CN106669627B - A kind of adsorption composite material and preparation method thereof - Google Patents
A kind of adsorption composite material and preparation method thereof Download PDFInfo
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- CN106669627B CN106669627B CN201611196737.0A CN201611196737A CN106669627B CN 106669627 B CN106669627 B CN 106669627B CN 201611196737 A CN201611196737 A CN 201611196737A CN 106669627 B CN106669627 B CN 106669627B
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- 238000001179 sorption measurement Methods 0.000 title claims abstract description 31
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 7
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 41
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 34
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 34
- OEGPRYNGFWGMMV-UHFFFAOYSA-N (3,4-dimethoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC OEGPRYNGFWGMMV-UHFFFAOYSA-N 0.000 claims abstract description 18
- HZUKSQHMCTUZJL-UHFFFAOYSA-N P(=O)(O)(O)OCC=1C(=C(C(=NC1)C)O)C=O.P(=O)(O)(O)OC=1C(=NC=C(C1C=O)CO)C Chemical compound P(=O)(O)(O)OCC=1C(=C(C(=NC1)C)O)C=O.P(=O)(O)(O)OC=1C(=NC=C(C1C=O)CO)C HZUKSQHMCTUZJL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004844 aliphatic epoxy resin Substances 0.000 claims abstract description 14
- KLIDCXVFHGNTTM-UHFFFAOYSA-N syringol Natural products COC1=CC=CC(OC)=C1O KLIDCXVFHGNTTM-UHFFFAOYSA-N 0.000 claims abstract description 14
- AWUCVROLDVIAJX-UHFFFAOYSA-N alpha-glycerophosphate Natural products OCC(O)COP(O)(O)=O AWUCVROLDVIAJX-UHFFFAOYSA-N 0.000 claims abstract description 13
- AWUCVROLDVIAJX-GSVOUGTGSA-N sn-glycerol 3-phosphate Chemical compound OC[C@@H](O)COP(O)(O)=O AWUCVROLDVIAJX-GSVOUGTGSA-N 0.000 claims abstract description 13
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims abstract description 12
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 150000002500 ions Chemical class 0.000 claims abstract description 8
- SWFNPENEBHAHEB-UHFFFAOYSA-N 2-amino-4-chlorophenol Chemical compound NC1=CC(Cl)=CC=C1O SWFNPENEBHAHEB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 8
- JSHJJLQJRLNBBA-UHFFFAOYSA-N 2-amino-3-chlorophenol Chemical compound NC1=C(O)C=CC=C1Cl JSHJJLQJRLNBBA-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 13
- 239000011347 resin Substances 0.000 claims 4
- 229920005989 resin Polymers 0.000 claims 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 14
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- 150000002894 organic compounds Chemical class 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003651 drinking water Substances 0.000 description 5
- 235000020188 drinking water Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 3
- 229960000907 methylthioninium chloride Drugs 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- DPZNOMCNRMUKPS-UHFFFAOYSA-N resorcinol dimethyl ether Natural products COC1=CC=CC(OC)=C1 DPZNOMCNRMUKPS-UHFFFAOYSA-N 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000003403 water pollutant Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical compound NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical class [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
The invention discloses a kind of adsorption composite materials, each substance comprising following composition by weight: 30-45 parts of active carbon, 25-35 parts of ion exchange resin, 8-12 parts of aliphatic epoxy resin, 7-13 parts of glycerophosphate, 10-15 parts of phosphopyridoxal pyridoxal phosphate, 11-16 parts of 4- chloro- Ortho-Aminophenol -6- sulfonic acid, 2,4-7 parts of 6- syringol, 8-12 parts of 3,4- dimethoxy-benzyl alcohol, 15-20 parts of diethylene glycol monobutyl ether.The present invention prepares the composite material for having fine adsorption effect to heavy metal ion and chemical organic compounds by mixing modified active carbon and modified ion exchange resin.
Description
Technical field
The invention belongs to technical field of composite materials, in particular to a kind of adsorption composite material and preparation method thereof.
Background technique
Along with the high speed development of industrialization and urbanization process, water resource pollution problem has become people and increasingly discusses
Focus, the especially pollution of drinking water, more people are paid close attention to.Chemical organic compounds and heavy metal component in drinking water
Value volume and range of product is all being continuously increased, and the various pathogenic microorganism factors also continuously emerge.The population that China also has more than 60% is drunk
Water does not meet water quality standard for drinking water.Therefore, the substances such as trace contaminant and heavy metal in drinking water are removed to have become
The vital task of water purification.
