CN106673176B - A kind of Y type gas-liquid mixed reactor - Google Patents
A kind of Y type gas-liquid mixed reactor Download PDFInfo
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- CN106673176B CN106673176B CN201611266907.8A CN201611266907A CN106673176B CN 106673176 B CN106673176 B CN 106673176B CN 201611266907 A CN201611266907 A CN 201611266907A CN 106673176 B CN106673176 B CN 106673176B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/12—Interdigital mixers, i.e. the substances to be mixed are divided in sub-streams which are rearranged in an interdigital or interspersed manner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/305—Treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to a kind of Y type gas-liquid mixed reactors, belong to water treatment facilities studying technological domain, it is in reaction supervisor outlet end concatenation n order reaction branch pipe group, form multiple branches, effectively prevent the merging of bubble, the mixing of speed up gas and liquid, accelerate bubble to the degradation of water pollutant and repairs ability again, the structure of each order reaction branch pipe and arrangement are subjected to rational deployment, pipe structure is comprehensively considered with angle, it greatly promotes gas-liquid mixed efficiency, improve reactor for treatment effect, greatly shorten the processing time.
Description
Technical field
The invention belongs to water treatment facilities studying technological domain, in particular to a kind of gas-liquid mixed reactor, more particularly to
A kind of Y type gas-liquid mixed reactor of micro air bubble processing organic pollutant.
Technical background
With making rapid progress for scientific technological advance, water pollution problems is increasingly severe, how to have solved water pollution problems
Become a focus of society and country's concern.It is shown according to China's water investigation in 2014: national ten big Drainage Water Qualities one
Half pollutes;Emphasis lake water quality 4 is controlled into pollution in state;31 large-scale water quality 17 pollutions of freshwater lake;In 9 important bays, the Liao Dynasty
It is big-and-middle to 118 that Dong Wan, Bohai Sea Gulf and Jiaozhou Bay's water quality inferiority, entrance of Changjiang River, Hangzhou Wan, Minjiang Estuary and the mouth of the Zhujiang River water quality are very poor ...
The water body that city is investigated shows that serious pollution accounts for 40%, and the bad V class of surface water (losing the water for using function) section ratio reaches
30% or more, contaminated underground water accounts for one third in national 4778 groundwater monitoring points, about sixty percent water quality it is poor and
It is very poor.Have 33% in 6834 Water Functional Zones that national main river,lake and reservior delimited according to " national comprehensive planning of water resources "
Water Functional Zone COD or ammonia nitrogen status pollutant enter river amount be more than its pollutant carrying capacity, and be its pollutant carrying capacity 4-5
Times, partial rivers (section) are even as high as 13 times.It is investigated according to the United Nations, China is one of 13 poor-water states in the world, currently, entirely
State year nearly 6200 billion cubic meter of water total amount, more than 500 billion cubic meters of normal year water shortage, with socio-economic development and global gas
Waiting variation influences aggravation, and the contradiction of supply and demand for the water resource will be more sharp, and on the one hand many water resources can not recycle, and aggravate water money
The deficient degree in source, the sustainable use of another aspect environment and economic sustainable development are seriously affected, and therefore, solve water
The harm of environmental pollution is of great practical significance with prevention and treatment.
Ozone is as a kind of high-level oxidation technology, and since it has extremely strong oxidisability, it is single former to decompose generation in water
The extremely strong substance of the oxidabilities such as sub- oxygen and hydroxyl can aoxidize gas chromatography and inorganic matter, thus obtain in water process
It is widely applied.But ozone is that there is the size of bubble diameter also affects the place of ozone in the form of bubble in water body
Manage effect.Since the eighties in last century, the researcher of countries in the world all attempts the smaller bubble application of diameter and water
Body reparation, the contact area that can be considerably increased with water because the diameter of bubble becomes smaller, while bubble surface energy, liquid-vapor interface
Upper gas molecule proportion, bubble service life all can significantly increase, various reaction speeds are also increase accordingly, gas transfer
Rate greatly improves.Then various microbubble generators come into being, and common is that Venturi tube or turbine generate gas-liquid mixed,
Moment has produced a large amount of micro-bubble, but micro-bubble mutually collides merging and easily becomes air pocket, affects bubble
Treatment effect, in order to solve this problem, the present invention design a kind of new reactor, and the merging of bubble can be effectively reduced, and accelerate
Bubble is to the degradation of water pollutant and repairs ability again.
