CN106674752A - Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof - Google Patents
Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof Download PDFInfo
- Publication number
- CN106674752A CN106674752A CN201611217035.6A CN201611217035A CN106674752A CN 106674752 A CN106674752 A CN 106674752A CN 201611217035 A CN201611217035 A CN 201611217035A CN 106674752 A CN106674752 A CN 106674752A
- Authority
- CN
- China
- Prior art keywords
- composite material
- percent
- scratch
- tacky
- static
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and a preparation method thereof. The composite material is prepared from the following raw materials in percentage by weight: 43 percent to 95 percent of polypropylene, 1 percent to 20 percent of ultra-high molecular weight polyethylene, 1 percent to 30 percent of inorganic filling, 1 percent to 8 percent of superconductive carbon black, 0.2 percent to 2 percent of a lubricant, 1 percent to 3 percent of a coupling agent, 0.1 percent to 1 percent of an antioxygen and 0.1 percent to 1 percent of a light stabilizer. The scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material has the advantages that 1, the polypropylene composite material prepared by adding the ultra-high molecular weight polyethylene has a relatively good scratching-resisting performance, and the mechanical property, particularly the impact property, of the material is relatively greatly improved; 2, compared with the prior art, a small molecular auxiliary agent is added to improve the scratching-resisting and antistatic properties, and the problems that the material is sticky and separated out in a utilization process are avoided on the basis that the scratching-resisting and antistatic properties are the same or higher.
Description
Technical field
The present invention relates to a kind of scratch-resistant, resist tacky and permanent anti-static PP composite material and preparation method thereof, be
A kind of process is simple, low cost, the PP composite material of good combination property, are mainly used in household electrical appliance, automobile interior exterior decorations
Deng part, belong to polymer modification and processing technique field.
Background technology
Polypropylene is because having preferable processing characteristics and excellent mechanics, physics, chemical property, while light weight is inexpensive, extensively
It is general to be applied to the industries such as automobile interior exterior decorations, household electrical appliance and electronics, it is the most fast universal thermoplastic of current growth rate.
However, because polypropylene surface hardness is low, the household appliances shell or inner and outer decorative parts of automobile scraping and wiping resistance performance being made from it are poor,
Product surface is easily scratched, so as to influence presentation quality.Meanwhile, polypropylene is higher due to specific insulation, and surface easily collects
Poly- electric charge and cannot conduct, cause product surface to carry electrostatic and cause the phenomenons such as dust suction and spark discharge.Therefore, how to improve
The scratch resistance and antistatic behaviour of polypropylene material turn into the key issue of this kind of material of exploitation.
At present, for polypropylene material scraping and wiping resistance performance difference and the not enough problem of antistatic effect, there are reports and
Solution, is concentrated mainly on to scratch-resistant auxiliary agent and antistatic additive is added in polypropylene material, such as amide-type and silicone
The antistatic additive of scratch-resistant auxiliary agent and ionic and nonionic surface active agent class.Chinese patent 200810023328.X is public
A kind of scraping-resistant automobile inner fitting special-purpose material and preparation method thereof is opened, using amide-type and silicone scratch-resistant additive compound
To improve the scraping and wiping resistance performance of PP composite material.United States Patent (USP) US4000102 discloses a kind of antistatic polypropylene and is combined
Material and preparation method thereof, polypropylene material is improved using anion surfactant fatty acid zinc as antistatic additive
Antistatic property.The scratch-resistant auxiliary agent and antistatic additive of these additions are mostly micromolecular compound, are easily moved in injection moulding process
Product surface is moved to, causes product in use the problems such as tacky and precipitation is also easy to produce in the presence of light and heat, influence
Using effect.Although short-acting impermanent, it is impossible to reach additionally, ionic surfactant class antistatic additive antistatic effect is good
To the requirement of permanent anti-static；And nonionic surface active agent class antistatic additive antistatic effect is poor, addition is more, cost compared with
It is high.
The content of the invention
The purpose of the present invention is exactly to provide a kind of with preferably resistance to for the defect for overcoming above-mentioned prior art to exist
Scratch performance and permanent antistatic performance, while tacky PP composite material and preparation method thereof can be resisted again.
