CN106654411A - Active agent for repairing lead-acid battery of electric vehicle and modulation method of active agent - Google Patents
Active agent for repairing lead-acid battery of electric vehicle and modulation method of active agent Download PDFInfo
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- CN106654411A CN106654411A CN201611206540.0A CN201611206540A CN106654411A CN 106654411 A CN106654411 A CN 106654411A CN 201611206540 A CN201611206540 A CN 201611206540A CN 106654411 A CN106654411 A CN 106654411A
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- China
- Prior art keywords
- parts
- acid battery
- distilled water
- electric motor
- motor car
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4242—Regeneration of electrolyte or reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Abstract
The invention provides an active agent for repairing a lead-acid battery of an electric vehicle and a modulation method of the active agent, and relates to the technical field of battery repairing. The active agent comprises the following components in parts by weight: 10-12 parts of diammonium hydrogen phosphate, 6-8 parts of potassium persulfate, 2-4 parts of sodium pyrophosphate, 4-6 parts of sodium thiosulfate, 0.2-1 part of zinc sulfate, 0.2-0.4 part of manganese dioxide, 0.02-0.08 part of bismuth trioxide, 0.001-0.01 part of thulium oxide, 1-2 parts of activated carbon and 100-200 parts of distilled water in sequence. The method comprises the steps of firstly pouring the distilled water into a plastic container, fully mixing the diammonium hydrogen phosphate, the potassium persulfate, the sodium pyrophosphate, the sodium thiosulfate and the zinc sulfate and then pouring a mixture into the distilled water in the container; and carrying out cooling until the temperature of the solution returns to 25 DEG C and adding the weighed manganese dioxide, bismuth trioxide, thulium oxide and activated carbon according to the parts by weight. The battery is good in performance after being repaired, long in service life, good in low temperature resistance and high in efficiency.
Description
Technical field:
The present invention relates to battery recovery technique field, the specifically a kind of agent of electric motor car lead-acid battery repairing activity and its modulation
Method.
Background technology:
Lead-acid battery phase after charging, electrolytic effect can be produced, evaporate the moist part in electrolyte.Battery is through length
After time discharge and recharge use, moisture can evaporate more, raise concentration of electrolyte, and liquid level declines.And in the mistake of Long-Time Service
There is this sulfation in journey, cause sulfuric acid also to tail off, at this moment require supplementation with distilled water and electrolyte, make build-up of fluid original
Highly, electrolyte maintains normal concentration, to ensure lead-acid accumulator service life.In prior art, in battery reparation typically all
The performance of the battery for referring to moisturizing and electrolyte to reply, also has and adds activating agent in battery is repaired, so that
Battery recovery phase performance is obtained, the species of existing activating agent is relatively simple, use time change is shorter after battery recovery, low temperature resistant
Poor-performing.
The content of the invention:
The technical problem to be solved is that the performance provided after a kind of battery reparation is good, and long service life is resistance to
The good electric motor car lead-acid battery repairing activity agent of cryogenic effect and its modulator approach.
The technical problem to be solved employs the following technical solutions to realize.
A kind of electric motor car lead-acid battery repairing activity agent, it is characterised in that:Include following components by weight, successively phosphoric acid
10~12 parts of two ammonium of hydrogen, 6~8 parts of potassium peroxydisulfate, 2~4 parts of sodium pyrophosphate, 4~6 parts of sodium thiosulfate, 0.2~1 part of zinc sulfate,
0.2~0.4 part of manganese dioxide, 0.02~0.08 part of bismuth oxide, 0.001~0.01 part of thulium oxide, 1~2 part of activated carbon and
100~200 parts of distilled water.
It is preferred that by weight include following components, successively 11 parts of diammonium hydrogen phosphate, 7 parts of potassium peroxydisulfate, 3 parts of sodium pyrophosphate,
5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, 0.05 part of bismuth oxide, 0.006 part of thulium oxide, activated carbon
1.5 parts and 150 parts of distilled water.
Also include 2~4 parts of sodium molybdate by weight.
A kind of modulator approach of electric motor car lead-acid battery repairing activity agent, it is characterised in that:Carry out according to the following steps, first will
Be heated to the distilled water of 40~50 DEG C of temperature to pour into a plastic containers, weigh by weight diammonium hydrogen phosphate, potassium peroxydisulfate,
Sodium pyrophosphate, sodium thiosulfate and zinc sulfate, in being sufficiently mixed distilled water that is rear and pouring container into, stir while adding, and cool down
When restoring to 25 DEG C Deng the temperature of solution, manganese dioxide, bismuth oxide, thulium oxide and the activity for weighing by weight is added
Charcoal, does not stop to stir.
Sticking plaster or glass bar are used when described stirring.