Summary of the invention
Air pocket, this hair are formed in order to overcome the problems, such as that microbubble present in existing microbubble generator is easy to merge
Bright to provide a kind of merging that can effectively prevent bubble, the mixing of speed up gas and liquid improves degradation and the remediation efficiency of water pollution,
And the Y type gas-liquid mixed reactor of processing time can be shortened.
The technical scheme adopted by the invention is that: this kind of Y type gas-liquid mixed reactor includes reaction supervisor 1 and is serially connected in
The n order reaction branch pipe group of 1 outlet end of reaction supervisor, n=1,2,3;Every first order reaction branch pipe group includes 2~4 be set side by side
In the reaction branch pipe that diffused is distributed, n-th grade of reaction branch pipe central axis is formed between branch pipe central axis with (n-1)th grade react
5~10 ° of angle, n-th grade of reaction branch pipe cross section S meet with (n+1)th grade of the branch pipe cross section s that reacts: S=9~12s.
It further limits, plane where described n-th grade of reaction branch pipe reacts branch pipe place plane same with (n+1)th grade
In one plane.
It further limits, plane where described n-th grade of reaction branch pipe reacts branch pipe place plane distribution with (n+1)th grade
In the plane that two intersect and angle is less than 90 °.
It further limits, the reaction branch pipe that the first order reaction branch pipe group of least significant end is arranged in is distributed in diffused, and anti-
The central axis of branch pipe is answered to intersect at any point of the central axis of reaction supervisor 1.
Further preferably, each reaction branch tube cavity is set in the first order reaction branch pipe group of least significant end apart from water outlet 40
The position of~50mm is provided with perforated plate 5, and the porosity of perforated plate 5 is 5~8%.
Further preferably, full between the cross section s of the order reaction branch pipe of the cross section S and (n+1)th of n-th grade of reaction branch pipe
Foot: S=10.5s.
It further limiting, the reaction branch pipe is round tube, and the caliber D of n-th grade of reaction branch pipe and (n+1)th grade
It reacts and meets D:d=3~3.46 between the caliber d of branch pipe.
It further limits, the reaction branch pipe is oval pipe, and the major cross-sectional axis A of n-th grade of reaction branch pipe, section
Meet between short axle B and (n+1)th grade of the major cross-sectional axis a for reacting branch pipe, cross-section minor axis b: A=3a;B=4b.
It further limits, the reaction branch pipe is square tube, n-th grade of the reaction side length of branch pipe and (n+1)th grade react
Meet between the side length of branch pipe:
Y type gas-liquid mixed reactor provided by the invention, by the way that reaction of high order branch pipe is arranged in the outlet end of reaction supervisor,
Multiple branches are formed, change gas-liquid flow direction in pipe, the mixing of energy speed up gas and liquid effectively prevents bubble from merging, accelerates bubble pair
The degradation of water pollutant and ability is repaired again, the structure of each order reaction branch pipe and arrangement are furthermore subjected to rational deployment, will be managed
Structure comprehensively considers with angle, greatly promotes gas-liquid mixed efficiency, improves reactor for treatment effect, greatly shortens the processing time.
Detailed description of the invention
Fig. 1 is n=2 and reacts the structural schematic diagram of Y type gas-liquid mixed reactor when branch pipe is 2.
Fig. 2 is the front view of Fig. 1.
Fig. 3 is the sectional view that reaction branch pipe in Fig. 1 is round tube.
Fig. 4 is the scheme of installation of Fig. 1 middle punch plate 5.
Fig. 5 is n=2 and reacts the structural schematic diagram of Y type gas-liquid mixed reactor when branch pipe is 4.
Fig. 6 is the A-A schematic cross-sectional view of Fig. 5.
The structural schematic diagram of Y type gas-liquid mixed reactor when Fig. 7 is n=2 and reacts branch pipe mal-distribution.
Fig. 8 is the top view of Fig. 7.
Fig. 9 is Y type gas-liquid when n=2 and second order reaction branch pipe are distributed in two planes intersected with first order reaction branch pipe
The structural schematic diagram of mixing reactor.
Figure 10 is the top view of Fig. 9.
Figure 11 is the sectional view of oval shaped reaction branch pipe.
Figure 12 is the sectional view of rectangular reaction branch pipe.
Y type gas-liquid mixed structure of reactor schematic diagram when Figure 13 is n=3.
Specific embodiment
Technical solution of the present invention is described in detail now in conjunction with drawings and examples.