A kind of scratch-resistant, anti-tacky and permanent anti-static PP composite material, are matched somebody with somebody by the raw material of following percentage by weight
It is made：
In the PP composite material system that the present invention is applicable, described polypropylene is in 230 DEG C, 2.16kg loading condictions
Under, melt flow rate (MFR) is 5~60g/10min.
The polypropylene is homo-polypropylene or block copolymerization propylene；The crystallinity of the homo-polypropylene more than 70%, etc.
Normality is more than 99%；The comonomer of described block copolymerization polypropylene is ethene, and vinyl monomer repeat unit molar content is 4
~10%.
Described ultra-high molecular weight polyethylene, relative molecular mass is 1.5-2.5 × 106, density is 0.93~0.94g/
cm3。
Described inorganic filler is the composition of one or more in talcum powder, calcium carbonate and barium sulfate, its particle diameter model
Enclose and be 1~10 μm.
The particle diameter of described superconductive carbon black is 20~50nm, and resistivity is 0.8~1.2 Ω .m.
Described lubricant is any one in Tissuemat E, oxidic polyethylene, paraffin.
Described coupling agent is any one in silane coupler, titanate coupling agent and aluminate coupling agent.
Described antioxidant includes primary antioxidant and auxiliary anti-oxidant, and primary antioxidant is hindered phenol or sulphur ester antioxidant；It is auxiliary
Antioxidant is phosphorite kind antioxidant.
Described primary antioxidant be 3114,1010 and DSTP in one or more mixing；Auxiliary anti-oxidant is 618 and 168
In one or two.
Described light stabilizer selects hindered amine light stabilizer, one or two the mixture in such as 944 and 770.
Above-mentioned scratch-resistant, anti-tacky and permanent anti-static PP composite material and preparation method thereof, its specific steps is such as
Under：
(1) raw material is weighed by proportioning；
(2) each raw material is placed in super mixer and is mixed 3~5 minutes；
(3) raw material of mixing is placed in dual-screw-stem machine, through melting extrusion, is granulated, its technique is：One area 190~200
DEG C, two 200~210 DEG C of areas, three 200~210 DEG C of areas, four 205~215 DEG C of areas；Screw speed is 100-1000r/min；Entirely
The residence time of extrusion is 1~2 minute, and pressure is 12~18MPa, and purging vacuum degree reaches 5~20kPa.
In order to improve the scratch resistance and antistatic behaviour of PP composite material, and solve tradition addition low molecule scratch-resistant
Tacky and precipitation the problem of the product that auxiliary agent and antistatic auxiliary are brought, the technical scheme is that in the base of polypropylene material
Ultra-high molecular weight polyethylene and superconductive carbon black are added in plinth formula, using the superpower wearability of ultra-high molecular weight polyethylene and certainly
Lubricity, high intensity and excellent resistance to ag(e)ing, and the excellent electric conductivity of superconductive carbon black, in the composite superelevation point
Sub- weight northylen strand and polypropylene molecular chain are cross-linked to form " linear interpenetrating networks " structure, superconductive carbon black it is dispersed its
In, while composite scraping and wiping resistance performance is greatly improved, can permanent anti-static, while material is being used after being made product
During the generation without tacky phenomenon.Further, since Super-conductive carbon electric conductivity is high, consumption is small, and the performance to material is basic
Without influence.
It is an advantage of the invention that：
1st, the present invention makes obtained PP composite material with preferably resistance to by adding ultra-high molecular weight polyethylene
Scratch performance, at the same the mechanical property of material especially impact property has lifting by a relatively large margin.
2nd, the present invention uses the superconductive carbon black with ultra-high conductivity energy as antistatic additive, uses less addition
The effect of permanent anti-static can just be reached.
3rd, the present invention improves the scratch resistance and antistatic behaviour of material compared to tradition by adding small molecule auxiliary agent, in tool
On the basis of having scratch resistance same or higher and an antistatic behaviour, it is to avoid material is produced tacky and separated out in use
Problem.
4th, scratch-resistant proposed by the present invention, resist tacky and permanent anti-static PP composite material preparation process is simple,
Easily realize industrialized production.
