CN106674801A - High-molecular polymerization reinforced plastic and preparation method thereof - Google Patents
High-molecular polymerization reinforced plastic and preparation method thereof Download PDFInfo
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- CN106674801A CN106674801A CN201611125505.6A CN201611125505A CN106674801A CN 106674801 A CN106674801 A CN 106674801A CN 201611125505 A CN201611125505 A CN 201611125505A CN 106674801 A CN106674801 A CN 106674801A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses high-molecular polymerization reinforced plastic. The high-molecular polymerization reinforced plastic is prepared from the following materials in parts by weight: 90 to 120 parts of polyvinyl chloride resin, 80 to 800 parts of phenolic resin, 80 to 100 parts of epoxy resin, 60 to 80 parts of wood flour, 20 to 36 parts of glass fiber, 16 to 28 parts of diatomaceous earth, 15 to 25 parts of asbestos fiber, 10 to 20 parts of tar stone powder, 11 to 19 parts of fiber cloth waste, 8 to 14 parts of antimonous oxide, 16 to 20 parts of graphite, 30 to 40 parts of dioctyl phthalate, 7 to 9 parts of stearate and 7 to 9 parts of organic tin. The high-molecular polymerization reinforced plastic has the advantages of high strength, corrosion resistance and wear resistance.
Description
Technical field
The present invention relates to a kind of new material, in particular, is related to a kind of high molecular polymerization reinforced plastics and its preparation side
Method.
Background technology
With scientific technological advance, people according to the achievement in research of modern science and technology, are developed on the basis of traditional material
New material.It is big for metal material, Inorganic Non-metallic Materials, high-molecular organic material, advanced composite material four that new material presses component
Class.It is divided into structural material and functional material by material property.Structural material mainly uses the mechanics and physicochemical property of material, with
Meet the performance requirement such as high intensity, high rigidity, high rigidity, high temperature resistant, wear-resisting, anti-corrosion, Flouride-resistani acid phesphatase；Functional material is mainly used
The effects such as electricity that material has, magnetic, sound, photo-thermal, to realize certain function, such as semi-conducting material, magnetic material, light-sensitive material,
Thermo-sensitive material, stealth material and manufacture atomic bomb, nuclear material of hydrogen bomb etc..New material acts on great in national defense construction.For example,
Hyperpure silicon, GaAs are succeeded in developing, and cause the birth of extensive and super large-scale integration, make the operational speed of a computer from every
Second hundreds of thousands time improves more than 10,000,000,000 times per second till now；The operating temperature of materials for aeroengines often improves 100 DEG C, thrust
24% can be increased；The infra-red radiation of stealth material energy electromagnetic wave absorption or reduction weaponry, makes enemy's detection system be difficult to find
Etc..
Elastomeric material：From the plants such as rubber tree, russian dandelion obtain latex, made by after processing have elasticity, insulating properties,
The waterproof and material of air proof.Belong to macromolecular compound.Rubber is widely used in industry and life each side.It is existing
Development for elastomeric material is so that extensive the creating for elastomeric article with varying strength and chemical resistance can
Energy.With the development of synthetic latex material, different elastomeric materials and polymeric material have been applied to manufacture various products.Synthesis
A kind of useful species of elastomeric material compound include nitrile rubber class, which is widely used for article of manufacture such as glove and resistance to
Oil seal bar.
Many encapsulants in for automobile and building field include ethylene-propylene copolymer rubber (EPR) and ethylene-
Propylene diene copolymerized thing rubber (EPDM), it all seems very excellent on thermostability, weatherability, processability and cost.EPR and
EPDM is widely applied very much, especially as the indispensable raw material of car door, chest and window sealing institute.With in vapour
In car field, service behaviour more and more higher and service life become increasingly longer, for these encapsulants need higher performance.
However, it is difficult to fully meet all required operational capabilitys by ordinary skill.But such a EPDM is there is no, using its energy
It is enough to obtain in sealing property and roll-in processing characteristics, shape retention, mechanical strength properties, thermostability, resistance to cold and resistance to
Excellent rubber is showed in compression set performance.
Therefore, unusual high, the corrosion-resistant and anti abrasive plastic of demand intensity, for substituting existing common modeling
Material, promotes industrial expansion.