By Fig. 1~13 it is found that Y type gas-liquid mixed reactor of the invention is to include 1, first order reaction branch pipe group of reaction supervisor
2 and second order reaction branch pipe group 3.The diameter of reaction supervisor 1 is 40mm, length 60mm, arrival end respectively with intake pump and defeated
Air pump connection mixes gas and liquid in reaction supervisor 1, first order reaction branch pipe group 2, level-one is delivered under gas-liquid pressure
Reaction branch pipe group 2 includes 2~4 reaction branch pipes for being connected to 1 outlet end of reaction supervisor side by side.
Fig. 1, in 2, it is connected with 2 reaction branch pipes, i.e. first order reaction branch pipe group side by side on the exit end face of reaction supervisor 1
2 include the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2, and the first first order reaction branch pipe 2-1 and the second level-one are anti-
It answers branch pipe 2-2 to pass through adapter respectively to be connected to supervisor 1 is reacted.First first order reaction branch pipe 2-1 and the second first order reaction branch pipe
2-2 is round tube, and referring to Fig. 3, it is 1 with the ratio between cross section of supervisor 1 is reacted that diameter, which is 13.3mm, pipe range 60mm:
9, the sectional area s of first order reaction branch pipe are responsible for 1 cross section less than 1/9 reaction, to compensate pressure loss during Liquid Flow
Brought influence.The central axis of first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 with react supervisor 1
Form 5 ° of angle between central axis, and the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 can be about
The distribution substantially symmetrical about its central axis of reaction supervisor 1, can also be with mal-distribution, i.e. the first first order reaction branch pipe 2-1 and the second level-one is anti-
It answers the angle between the central axis of branch pipe 2-2 and the central axis of reaction supervisor 1 can be different, is adjusted in the range of 5~10 °,
Because angle is excessive, hydraulic losses are too big, arrive hydraulic pressure deficiency in next order reaction branch pipe, will affect gas-liquid mixed and cavitation effect
Fruit.Second order reaction branch pipe group is connected separately in the outlet end of the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2
3, second order reaction branch pipe group 3 includes the first second order reaction branch pipe 3-1, the second second order reaction branch pipe 3-2, third second order reaction branch pipe
3-3 and the 4th second order reaction branch pipe 3-4 is connected with first by adapter in the outlet end of the first first order reaction branch pipe 2-1
Second order reaction branch pipe 3-1 and the second second order reaction branch pipe 3-2, in the outlet end of the second first order reaction branch pipe 2-2 also by switching
Head is connected with third second order reaction branch pipe 3-3 and the 4th second order reaction branch pipe 3-4.First second order reaction branch pipe 3-1 and the two or two
Plane where order reaction branch pipe 3-2 and the plane where the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 are same
One plane, the first second order reaction branch pipe 3-1 and the second second order reaction branch pipe 3-2 are round tube, and pipe range 60mm is managed interior straight
Diameter is 4.16mm, and the condition of D:d=3~3.46, cross section s are met with the diameter ratio of first order reaction branch pipecIt is anti-with level-one
Answer the cross section S of branch pipecThe ratio between be Sc=10.22sc, can also float in the range of 9~12 times, in order to compensate for pipeline internal pressure
Power loss, guarantee gas-liquid mixed effect simultaneously effectively prevent microbubble to merge during output, second order reaction branch pipe group 3 it is transversal
Face increases as Fluid pressure is lost and reduces step by step.Further for the cavitation effect for improving second order reaction branch pipe group 3, generate
A large amount of microbubbles, the position in pipe apart from outlet end 50mm are equipped with perforated plate 5, as shown in figure 4, the aperture of perforated plate 5 is
1mm, porosity 6%, porosity be according to afterbody react branch pipe hydraulic pressure and cross section size and comprehensively consider, can
To be adjusted in 5%~8% range.Plane and first where third second order reaction branch pipe 3-3 and the 4th second order reaction branch pipe 3-4
Plane where first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 is led in same plane, i.e. second order reaction branch pipe in reaction
The central axis two sides asymmetric distribution of pipe 1.Third second order reaction branch pipe 3-3 and the 4th second order reaction branch pipe 3-4 is round tube,
Its diameter is 4.16mm, pipe range 60mm, cross section sDWith the cross section S of first order reaction branch pipeDBetween meet: SD=
10.22sD, the position in pipe apart from outlet end 50mm is equipped with perforated plate 5, and the aperture of perforated plate 5 is 1mm, and porosity is
7%, make to generate a large amount of microbubbles, and the outlet end dispersed distribution of second order reaction pipe in the outlet end of second order reaction pipe, wherein
Mandrel intersects on the central axis of reaction supervisor 1, guarantees water discharging direction dispersion.