Forbid to fall into other impurities during described mixing.
The present invention is special battery repairing activity agent, can greatly improve the efficiency of battery recovery, more convenient operation,
Faster, and the efficiency after battery recovery is more preferably, can reach the 75% of at least original battery efficiency for speed.
The invention has the beneficial effects as follows:Performance after battery of the present invention is repaired is good, and long service life, low temperature resistant effect is good
Efficiency is high.
Specific embodiment:
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment one
A kind of electric motor car lead-acid battery repairing activity agent, by weight including following components, successively 10 parts of diammonium hydrogen phosphate,
Potassium peroxydisulfate part, 2 parts of sodium pyrophosphate, 4 parts of sodium thiosulfate, 0.2 part of zinc sulfate, 0.2 part of manganese dioxide, bismuth oxide 0.02
Part, 0.001 part of thulium oxide, 1 part of activated carbon and 100 parts of distilled water.
A kind of modulator approach of electric motor car lead-acid battery repairing activity agent, is carried out according to the following steps, first would be heated to 40~
The distilled water of 50 DEG C of temperature is poured into a plastic containers, weigh by weight diammonium hydrogen phosphate, potassium peroxydisulfate, sodium pyrophosphate,
Sodium thiosulfate and zinc sulfate, in being sufficiently mixed distilled water that is rear and pouring container into, stir while adding, the temperature of the solution such as cooling
When degree is restored to 25 DEG C, manganese dioxide, bismuth oxide, thulium oxide and the activated carbon for weighing by weight is added, do not stop to stir
Mix uniform.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
Embodiment two
A kind of electric motor car lead-acid battery repairing activity agent, by weight including following components, successively 11 parts of diammonium hydrogen phosphate,
7 parts of potassium peroxydisulfate, 3 parts of sodium pyrophosphate, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, bismuth oxide
150 parts of 0.05 part, 0.006 part of thulium oxide, 1.5 parts of activated carbon and distilled water.
Also include 2~4 parts of sodium molybdate by weight.
A kind of modulator approach of electric motor car lead-acid battery repairing activity agent, is carried out according to the following steps, first would be heated to 40~
The distilled water of 50 DEG C of temperature is poured into a plastic containers, weigh by weight diammonium hydrogen phosphate, potassium peroxydisulfate, sodium pyrophosphate,
Sodium thiosulfate, sodium molybdate and zinc sulfate, in being sufficiently mixed distilled water that is rear and pouring container into, stir while adding, cooling etc.
When the temperature of solution is restored to 25 DEG C, manganese dioxide, bismuth oxide, thulium oxide and the activated carbon for weighing by weight is added,
Do not stop to stir.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
Embodiment three
A kind of electric motor car lead-acid battery repairing activity agent, by weight including following components, successively 12 parts of diammonium hydrogen phosphate,
8 parts of potassium peroxydisulfate, 4 parts of sodium pyrophosphate, 6 parts of sodium thiosulfate, 1 part of zinc sulfate, 0.4 part of manganese dioxide, bismuth oxide 0.08
Part, 0.01 part of thulium oxide, 2 parts of activated carbon and 200 parts of distilled water.
A kind of modulator approach of electric motor car lead-acid battery repairing activity agent, is carried out according to the following steps, first would be heated to 40~
The distilled water of 50 DEG C of temperature is poured into a plastic containers, weigh by weight diammonium hydrogen phosphate, potassium peroxydisulfate, sodium pyrophosphate,
Sodium thiosulfate and zinc sulfate, in being sufficiently mixed distilled water that is rear and pouring container into, stir while adding, the temperature of the solution such as cooling
When degree is restored to 25 DEG C, manganese dioxide, bismuth oxide, thulium oxide and the activated carbon for weighing by weight is added, do not stop to stir
Mix uniform.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and specification this
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (6)
1. a kind of electric motor car lead-acid battery repairing activity agent, it is characterised in that:Include following components by weight, successively phosphoric acid hydrogen
Two 10~12 parts of ammoniums, 6~8 parts of potassium peroxydisulfate, 2~4 parts of sodium pyrophosphate, 4~6 parts of sodium thiosulfate, 0.2~1 part of zinc sulfate, two
0.2~0.4 part of manganese oxide, 0.02~0.08 part of bismuth oxide, 0.001~0.01 part of thulium oxide, 1~2 part of activated carbon and steaming
100~200 parts of distilled water.
2. a kind of electric motor car lead-acid battery repairing activity agent according to claim 1, it is characterised in that:A kind of electric motor car lead
Sour battery repairing activity agent, it is characterised in that:Include following components by weight, successively 11 parts of diammonium hydrogen phosphate, potassium peroxydisulfate 7
Part, 3 parts of sodium pyrophosphate, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, 0.05 part of bismuth oxide, oxidation
150 parts of 0.006 part of thulium, 1.5 parts of activated carbon and distilled water.
