CN106669957A - Flotation technology for fine-grain middling coal - Google Patents

Flotation technology for fine-grain middling coal Download PDF

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Publication number
CN106669957A
CN106669957A CN201610446935.1A CN201610446935A CN106669957A CN 106669957 A CN106669957 A CN 106669957A CN 201610446935 A CN201610446935 A CN 201610446935A CN 106669957 A CN106669957 A CN 106669957A
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coal
coarse
particulate
equipment
fine
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CN106669957B (en
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桂夏辉
曹亦俊
邢耀文
李臣威
杨自立
王东岳
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China University of Mining and Technology CUMT
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China University of Mining and Technology CUMT
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B1/00Conditioning for facilitating separation by altering physical properties of the matter to be treated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B5/00Washing granular, powdered or lumpy materials; Wet separating
    • B03B5/48Washing granular, powdered or lumpy materials; Wet separating by mechanical classifiers
    • B03B5/52Spiral classifiers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/005General arrangement of separating plant, e.g. flow sheets specially adapted for coal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/01Organic compounds containing nitrogen

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Abstract

The invention relates to a flotation technology for fine-grain middling coal. The technology comprises the following steps: carrying out pulp mixing operation on the fine-grain middling coal; using coarse slime sorting equipment to carry out previous tailing discarding operation; using classifying equipment to carry out classification, and producing fine-grain coarse clean coal and coarse-grain coarse clean coal; using coal grinding equipment to dissociate the coarse-grain coarse clean coal; using pulp mixing equipment to carry out flotation operation on the fine-grain coarse clean coal; using rougher flotation equipment to carry out rougher flotation on ore pulp which is obtained after pulp mixing is carried out on the fine-grain coarse clean coal and producing rougher flotation clean coal; and using concentration equipment to carry out concentration on the rougher flotation clean coal and producing clean coal. The flotation technology provided by the invention is simple in process, mature in technology, low in investment, low in running fees and remarkable in economical benefit. The flotation technology not only ensures the ash content of tailings, but also ensures that materials with middle ash content and low ash content are fully dissociated. Gangue is prevented from entering a mill, so that the load of the mill is greatly reduced. Energy consumption is reduced, and the recycling rate of the tailings and the clean coal is increased.

Description

The floatation process of coal in a kind of particulate
Technical field
The present invention relates to the floatation process technical field of coal, more particularly in a kind of particulate coal floatation process.
Background technology
The present invention is that, based on the broken practical technique selected again of coal in coking particulate, main purpose is to reclaim rare coking coal Resource.
Rich coal resources in China, coal is complete, but each coal reserves differ greatly, and wherein coking coal resource reserves are not To 1/3rd of gross reserves.Coal average yield is more than 30% in the coking of production every year of the Oversized Coking Coal Cleaning Plant of China, this Coal does not reach the requirement of coking and uses often as thermal coal in the coking of part, and the irrational utilization of resource result in great wave Take, therefore study coal dissociation in coking and select have great importance again.
Middle coal source has two kinds, and one is, because sharpness of separation is not high, to be formed by mispairing;Two is low ash extract coal and inorganic ore deposit Often with superfine granularity mutually embedding cloth, coal selects again needs through further dissociation to thing component in this part.Domestic is many special Family scholar selects again from the angle centering coal for improving sharpness of separation or dissociation and has carried out many beneficial explorations.Lv Yuting etc. is to high Moral coal preparation plant individually sorts coal in jigging when transforming using a jigging machine, and final clean coal yield increased 6.76 percentage points, Per year 1500000 tons of meters of feed coal, at least can increase benefit 20,000,000 yuan every year;Liu Junling etc. uses one section of two product dense medium eddy flow Device to sort jigging in coal, make final clean coal yield improve 5.39%, increase profit more than 10,000,000 yuan.Zhao Wenda et al. is right Coal has carried out dissociation and has selected experimental study again in Wuhai coal preparation plant dense medium, and the 3-0.5mm grades in crushed product are entered using TBS Go sorting, obtain the cleaned coal that yield is 60%.But the middle coal thinner for disseminated grain size, conventional cracking and sorting is usually Satisfied separation results cannot be obtained, this apoplexy due to endogenous wind coal generally requires coal-grinding and just can guarantee that a certain degree of solution to thinner granularity From after such as Zhang Lei crushes to coal in the dense medium of head of the horse coal preparation plant, the big cone angle cyclone of 3-0.5mm grades Jing sorts clean coal yield Only 4.22%, therefore again recovery of the selecting technology to coking coal resource is significant to develop coal in new particulate, it is following for dynamic Power coal may carry out select again for middle coal and also have certain reference.