The content of the invention
In view of this, it is an object of the present invention to provide a kind of high, the corrosion-resistant and anti abrasive high molecular polymerization of intensity strengthens modeling
Material.
In order to solve above-mentioned technical problem, the technical scheme is that：A kind of high molecular polymerization reinforced plastics, by following
The material of weight portion is made, including Corvic 90-120 parts, phenolic resin 80-100 parts, epoxy resin 80-100 parts,
Wood powder 60-80 parts, glass fibre 20-36 parts, kieselguhr 16-28 parts, asbestos fibre 15-25 parts, tar stone powder 10-20 parts, fibre
Dimension cloth waste 11-19 parts, antimony oxide 8-14 parts, graphite 16-20 parts, dioctyl phthalate 30-40 parts, hard hydrochlorate 7-
9 parts and organotin 7-9 parts.
Further, the high molecular polymerization reinforced plastics is made up of the material of following weight portion, including polrvinyl chloride tree
120 parts of fat, 80 parts of phenolic resin, 80 parts of epoxy resin, 60 parts of wood powder, 20 parts of glass fibre, 16 parts of kieselguhr, asbestos fibre 15
Part, 10 parts of tar stone powder, 11 parts of fiber cloth waste, 8 parts of antimony oxide, 16 parts of graphite, 30 parts of dioctyl phthalate, hard
7 parts of 7 parts of hydrochlorate and organotin.
Further, the high molecular polymerization reinforced plastics is made up of the material of following weight portion, including polrvinyl chloride tree
90 parts of fat, 100 parts of phenolic resin, 100 parts of epoxy resin, 80 parts of wood powder, 36 parts of glass fibre, 28 parts of kieselguhr, asbestos fibre
25 parts, 20 parts of tar stone powder, 19 parts of fiber cloth waste, 14 parts of antimony oxide, 20 parts of graphite, 40 parts of dioctyl phthalate,
9 parts of 9 parts of hard hydrochlorate and organotin.
Further, the high molecular polymerization reinforced plastics is made up of the material of following weight portion, including polrvinyl chloride tree
105 parts of fat, 90 parts of phenolic resin, 90 parts of epoxy resin, 70 parts of wood powder, 28 parts of glass fibre, 22 parts of kieselguhr, asbestos fibre 20
It is part, 15 parts of tar stone powder, 15 parts of fiber cloth waste, 11 parts of antimony oxide, 18 parts of graphite, 35 parts of dioctyl phthalate, hard
8 parts of 8 parts of matter hydrochlorate and organotin.
The invention solves the problems that another technical problem be that a kind of preparation method of high molecular polymerization reinforced plastics is provided, including
Following steps：
1）Take Corvic 90-120 parts, phenolic resin 80-100 parts and epoxy resin 80-100 parts to be put in smelting furnace, and
It is heated to 320-400 DEG C so that Corvic, phenolic resin and epoxy resin melt rapidly at high temperature, mixing is obtained
Glue, it is standby；
2）Take dioctyl phthalate 30-40 parts and hard hydrochlorate 7-9 parts and organotin 7-9 parts are added to step 1）It is obtained
In mixed glue solution, 150 DEG C, and keeping temperature 1-2 hour are heated to so that mixed glue solution and dioctyl phthalate and hard
Hydrochlorate hybrid reaction, promotes the convergence reaction of glue, standby；
3）Take wood powder 60-80 parts, glass fibre 20-36 parts, kieselguhr 16-28 parts, asbestos fibre 15-25 parts, tar stone powder 10-
20 parts, antimony oxide 8-14 parts and graphite 16-20 parts are slowly stirred under the rotating speed of 50rpm by blender so that wood powder,
Glass fibre, kieselguhr, asbestos fibre, tar stone powder, antimony oxide and graphite mix homogeneously, are obtained mixed fillers, standby；
4）By step 3）The mixed-powder for stirring is put in agitator, by weight 2:3 ratio addition water, then passes through
Mixed fillers are mixed with water by blender with the rotating speed of 70rpm, and serosity is obtained, standby；
5）By step 4）Obtained serosity and step 2）It is obtained the mixing of reacted glue, and in homogenizer with per minute 80
Serosity and mixed glue solution are stirred by the rotating speed for turning, standby；
6）By step 5）Mixed glue solution after stirring is heated to 168 DEG C, while slow with 50 turns per minute of rotating speed by blender
It is slow to stir, while adding fiber cloth waste 11-19 parts so that fiber cloth waste is stirred with mixed glue solution, standby；
7）By step 6）Obtained mixed glue solution is injected on the mould got ready by casting machine, is stood natural cooling, is obtained final product.