Currently, Advanced Drinking Water Purification Technology used in the prior art has: UF membrane, ozone oxidation, semiconductor light
The technologies such as catalysis oxidation, absorption.Membrane separation technique has the characteristics that efficient, the simple process etc. that can reconcile is excellent, but due to its membrane aperture
Very small, the ion (including the micro member beneficial to human body) in water almost removes, this water of long-term drinking, to the health of people
It is harmful.In addition, the cost of film is high, contamination resistance is poor, operating pressure is big, the higher deficiency of energy consumption limits its large-scale application.
Although ozone can be reacted with most of Organic substance in water, ozone oxidation is used alone, it is limited to purification of water quality treatment effect.
Some researches show that, ozone oxidations to the chloroform formed in water almost without removal effect, to the heavy metal in water from
Son is acted on without removal.Photocatalysis oxidation technique is a kind of emerging modern water treatment technology, the crowd used in light-catalyzed reaction
In multiple semiconductor catalyst, nano titania particle is rotten due to stable, nontoxic, the anti-chemistry of, property high with catalytic activity and light
The advantages that erosion and become numerous researchers first choice.However since nano-titanium oxide partial size is small, it is easy to run off, later period catalyst
Separation and recycling it is difficult, make it difficult to be widely applied in drink water purifying processing.Research work mostly rests on laboratory
In the stage, the application in water process Practical Project is seldom.Absorption rule is the surface nature and Large ratio surface using adsorbent material
Product carries out enrichment and separation to water pollutant, has the advantages that convenient operation and management and low energy consumption, be always what people studied
Hot spot.The active charcoal of common adsorbent material, expanded graphite, clay mineral, zeolite, hydrotalcite, metal oxide, metal tripolyphosphate
Salt and flyash etc..Adsorbent material has the characteristics that selective absorption, active carbon and expanded graphite to having in water to water pollutant
Machine object adsorption effect is fine, but to less effective heavy metal ion adsorbed in water；The inorganic material such as clay mineral and zeolite are to water
Middle removal of heavy metal ions rate is high, and to some organic matters in water, then possible absorption property is poor.
Summary of the invention
In view of the foregoing drawbacks, the object of the present invention is to provide a kind of adsorption composite materials and preparation method thereof, by that will change
Property after active carbon and modified ion exchange resin mixing, preparing all has very heavy metal ion and chemical organic compounds
The composite material of good adsorption effect.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of adsorption composite material, each substance comprising following composition by weight: 30-45 parts of active carbon, ion exchange resin
25-35 parts, 8-12 parts of aliphatic epoxy resin, 7-13 parts of glycerophosphate, 10-15 parts of phosphopyridoxal pyridoxal phosphate, the chloro- 2- aminobenzene of 4-
11-16 parts of phenol -6- sulfonic acid, 4-7 parts of 2,6- syringol, 8-12 parts of 3,4 dimethoxy benzyl alcohol, diethylene glycol monobutyl ether
15-20 parts.
Preferably, described active carbon 35-40 parts, it is 27-30 parts of ion exchange resin, 9-11 parts of aliphatic epoxy resin, sweet
8-12 parts of oleophosphoric acid ester, 12-14 parts of phosphopyridoxal pyridoxal phosphate, 13-15 parts of 4- chloro- Ortho-Aminophenol -6- sulfonic acid, 2,6- dimethoxy benzene
5-7 parts of phenol, 8-10 parts of 3,4 dimethoxy benzyl alcohol, 17-19 parts of diethylene glycol monobutyl ether.
Preferably, 38 parts of the active carbon, 28 parts of ion exchange resin, 10 parts of aliphatic epoxy resin, glycerophosphate
11 parts, 13 parts of phosphopyridoxal pyridoxal phosphate, 14 parts of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4-, 6 parts of 2,6- syringol, 3,4- dimethoxy
9 parts of base benzylalcohol, 18 parts of diethylene glycol monobutyl ether.
Preferably, the ion exchange resin is the mixing of ion exchange resin XAD-4 and ion exchange resin XAD-10
Object, the two mixed proportion are 1-3:1.