Specific embodiment
With reference to embodiment, the present invention is described in further detail.The scope of the present invention is not by these embodiments
Limitation, the scope of the present invention is proposed in detail in the claims.
In the composite-material formula of embodiment and comparative example, polypropylene used is the copolymerization poly- third of oil of SPC production
Alkene, melt flow rate (MFR) is 15g/10min.Ultra-high molecular weight polyethylene used is the supra polymer of Beijing second auxiliary factory production
Weight northylen, product designation M- II, its average molecular mass is 2.5 × 106, it is white powder, density is 0.93~
0.94g/cm3.Inorganic filler used is the talcum powder of 5000 mesh, and average grain diameter is 2.5 μm.Superconductive carbon black used it is flat
Equal particle diameter is 25nm, and resistivity is 0.8~1.2 Ω m, and specific surface area is (6~8) × 105m2/ kg, pH value 8.0, its addition
Percentage by weight be 1~10%.Lubricant used is Tissuemat E.Coupling agent used is Silane coupling agent KH550.Institute
Primary antioxidant be BASF AG produce 3114, product designation Irganox 3114, chemical name be 3,5- di-t-butyls-
4- hydroxybenzyl phosphate diethylesters, and the DSTP, product designation Negonox DSTP, chemical name that ICE companies of Britain produce
It is thio-2 acid octadecyl ester.Auxiliary anti-oxidant is the 168 of BASF AG's product, product designation Irgafos 168, and chemical name is
Three (2,4- di-tert-butyl-phenyls) phosphite esters.Light stabilizer used is the 944 of BASF AG's production, and chemical name is poly-
{ double [(2,2,6,6- tetramethyl-4-piperidyls) imido of [6- [(1,1,3,3- tetramethyl butyls) amino]] -1,3,5- triazines -2,4-
Base] -1,6- oneself two support [(2,2,6,6- tetramethyl -4- piperidyls) imino group], and BASF AG produce 770, chemical name
It is double (2,2,6,6- tetramethyl-piperidyls) sebacates.
Using preceding, raw material is weighed by said components and weight proportion, dry-mixed 3~5 minutes in super mixer；Will mixing
Raw material be placed in dual-screw-stem machine, through melting extrusion, granulation, its technique is：One 190~200 DEG C of area, two 200~210 DEG C of areas,
Three 200~210 DEG C of areas, four 205~215 DEG C of areas, double screw extruder rotating speed is 600r/min；During the stop of whole extrusion
Between be 1~2 minute, pressure is 12~18MPa, and purging vacuum degree reaches 5~20kPa.
Embodiment 1
PP composite material key component of the present invention includes 72.1% polypropylene, 5% ultra-high molecular weight polyethylene, 15%
Talcum powder, 3% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and
0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Embodiment 2
PP composite material key component of the present invention include 67.1% polypropylene, 10% ultra-high molecular weight polyethylene,
15% talcum powder, 3% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant
DSTP and 0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Embodiment 3
PP composite material key component of the present invention include 62.1% polypropylene, 15% ultra-high molecular weight polyethylene,
15% talcum powder, 3% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant
DSTP and 0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Embodiment 4
PP composite material key component of the present invention includes 88.1% polypropylene, 5% ultra-high molecular weight polyethylene, 2%
Superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and 0.2% antioxidant
168th, 0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Embodiment 5
PP composite material key component of the present invention include 61.1% polypropylene, 10% ultra-high molecular weight polyethylene,
20% talcum powder, 4% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant
DSTP and 0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Embodiment 6
PP composite material key component of the present invention include 43.1% polypropylene, 15% ultra-high molecular weight polyethylene,
30% talcum powder, 6% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant
DSTP and 0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,2% black masterbatch.
Embodiment 7
PP composite material key component of the present invention include 41.1% polypropylene, 15% ultra-high molecular weight polyethylene,
30% talcum powder, 8% superconductive carbon black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant
DSTP and 0.2% irgasfos 168,0.15% light stabilizer 944 and 0.15% light stabilizer 770,2% black masterbatch.
