CN106637981A - Oil emulsion capable of improving weaving efficiency of fiber yarns and method of improving weaving efficiency - Google Patents
Oil emulsion capable of improving weaving efficiency of fiber yarns and method of improving weaving efficiency Download PDFInfo
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- CN106637981A CN106637981A CN201611108986.XA CN201611108986A CN106637981A CN 106637981 A CN106637981 A CN 106637981A CN 201611108986 A CN201611108986 A CN 201611108986A CN 106637981 A CN106637981 A CN 106637981A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The invention relates to an oil emulsion capable of improving weaving efficiency of fibers and a method of improving weaving efficiency. The oil emulsion comprises non-water components and water, wherein the mass concentration of non-water components is 10 to 20%; the non-water component comprises 20 to 30 parts of modified polyvinyl alcohol with silyl, 6 to 10 parts of polysiloxane high-grade aliphatic ester, 0.5 to 1.5 parts of dimethylformamide, 5 to 6 parts of wood vinegar, 2 to 3 parts of antistatic agent, 0.5 to 2 parts of emulsified silicon oil, and 0.5 to 1.5 parts of DTY (draw texturing yarn) elasticity enhancing oil. The method comprises the following steps of spraying to fiber monofilament in the spooling process, or touching the oil emulsion to form an oil film. The oil emulsion capable of improving weaving efficiency of fibers and a method of improving weaving efficiency have the advantages that the weaving efficiency is obviously improved, the problem of crack of a warp shaft is solved, the waste is avoided, and the cost is reduced; the operation is simple, the equipment requirement is low, the cost is low, and the pollution to environment is little.
Description
Technical field
The present invention relates to a kind of finish emulsion and method for improving filament weaving efficiency.
Background technology
With fine industrial expansion is closed, the exploitation of product, the research of Artificial Silk is extremely urgent, because people are to clothing
And require more and more higher, in recent years real silk fabric demand is also increasing, but the in short supply of real silk raw material brings to Weaving Industry
Great threat, is to wait for rice to put in one's pan, or is separately found a way out, and this is the common issue that current Weaving Industry faces.Silk is produced
The research of product is optimal direction.Since claiming to Silk, the source of raw material is based on terylene naturally.To reach light and thin type
Silk broadcloth style, it is necessary to fine polyester filament is closed be to make an effort on fine denier filament.The fine denier filament applied on Silk at present has
75D/72F, 68D/48F and(20D-30D).
The Jing 50D/36F of Silk such as striped crepe de chine are applied at present, and latitude 75D/72F, monofilament is more, brings to weaving
Very big difficulty, particularly difficult is latitude 75D/72F, and fine denier filament needs high (strong) the sth. made by twisting processes of Jing(25.29T/cm.9000 rev/min),
Silk after taking traditional sizing technique to process, during twisted filament, lousiness, broken end are serious.Efficiency on twisting frame only 13-15%, causes
The significant wastage of raw material, while energy resource consumption is big, to woven strip very big difficulty is carried out.Additionally, sizing technique also there are problems that it is a lot,
One is, need to adopt large-scale device for sizing, and equipment is complicated, and air pollution and contaminated wastewater are serious;Two are, starching amount needs 4% ~ 8%,
Desizing difficulty is big;Three are, organizine roller made by after starching PFY starching has more than 20% ~ 40% to cause to split axle, if
Do not process it is appropriate will scrap, cause serious commercial to waste, and bring pollution, increase production cost.
In order to solve many phenomenons of lousiness, broken end, improve efficiency, before we had once inquired into this process route that oils,
Start first with finish applications such as polyamide fibre oil, silicone emulsions.But the effect of finish is only to increase flatness, the collection to 72 monofilament
Shu Zuoyong is less, inefficient therefore still undesirable.
The content of the invention
Problem to be solved by this invention is to overcome the deficiencies in the prior art to provide one kind to improve filament weaving efficiency
With solve the problems, such as that warp beam splits the finish emulsion and method of axle.
