of heavy-duty car, it is characterised in that its raw material includes by weight：Acrylate rubber
30-50 parts, silicone rubber 10-30 parts, polyurethane rubber 20-40 parts, silane coupler KH-551 2-4 parts, nano silicon
10-20 parts, silicon nitride 20-40 parts, aluminium borate whisker 10-20 parts, ceramic microsphere 16-20 parts, modified peanut fiber 25-45
Part, antioxidant 264 2-4 parts, antioxidant 1076 2-4 parts, Sorbitol 2-3 parts, triallyl cyanurate 1-3 part, phosphoric acid
Trimethyl 2-5 parts, tricresyl phosphate 0.5-0.8 parts, microcrystalline wax 1.5-2.5 parts, dibutyl tin laurate 0.4-1.2
Part, magnesium stearate 1.5-2.5 part, sulfur 1.5-2.5 parts, cumyl peroxide 1-2 parts.
2. the wear-resisting silastic material of heavy-duty car according to claim 1, it is characterised in that silane coupler KH-551,
Nano silicon, silicon nitride, aluminium borate whisker, ceramic microsphere, the weight ratio of modified peanut fiber are 2.5-3.5：12-
18：25-35：12-18：17-19：30-40.
3. the wear-resisting silastic material of heavy-duty car according to claim 1 or claim 2, it is characterised in that antioxidant 264, antioxygen
The weight ratio of agent 1076, Sorbitol is 2.5-3.5：2.5-3.5：2.2-2.8.
4. the wear-resisting silastic material of the heavy-duty car according to any one of claim 1-3, it is characterised in that its raw material is by weight
Amount part includes：Acrylate rubber 35-45 part, silicone rubber 15-25 parts, polyurethane rubber 25-35 parts, silane coupler KH-551
2.5-3.5 parts, nano silicon 12-18 parts, silicon nitride 25-35 parts, aluminium borate whisker 12-18 parts, ceramic microsphere 17-19
Part, modified peanut fiber 30-40 parts, antioxidant 264 2.5-3.5 parts, antioxidant 1076 2.5-3.5 parts, Sorbitol
2.2-2.8 parts, triallyl cyanurate 1.5-2.5 part, trimethyl phosphate 3-4 parts, tricresyl phosphate 0.6-0.7 parts are micro-
Spar wax 1.8-2.2 parts, dibutyl tin laurate 0.8-1 parts, magnesium stearate 1.8-2.2 part, sulfur 1.8-2.2 parts, peroxide
Change diisopropylbenzene (DIPB) 1.3-1.7 parts.
5. the wear-resisting silastic material of the heavy-duty car according to any one of claim 1-4, it is characterised in that modified peanut
Fiber is prepared using following technique：Semen arachidis hypogaeae case fibre is sent in dichloromethane and is soaked, filter, washing adds sodium hydroxide water
Solution, heat up stirring, filters, and successively with water, ethanol and washing with acetone, dry, pulverize, and adds diethyl pentetic acid, nothing
Aqueous carbonate potassium is stirred, and is filtered, and washing, vacuum drying, crushing obtains modified peanut fiber.
6. the wear-resisting silastic material of the heavy-duty car according to any one of claim 1-5, it is characterised in that modified peanut
Fiber is prepared using following technique：25-35 part Semen arachidis hypogaeaes case fibre is sent in 70-90 part dichloromethane is by weight soaked, mistake
Filter, washing adds the sodium hydrate aqueous solution that 70-90 parts concentration is 1-2mol/L, and heat up stirring, filters, successively with water, ethanol
And washing with acetone, dry, pulverize, 15-25 part diethyl pentetic acids, the stirring of 80-120 parts Anhydrous potassium carbonate are added, filter,
Washing, vacuum drying, crushing obtains modified peanut fiber.
7. the wear-resisting silastic material of the heavy-duty car according to any one of claim 1-6, it is characterised in that modified peanut
Fiber is prepared using following technique：25-35 part Semen arachidis hypogaeaes case fibre is sent in 70-90 part dichloromethane by weight soaks 4-
8h, filters, washing, the sodium hydrate aqueous solution for adding 70-90 parts concentration to be 1-2mol/L, is warming up to 70-80 DEG C of stirring 60-
120min, filters, and successively with water, ethanol and washing with acetone, 80-90 DEG C dry, pulverize, and adds 15-25 parts diethyl triamine five
Acetic acid, 80-120 parts Anhydrous potassium carbonate stirring 4-10h, whipping temp is 70-80 DEG C, is filtered, washing, and 95-105 DEG C of vacuum is done
Dry, crushing obtains modified peanut fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611139504.7A CN106674841A (en) | 2016-12-12 | 2016-12-12 | Wear-resistant silicone rubber material for heavy-duty vehicle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611139504.7A CN106674841A (en) | 2016-12-12 | 2016-12-12 | Wear-resistant silicone rubber material for heavy-duty vehicle |
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| Publication Number | Publication Date |
|---|---|
| CN106674841A true CN106674841A (en) | 2017-05-17 |
Family
ID=58868084
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611139504.7A Withdrawn CN106674841A (en) | 2016-12-12 | 2016-12-12 | Wear-resistant silicone rubber material for heavy-duty vehicle |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107099145A (en) * | 2017-05-23 | 2017-08-29 | 黄山市尚义橡塑制品有限公司 | A kind of phenyl siloxane rubber nano composite material and preparation method thereof |
| CN110448723A (en) * | 2019-07-12 | 2019-11-15 | 四川大学 | Cooperate with high crosslinked ultra-high-molecular-weight polyethylene artificial joint material of antioxidant and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0542268A1 (en) * | 1991-11-12 | 1993-05-19 | Sumitomo Rubber Industries Limited | Latex rubber product and method for manufacturing the same |
| CN103923360A (en) * | 2014-05-10 | 2014-07-16 | 任新年 | Abrasion-resistant rubber for tire and preparing method of abrasion-resistant rubber |
| CN105504414A (en) * | 2016-01-01 | 2016-04-20 | 崇夕山 | Rubber for vessel fenders |
| CN105733245A (en) * | 2016-04-15 | 2016-07-06 | 宿松县焕然机电有限责任公司 | High-strength wear-resistant insulating material for motor slot wedge |
-
2016
- 2016-12-12 CN CN201611139504.7A patent/CN106674841A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0542268A1 (en) * | 1991-11-12 | 1993-05-19 | Sumitomo Rubber Industries Limited | Latex rubber product and method for manufacturing the same |
| CN103923360A (en) * | 2014-05-10 | 2014-07-16 | 任新年 | Abrasion-resistant rubber for tire and preparing method of abrasion-resistant rubber |
| CN105504414A (en) * | 2016-01-01 | 2016-04-20 | 崇夕山 | Rubber for vessel fenders |
| CN105733245A (en) * | 2016-04-15 | 2016-07-06 | 宿松县焕然机电有限责任公司 | High-strength wear-resistant insulating material for motor slot wedge |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107099145A (en) * | 2017-05-23 | 2017-08-29 | 黄山市尚义橡塑制品有限公司 | A kind of phenyl siloxane rubber nano composite material and preparation method thereof |
| CN110448723A (en) * | 2019-07-12 | 2019-11-15 | 四川大学 | Cooperate with high crosslinked ultra-high-molecular-weight polyethylene artificial joint material of antioxidant and preparation method thereof |
| CN110448723B (en) * | 2019-07-12 | 2022-04-05 | 四川大学 | Synergistic antioxidant type high-crosslinking ultrahigh molecular weight polyethylene artificial joint material and preparation method thereof |
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Application publication date: 20170517 |