The content of the invention
In view of above-mentioned analysis, the present invention is intended to provide in a kind of particulate coal floatation process, to overcome therefrom coal in The deficiency of the conventional art of low ash extract coal is reclaimed, fundamentally solving existing rare coking coal resource cannot recycling Problem.
The purpose of the present invention is mainly achieved through the following technical solutions:
A kind of floatation process of coal in particulate, the flow process of the technique is as follows:
S1, carry out operation of sizing mixing, ore pulp after coal is sized mixing in output particulate using coal size mixing equipment in particulate;
S2, coal in particulate is sized mixing using separation of coarse slime equipment after ore pulp thrown tail operation in advance, output sorting is thick Cleaned coal and sorting tail coal, sorting tail coal is used as gangue treatment;
S3, carry out graded operation, the coarse-fine coal of output particulate and the coarse-fine coal of coarse grain to sorting coarse-fine coal using classifying equipoment;
S41, dissociation operation is carried out to the coarse-fine coal of coarse grain using coal-grinding equipment, product and recycled after output mill;
S42, the coarse-fine coal of particulate is mixed with floating agent, operation of sizing mixing is carried out to mixture using size mixing equipment, The coarse-fine coal of output particulate size mixing after ore pulp;
S5, the coarse-fine coal of particulate is sized mixing using roughing separation equipment after ore pulp carry out roughly selecting operation, output is roughly selected cleaned coal and is roughly selected Tail coal;
S6, carry out selected operation, output cleaned coal and selected tail coal to roughly selecting cleaned coal using picking equipment.
The cleaned coal for needing further process that coarse-fine coal is that sorting is obtained is sorted, sorting tail coal is used directly as spoil, Not think to possess and further process the value that cleaned coal is obtained.The coarse-fine coal of particulate is the less coarse-fine coal of particle diameter obtained after classification, Because its particle diameter is less, thus flotation operation can be directly carried out;The coarse-fine coal of coarse grain is larger thick of the particle diameter that obtains after classification Cleaned coal, because its particle diameter is larger, should not directly carry out that more spoil may be contained in flotation operation, and granule, so that Further crushed so as to become the less granule of particle diameter, repeated graded operation, removed the impurity such as spoil therein, into For the coarse-fine coal of particulate, carry out it is further selected.
The raw material of floating agent and by total weight percent proportioning be following one of which:
N-octyl alcohol 23%-33%, kerosene 62%-72%, alkylphenol polyoxyethylene 1%-2%, methyl isobutyl carbinol 1%-2%, dimethylbenzene 1%-2%;
N-butyl alcohol 27%-37%, kerosene 58%-68%, alkylphenol polyoxyethylene 1%-2%, methyl isobutyl carbinol 1%-2%, glycol polypropylene 1%-2%;
α-terpinol 30%-40%, Paraffin liquid heavy 55%-65%, alkylphenol polyoxyethylene 1%-2%, silicic acid Sodium 1%-2%, glycol polypropylene 1%-2%.
Alkylphenol polyoxyethylene be ethers suds booster, methyl isobutyl carbinol, glycol polypropylene, glycol polypropylene For hydroxy compound species suds booster, sodium silicate is silicate regulator.
Preferably, the raw material of floating agent and by total weight percent proportioning it is:N-octyl alcohol 26%, kerosene 70%, alkyl Phenol polyethenoxy ether 1.2%, methyl isobutyl carbinol 1.3%, dimethylbenzene 1.5%.
Preferably, the raw material of floating agent and by total weight percent proportioning it is:N-butyl alcohol 31%, kerosene 65%, alkyl Phenol polyethenoxy ether 1.6%, methyl isobutyl carbinol 1.1%, glycol polypropylene 1.3%.
Preferably, the raw material of floating agent and by total weight percent proportioning it is:α-terpinol 36%, Paraffin liquid heavy 59%th, alkylphenol polyoxyethylene 1.8%, sodium silicate 1.7%, glycol polypropylene 1.5%.
Paraffin liquid heavy is industrial products, and main component is that carbon atom number is more than or equal to 12 and is less than or equal in molecule 18 n-alkane and aromatic hydrocarbon.
Coal-grinding equipment is short body rod mill or short body autogenous tumbling mill.