To solve above technical problem, one aspect of the present invention provides a kind of finish breast for improving filament weaving efficiency
Liquid, the finish emulsion is made up of nonaqueous component and water, and the mass concentration of the nonaqueous component is 10% ~ 20%, in parts by weight,
The nonaqueous component includes following component:20 ~ 30 parts of modified polyvinyl alcohol with silicyl;Polysiloxanes higher aliphatic
6 ~ 10 parts of acid esters;0.5 ~ 1.5 part of dimethylformamide;5 ~ 6 parts of wooden vinegar;2 ~ 3 parts of antistatic additive;0.5 ~ 2 part of silicone emulsion;
0.5 ~ 1.5 part of DTY texturing oils.
Preferably, the nonaqueous component is included:20 ~ 25 parts of modified polyvinyl alcohol with silicyl;Polysiloxanes is high
7 ~ 8 parts of fatty acid ester of level;0.8 ~ 1.2 part of dimethylformamide;5 ~ 6 parts of wooden vinegar;2.5 ~ 3 parts of antistatic additive;Silicone emulsion 1
~ 1.5 parts;0.8 ~ 1 part of DTY texturing oils.
According to the present invention, the modified polyvinyl alcohol with silicyl can be obtained by saponified ethylene ester based polymer
's.Saponification degree is generally with 70 ~ 100 moles of % scopes.Wherein the modified polyvinyl alcohol with silicyl is by vinyl alcohol units and spreads out
The unit for being conigenous monomer (a) is constituted, and the degree of polymerization is usually 10 ~ 3000.
For the vinyl acetate system monomer used in the manufacture of vinyl ester polymer, it is not particularly limited, but can
Enumerate:Vinyl formate, vinyl acetate, oxalic acid vinyl acetate, propionate, vinyl butyrate, vinyl isobutyrate ester, front three
It is vinyl acetate, tertiary ethylene carbonate, vinyl caproate, sad vinyl acetate, vinyl laurate, vinyl palmitate, hard
Resin acid vinyl acetate, oleic acid vinyl acetate, vinyl benzoate etc..Wherein, from the economic preferred vinyl acetate of viewpoint.
At least a kind monomer of the above-mentioned monomer (a) in the silyl compound with unsaturated double-bond.
For the above-mentioned silyl compound with unsaturated double-bond, can enumerate vinyltrimethoxy silane,
Compound containing unsaturated double-bond and trialkoxysilyl such as VTES etc..Wherein preferred vinyl
Trimethoxy silane.
For the containing ratio of the unit derived from monomer (a) in vinyl ester polymer, based on composition vinyl acetate system
The molal quantity of whole monomeric units of polymer, common content is 0.01 ~ 10 mole of %, with 0.02 ~ 5 mole of % preferably, 0.05 ~
2 moles of % are it is further preferred that 0.1 ~ 1 mole of % is further preferred.
According to the present invention, the method for saponification is known, can be implemented using conventional meanses, such as first by above-mentioned second
Alkene ester system's monomer and monomer (a) carry out copolymerization with radical initiator, and being subsequently adding alkali makes EVA saponification.
According to the present invention, the modified polyvinyl alcohol with silicyl can also be by using silication agent is to polyvinyl alcohol or contains
The modified polyvinyl alcohol for having hydroxyl carries out denaturation and introduces silicyl acquisition.
One of the invention concrete and preferred aspect, the modified polyvinyl alcohol with silicyl is acetic acid second
Allyl ester monomer and vinyltrimethoxy silane monomer copolymer Jing saponification are obtained.
Preferably, polysiloxanes high-grade aliphatic ester is dimethyl silicone polymer stearate.
Preferably, the silicone emulsion is Simethicone.
Preferably, the mass concentration of the nonaqueous component is 15% ~ 20%.
Preferably, the wooden vinegar is lemon vinegar.
