CN106654055A - Flexible display and making method thereof - Google Patents

Flexible display and making method thereof Download PDF

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Publication number
CN106654055A
CN106654055A CN201610824637.1A CN201610824637A CN106654055A CN 106654055 A CN106654055 A CN 106654055A CN 201610824637 A CN201610824637 A CN 201610824637A CN 106654055 A CN106654055 A CN 106654055A
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CN
China
Prior art keywords
transparent substrates
flexible display
preparation
curing agent
tack coat
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Granted
Application number
CN201610824637.1A
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Chinese (zh)
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CN106654055B (en
Inventor
黄梦
刘红林
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Chengdu Vistar Optoelectronics Co Ltd
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Kunshan Guoxian Photoelectric Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K77/00Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
    • H10K77/10Substrates, e.g. flexible substrates
    • H10K77/111Flexible substrates
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/851Division of substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

The invention relates to a making method of a flexible display, comprising the following steps: evenly coating the surface of a transparent base plate with adhesive to form a bonding layer; coating the bonding layer with curing agent to cure the bonding layer in contact with the curing agent; evenly coating the surface of bonding layer with polymer solution to form a flexible substrate; forming a barrier layer, a TFT array layer, an OLED layer and an encapsulation layer on the flexible substrate in turn; and exposing the surface of the other side of the transparent base plate to make the flexible substrate separated from the transparent base plate due to curing failure of the curing agent. Through the making method of the flexible display, the flexible substrate can be easily separated from the transparent base plate, the problem that the flexible substrate is carbonized by laser to produce a large number of particles in the traditional production process is avoided, and furthermore, contamination to OLED displays is avoided.