Comparative example 1
PP composite material key component of the present invention includes that 67.1% polypropylene, 15% talcum powder, 3% superconduct charcoal
Black, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and 0.2% irgasfos 168,
0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Comparative example 2
PP composite material key component of the present invention includes 93.1% polypropylene, 2% superconductive carbon black, 1.2% lubrication
Agent, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and 0.2% irgasfos 168,0.15% light stabilizer
944 and 0.15% light stabilizer 770,1% black masterbatch.
Comparative example 3
PP composite material key component of the present invention include 65.1% polypropylene, 10% ultra-high molecular weight polyethylene,
20% talcum powder, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and 0.2% antioxidant
168th, 0.15% light stabilizer 944 and 0.15% light stabilizer 770,1% black masterbatch.
Comparative example 4
PP composite material key component of the present invention include 49.1% polypropylene, 15% ultra-high molecular weight polyethylene,
30% talcum powder, 1.2% lubricant, 2% coupling agent, 0.1% antioxidant 3114,0.1% antioxidant DSTP and 0.2% antioxidant
168th, 0.15% light stabilizer 944 and 0.15% light stabilizer 770,2% black masterbatch.
Embodiment and comparative example main component weight/mass percentage composition are shown in Table 1.
The embodiment 1-7 of table 1 and comparative example 1-4 material prescriptions table (weight %)
Performance evaluation mode and implementation standard：
The particulate material that will be prepared as stated above, it is dry 2~3 hours in 90~100 DEG C of air dry oven, then
Again by dried particle on injection machine injection moulding sample.
Tensile property is tested：Carried out by ISO 527-2 standards, specimen size is 170 × 10 × 4mm, draw speed is
50mm/min；
Bending property is tested：Carried out by the standards of ISO 178, specimen size is 80 × 10 × 4mm, and rate of bending is 2mm/
Min, span is 64mm；
Notch impact strength is tested：Carried out by ISO 179-1 standards, specimen size is 80 × 10 × 4mm, notch depth is
/ 3rd of sample thickness, test temperature is 23 DEG C；
Scraping and wiping resistance performance is tested：Tested by popular standard PV3952,150 × 100 × 3.2mm of size of sample, with negative
Lotus is 10N, and the scratch hardness tester of a diameter of 1mm of nib carries out scratch test, cut interval 2mm, horizontal and vertical each stroke
20 lines, the color change before and after being scraped using color difference meter test, the △ L values of recording materials, △ L values are smaller to show scratch resistance
Can be better；
Surface resistivity is tested：By the standards of GB/T 1410, measured using sheet resistance instrument, size of sample 150 ×
100 × 3.2mm, test environment is 23 ± 2 DEG C, relative humidity 50 ± 5%.
Surfaces of tacky situation：Tested by popular standard PV1306, described by the Appreciation gist table 2 below of sample etc.
Level：
The surfaces of tacky grade of table 2 and evaluation result
| Grade | Evaluation result | Grade | Evaluation result |
| 1 | OK | 5 | It is very glutinous |
| 2 | It is slight tacky | H | Resinification |
| 3 | It is tacky | W | Surface is smooth, wax-like |
| 4 | Relatively glue | X | There is crackle in sample, it is impossible to evaluate |
The performance test results of embodiment of the present invention 1-7 and comparative example 1-4 PP composite materials are shown in Table 3 respectively.
The embodiment 1-7 of table 3 and comparative example 1-4 material property tables
From the contrast of embodiment 1-3 and comparative example 1, and embodiment 4 superelevation point is can be seen that with the contrast of comparative example 2
Sub- weight northylen can effectively improve the scraping and wiping resistance performance of PP composite material system, while the toughness of composite system
There is lifting by a relatively large margin.Embodiment 5 can be seen that poly- third with comparative example 3 and embodiment 6-7 with the contrast of comparative example 4
Superconductive carbon black is added in alkene composite, the antistatic property of compound system can be greatly improved, and addition is few, to material
The mechanical property of material substantially without influence, while compound system can reach permanent antistatic performance.From all embodiments and contrast
Example is as can be seen that PP composite material system reaches anti-tacky effect.
Claims (12)
1. a kind of scratch-resistant, resist tacky and permanent anti-static PP composite material, it is characterised in that：By following percentage by weight
Raw material be configured to：
2. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Under 230 DEG C, 2.16kg loading condictions, melt flow rate (MFR) is 5~60g/10min to described polypropylene.