It is as follows to the recycling mode of product after mill:
After mill product meet simultaneously density level less than 1.6kg/L, yield less than 10%, ash be less than 70% when, be back to Flow process S3, using classifying equipoment graded operation is carried out to product after mill, and is sequentially completed flow process S41, S42, S5, S6;Otherwise, return Be back to flow process S2, using separation of coarse slime equipment Throwing tail operations carried out to product after mill, and be sequentially completed flow process S3, S41, S42, S5、S6。
Tail coal will be roughly selected to mix with selected tail coal, output tail coal.
Coal size mixing equipment is agitator in particulate;Agitator uses BGT series surface modification pulp mixing machines;
Separation of coarse slime equipment is spiral;Spiral uses high weir spiral classifier or sinking spiral Grader;
Size mixing equipment is action of forced stirring device;
Roughing separation equipment is flotation device;
Picking equipment is flotation column;
Classifying equipoment is vibration sieve bend.
The slot size of vibration sieve bend is 0.5-1mm, to ensure siftage granularity in the range of suitable flotation;
The present invention has the beneficial effect that:
1st, the present invention proposes the floatation process of coal in a kind of flotation that dissociation is crushed based on middle coal, realizes to rare refining The efficient recovery of coking coal resource.
2nd, spiral separating density is higher, can throw in advance under its optimal separating density except the broken dissociation of a part of Jing The high ash material for going out, both ensure that tail coal ash, and while avoiding spoil enters grinding machine, significantly reduce the negative of grinding machine Lotus, reduces energy consumption, alleviates the pollution to follow-up flotation operation after high ash material grinds.
3rd, the quick pan feeding of short body grinding machine, quick discharge, in both ensure that, low-ash material fully dissociated, and not It is unfavorable for the overground phenomenon of follow-up flotation operation as generation.
4th, the action of forced stirring device of flotation operation can be fully dispersed by medicament, raising pharmacy effect effect, and due to Scrubbing action of the high shear to coal particle surface, thin mud cover lid effect mitigates significantly.
5th, floating agent is mixed with by various medicaments, and the foaming effect of confection is substantially due to being used alone a kind of medicine Effect of the agent as floating agent:Under the same terms, using the foam height of confection unit volume far above using independent The foam height of medicament;Under the same terms, the life-span of the foam produced using confection compares what a kind of individually medicament was produced The life-span of foam is longer.
6th, the recovery that operation ensure that low ash particle using flotation device is roughly selected, selected operation guarantees that flotation is selected using flotation column Selecting property.
7th, flotation process proposed by the present invention is simple, technology maturation, small investment, operating cost are low, and economic benefit shows Write.
Other features and advantages of the present invention will be illustrated in the following description, also, the partial change from description Obtain it is clear that or being understood by implementing the present invention.The purpose of the present invention and other advantages can be by the explanations write Specifically noted structure is realizing and obtain in book, claims and accompanying drawing.
Description of the drawings
Fig. 1 is flotation process figure according to the present invention.
Fig. 2 is the equipment schematic diagram of floatation process according to the present invention.
In Fig. 2, coal in 1 particulate, ore pulp after coal is sized mixing in 2 particulates, 3 sorting tail coals, the coarse-fine coal of 4 sortings, 5 coarse grain are coarse-fine Coal, product after 6 mills, the coarse-fine coal of 7 particulates, 8 floating agents, the coarse-fine coal of 9 particulates size mixing after ore pulp, 10 roughly select cleaned coal, 11 cleaned coal, 12 Tail coal, A agitators, B spirals, C vibration sieve bends, the short body rod mills of D, E action of forced stirring devices, F flotation devices, G flotation Post.
Specific embodiment
Below in conjunction with the accompanying drawings specifically describing the preferred embodiments of the present invention, wherein, accompanying drawing constitutes the application part, and It is used to together with embodiments of the present invention explain the principle of the present invention.
Embodiment one
As shown in Fig. 2 the concrete flotation process of the present invention is as follows
S1, by granularity, coal 1 (raw material) feeds agitator A by feed pump (being not drawn in figure) in the particulate of below 3mm Sized mixing, ore pulp 2 after coal is sized mixing in output particulate.
S2, coal in particulate is sized mixing after ore pulp 2 feed spiral B and carry out spiral and throw tail operation, the high ash spoil of output Granule is used as sorting tail coal 3, while output and retaining the coarse-fine coal 4 of sorting;The ash of sorting tail coal 3 can reach 70% or so, make For gangue treatment.