A kind of preparation method of adsorption composite material, includes the following steps:
S1: 30-45 parts of active carbon, 11-16 parts and 10-15 parts of phosphopyridoxal pyridoxal phosphate of 4- chloro- Ortho-Aminophenol -6- sulfonic acid are mixed
It closes, is stirred to react 1-2h at 150-180 DEG C of temperature, filtered active carbon drying will be reacted, obtained in 300-350 DEG C of roasting
Modified active carbon；
S2: by 25-35 parts of ion exchange resin, 8-12 parts of aliphatic epoxy resin and 15-20 parts of diethylene glycol monobutyl ether
Mixing, and it is stirred to react 1.5-2h at 140-160 DEG C of temperature, obtain modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 7-13 parts of glycerophosphate in 70-80 DEG C of reaction 20-30min of temperature；
S4: 4-7 parts and 8-12 parts of 3,4- dimethoxy-benzyl alcohol of 2,6-- syringol are then added, increases temperature extremely
100-120 DEG C, 2-3h is stirred to react with rate 800-1000r/min；It is multiple that the absorption can be obtained after cooling, molding after
Condensation material.
Preferably, the temperature stirred in step S1 is 175 DEG C, and stirring rate 400-500r/min is stirred to react 1.5h,
330 DEG C of maturing temperature, calcining time 10-15min.
Preferably, temperature described in step S2 is 150 DEG C, and stirring rate 500-600r/min is stirred to react 100min.
Preferably, 75 DEG C of temperature described in step S3 react 25min.
Preferably, temperature described in step S4 is 112 DEG C, and rate 850r/min is stirred to react 2.5h.
Compared with prior art, the present invention has the advantages that:
The preparation method of adsorption composite material of the present invention, by being modified respectively to active carbon and ion exchange resin,
Change the active group on their surfaces, and the two is passed through into glycerophosphate, 2,6-- syringol and 3,4- dimethoxy
Benzylalcohol combines well, does not influence absorption property each other, and then all keeps to Organic substance in water and heavy metal substance preferable
Adsorption effect, avoid water resource caused by single combination in the prior art can not deep purifying defect.The absorption is compound
Material is 180-220mg/g to methylene blue adsorption number amount, is 170-200mg/g to active red adsorbance, is to Pb adsorbance
140-160mg/g is 100-120mg/g to Cr adsorbance.
Specific embodiment
The present invention is further illustrated with reference to embodiments.
Embodiment 1
S1: by 30 parts of active carbon, 11 parts and 10 parts of phosphopyridoxal pyridoxal phosphate of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4- mixing, in temperature
At 150 DEG C, 1h is stirred to react with rate 400r/min, filtered active carbon drying will be reacted, obtained in 300 DEG C of roasting 10min
To modified active carbon；
S2: described by 25 parts of ion exchange resin, 8 parts of aliphatic epoxy resin and 15 parts of diethylene glycol monobutyl ether mixing
Ion exchange resin is the mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, and the two mixed proportion is 1-
3:1；And at 140 DEG C of temperature, 1.5h is stirred to react with rate 500r/min, obtains modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 7 parts of glycerophosphate and reacts 20min in temperature 70 C；
S4: being then added 4 parts of 2,6-- syringol and 3,8 parts of 4- dimethoxy-benzyl alcohol, increases temperature to 100 DEG C,
2h is stirred to react with rate 800r/min；The adsorption composite material can be obtained after cooling, molding after.
Comparative example 1
By 30 parts of active carbon, 25 parts of ion exchange resin and 3,8 parts of 4- dimethoxy-benzyl alcohol, temperature is increased to 100 DEG C, with
Rate 800r/min is stirred to react 2h；Adsorption composite material can be obtained after cooling, molding after.
Embodiment 2
S1: by 45 parts of active carbon, 16 parts and 15 parts of phosphopyridoxal pyridoxal phosphate of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4- mixing, in temperature
At 180 DEG C, 2h is stirred to react with rate 500r/min, filtered active carbon drying will be reacted, obtained in 350 DEG C of roasting 15min
To modified active carbon；
S2: described by 35 parts of ion exchange resin, 12 parts of aliphatic epoxy resin and 20 parts of diethylene glycol monobutyl ether mixing
Ion exchange resin is the mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, and the two mixed proportion is 1-
3:1；And at 160 DEG C of temperature, 2h is stirred to react with rate 600r/min, obtains modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 13 parts of glycerophosphate in 80 DEG C of reaction 30min of temperature；
S4: 7 parts of 2,6-- syringol and 3 are then added, 12 parts of 4- dimethoxy-benzyl alcohol, increase temperature to 120
DEG C, 3h is stirred to react with rate 1000r/min；The adsorption composite material can be obtained after cooling, molding after.