Description

Flexible display and preparation method thereof
Technical field
The present invention relates to flexible display apparatus field, more particularly to a kind of flexible display and preparation method thereof.
Background technology
Flexible display is the study hotspot of each colleges and universities of recent domestic and research structure, is also that all big enterprises fall over each other cloth The emphasis of office.Compared with regular display, flexible display has many advantages, such as:Lightweight, small volume, slimming, carrying side Just;High-low temperature resistant, impact resistance, shock resistance are higher, and adaptable working environment is wider;Rollable, profile sets with more art The aesthetic feeling of meter;Using the coil type production technology of typography, cost is cheaper;It is low in energy consumption, it is more energy efficient;Organic material is more Environmental protection.Flexible display is to use flexible substrate material as device bearing substrate, and requires electrode layer, TFT matrixes, shows Device and encapsulated layer have certain bending radius to realize flexibility.
At present, the production technology of Flexible Displays product is broadly divided into two classes:The first kind is using R2R (roll to roll) Production technology, i.e., directly prepare on flexible substrates display device by way of printing, but due to by printing technology and The restriction of ink material is shown, the display device prepared does not reach the requirement that high accuracy shows, and yields is low, reliability Difference;Equations of The Second Kind is, using S2S (sheet to sheet) production technology, the method peeled off afterwards first to be attached with reference to flexible base board, first Flexible base board is attached on hard carrier substrate and prepares display device, prepared and peel off again after display device hard substrate, Flexible display device is taken out, this technique does not affect the making precision of display device, and making apparatus and technique and making tradition TFT-LCD it is similar, it is not necessary to do too big adjustment, therefore in a short time closer to volume production application.
In conventionally employed S2S production technologies, after completing to prepare display device, using under integrating laser carbonization flexible base board Layer, makes flexible base board separate with hard substrate, but in above-mentioned carbonisation, easily causes substantial amounts of particulate matter, these particles Thing can be polluted to display device, and display device needs to be cleaned in subsequent handling, increased the complexity of manufacture craft Degree.
The content of the invention
Based on this, it is necessary to for the above-mentioned particle caused due to carrying out being carbonized to the lower floor of flexible base board using laser Pollution of the thing to display device, and then increased the challenge of manufacture craft, there is provided one kind does not produce particulate matter, and simplifies system Make flexible display of technique and preparation method thereof.
A kind of preparation method of flexible display, comprises the following steps:
In the side of transparent substrates uniformly coated with adhesive, to form tack coat;
Curing agent is coated on the tack coat, the tack coat for making the contact curing agent solidifies;
In the uniformly coated polymer solution of the tack coat, to form flexible substrate;
Barrier layer, tft array layer, oled layer and encapsulated layer are sequentially formed in the flexible substrate;
Another side surface of transparent substrates is exposed, so that the flexible substrate is because of curing agent solidification failure and institute State transparent substrates separation.
By the preparation method of above-mentioned flexible display, flexible substrate can be made easily to separate with above-mentioned transparent substrates, it is to avoid In traditional processing technology, make flexible substrate that substantial amounts of particle is produced because of carbonization using laser, and then avoid to OLED display Pollution.
Wherein in one embodiment, in the uniformly coated with adhesive in transparent substrates, to form bonding It is further comprising the steps of before the step of layer:
The surface that transparent substrates are used for coated with adhesive is surface-treated so that the surface of transparent substrates is in hydrophobic Property.
It is described that the surface that transparent substrates are used for coated with adhesive is surface-treated wherein in one embodiment, make Obtain the surface of transparent substrates includes in hydrophobic step:
Hydrophober is coated on the surface of the transparent substrates.
Wherein in one embodiment, the hydrophober is dimethicone.
Wherein in one embodiment, the binding agent includes polyurethane.
Wherein in one embodiment, the curing agent includes polymethyl methacrylate.
It is described that another side surface of transparent substrates is exposed wherein in one embodiment, so that the flexible substrate In the step of separating with the transparent substrates because of curing agent solidification failure, including:
Transparent substrates are exposed using ultraviolet.
Wherein in one embodiment, the transparent substrates are glass substrate.
Wherein in one embodiment, curing agent is coated on the tack coat, make the described viscous of the contact curing agent During knot layer is the step of solidify, the curing agent is coated in the surrounding of the close tack coat marginal position, and the tack coat is consolidated Change width is 80-120um.
A kind of flexible display, is made by the preparation method of above-described flexible display.
The preparation method that above-mentioned flexible display passes through above-mentioned flexible display, can make flexible substrate easily with above-mentioned printing opacity Substrate is separated, it is to avoid in traditional processing technology, is made flexible substrate that substantial amounts of particle is produced because of carbonization using laser, and then is avoided Pollution to flexible display, improves the yield of flexible display.
Description of the drawings
Fig. 1 is the flow chart of the method for fabricating flexible display of a preferred embodiment of the invention;
Fig. 2 is to form barrier layer in transparent substrates in the method for fabricating flexible display of a preferred embodiment of the invention And cross section structure diagram during encapsulated layer.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, and It is not used in the restriction present invention.
Unless otherwise defined, all of technology used herein and scientific terminology and the technical field for belonging to the present invention The implication that technical staff is generally understood that is identical.The term for being used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that of the invention in limiting.Term as used herein " and/or " include one or more phases The arbitrary and all of combination of the Listed Items of pass.
A kind of flexible display 100 of one preferred embodiment of the present invention, the flexible display 100 is by following preparation method systems Form, the preparation method is comprised the following steps:
S11:The surface that transparent substrates are used for coated with adhesive is surface-treated so that the surface of transparent substrates is in thin It is aqueous.