S3, the coarse-fine coal 4 of sorting is fed vibration sieve bend C and carries out graded operation, the slot size of vibration sieve bend is 0.5mm, about between 0.25-1mm, oversize is the coarse-fine coal 5 of coarse grain to partition size, and siftage is the coarse-fine coal 7 of particulate.
S41, the coarse-fine coal 5 of coarse grain is fed short body rod mill D carry out coal-grinding dissociation, product 6 after output mill, by controlling mill The coal time so that product 6 is in below 0.5mm after mill but is unlikely to overground phenomenon.Product meets density level simultaneously after mill When being less than 70% less than 10%, ash less than 1.6kg/L, yield, flow process S3 is back to, product after mill is entered using classifying equipoment Row graded operation, and it is sequentially completed flow process S41, S42, S5, S6;Otherwise, flow process S2 is back to, using separation of coarse slime equipment pair Product carries out Throwing tail operations after mill, and is sequentially completed flow process S3, S41, S42, S5, S6.
S42, the coarse-fine coal 7 of particulate and floating agent 8 are fed into action of forced stirring device E carry out operation of sizing mixing, output particulate is thick Cleaned coal size mixing after ore pulp 9.
S5, the coarse-fine coal of particulate is sized mixing after ore pulp 9 feed flotation device F and carry out roughly selecting operation first, pan feeding pulp density is 80g/L, Jing flotation device F roughly selects output ash roughly selecting cleaned coal 10 and roughly select tail coal for 14-15%.
S6, cleaned coal 10 will be roughly selected feed flotation column G and carry out selected operation, output cleaned coal 11 and selected tail coal, cleaned coal 11 will be most Whole ash is 12.5% or so, and selected tail coal mixes output tail coal 12 with tail coal is roughly selected.
Floating agent use quality percentage ratio:N-octyl alcohol 28%, kerosene 67%, alkylphenol polyoxyethylene 1.9%, methyl Isobutyl carbinol 1.6%, dimethylbenzene 1.5%.
Embodiment two
As shown in Fig. 2 the concrete flotation process of the present invention is as follows
S1, by granularity, coal 1 (raw material) feeds agitator A by feed pump (being not drawn in figure) in the particulate of below 3mm Sized mixing, ore pulp 2 after coal is sized mixing in output particulate.
S2, coal in particulate is sized mixing after ore pulp 2 feed spiral B and carry out spiral and throw tail operation, the high ash spoil of output Granule is used as sorting tail coal 3, while output and retaining the coarse-fine coal 4 of sorting;Sorting tail coal 3 is used as gangue treatment.
S3, the coarse-fine coal 4 of sorting is fed vibration sieve bend C and carries out graded operation, the slot size of vibration sieve bend is 0.7mm, about between 0.25-1mm, oversize is the coarse-fine coal 5 of coarse grain to partition size, and siftage is the coarse-fine coal 7 of particulate.
S41, the coarse-fine coal 5 of coarse grain is fed short body rod mill D carry out coal-grinding dissociation, product 6 after output mill, by controlling mill The coal time so that product 6 is in below 0.5mm after mill but is unlikely to overground phenomenon.Product meets density level simultaneously after mill When being less than 70% less than 10%, ash less than 1.6kg/L, yield, flow process S3 is back to, product after mill is entered using classifying equipoment Row graded operation, and it is sequentially completed flow process S41, S42, S5, S6;Otherwise, flow process S2 is back to, using separation of coarse slime equipment pair Product carries out Throwing tail operations after mill, and is sequentially completed flow process S3, S41, S42, S5, S6.
S42, the coarse-fine coal 7 of particulate and floating agent 8 are fed into action of forced stirring device E carry out operation of sizing mixing, output particulate is thick Cleaned coal size mixing after ore pulp 9.
S5, the coarse-fine coal of particulate is sized mixing after ore pulp 9 feed flotation device F and carry out roughly selecting operation first, pan feeding pulp density is 80g/L, Jing flotation device F roughly selects output ash roughly selecting cleaned coal 10 and roughly select tail coal for 14-15%.
S6, cleaned coal 10 will be roughly selected feed flotation column G and carry out selected operation, output cleaned coal 11 and selected tail coal, cleaned coal 11 will be most Whole ash is 12.5% or so, and selected tail coal mixes output tail coal 12 with tail coal is roughly selected.