According to the present invention, the DTY texturing oils can be not particularly limited using those common on market.But it is excellent
Choosing adopts DTY texturing oils as described below of the invention.
According to the present invention, DTY texturing oils by base oil 88% ~ 91%, emulsifier op-4 3.5% ~ 5%, benzene sulfonic acid 1.5% ~
2%th, triethanolamine 0.8% ~ 2% and oleic acid 1.8% ~ 3% are constituted, wherein base oil by No. 5 machine oil and No. 15 machine oil in mass ratio 8 ~
10:1 composition.The synergy of the finish and the modified polyvinyl alcohol with silicyl is taken, hair is effectively solved
Silk, broken end, warp beam split axle problem, greatly improve weaving efficiency.
According to the present invention, described antistatic additive is preferably PK antistatic additive, specifically such as MOA3PK-40.
Further, the finish emulsion can in proportion be mixed by the component.
Second aspect present invention provides a kind of method for improving filament weaving efficiency, and the method includes the step that oils:It is logical
Cross during winder and to spray on fibre single thread or contact finish emulsion as above to form oil film.
Preferably, oil applying rate is controlled for 0.2wt% ~ 0.5wt%.It is highly preferred that controlling oil applying rate for 0.2wt% ~ 0.25wt%.
A specific aspect of the invention, the filament of the present invention is Silk fine denier filament.
Because above-mentioned technical proposal is used, the present invention has compared with prior art following advantages:
Weaved using the finish emulsion and silk method for weaving of the present invention, during twisted filament, lousiness, breakage phenomena are significantly changed
It is kind, significantly improve weaving efficiency(Reach more than 90%), and solve the problems, such as that warp beam splits axle(Only 1% ~ 2% splits axle), it is to avoid wave
Take, reduces cost.Additionally, the inventive method is simple to operate, equipment requirement is low, and low cost, environmental pollution is little.Without the need for specially arranging
Desizing operation, the oil film formed on silk in the dyeing course and water-washing process after fabric is weaved into will be effectively removed.
Specific embodiment
The present invention provides a kind of finish emulsion for being remarkably improved a weaving efficiency, and the emulsion can be by spray pump or food tray
Oil, the optimum concentration of emulsion is 15-20%.To POY dacron threads should the amount of water conservation, therefore typically using the concentration of 18-20%.
Based on fibre weight, suitable oil applying rate is 0.2-0.5% solids(Oiled with 18% aqueous emulsion).
When being oiled using food tray, the concentration range of emulsion should be 15-20%, and when using spray oiling machine, should using 18% ~
20% emulsion.Finish can splash or shed at anti-food tray, in order to avoid cause at the traveller in front of volume small item given away free traversing device
Filament breakage.
The finish emulsion of the present invention has successfully been used in new-type dwarf forms false twisting machine of the speed more than 700 ms/min.Do not exist
Deposition residues in heating plate.On spindle type false twisting machine and friction-type false twisting machine, any resistance, Ke Yishun are not added with during sth. made by twisting
Profit unwinding, the monofilament after boundling stands 25.29T/cm and twists with the fingers high(By force)The environment of sth. made by twisting process, using good.
The employing of the finish emulsion of the present invention, can replace traditional sizing technique and desizing, and make the effect of twisting frame
Rate rises to more than 90% from less than less than 15%, complies fully with technological requirement.Silk using finish of the present invention is without the need for specially arranging
Desizing operation, will be effectively removed in the dyeing course and water-washing process after fabric is weaved into.
Below in conjunction with specific embodiment, the present invention will be further described in detail, but the invention is not restricted to following reality
Apply example.
In the present invention when not clearly stating, " % " or " percentage " for representing content is weight percentage content.Below
In embodiment, not marked experiment condition is conventional experiment condition.Used raw material is by commercially available.
Embodiment 1
The present invention provides a kind of finish emulsion for improving filament weaving efficiency, in parts by weight, non-aqueous in the finish emulsion
Concentration of component is for about 20%, and water content is for about 80%.