3. a kind of scratch-resistant according to claim 2, resist tacky and permanent anti-static PP composite material, its feature exists
In：The polypropylene is homo-polypropylene or block copolymerization propylene；The crystallinity of the homo-polypropylene is more than 70%, and isotacticity is big
In 99%；The comonomer of described block copolymerization polypropylene be ethene, vinyl monomer repeat unit molar content be 4~
10%.
4. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Described ultra-high molecular weight polyethylene, relative molecular mass is 1.5-2.5 × 106, density is 0.93~0.94g/cm3。
5. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Described inorganic filler is the composition of one or more in talcum powder, calcium carbonate and barium sulfate, and its particle size range is
1~10 μm.
6. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：The particle diameter of described superconductive carbon black is 20~50nm, and resistivity is 0.8~1.2 Ω .m.
7. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Described lubricant is any one in Tissuemat E, oxidic polyethylene, paraffin.
8. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Described coupling agent is any one in silane coupler, titanate coupling agent and aluminate coupling agent.
9. a kind of scratch-resistant according to claim 1, resist tacky and permanent anti-static PP composite material, its feature exists
In：Described antioxidant includes primary antioxidant and auxiliary anti-oxidant, and primary antioxidant is hindered phenol or sulphur ester antioxidant；Auxiliary anti-oxidant
It is phosphorite kind antioxidant.
10. a kind of scratch-resistant according to claim 9, resist tacky and permanent anti-static PP composite material, its feature
It is：Described primary antioxidant be 3114,1010 and DSTP in one or more mixing；Auxiliary anti-oxidant is in 618 and 168
One or two.
A kind of 11. scratch-resistants according to claim 1, anti-tacky and permanent anti-static PP composite material, its feature
It is：Described light stabilizer is from one or two the mixture in hindered amine light stabilizer 944 and 770.
12. a kind of scratch-resistant, anti-tacky and permanent anti-static PP composite material the system according to claim 1-11
Preparation Method, it is characterised in that：It is comprised the following steps that：
(1) raw material is weighed by proportioning；
(2) each raw material is placed in super mixer and is mixed 3~5 minutes；
(3) raw material of mixing is placed in dual-screw-stem machine, through melting extrusion, is granulated, its technique is：One 190~200 DEG C of area, two
200~210 DEG C of area, three 200~210 DEG C of areas, four 205~215 DEG C of areas；Screw speed is 100-1000r/min；Entirely extruded
The residence time of journey is 1~2 minute, and pressure is 12~18MPa, and purging vacuum degree reaches 5~20kPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611217035.6A CN106674752A (en) | 2016-12-26 | 2016-12-26 | Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611217035.6A CN106674752A (en) | 2016-12-26 | 2016-12-26 | Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674752A true CN106674752A (en) | 2017-05-17 |
Family
ID=58870516
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611217035.6A Pending CN106674752A (en) | 2016-12-26 | 2016-12-26 | Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674752A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976691A (en) * | 2018-08-03 | 2018-12-11 | 朴蓝聚烯烃科技发展（上海）有限公司 | The vehicle inside decoration PP composite material composition of performance with low cost and scratch-resistant and application |
| CN109796658A (en) * | 2019-01-03 | 2019-05-24 | 福建师范大学 | A kind of high intensity isolation structure UHMWPE/PP/ superconduction Carbon Black Conductive Composite and preparation method thereof |
| CN110724340A (en) * | 2019-09-26 | 2020-01-24 | 万华化学（宁波）有限公司 | Permanent antistatic polypropylene composite material and preparation method thereof |
| WO2021129115A1 (en) * | 2019-12-23 | 2021-07-01 | 金发科技股份有限公司 | Polypropylene composite material and preparation method therefor |
| CN113754955A (en) * | 2021-08-27 | 2021-12-07 | 滁州杰事杰新材料有限公司 | High-elongation-at-break and scratch-resistant polypropylene composite material and preparation method thereof |
-
2016
- 2016-12-26 CN CN201611217035.6A patent/CN106674752A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| I.MIRONI-HARPAZ ETAL: "Electrical Behavior and Structure of Polypropylene/Ultrahigh Molecular Weight Polyethylene/Carbon Black Immiscible Blends", 《JOURNAL OF APPLIED POLYMER SCIENCE》 * |