Floating agent use quality percentage ratio:N-butyl alcohol 31%, kerosene 65%, alkylphenol polyoxyethylene 1.3%, methyl Isobutyl carbinol 1.1%, glycol polypropylene 1.6%.
Embodiment three
As shown in Fig. 2 the concrete flotation process of the present invention is as follows
S1, by granularity, coal 1 (raw material) feeds agitator A by feed pump (being not drawn in figure) in the particulate of below 3mm Sized mixing, ore pulp 2 after coal is sized mixing in output particulate.
S2, coal in particulate is sized mixing after ore pulp 2 feed spiral B and carry out spiral and throw tail operation, the high ash spoil of output Granule is used as sorting tail coal 3, while output and retaining the coarse-fine coal 4 of sorting;Sorting tail coal 3 is used as gangue treatment.
S3, the coarse-fine coal 4 of sorting is fed vibration sieve bend C and carries out graded operation, the slot size of vibration sieve bend is 1mm, about between 0.25-1mm, oversize is the coarse-fine coal 5 of coarse grain to partition size, and siftage is the coarse-fine coal 7 of particulate.
S41, the coarse-fine coal 5 of coarse grain is fed short body rod mill D carry out coal-grinding dissociation, product 6 after output mill, by controlling mill The coal time so that product 6 is in below 0.5mm after mill but is unlikely to overground phenomenon.Product meets density level simultaneously after mill When being less than 70% less than 10%, ash less than 1.6kg/L, yield, flow process S3 is back to, product after mill is entered using classifying equipoment Row graded operation, and it is sequentially completed flow process S41, S42, S5, S6;Otherwise, flow process S2 is back to, using separation of coarse slime equipment pair Product carries out Throwing tail operations after mill, and is sequentially completed flow process S3, S41, S42, S5, S6.
S42, the coarse-fine coal 7 of particulate and floating agent 8 are fed into action of forced stirring device E carry out operation of sizing mixing, output particulate is thick Cleaned coal size mixing after ore pulp 9.
S5, the coarse-fine coal of particulate is sized mixing after ore pulp 9 feed flotation device F and carry out roughly selecting operation first, pan feeding pulp density is 80g/L, Jing flotation device F roughly selects output ash roughly selecting cleaned coal 10 and roughly select tail coal for 14-15%.
S6, cleaned coal 10 will be roughly selected feed flotation column G and carry out selected operation, output cleaned coal 11 and selected tail coal, cleaned coal 11 will be most Whole ash is 12.5% or so, and selected tail coal mixes output tail coal 12 with tail coal is roughly selected.
Floating agent use quality percentage ratio:α-terpinol 34%, Paraffin liquid heavy 61%, alkylphenol polyoxyethylene 1.4%th, sodium silicate 1.9%, glycol polypropylene 1.7%.
In sum, a kind of floatation process of coal in particulate is embodiments provided, during this selects again work to be based on for skill Coal crushes the floatation process of coal in a kind of flotation of dissociation, realizes the efficient recovery to rare coking coal resource;The flotation work Skill flow process is simple, technology maturation, small investment, operating cost are low, remarkable in economical benefits.Additionally, spiral separating density compared with High (generally in more than 1.6Kg/L), can throw in advance except a part of Jing crushes the high ash for dissociateing under its optimal separating density Material, both ensure that tail coal ash, and while avoiding spoil enters grinding machine, significantly reduce the load of grinding machine, reduce energy Consumption, alleviates the pollution to follow-up flotation operation after high ash material grinds;Short body grinding machine (autogenous tumbling mill or rod mill) is quick Pan feeding, quick discharge, in both ensure that, low-ash material fully dissociated, generation is unlikely to again and is unfavorable for follow-up flotation The overground phenomenon of operation;Bulk flotation medicament not only increases the amount of expansion of floatation process, also increases the life-span of foam;It is floating The action of forced stirring device for being elected to be industry can be fully dispersed by medicament, improves pharmacy effect effect, and because high shear is to coal The scrubbing action on grain surface, thin mud cover lid effect mitigates significantly;The recovery that operation ensure that low ash particle using flotation device is roughly selected, Selected operation guarantees flotation selectivity using flotation column.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, the change or replacement that can be readily occurred in, All should be included within the scope of the present invention.