Comparative example 2
By 45 parts of active carbon, 35 parts of ion exchange resin and 3,12 parts of 4- dimethoxy-benzyl alcohol, temperature is increased to 120 DEG C,
3h is stirred to react with rate 1000r/min；Composite material can be obtained after cooling, molding after.
Embodiment 3
S1: by 35 parts of active carbon, 13 parts and 12 parts of phosphopyridoxal pyridoxal phosphate of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4- mixing, in temperature
At 160 DEG C, 1h is stirred to react with rate 400r/min, filtered active carbon drying will be reacted, obtained in 300 DEG C of roasting 10min
To modified active carbon；
S2: described by 27 parts of ion exchange resin, 9 parts of aliphatic epoxy resin and 17 parts of diethylene glycol monobutyl ether mixing
Ion exchange resin is the mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, and the two mixed proportion is 1-
3:1；And at 140 DEG C of temperature, 1.5h is stirred to react with rate 500r/min, obtains modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 8 parts of glycerophosphate and reacts 20min in temperature 70 C；
S4: being then added 5 parts of 2,6-- syringol and 3,8 parts of 4- dimethoxy-benzyl alcohol, increases temperature to 100 DEG C,
32h is stirred to react with rate 800r/min；The adsorption composite material can be obtained after cooling, molding after.
Embodiment 4
S1: by 40 parts of active carbon, 15 parts and 14 parts of phosphopyridoxal pyridoxal phosphate of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4- mixing, in temperature
At 170 DEG C, 2h is stirred to react with rate 500r/min, filtered active carbon drying will be reacted, obtained in 350 DEG C of roasting 15min
To modified active carbon；
S2: described by 30 parts of ion exchange resin, 11 parts of aliphatic epoxy resin and 19 parts of diethylene glycol monobutyl ether mixing
Ion exchange resin is the mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, and the two mixed proportion is 1-
3:1；And at 160 DEG C of temperature, 2h is stirred to react with rate 600r/min, obtains modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 12 parts of glycerophosphate in 80 DEG C of reaction 30min of temperature；
S4: 7 parts of 2,6-- syringol and 3 are then added, 10 parts of 4- dimethoxy-benzyl alcohol, increase temperature to 120
DEG C, 3h is stirred to react with rate 1000r/min；The adsorption composite material can be obtained after cooling, molding after.
Embodiment 5
S1: by 38 parts of active carbon, 14 parts and 13 parts of phosphopyridoxal pyridoxal phosphate of the chloro- Ortho-Aminophenol -6- sulfonic acid of 4- mixing, in temperature
At 175 DEG C, 1.5h is stirred to react with rate 450r/min, filtered active carbon drying will be reacted, in 330 DEG C of roasting 12min
Obtain modified active carbon；
S2: described by 28 parts of ion exchange resin, 10 parts of aliphatic epoxy resin and 18 parts of diethylene glycol monobutyl ether mixing
Ion exchange resin is the mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, and the two mixed proportion is 1-
3:1；And at 150 DEG C of temperature, 100min is stirred to react with rate 550r/min, obtains modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, is added
Enter 11 parts of glycerophosphate in 75 DEG C of reaction 25min of temperature；
S4: being then added 6 parts of 2,6-- syringol and 3,9 parts of 4- dimethoxy-benzyl alcohol, increases temperature to 112 DEG C,
2.5h is stirred to react with rate 850r/min；The adsorption composite material can be obtained after cooling, molding after.
By above each resulting adsorption composite material performance test of embodiment and comparative example, the result is as follows:
It is 180-220mg/g to methylene blue adsorption number amount, is 170-200mg/g to active red adsorbance, to Pb adsorbance
It is 100-120mg/g to Cr adsorbance for 140-160mg/g.
Table 1
| Test | Methylene blue adsorption number amount (mg/g) | Active red adsorbance (mg/g) | Pb adsorbance (mg/g) | Cr adsorbance (mg/g) |
| Embodiment 1 | 180 | 170 | 140 | 100 |
| Comparative example 1 | 87 | 63 | 75 | 57 |
| Embodiment 2 | 189 | 178 | 145 | 104 |
| Comparative example 2 | 94 | 85 | 80 | 83 |
| Embodiment 3 | 196 | 185 | 150 | 110 |
| Embodiment 4 | 215 | 194 | 158 | 116 |
| Embodiment 5 | 220 | 200 | 160 | 120 |
The present invention is not limited to embodiment here, those skilled in the art's announcement according to the present invention does not depart from the present invention
The improvement and modification that scope is made all should be within protection scope of the present invention.