3. a kind of electric motor car lead-acid battery repairing activity agent according to claim 1, it is characterised in that:Also wrap by weight
Include 2~4 parts of sodium molybdate.
4. the modulator approach of a kind of electric motor car lead-acid battery repairing activity agent according to claim 1, it is characterised in that:Press
Following steps are carried out, and the distilled water that first would be heated to 40~50 DEG C of temperature is poured into a plastic containers, and phosphorus is weighed by weight
The ammonium of sour hydrogen two, potassium peroxydisulfate, sodium pyrophosphate, sodium thiosulfate and zinc sulfate, in being sufficiently mixed distilled water that is rear and pouring container into,
Stir while adding, when the temperature of the solution such as cooling is restored to 25 DEG C, add manganese dioxide, three oxidations two for weighing by weight
Bismuth, thulium oxide and activated carbon, do not stop to stir.
5. the modulator approach of a kind of electric motor car lead-acid battery repairing activity agent according to claim 4, it is characterised in that:Institute
Sticking plaster or glass bar are used when the stirring stated.
6. the modulator approach of a kind of electric motor car lead-acid battery repairing activity agent according to claim 4, it is characterised in that:Institute
Forbid to fall into other impurities during the mixing stated.
Priority Applications (1)
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CN201611206540.0A CN106654411A (en) | 2016-12-23 | 2016-12-23 | Active agent for repairing lead-acid battery of electric vehicle and modulation method of active agent |
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CN201611206540.0A CN106654411A (en) | 2016-12-23 | 2016-12-23 | Active agent for repairing lead-acid battery of electric vehicle and modulation method of active agent |
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Citations (12)
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WO1999044942A1 (en) * | 1998-03-03 | 1999-09-10 | Nile Limited | Thermal process for conversion of active material from spent lead acid batteries to lead monoxide |
CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
CN1630957A (en) * | 2001-12-20 | 2005-06-22 | 吉莱特公司 | Additive for alkaline batteries |
JP2006073448A (en) * | 2004-09-06 | 2006-03-16 | Ysd:Kk | Method for regenerating lead-acid battery and method for regenerating lead electrode |
CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
CN101853960A (en) * | 2009-04-03 | 2010-10-06 | 王海湘 | Lead-acid battery active agent |
CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
CN102689923A (en) * | 2011-03-24 | 2012-09-26 | 杨春晓 | Preparation method of lead-acid battery PbO nano-powder |
CN102082305B (en) * | 2010-12-21 | 2013-08-21 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
CN103280606A (en) * | 2013-06-08 | 2013-09-04 | 唐春正 | Method for reactivating lead acid battery through utilizing activated electrolyte |
CN105529503A (en) * | 2015-03-05 | 2016-04-27 | 沈阳一正能源科技有限公司 | Neutral repair liquid for lead-acid storage battery and preparation technology of neutral repair liquid |
CN105914416A (en) * | 2016-05-18 | 2016-08-31 | 山西嘉禾兴节能技术有限公司 | Waste lead-acid storage battery repairing activating agent and use method thereof |
-
2016
- 2016-12-23 CN CN201611206540.0A patent/CN106654411A/en active Pending
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
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WO1999044942A1 (en) * | 1998-03-03 | 1999-09-10 | Nile Limited | Thermal process for conversion of active material from spent lead acid batteries to lead monoxide |
CN1630957A (en) * | 2001-12-20 | 2005-06-22 | 吉莱特公司 | Additive for alkaline batteries |
CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
JP2006073448A (en) * | 2004-09-06 | 2006-03-16 | Ysd:Kk | Method for regenerating lead-acid battery and method for regenerating lead electrode |
CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
CN101853960A (en) * | 2009-04-03 | 2010-10-06 | 王海湘 | Lead-acid battery active agent |
CN102082305B (en) * | 2010-12-21 | 2013-08-21 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
CN102689923A (en) * | 2011-03-24 | 2012-09-26 | 杨春晓 | Preparation method of lead-acid battery PbO nano-powder |
CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
CN103280606A (en) * | 2013-06-08 | 2013-09-04 | 唐春正 | Method for reactivating lead acid battery through utilizing activated electrolyte |
CN105529503A (en) * | 2015-03-05 | 2016-04-27 | 沈阳一正能源科技有限公司 | Neutral repair liquid for lead-acid storage battery and preparation technology of neutral repair liquid |
CN105914416A (en) * | 2016-05-18 | 2016-08-31 | 山西嘉禾兴节能技术有限公司 | Waste lead-acid storage battery repairing activating agent and use method thereof |
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Application publication date: 20170510 |