Claims (10)

1. in a kind of particulate coal floatation process, it is characterised in that the flow process of the technique is as follows:
S1, carry out operation of sizing mixing, ore pulp after coal is sized mixing in output particulate using coal size mixing equipment in particulate;
S2, coal in the particulate is sized mixing using separation of coarse slime equipment after ore pulp thrown tail operation in advance, output sorting is thick Cleaned coal and sorting tail coal, sorting tail coal is used as gangue treatment;
S3, graded operation, the coarse-fine coal of output particulate and the coarse-fine coal of coarse grain are carried out to the coarse-fine coal of the sorting using classifying equipoment;
S41, dissociation operation is carried out to the coarse-fine coal of the coarse grain using coal-grinding equipment, product and recycled after output mill;
S42, the coarse-fine coal of the particulate is mixed with floating agent, operation of sizing mixing is carried out to mixture using size mixing equipment, The coarse-fine coal of output particulate size mixing after ore pulp;
S5, the coarse-fine coal of the particulate is sized mixing using roughing separation equipment after ore pulp carry out roughly selecting operation, output is roughly selected cleaned coal and is roughly selected Tail coal;
S6, selected operation, output cleaned coal and selected tail coal are carried out to the cleaned coal of roughly selecting using picking equipment;
The raw material of the floating agent and by total weight percent proportioning be following one of which:
N-octyl alcohol 23%-33%, kerosene 62%-72%, alkylphenol polyoxyethylene 1%-2%, methyl isobutyl carbinol 1%- 2%th, dimethylbenzene 1%-2%;
N-butyl alcohol 27%-37%, kerosene 58%-68%, alkylphenol polyoxyethylene 1%-2%, methyl isobutyl carbinol 1%- 2%th, glycol polypropylene 1%-2%;
α-terpinol 30%-40%, Paraffin liquid heavy 55%-65%, alkylphenol polyoxyethylene 1%-2%, sodium silicate 1%-2%, glycol polypropylene 1%-2%.
2. in particulate according to claim 1 coal floatation process, it is characterised in that the coal-grinding equipment be short body rod milling Machine or short body autogenous tumbling mill.
3. in particulate according to claim 2 coal floatation process, it is characterised in that to after the mill product recovery profit It is as follows with mode:
After the mill product meet simultaneously density level less than 1.6kg/L, yield less than 10%, ash be less than 70% when, be back to Flow process S3, using classifying equipoment graded operation is carried out to product after mill, and is sequentially completed flow process S41, S42, S5, S6;It is no Then, flow process S2 is back to, Throwing tail operations is carried out to product after mill using separation of coarse slime equipment, and be sequentially completed flow process S3、S41、S42、S5、S6。
4. in particulate according to claim 1 coal floatation process, it is characterised in that by the tail coal of roughly selecting with selected tail Coal mixes, output tail coal.
5. in particulate according to claim 1 coal floatation process, it is characterised in that coal size mixing equipment is in the particulate Agitator;The agitator uses BGT series surface modification pulp mixing machines;
The separation of coarse slime equipment is spiral;The spiral uses high weir spiral classifier or sinking Spiral classifier;
The size mixing equipment is action of forced stirring device;
The roughing separation equipment is flotation device;
The picking equipment is flotation column;
The classifying equipoment is vibration sieve bend.
6. in particulate according to claim 5 coal floatation process, it is characterised in that the sieve aperture of the vibration sieve bend is big It is little for 0.5-1mm, to ensure siftage granularity in the range of suitable flotation.
7. in particulate according to claim 1 coal floatation process, it is characterised in that the raw material of the floating agent and press Total weight percent proportioning is:N-octyl alcohol 26%, kerosene 70%, alkylphenol polyoxyethylene 1.2%, methyl isobutyl carbinol 1.3%th, dimethylbenzene 1.5%.
8. in particulate according to claim 1 coal floatation process, it is characterised in that the raw material of the floating agent and press Total weight percent proportioning is:N-butyl alcohol 31%, kerosene 65%, alkylphenol polyoxyethylene 1.6%, methyl isobutyl carbinol 1.1%th, glycol polypropylene 1.3%.
9. in particulate according to claim 1 coal floatation process, it is characterised in that the raw material of the floating agent and press Total weight percent proportioning is:α-terpinol 36%, Paraffin liquid heavy 59%, alkylphenol polyoxyethylene 1.8%, sodium silicate 1.7%th, glycol polypropylene 1.5%.
10. in the particulate according to claim 1-9 coal floatation process, it is characterised in that the Paraffin liquid heavy is Industrial products, main component is that carbon atom number is more than or equal to 12 and n-alkane and aromatic hydrocarbon less than or equal to 18 in molecule.
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