The technology of the present invention effect major embodiment is in the following areas：By Corvic, phenolic resin, epoxy resin Jing
Cross high-temperature fusion, obtained glue, and add wood powder, glass fibre, kieselguhr, asbestos fibre, tar stone powder, fiber cloth waste,
Antimony oxide and graphite etc. increase the additive such as filler and dioctyl phthalate, hard hydrochlorate and organotin and mix
After uniform, die sinking can be obtained the high molecular polymerization reinforced plastics for having the advantages that intensity is high, corrosion-resistant and wear-resistant.
Specific embodiment
Embodiment 1
A kind of high molecular polymerization reinforced plastics, is made up of the raw material of following weight portion, is made up of the material of following weight portion, bag
Include 120 parts of Corvic, 80 parts of phenolic resin, 80 parts of epoxy resin, 60 parts of wood powder, 20 parts of glass fibre, kieselguhr 16
Part, 15 parts of asbestos fibre, 10 parts of tar stone powder, 11 parts of fiber cloth waste, 8 parts of antimony oxide, 16 parts of graphite, phthalic acid two
7 parts of 30 parts of monooctyl ester, 7 parts of hard hydrochlorate and organotin.
A kind of preparation method of high molecular polymerization reinforced plastics, comprises the following steps：
1）Take 80 parts of 120 parts of Corvic, 80 parts of phenolic resin and epoxy resin to be put in smelting furnace, and be heated to 320 DEG C,
So that Corvic, phenolic resin and epoxy resin melt rapidly at high temperature, mixed glue solution is obtained, it is standby；
2）Take 7 parts of 30 parts of dioctyl phthalate and hard hydrochlorate and 7 parts of organotin is added to step 1）Obtained epoxy glue
In liquid, 150 DEG C are heated to, and keeping temperature 1 hour so that mixed glue solution is mixed with dioctyl phthalate and hard hydrochlorate
Reaction, promotes the convergence reaction of glue, standby；
3）Take 60 parts of wood powder, 20 parts of glass fibre, 16 parts of kieselguhr, 15 parts of asbestos fibre, 10 parts of tar stone powder, antimony oxide
8 parts are slowly stirred by blender under the rotating speed of 50rpm with 16 parts of graphite so that wood powder, glass fibre, kieselguhr, asbestos
Fiber, tar stone powder, antimony oxide and graphite mix homogeneously, are obtained mixed fillers, standby；
4）By step 3）The mixed-powder for stirring is put in agitator, by weight 2:3 ratio addition water, then passes through
Mixed fillers are mixed with water by blender with the rotating speed of 70rpm, and serosity is obtained, standby；
5）By step 4）Obtained serosity and step 2）It is obtained the mixing of reacted glue, and in homogenizer with per minute 80
Serosity and mixed glue solution are stirred by the rotating speed for turning, standby；
6）By step 5）Mixed glue solution after stirring is heated to 168 DEG C, while slow with 50 turns per minute of rotating speed by blender
It is slow to stir, while adding 11 parts of fiber cloth waste so that fiber cloth waste is stirred with mixed glue solution, standby；
7）By step 6）Obtained mixed glue solution is injected on the mould got ready by casting machine, is stood natural cooling, is obtained final product.
Embodiment 2
A kind of high molecular polymerization reinforced plastics, is made up of the material of following weight portion, including 90 parts of Corvic, phenolic aldehyde tree
100 parts of fat, 100 parts of epoxy resin, 80 parts of wood powder, 36 parts of glass fibre, 28 parts of kieselguhr, 25 parts of asbestos fibre, tar stone powder
20 parts, 19 parts of fiber cloth waste, 14 parts of antimony oxide, 20 parts of graphite, 40 parts of dioctyl phthalate, 9 parts of hard hydrochlorate and
9 parts of organotin.