Fig. 5, in 6, it is connected with 4 first order reaction branch pipe groups 2 side by side on the exit end face of reaction supervisor 1, that is, is respectively
First first order reaction branch pipe 2-1, the second first order reaction branch pipe 2-2, third first order reaction branch pipe 2-3 and the 4th first order reaction branch
Pipe 2-4, the first first order reaction branch pipe 2-1, the second first order reaction branch pipe 2-2, third first order reaction branch pipe 2-3 and the 4th level-one
It reacts branch pipe 2-4 uniformly and in diffused to be distributed on the exit end face of reaction supervisor 1, and the first first order reaction branch pipe 2-1, the
The central axis of two first order reaction branch pipe 2-2, third first order reaction branch pipe 2-3 and the 4th first order reaction branch pipe 2-4 with react master
Angle between the central axis of pipe 1 is 10 °.In the first first order reaction branch pipe 2-1, the second first order reaction branch pipe 2-2, third level-one
It reacts and is connected separately with 4 second order reaction branch pipe groups 3 on the exit end face of branch pipe 2-3 and the 4th first order reaction branch pipe 2-4,
Each second order reaction branch pipe group 3 includes 4 second order reaction branch pipes, each second order reaction branch pipe central axis and corresponding first order reaction
Angle between branch pipe central axis is 8 °, and 4 second order reaction branch pipes are distributed in outside diffused, guarantees second order reaction branch pipe group 3
Water discharging direction it is different, outside radial pattern.
In addition, the first order reaction branch pipe place plane and second order reaction branch pipe place plane in above-described embodiment can be together
One plane, as shown in Fig. 2, be also possible to cross one another two planes, when being distributed in two planes of intersection, two planes it
Between angle be no more than 90 °.
Illustrate for shown in Fig. 7 and 8, the first first order reaction branch pipe 2-1 and the second place first order reaction branch pipe 2-2 plane
It is same plane with the plane where the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2.Third second order reaction branch
Plane and the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 where pipe 3-3 and the 4th second order reaction branch pipe 3-4
Place level-crossing, and the angle of two plane of place is 30 °, i.e., second order reaction branch pipe is non-in the central axis two sides of reaction supervisor 1
It is symmetrical.
Further illustrate for shown in Fig. 9,10, the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2 institute
Plane where plane, third second order reaction branch pipe 3-3 and the 4th second order reaction branch pipe 3-4 with the first first order reaction branch pipe 2-
1 and the second level-crossing where first order reaction branch pipe 2-2, and the angle of two plane of place is 45 °, i.e. second order reaction branch pipe exists
The central axis two sides of reaction supervisor 1 are symmetrical.
The pipe structure of first order reaction branch pipe group 2 and second order reaction branch pipe group 3 in above-described embodiment can also be ellipse
Pipe or rectangular tube, as shown in FIG. 11 and 12, it is preferable that when first order reaction branch pipe and second order reaction branch pipe are oval pipe structure
When, major cross-sectional axis a, the cross-section minor axis b of each second order reaction branch pipe and the major cross-sectional axis A of each first order reaction branch pipe, section are short
Meet between axis B: A=3a, B=4b.When first order reaction branch pipe and second order reaction branch pipe are rhs-structure, each second level is anti-
Answer the side length y of branch pipen+1With the side length y of each first order reaction branch pipenBetween meet:
As shown in figure 13, the outlet end of the second order reaction branch pipe of above-described embodiment can also add third-order reaction by adapter
Branch pipe 4 is separately connected 2 identical three in the outlet end of the first first order reaction branch pipe 2-1 and the second first order reaction branch pipe 2-2
Order reaction branch pipe 4-1,4-2 also connect respectively in the outlet end of third second order reaction branch pipe 3-3 and the 4th second order reaction branch pipe 3-4
Meet 2 identical third-order reaction branch 4-3,4-4.4 place plane of third-order reaction branch pipe and 3 place plane of second order reaction branch pipe are handed over
Fork, 4 place plane of third-order reaction branch pipe and 2 place plane of first order reaction branch pipe are in same plane.Second order reaction pipe 3 it is transversal
Face is 2.5 times of the cross section of third-order reaction pipe 4, can also be floated in the range of 2.2~2.6 times, the pipe of second order reaction pipe 3
Length is 1.5 times of the pipe range of third-order reaction pipe 4, can be floated in the range of 1~1.5 times.Ibid, in each third-order reaction branch
Perforated plate 5 is installed at position in pipe 4 apart from outlet end 50mm.