Claims (8)
1. a kind of adsorption composite material, which is characterized in that each substance comprising following composition by weight: 30-45 parts of active carbon, ion
25-35 parts of exchanger resin, 8-12 parts of aliphatic epoxy resin, 7-13 parts of glycerophosphate, 10-15 parts of phosphopyridoxal pyridoxal phosphate, 4- are chloro-
11-16 parts of Ortho-Aminophenol -6- sulfonic acid, 4-7 parts of 2,6- syringol, 8-12 parts of 3,4 dimethoxy benzyl alcohol, diethyl two
15-20 parts of alcohol monobutyl ether；
A kind of adsorption composite material is prepared by following preparation methods:
S1: 30-45 parts of active carbon, 11-16 parts and 10-15 parts of phosphopyridoxal pyridoxal phosphate of 4- chloro- Ortho-Aminophenol -6- sulfonic acid are mixed,
It is stirred to react 1-2h at 150-180 DEG C of temperature, filtered active carbon drying will be reacted, changed in 300-350 DEG C of roasting
Active carbon after property；
S2: 25-35 parts of ion exchange resin, 8-12 parts of aliphatic epoxy resin and 15-20 parts of diethylene glycol monobutyl ether are mixed,
And it is stirred to react 1.5-2h at 140-160 DEG C of temperature, obtain modified ion exchange resin；
S3: modified ion exchange resin described in modified active carbon described in step S1 and step S2 is mixed, and is added sweet
7-13 parts of oleophosphoric acid ester, in 70-80 DEG C of reaction 20-30min of temperature；
S4: being then added 4-7 parts and 8-12 parts of 3,4- dimethoxy-benzyl alcohol of 2,6-- syringol, increases temperature to 100-
120 DEG C, 2-3h is stirred to react with rate 800-1000r/min；The absorption composite wood can be obtained after cooling, molding after
Material.
2. a kind of adsorption composite material according to claim 1, which is characterized in that the temperature stirred in step S1 is 175
DEG C, stirring rate 400-500r/min is stirred to react 1.5h, and 330 DEG C of maturing temperature, calcining time 10-15min.
3. a kind of adsorption composite material according to claim 1, which is characterized in that temperature described in step S2 is 150 DEG C,
Stirring rate is 500-600r/min, is stirred to react 100min.
4. a kind of adsorption composite material according to claim 1, which is characterized in that 75 DEG C of temperature described in step S3, instead
Answer 25min.
5. a kind of adsorption composite material according to claim 1, which is characterized in that temperature described in step S4 is 112 DEG C,
Rate 850r/min is stirred to react 2.5h.
6. a kind of adsorption composite material according to claim 1, which is characterized in that described active carbon 35-40 parts, ion friendship
Change 27-30 parts of resin, 9-11 parts of aliphatic epoxy resin, 8-12 parts of glycerophosphate, 12-14 parts of phosphopyridoxal pyridoxal phosphate, the chloro- 2- of 4-
13-15 parts of amino-phenol -6- sulfonic acid, 5-7 parts of 2,6- syringol, 8-10 parts of 3,4 dimethoxy benzyl alcohol, diethylene glycol
17-19 parts of monobutyl ether.
7. a kind of adsorption composite material according to claim 1, which is characterized in that 38 parts of the active carbon, ion exchange
28 parts of resin, 10 parts of aliphatic epoxy resin, 11 parts of glycerophosphate, 13 parts of phosphopyridoxal pyridoxal phosphate, the chloro- Ortho-Aminophenol -6- of 4-
14 parts of sulfonic acid, 6 parts of 2,6- syringol, 9 parts of 3,4 dimethoxy benzyl alcohol, 18 parts of diethylene glycol monobutyl ether.
8. a kind of adsorption composite material according to claim 1, which is characterized in that the ion exchange resin is ion friendship
The mixture of resin XAD-4 and ion exchange resin XAD-10 are changed, the two mixed proportion is 1-3:1.
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| CN105565533A (en) * | 2014-10-08 | 2016-05-11 | 深圳市汇利龙科技有限公司 | Zero-discharge on-line treatment process for preparing deionized water from copper sulphate electroplating waste water |
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| CN105565533A (en) * | 2014-10-08 | 2016-05-11 | 深圳市汇利龙科技有限公司 | Zero-discharge on-line treatment process for preparing deionized water from copper sulphate electroplating waste water |
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