A kind of preparation method of high molecular polymerization reinforced plastics, comprises the following steps：
1）Take 100 parts of 90 parts of Corvic, 100 parts of phenolic resin and epoxy resin to be put in smelting furnace, and be heated to 400
DEG C so that Corvic, phenolic resin and epoxy resin melt rapidly at high temperature, and mixed glue solution is obtained, standby；
2）Take 9 parts of 40 parts of dioctyl phthalate and hard hydrochlorate and 9 parts of organotin is added to step 1）Obtained epoxy glue
In liquid, 150 DEG C are heated to, and keeping temperature 2 hours so that mixed glue solution is mixed with dioctyl phthalate and hard hydrochlorate
Reaction, promotes the convergence reaction of glue, standby；
3）Take 80 parts of wood powder, 36 parts of glass fibre, 28 parts of kieselguhr, 25 parts of asbestos fibre, 20 parts of tar stone powder, antimony oxide
14 parts are slowly stirred by blender under the rotating speed of 50rpm with 20 parts of graphite so that wood powder, glass fibre, kieselguhr, asbestos
Fiber, tar stone powder, antimony oxide and graphite mix homogeneously, are obtained mixed fillers, standby；
4）By step 3）The mixed-powder for stirring is put in agitator, by weight 2:3 ratio addition water, then passes through
Mixed fillers are mixed with water by blender with the rotating speed of 70rpm, and serosity is obtained, standby；
5）By step 4）Obtained serosity and step 2）It is obtained the mixing of reacted glue, and in homogenizer with per minute 80
Serosity and mixed glue solution are stirred by the rotating speed for turning, standby；
6）By step 5）Mixed glue solution after stirring is heated to 168 DEG C, while slow with 50 turns per minute of rotating speed by blender
It is slow to stir, while adding 19 parts of fiber cloth waste so that fiber cloth waste is stirred with mixed glue solution, standby；
7）By step 6）Obtained mixed glue solution is injected on the mould got ready by casting machine, is stood natural cooling, is obtained final product.
Embodiment 3
A kind of high molecular polymerization reinforced plastics, is made up of the material of following weight portion, including 105 parts of Corvic, phenolic aldehyde
90 parts of resin, 90 parts of epoxy resin, 70 parts of wood powder, 28 parts of glass fibre, 22 parts of kieselguhr, 20 parts of asbestos fibre, tar stone powder
15 parts, 15 parts of fiber cloth waste, 11 parts of antimony oxide, 18 parts of graphite, 35 parts of dioctyl phthalate, 8 parts of hard hydrochlorate and
8 parts of organotin.
A kind of preparation method of high molecular polymerization reinforced plastics, comprises the following steps：
1）Take 90 parts of 105 parts of Corvic, 90 parts of phenolic resin and epoxy resin to be put in smelting furnace, and be heated to 360 DEG C,
So that Corvic, phenolic resin and epoxy resin melt rapidly at high temperature, mixed glue solution is obtained, it is standby；
2）Take 8 parts of 35 parts of dioctyl phthalate and hard hydrochlorate and 8 parts of organotin is added to step 1）Obtained epoxy glue
In liquid, 150 DEG C are heated to, and keeping temperature 1.5 hours so that mixed glue solution is mixed with dioctyl phthalate and hard hydrochlorate
Reaction is closed, promotes the convergence reaction of glue, it is standby；
3）Take 70 parts of wood powder, 28 parts of glass fibre, 22 parts of kieselguhr, 20 parts of asbestos fibre, 15 parts of tar stone powder, antimony oxide
11 parts are slowly stirred by blender under the rotating speed of 50rpm with 18 parts of graphite so that wood powder, glass fibre, kieselguhr, asbestos
Fiber, tar stone powder, antimony oxide and graphite mix homogeneously, are obtained mixed fillers, standby；
4）By step 3）The mixed-powder for stirring is put in agitator, by weight 2:3 ratio addition water, then passes through
Mixed fillers are mixed with water by blender with the rotating speed of 70rpm, and serosity is obtained, standby；
5）By step 4）Obtained serosity and step 2）It is obtained the mixing of reacted glue, and in homogenizer with per minute 80
Serosity and mixed glue solution are stirred by the rotating speed for turning, standby；
6）By step 5）Mixed glue solution after stirring is heated to 168 DEG C, while slow with 50 turns per minute of rotating speed by blender
It is slow to stir, while adding 15 parts of fiber cloth waste so that fiber cloth waste is stirred with mixed glue solution, standby；
7）By step 6）Obtained mixed glue solution is injected on the mould got ready by casting machine, is stood natural cooling, is obtained final product.