The structure of the Y type gas-liquid mixed reactor of above-described embodiment is also possible to only connect in the outlet end of reaction supervisor 1
Level-one branch pipe group 2, level-one branch pipe group 2 includes 2~3 level-one branch pipes, and level-one branch pipe is uniform on the section of reaction supervisor 1
Distribution, but this kind of structure is suitable for handling the relatively fewer situation of water.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, for each order reaction branch
The pipe range and pipe diameter size of pipe then can be with appropriate adjustments, for reacting the grade of branch pipe in the zone of reasonableness for following above-mentioned offer
It is several then to be determined according to installation environment and for processing water size, all within the spirits and principles of the present invention, made
What modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of Y type gas-liquid mixed reactor, it is characterised in that including reaction supervisor (1) and be serially connected in reaction supervisor (1) out
The n order reaction branch pipe group at mouth end, n=2,3;Every first order reaction branch pipe group includes that 2~4 be set side by side are distributed in diffused
React branch pipe, n-th grade of reaction branch pipe central axis and (n-1)th grade of the angle for reacting between branch pipe central axis 5~10 ° of formation,
N-th grade of reaction branch pipe cross section S meets with (n+1)th grade of the branch pipe cross section s that reacts: S=9~12s;Described n-th grade anti-
Plane where branch pipe is answered to react branch pipe place plane in the same plane with (n+1)th grade.
2. Y type gas-liquid mixed reactor according to claim 1, it is characterised in that: the first order reaction of least significant end is arranged in
The reaction branch pipe of branch pipe group is distributed in diffused, and the central axis for reacting branch pipe intersects at the central axis of reaction supervisor (1)
Any point.
3. Y type gas-liquid mixed reactor according to claim 2, it is characterised in that: the first order reaction of least significant end is arranged in
Position of each reaction branch tube cavity apart from 40~50mm of water outlet is provided with perforated plate (5) in branch pipe group, the hole of perforated plate (5)
Gap rate is 5~8%.
4. described in any item Y type gas-liquid mixed reactors according to claim 1~3, it is characterised in that: n-th grade of reaction branch
Meet between the cross section s of the order reaction branch pipe of the cross section S and (n+1)th of pipe: S=10.22s.
5. Y type gas-liquid mixed reactor according to claim 4, it is characterised in that: the reaction branch pipe is round tube,
And meet D:d=3~3.46 between n-th grade of the caliber D of reaction branch pipe and (n+1)th grade of the caliber d for reacting branch pipe.
6. Y type gas-liquid mixed reactor according to claim 4, it is characterised in that: the reaction branch pipe is ellipse
Pipe, and the major cross-sectional axis a that reacts branch pipe of major cross-sectional axis A, the cross-section minor axis B of n-th grade of reaction branch pipe with (n+1)th grade, section
Meet between short axle b: A=3a;B=4b.
7. Y type gas-liquid mixed reactor according to claim 4, it is characterised in that: the reaction branch pipe is square tube, the
The side length y of n grades of reaction branch pipenWith (n+1)th grade of the side length y for reacting branch pipen+1Between meet:
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CN112439318A (en) * | 2019-09-05 | 2021-03-05 | 大连海事大学 | High-efficient SOx/NOx control integration system of low temperature tail gas |
CN111359539B (en) * | 2020-02-17 | 2022-03-18 | 华东理工大学 | Gas-liquid reaction method and gas-liquid reaction device capable of entering reaction preparation state in advance |
CN113041871A (en) * | 2021-04-22 | 2021-06-29 | 昆明有色冶金设计研究院股份公司 | Stirring-free multiphase mixing and distributing device |
CN113750926B (en) * | 2021-09-18 | 2023-01-10 | 浙江工业大学 | Reaction unit suitable for strong exothermic system |
CN219615297U (en) * | 2022-12-09 | 2023-09-01 | 刘伟 | Gas-liquid mixing pipe, downpipe, drainage system and filter box |
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CN102531146A (en) * | 2011-11-23 | 2012-07-04 | 深圳市宇力科技有限公司 | Device for degrading waste water organic matters by combined type hydraulic power cavitation |
CN103920402A (en) * | 2014-04-28 | 2014-07-16 | 郑州家元环保科技有限公司 | Gain-type slow-release throttling micro nano bubble generator |
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CN102531146A (en) * | 2011-11-23 | 2012-07-04 | 深圳市宇力科技有限公司 | Device for degrading waste water organic matters by combined type hydraulic power cavitation |
CN103920402A (en) * | 2014-04-28 | 2014-07-16 | 郑州家元环保科技有限公司 | Gain-type slow-release throttling micro nano bubble generator |
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