| 陈华辉主编: "《耐磨材料应用手册（第2版）》", 31 October 2012, 机械工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976691A (en) * | 2018-08-03 | 2018-12-11 | 朴蓝聚烯烃科技发展（上海）有限公司 | The vehicle inside decoration PP composite material composition of performance with low cost and scratch-resistant and application |
| CN109796658A (en) * | 2019-01-03 | 2019-05-24 | 福建师范大学 | A kind of high intensity isolation structure UHMWPE/PP/ superconduction Carbon Black Conductive Composite and preparation method thereof |
| CN110724340A (en) * | 2019-09-26 | 2020-01-24 | 万华化学（宁波）有限公司 | Permanent antistatic polypropylene composite material and preparation method thereof |
| CN110724340B (en) * | 2019-09-26 | 2022-04-22 | 万华化学（宁波）有限公司 | Permanent antistatic polypropylene composite material and preparation method thereof |
| WO2021129115A1 (en) * | 2019-12-23 | 2021-07-01 | 金发科技股份有限公司 | Polypropylene composite material and preparation method therefor |
| CN113754955A (en) * | 2021-08-27 | 2021-12-07 | 滁州杰事杰新材料有限公司 | High-elongation-at-break and scratch-resistant polypropylene composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106674752A (en) | Scratching-resisting, anti-sticky and permanent antistatic polypropylene composite material and preparation method thereof | |
| CN101173074B (en) | Polypropelene composition with scratch resistant capability and processes for producing same | |
| CN102504407B (en) | Polypropylene composition for solar battery and preparation method thereof | |
| CN103214740B (en) | Polypropylene composite material for automobile internal ornament, preparation method thereof and internal ornament | |
| CN105602103A (en) | Graphene-containing antistatic polypropylene material and preparation method thereof | |
| CN101759917A (en) | Antistatic polypropylene composite material and method for preparing same | |
| CN104558834A (en) | Injection molding-grade high-performance polypropylene composite material with good appearance and preparation method of injection molding-grade high-performance polypropylene composite material | |
| CN102532774B (en) | A kind of low-luster polypropylene composite material and preparation method thereof | |
| CN105504498B (en) | A kind of injection grade polypropylene microporous foam composite material and preparation method thereof | |
| CN106751004A (en) | A kind of easy processing efficient anti-static PP composite material and preparation method thereof | |
| WO2022052408A1 (en) | Carbon nanotube master batch, and preparation method therefor and application thereof | |
| CN103042796B (en) | Antistatic polyethylene film and preparation method thereof | |
| CN111087690B (en) | Flame-retardant polypropylene composite material with electromagnetic shielding effect and scratch resistance and preparation method thereof | |
| CN102585359B (en) | Modified polypropylene composition for solar cell back panel and preparation method thereof | |
| CN110408120B (en) | Antistatic spraying-free polypropylene composite material with low linear thermal expansion coefficient and preparation method thereof | |
| CN101759918A (en) | Conductive polypropylene composite material and preparation method thereof | |
| CN105385088B (en) | A kind of polypropene composition and preparation method thereof | |
| CN108102223A (en) | A kind of low coefficient of linear thermal expansion, imitative flocking effect PP composite material and preparation method thereof | |
| CN104558856A (en) | Creep-resistant low-temperature-impact-resistant polypropylene composition and preparation method thereof | |
| CN104558836A (en) | Scratching-resistant polypropylene composite material capable of resisting stress whitening and preparation method thereof | |
| CN105820494A (en) | Antistatic spraying-free polypropylene composite material and preparation method thereof | |
| CN105504528A (en) | Polypropylene composite material capable of realizing light weight and with low linear expansion coefficient and preparation method thereof | |
| CN104558837A (en) | Scratching-resistant low-gloss polypropylene composite material and preparation method thereof | |
| CN101759921B (en) | Novel antistatic polypropylene material and preparation method thereof | |
| CN102532696A (en) | Polypropylene composition with high surface tension and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170517 |