Experimental example
Experimental subject：Using propylene is fine, the high score of polytrifluorochloroethylene, politef, Polyphenylene Sulfone and polyamide and the application
Son polymerization reinforced plastics is contrasted.
Requirement of experiment：Above-mentioned propylene is fine, polytrifluorochloroethylene, politef, Polyphenylene Sulfone and polyamide and this Shen
The consistency of thickness of high molecular polymerization reinforced plastics please, and area is consistent.
Experimental technique：By, polytrifluorochloroethylene fine to propylene, politef, Polyphenylene Sulfone and polyamide and this Shen
High molecular polymerization reinforced plastics please carries out yield strength test, the modulus of elasticity in static bending, shrinkage factor test and durability degree test,
In this experimental example, durability degree test includes anti-wear performance, pressure performance, backwash flexibility test, ageing-resistant performance, heat-resisting and resistance to
Cryogenic property etc. is tested.
Concrete outcome is as shown in the table：
With reference to upper table, the data of different rubber gained under identical experimental technique, a kind of polyphosphazene polymer of the present invention are contrasted
The test data for closing reinforced plastics is above the various plastics for contrast.
The technology of the present invention effect major embodiment is in the following areas：By Corvic, phenolic resin, epoxy resin Jing
Cross high-temperature fusion, obtained glue, and add wood powder, glass fibre, kieselguhr, asbestos fibre, tar stone powder, fiber cloth waste,
Antimony oxide and graphite etc. increase the additive such as filler and dioctyl phthalate, hard hydrochlorate and organotin and mix
After uniform, die sinking can be obtained the high molecular polymerization reinforced plastics for having the advantages that intensity is high, corrosion-resistant and wear-resistant.
Certainly, the above is the representative instance of the present invention, and in addition, the present invention can also have other various to be embodied as
The technical scheme that mode, all employing equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.
Claims (4)
1. a kind of high molecular polymerization reinforced plastics, it is characterised in that：It is made up of the material of following weight portion, including polrvinyl chloride tree
Fat 90-120 parts, phenolic resin 80-100 parts, epoxy resin 80-100 parts, wood powder 60-80 parts, glass fibre 20-36 parts, diatom
Native 16-28 parts, asbestos fibre 15-25 parts, tar stone powder 10-20 parts, fiber cloth waste 11-19 parts, antimony oxide 8-14 parts, stone
Black 16-20 parts, dioctyl phthalate 30-40 parts, hard hydrochlorate 7-9 parts and organotin 7-9 parts.
2. a kind of high molecular polymerization reinforced plastics as claimed in claim 1, it is characterised in that：By the material system of following weight portion
Into including 120 parts of Corvic, 80 parts of phenolic resin, 80 parts of epoxy resin, 60 parts of wood powder, 20 parts of glass fibre, diatom
16 parts of soil, 15 parts of asbestos fibre, 10 parts of tar stone powder, 11 parts of fiber cloth waste, 8 parts of antimony oxide, 16 parts of graphite, O-phthalic
7 parts of 30 parts of dioctyl phthalate, 7 parts of hard hydrochlorate and organotin.
3. a kind of high molecular polymerization reinforced plastics as claimed in claim 1, it is characterised in that：By the material system of following weight portion
Into including 90 parts of Corvic, 100 parts of phenolic resin, 100 parts of epoxy resin, 80 parts of wood powder, 36 parts of glass fibre, silicon
28 parts of diatomaceous earth, 25 parts of asbestos fibre, 20 parts of tar stone powder, 19 parts of fiber cloth waste, 14 parts of antimony oxide, 20 parts of graphite, adjacent benzene
9 parts of 40 parts of diformazan dioctyl phthalate, 9 parts of hard hydrochlorate and organotin.