In this step, by being surface-treated on transparent substrates 110 so that the surface of transparent substrates 110 is in thin It is aqueous.And then facilitate follow-up tack coat 120 to peel off from transparent substrates 110.In more detail, on the surface of above-mentioned transparent substrates Coating hydrophober, such as so, the surface for coating the transparent substrates of hydrophober is just in hydrophobicity, and above-mentioned hydrophober can be diformazan Base silicone oil, but as long as the table surface of its transparent substrates 110 can be made in hydrophobic hydrophober, reaches the goal of the invention of the present invention , here of the present invention is simultaneously not construed as limiting.
S12:In the side of transparent substrates uniformly coated with adhesive, to form tack coat.
As shown in Fig. 2 the surface coating in the transparent substrates 110 of one layer of hydrophober of above-mentioned coating is evenly coated with binding agent 120, the binding agent 120 includes polyurethane, is mainly used for for follow-up flexible substrate 140 being bonded in above-mentioned transparent substrates 110 Surface.Usually, what above-mentioned binding agent 120 was coated in the surface of transparent substrates 110 connects ectocentral position, and not exclusively covers The surface of whole transparent substrates 110 is covered, in order to subsequent cure agent coating.
S13:Curing agent is coated on the tack coat, the tack coat for making the contact curing agent solidifies.
In this step, curing agent 130 (such as crosslinking agent) is coated on above-mentioned binding agent 120, will in present embodiment Above-mentioned curing agent 130 is coated in the surrounding of the close marginal position of above-mentioned binding agent 120, and the curing agent 130 includes polymethyl Sour methyl esters, it is mainly used in being contacted with above-mentioned binding agent 120, in detail, binding agent 120 formed it is outermost one circle with Curing agent 130 can solidify within a short period of time after contacting, wherein the solidification width of the tack coat is 80-120um, in binding agent Interior between 120 no completely crued this section, polymer thin film of the subsequent coated on the surface of tack coat can consolidating with binding agent 120 Change, make flexible substrate 140 be bonded in the surface of above-mentioned transparent substrates 110.
Certainly, above-mentioned curing agent 130 can be also coated in the whole surface of above-mentioned binding agent 120, as long as this can be reached The goal of the invention of invention, the present invention is not construed as limiting to this.
S14:In the uniformly coated polymer solution of the tack coat, to form flexible substrate.
Before above-mentioned binding agent 120 is not fully cured, the upper surface of the tack coat formed in above-mentioned binding agent 120 Polymer solution is evenly coated with, then such as PI solution can be sent in high temperature oven, carry out at high-temperature heating Reason, solidifies polymer solution and forms flexible substrate 140, i.e. flexible substrate, and the coating method of polymer solution can be with It is the methods such as spin-coating method (Spin), knife coating (slit) or ink jet printing (inkjet printing), and it is molten to control polymer The characterisitic parameters such as thickness, uniformity and surface roughness that liquid is coated.
S15:Barrier layer 150, tft array layer 160, oled layer 170 and encapsulated layer are sequentially formed in the flexible substrate 180。
Because the water oxygen transmitance of flexible substrate 140 is high, the stability and service life of OLED are had seriously Affect, so in this step, need to form barrier layer 150 in flexible substrate 140, to prevent water oxygen from passing through, device is protected Shield, used as preferred embodiment of the invention, the barrier layer 150 is the alternating structure that organic material/inorganic material is formed, or The alternating structure that person's inorganic material/inorganic material is formed.Preferably, the organic material/inorganic material alternating structure is parylene/SiNx/parylene/SiNx;Further, the inorganic material/inorganic material alternating structure is SiNxSiO2/ SiNx.Then the tft array 160 for driving flexible display device is made on barrier layer 150, such as Oxide-TFT, according to The difference of TFT technological temperatures, needs from the different flexible substrate material of heat resistance.Then each layer organic material and electricity are deposited with Pole material, makes OLED display device 170, and by tft array layer 160 and oled layer 170 AMOLED layers are constituted, and finally makes encapsulation Layer 180, plays the impact for protecting flexible display from steam, oxygen, dust and stress.
S16:Another side surface of transparent substrates is exposed, so that the flexible substrate fails because of curing agent solidification Separate with the transparent substrates.
After the completion of above-mentioned element manufacturing, the back side of transparent substrates 110 can be exposed, usually, the transparent substrates 110 is glass substrate, for example, the back side of transparent substrates 110 is exposed using ultraviolet, and light enters transparent substrates 110 The back side, because transparent substrates 110 can be such that light enters in it, and then exposes to and is cured positioned at the positive of transparent substrates 110 The tack coat of agent solidification, at this moment, due to being irradiated by light, curing agent 130 fails, and then the tack coat for causing to be cured is saturating with this Photopolymer substrate 110 and flexible substrate are separated, and flexible display just can be cut and be peeled off by such staff along line of cut easily Get off, wherein, tack coat is located adjacent to not being cured for the middle position of transparent substrates 110, and the surface of transparent substrates 110 With certain hydrophobicity, transparent substrates 110 are poor with the cementability of the zone line of adhesive linkage, so make binding agent 120 with Flexible substrate departs from together transparent substrates, so when in follow-up flow chart as also needed to position OLED display device When, the binding agent 120 may be repeated and use.
By the preparation method of above-mentioned flexible display, flexible substrate can be made easily to separate with above-mentioned transparent substrates, be simplified Production technology, and avoid in traditional processing technology, using laser make flexible substrate that substantial amounts of particle is produced because of carbonization, and then The pollution to OLED display is avoided, the yield of flexible display is improve.
Another preferred embodiment of the present invention discloses a kind of flexible display, and the flexible display is by above-mentioned embodiment In the preparation method of flexible display be made.
The preparation method that above-mentioned flexible display passes through above-mentioned flexible display, can make flexible substrate easily with above-mentioned printing opacity Substrate is separated, it is to avoid in traditional processing technology, is made flexible substrate that substantial amounts of particle is produced because of carbonization using laser, and then is kept away Exempt from the pollution to flexible display, improve the yield of flexible display.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more concrete and detailed, but and Can not therefore be construed as limiting the scope of the patent.It should be pointed out that for one of ordinary skill in the art comes Say, without departing from the inventive concept of the premise, some deformations and improvement can also be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be defined by claims.