In parts by weight, nonaqueous component is included:23 parts of modified polyvinyl alcohol with silicyl;Polysiloxanes is senior
7.5 parts of fatty acid ester;1 part of dimethylformamide;5.5 parts of wooden vinegar;2.8 parts of MOA3PK-40 antistatic additive;Silicone emulsion
1.2 part;0.8 part of DTY texturing oils, wherein the modified polyvinyl alcohol with silicyl is vinyl acetate monomer and ethene
Base trimethoxy silane monomer copolymer Jing saponification is obtained(Purchased from Shanghai auxiliary reagent factory), wherein wooden vinegar is lemon vinegar, wherein DTY adds
Finish is played by base oil 89.7%, emulsifier op-4 4.13%, 2.15% group of benzene sulfonic acid 1.79%, triethanolamine 0.95% and oleic acid
Into wherein base oil is by No. 5 machine oil and No. 15 machine oil in mass ratio 9:1 composition.
This example finish emulsion can be mixed to prepare with water by said components below 40 DEG C, and outward appearance is in weak yellow liquid(30
℃), pH is 6 ~ 6.5.
Embodiment 2
The present invention provides a kind of finish emulsion for improving filament weaving efficiency, its nonaqueous component concentration about 15%, and water content is
About 85%, the ratio for constituting each composition of nonaqueous component is as follows, 20 parts of the modified polyvinyl alcohol with silicyl;Polysiloxanes
7 parts of high-grade aliphatic ester;1 part of dimethylformamide;5.5 parts of wooden vinegar;2.8 parts of MOA3PK-40 antistatic additive;Silicone emulsion
1.2 part;0.8 part of DTY texturing oils.Each composition is with embodiment 1.
This example finish emulsion can be mixed to prepare with water by said components below 40 DEG C, and outward appearance is in weak yellow liquid(30
℃), pH is 6 ~ 6.5.
Embodiment 3
This example provides the test of the finish emulsion in weaving using embodiment 2.
When 150 denier/34 piece POY long filaments are produced, spinning winding speed is 3600 ms/min, without draw-off godet, in bobbin-winding machine
On, oiled using the single food tray with ceramic cap, preliminary test is carried out using following condition:
Oiling roller rotating speed:12 revs/min
Roller diameter:200 millimeters
Through the long filament that oils in frictional disk false twisting and spindle false twisting process, high-speed winder is made(3600 ms/min)And friction
Texturing machine operating is smooth, and with following characteristic:
1st, can be to obtain 12-13 kilogram of the high-quality package of weighing under 3600 ms/min of winding speed, without causing " spider web
Silk ", " turned-down edge " or other winding defects, nothing splits axle problem.
, prevent oiling roller oil agent " splash " or " " shedding ", thus avoid long filament before winding head traversing device
Disconnect on traveller.
, on new-type short deformation equipment application success, speed can be more than 700 ms/min.
Above-described embodiment technology design only to illustrate the invention and feature, its object is to allow person skilled in the art's energy
Solution present disclosure much of that is simultaneously implemented according to this, can not be limited the scope of the invention with this, all according to spirit of the invention
Equivalence changes or modification that essence is made, all should be included within the scope of the present invention.
Claims (10)
1. a kind of finish emulsion for improving filament weaving efficiency, it is characterised in that the finish emulsion by nonaqueous component and
Water is constituted, and the mass concentration of the nonaqueous component is 10% ~ 20%, and in parts by weight, the nonaqueous component includes following component:
20 ~ 30 parts of modified polyvinyl alcohol with silicyl;6 ~ 10 parts of polysiloxanes high-grade aliphatic ester;Dimethylformamide
0.5 ~ 1.5 part;5 ~ 6 parts of wooden vinegar;2 ~ 3 parts of antistatic additive;0.5 ~ 2 part of silicone emulsion;0.5 ~ 1.5 part of DTY texturing oils.
2. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that described non-aqueous group
Subpackage contains:20 ~ 25 parts of modified polyvinyl alcohol with silicyl;7 ~ 8 parts of polysiloxanes high-grade aliphatic ester;Dimethyl methyl
0.8 ~ 1.2 part of acid amides;5 ~ 6 parts of wooden vinegar;2.5 ~ 3 parts of antistatic additive;1 ~ 1.5 part of silicone emulsion;DTY texturing oils 0.8 ~ 1
Part.
3. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that described with first
The modified polyvinyl alcohol of silylation is that vinyl acetate monomer and vinyltrimethoxy silane monomer copolymer Jing saponification are obtained.
4. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that polysiloxanes is high
Level fatty acid ester is dimethyl silicone polymer stearate.
5. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that the emulsification silicon
Oil is Simethicone.
6. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that described non-aqueous group
The mass concentration divided is 15% ~ 20%.
7. the finish emulsion for improving filament weaving efficiency according to claim 1, it is characterised in that with quality percentage
Content meter, the DTY texturing oils are by base oil 88% ~ 91%, emulsifier op-4 3.5% ~ 5%, benzene sulfonic acid 1.5% ~ 2%, three ethanol
Amine 0.8% ~ 2% and oleic acid 1.8% ~ 3% are constituted, and wherein base oil is by No. 5 machine oil and No. 15 machine oil in mass ratio 8 ~ 10:1 composition.
8. it is a kind of improve filament weaving efficiency method, it is characterised in that:The method includes the step that oils:By in winder mistake
Spray on fibre single thread in journey or contact finish emulsion as described in any one of claim 1 to 7 claim to be formed
Oil film.
9. it is according to claim 8 improve filament weaving efficiency method, it is characterised in that:Controlling oil applying rate is
0.2wt%~0.5wt%。
10. it is according to claim 8 improve filament weaving efficiency method, it is characterised in that:The filament is imitative
Real silk fine denier filament.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59187677A (en) * | 1983-04-05 | 1984-10-24 | 株式会社クラレ | Warp yarn size agent for water jet loom |
CN1354189A (en) * | 2001-12-05 | 2002-06-19 | 中国化工建设总公司常州涂料化工研究院 | Stable organosilicon modified copolymer emulsion and its preparation method |
EP1339018A1 (en) * | 2000-11-30 | 2003-08-27 | Canon Kabushiki Kaisha | Image processing device, image processing method, recording medium and program |
CN1663973A (en) * | 2004-03-05 | 2005-09-07 | 日本合成化学工业株式会社 | Aqueous emulsion and uses thereof |
CN1887921A (en) * | 2006-06-08 | 2007-01-03 | 武汉大学 | High performance organo-silicon modified vinyl acetate emulsion and its prepn |
CN103469571A (en) * | 2013-09-16 | 2013-12-25 | 天津工大纺织助剂有限公司 | Water-soluble vinylon oiling agent and preparation method thereof |
-
2016
- 2016-12-06 CN CN201611108986.XA patent/CN106637981B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59187677A (en) * | 1983-04-05 | 1984-10-24 | 株式会社クラレ | Warp yarn size agent for water jet loom |
EP1339018A1 (en) * | 2000-11-30 | 2003-08-27 | Canon Kabushiki Kaisha | Image processing device, image processing method, recording medium and program |
CN1354189A (en) * | 2001-12-05 | 2002-06-19 | 中国化工建设总公司常州涂料化工研究院 | Stable organosilicon modified copolymer emulsion and its preparation method |
CN1663973A (en) * | 2004-03-05 | 2005-09-07 | 日本合成化学工业株式会社 | Aqueous emulsion and uses thereof |
CN1887921A (en) * | 2006-06-08 | 2007-01-03 | 武汉大学 | High performance organo-silicon modified vinyl acetate emulsion and its prepn |
CN103469571A (en) * | 2013-09-16 | 2013-12-25 | 天津工大纺织助剂有限公司 | Water-soluble vinylon oiling agent and preparation method thereof |
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