4. a kind of high molecular polymerization reinforced plastics as claimed in claim 1, it is characterised in that：By the material system of following weight portion
Into including 105 parts of Corvic, 90 parts of phenolic resin, 90 parts of epoxy resin, 70 parts of wood powder, 28 parts of glass fibre, diatom
22 parts of soil, 20 parts of asbestos fibre, 15 parts of tar stone powder, 15 parts of fiber cloth waste, 11 parts of antimony oxide, 18 parts of graphite, adjacent benzene two
8 parts of 35 parts of formic acid dioctyl ester, 8 parts of hard hydrochlorate and organotin.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611125505.6A CN106674801A (en) | 2016-12-09 | 2016-12-09 | High-molecular polymerization reinforced plastic and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107365474A (en) * | 2017-08-22 | 2017-11-21 | 安徽悦尔伟塑料机械有限公司 | Formica and preparation method thereof |
| CN107383765A (en) * | 2017-08-22 | 2017-11-24 | 安徽悦尔伟塑料机械有限公司 | Engineering flame retardant plastic flitch and preparation method thereof |
| CN107915952A (en) * | 2017-10-19 | 2018-04-17 | 安徽奥兹信息科技有限公司 | High-strength V R glasses housings and preparation method thereof |
| CN107936463A (en) * | 2017-10-19 | 2018-04-20 | 安徽奥兹信息科技有限公司 | High-strength V R glasses housings and preparation method thereof |
| CN107955326A (en) * | 2017-10-19 | 2018-04-24 | 周夕和 | A kind of lightweight non-metallic ball grinding machine lining board |
| CN107952193A (en) * | 2017-11-03 | 2018-04-24 | 浙江超亿消防设备有限公司 | A kind of double-layer explosion-proof fire extinguisher |
| CN108384151A (en) * | 2018-03-29 | 2018-08-10 | 合肥市闵葵电力工程有限公司 | A kind of high-low voltage electric power distribution cabinet cabinet plate and preparation method thereof |
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| CN109096702A (en) * | 2018-08-25 | 2018-12-28 | 马鞍山卓凡新材料科技有限公司 | A kind of expoxy glass Steel material of acid-alkali-corrosive-resisting |
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2016
- 2016-12-09 CN CN201611125505.6A patent/CN106674801A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107365474A (en) * | 2017-08-22 | 2017-11-21 | 安徽悦尔伟塑料机械有限公司 | Formica and preparation method thereof |
| CN107383765A (en) * | 2017-08-22 | 2017-11-24 | 安徽悦尔伟塑料机械有限公司 | Engineering flame retardant plastic flitch and preparation method thereof |
| CN107915952A (en) * | 2017-10-19 | 2018-04-17 | 安徽奥兹信息科技有限公司 | High-strength V R glasses housings and preparation method thereof |
| CN107936463A (en) * | 2017-10-19 | 2018-04-20 | 安徽奥兹信息科技有限公司 | High-strength V R glasses housings and preparation method thereof |
| CN107955326A (en) * | 2017-10-19 | 2018-04-24 | 周夕和 | A kind of lightweight non-metallic ball grinding machine lining board |
| CN107952193A (en) * | 2017-11-03 | 2018-04-24 | 浙江超亿消防设备有限公司 | A kind of double-layer explosion-proof fire extinguisher |
| CN108384151A (en) * | 2018-03-29 | 2018-08-10 | 合肥市闵葵电力工程有限公司 | A kind of high-low voltage electric power distribution cabinet cabinet plate and preparation method thereof |
| CN108976699A (en) * | 2018-06-28 | 2018-12-11 | 太仓市晨洲塑业有限公司 | A kind of engineering plastics for mold |
| CN109096702A (en) * | 2018-08-25 | 2018-12-28 | 马鞍山卓凡新材料科技有限公司 | A kind of expoxy glass Steel material of acid-alkali-corrosive-resisting |
| CN109294161A (en) * | 2018-10-05 | 2019-02-01 | 浙江尚居环保科技股份有限公司 | A kind of mould proof bamboo and wood circuit board and preparation method thereof |
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