Claims (10)

1. a kind of preparation method of flexible display, it is characterised in that comprise the following steps:
In the side of transparent substrates uniformly coated with adhesive, to form tack coat;
Curing agent is coated on the tack coat, the tack coat for making the contact curing agent solidifies;
In the uniformly coated polymer solution of the tack coat, to form flexible substrate;
Barrier layer, tft array layer, oled layer and encapsulated layer are sequentially formed in the flexible substrate;
Another side surface of transparent substrates is exposed so that the flexible substrate because the curing agent solidification failure with it is described Photopolymer substrate is separated.
2. the preparation method of flexible display according to claim 1, it is characterised in that on the surface in transparent substrates Be evenly coated with binding agent, the step of to form tack coat before it is further comprising the steps of:
The surface that transparent substrates are used for coated with adhesive is surface-treated so that the surface of transparent substrates is in hydrophobicity.
3. the preparation method of flexible display according to claim 2, it is characterised in that described to be used to apply to transparent substrates The surface for covering binding agent is surface-treated so that the surface of transparent substrates includes in hydrophobic step:
Hydrophober is coated on the surface of the transparent substrates.
4. the preparation method of flexible display according to claim 3, it is characterised in that the hydrophober is dimethyl-silicon Oil.
5. the preparation method of flexible display according to claim 1, it is characterised in that the binding agent includes polyurethane.
6. the preparation method of flexible display according to claim 1, it is characterised in that the curing agent includes poly- methyl-prop E pioic acid methyl ester.
7. the preparation method of flexible display according to claim 1, it is characterised in that described to transparent substrates opposite side Surface is exposed, so that the flexible substrate fails in the step of separating with the transparent substrates because of curing agent solidification, Including:
Transparent substrates are exposed using ultraviolet.
8. the preparation method of flexible display according to claim 1, it is characterised in that the transparent substrates are glass base Plate.
9. the preparation method of flexible display according to claim 1, it is characterised in that coat on the tack coat solid Agent, the step of solidify the tack coat of the contact curing agent in, the curing agent is coated in the close tack coat The surrounding of marginal position, the solidification width of the tack coat is 80-120um.
10. a kind of flexible display, it is characterised in that by the preparation method system of the flexible display of any one of claim 1-9 Form.
CN201610824637.1A 2016-09-14 2016-09-14 Flexible display and preparation method thereof Active CN106654055B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108807486A (en) * 2018-06-26 2018-11-13 武汉华星光电半导体显示技术有限公司 A kind of preparation method and display device of display panel
CN109475041A (en) * 2018-10-31 2019-03-15 上海奕瑞光电子科技股份有限公司 A kind of binding method of flexible parent metal display panel
CN109904106A (en) * 2019-02-28 2019-06-18 云谷(固安)科技有限公司 The preparation method of flexible display panels and flexible display panels

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103325731A (en) * 2013-05-20 2013-09-25 Tcl集团股份有限公司 Manufacturing method of flexible display device
CN103540269A (en) * 2013-08-27 2014-01-29 Tcl集团股份有限公司 Preparation method of ultraviolet light reversible glue and flexible display device
US20140042649A1 (en) * 2012-08-09 2014-02-13 Au Optronics Corporation Method for fabricating flexible display module
CN105024018A (en) * 2014-04-29 2015-11-04 Tcl集团股份有限公司 Flexible display and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140042649A1 (en) * 2012-08-09 2014-02-13 Au Optronics Corporation Method for fabricating flexible display module
CN103325731A (en) * 2013-05-20 2013-09-25 Tcl集团股份有限公司 Manufacturing method of flexible display device
CN103540269A (en) * 2013-08-27 2014-01-29 Tcl集团股份有限公司 Preparation method of ultraviolet light reversible glue and flexible display device
CN105024018A (en) * 2014-04-29 2015-11-04 Tcl集团股份有限公司 Flexible display and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108807486A (en) * 2018-06-26 2018-11-13 武汉华星光电半导体显示技术有限公司 A kind of preparation method and display device of display panel
CN108807486B (en) * 2018-06-26 2020-10-02 武汉华星光电半导体显示技术有限公司 Preparation method of display panel and display device
CN109475041A (en) * 2018-10-31 2019-03-15 上海奕瑞光电子科技股份有限公司 A kind of binding method of flexible parent metal display panel
CN109904106A (en) * 2019-02-28 2019-06-18 云谷(固安)科技有限公司 The preparation method of flexible display panels and flexible display panels

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Effective date of registration: 20201207

Address after: No.146 Tianying Road, high tech Zone, Chengdu, Sichuan Province

Patentee after: Chengdu CHENXIAN photoelectric Co.,Ltd.

Address before: 215300, No. 1, Longteng Road, Kunshan Development Zone, Jiangsu, Suzhou, 4

Patentee before: KunShan Go-Visionox Opto-Electronics Co.,Ltd.