CN106637920A - Hardness adjusting method and application of fiber cloth - Google Patents
Hardness adjusting method and application of fiber cloth Download PDFInfo
- Publication number
- CN106637920A CN106637920A CN201611202485.8A CN201611202485A CN106637920A CN 106637920 A CN106637920 A CN 106637920A CN 201611202485 A CN201611202485 A CN 201611202485A CN 106637920 A CN106637920 A CN 106637920A
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- Prior art keywords
- fiber cloth
- hardness
- parts
- agent
- adjustment
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 239000000835 fiber Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000003292 glue Substances 0.000 claims abstract description 18
- 239000013543 active substance Substances 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004073 vulcanization Methods 0.000 claims abstract description 9
- 239000012948 isocyanate Substances 0.000 claims abstract description 8
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
- 239000011230 binding agent Substances 0.000 claims description 17
- 230000001680 brushing effect Effects 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 12
- 239000002105 nanoparticle Substances 0.000 claims description 12
- 230000002787 reinforcement Effects 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 11
- 239000004014 plasticizer Substances 0.000 claims description 11
- 239000006229 carbon black Substances 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims description 8
- 239000005062 Polybutadiene Substances 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 229920002857 polybutadiene Polymers 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 7
- 238000004026 adhesive bonding Methods 0.000 claims description 7
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- 239000006238 High Abrasion Furnace Substances 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 239000002174 Styrene-butadiene Substances 0.000 claims description 5
- 239000011115 styrene butadiene Substances 0.000 claims description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 4
- 238000004513 sizing Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 16
- 239000005060 rubber Substances 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract 3
- 230000001070 adhesive effect Effects 0.000 abstract 3
- 239000012528 membrane Substances 0.000 abstract 3
- 230000032683 aging Effects 0.000 abstract 1
- 239000012763 reinforcing filler Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
-
- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/438—Sulfonamides ; Sulfamic acids
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Diaphragms And Bellows (AREA)
Abstract
The invention relates to a hardness adjusting method and application field of a fiber cloth, which is particularly applied to the manufacturing of a water pump membrane. The hardness adjusting method is realized through the step that hardness adjusting glue is coated on the surface of the fiber cloth, wherein the hardness adjusting glue is made by mixing 90-110 parts of polymer, 90-110 parts of a reinforcing filler agent, 2.5-4 parts of an aging resister, 30-40 parts of a plastifier, 5-7 parts of a novel environmentally-friendly adhesive, 4-5.5 parts of a nanometer active agent and 4-6 parts of a vulcanization system, and the fiber cloth having the adjusted hardness can be used for manufacturing the water pump membrane. According to the hardness adjusting method disclosed by the invention, the flexibility and the hardness of the fiber cloth manufactured by the hardness adjusting method disclosed by the invention are well controlled; the hardness of the manufactured water pump membrane is effectively controlled and is stabilized within a required range; the adhesive force between rubber materials and the fiber cloth is also improved, and the cohesive force is greater than 150N/cm; the problem that the fiber is hardened caused by only coating an isocyanate adhesive is solved; and the control problem of the production technology brought by only adjusting rubber hardness is also further solved.
Description
Technical field
The present invention relates to fiber cloth hardness method of adjustment and application, are specifically for use in the making of water pump barrier film.
Background technology
Existing barrier film is made up of metal, rubber, fiber cloth, and sheet metal is contacted with regulating bolt, and sheet metal is in barrier film
Effect is:Increase and the contact area of rubber, reduce and adjust pressure and protect rubber diaphragm;Fiber cloth rise in diaphragm enhancing every
Film fatigability, the edge seal of diaphragm of rubber is fixed on valve body, and the effect of diaphragm of rubber is:Hydraulic pressure increases and valve is closed,
Hydraulic pressure reduces and valve is opened, and carries out Flow-rate adjustment.
In use the hardness of diaphragm of rubber is exchanged amount of restriction and is played a crucial role, and hardness is higher, and low pressure flow can not be adjusted;
Conversely, high pressure flow can not be adjusted.With this understanding, the integral hardness for adjusting control diaphragm of rubber is for key.Diaphragm of rubber
Hardness in addition to being affected by rubber compounding, rubber process, between the jelly that fiber cloth is brushed with it bond hardness be associated, because
And, how to adjust fiber cloth hardness then becomes the problem of industry concern, so as to lift water pump barrier film quality.
The content of the invention
In view of this, it is an object of the invention to provide a kind of fiber cloth hardness method of adjustment and application, it is convenient to draw materials, operation
It is easily controlled, the pliability of fiber cloth, hardness is also well controlled, the barrier film hardness stabilization of making causes valve body flow
Stable control is obtained in use.
To reach above-mentioned purpose, what the present invention was achieved through the following technical solutions:
A kind of fiber cloth hardness method of adjustment, in fiber cloth surface hardness adjustment glue is coated with, and the hardness adjustment glue is adopted to be used in combination
Polymer, reinforcement and filler body agent, anti-old body agent, plasticizer, novel environment friendly binder, nanoparticle active agent and vulcanizing system mixing system
Obtain.
In such scheme, the weight of each component of the hardness adjustment glue is:And with 90 ~ 110 parts of polymer, reinforcement and filler
90 ~ 110 parts of body agent, anti-2.5 ~ 4 parts of old body agent, 30 ~ 40 parts of plasticizer, 5 ~ 7 parts of novel environment friendly binder, nanoparticle active agent 4 ~
5.5 parts, 4 ~ 6 parts of vulcanizing system;When mixing makes, first will and with polymer on a mill chilling roller it is thin it is logical plasticate, Ran Hou
Banburying in ratcheting type banbury, addition reinforcement and filler body agent, anti-old body agent, novel environment friendly binder, nanoparticle active agent, treats agglomerating
After add plasticizer, then add vulcanizing system on a mill, it is thin it is logical plasticate, plasticity goes out on a mill up to more than 0.60
Flakiness, is put in the container for filling toluene, is ceaselessly stirred with agitator, can use after sizing material is completely dissolved, you can brush
In fiber cloth.
In such scheme, it is described and with polymer include ABS, polybutadiene and styrene-butadiene, its
The weight ratio of middle ABS, polybutadiene and styrene-butadiene is 7:2:1.
In such scheme, reinforcement and filler body agent includes white carbon, high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black N774,
The weight ratio of wherein white carbon, high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black N774 is 1:5:4.
It is described to prevent that old body agent includes antioxidant 4010NA and age resistor TMQ in such scheme, wherein antioxidant 4010NA and
The weight ratio of age resistor TMQ is 2:1.
In such scheme, the vulcanizing system includes stearic acid, insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and rush
Enter agent DM, the weight ratio of wherein stearic acid, insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and altax is 1:1.2:2:
0.5:0.3.
In such scheme, the novel environment friendly binder is novel environment friendly binder PN759.
In such scheme, the nanoparticle active agent is nano zine oxide.
In such scheme, be set forth in fiber cloth surface be coated with hardness adjustment glue step it is as follows:
Firstth, fiber cloth is processed, and is cleaned with toluene, go under the class material that degreases, natural temperature to dry more than 2 hours it is stand-by;
Secondth, again in the fiber cloth dried, the hardness adjustment glue for just having prepared is brushed, THICKNESS CONTROL treats fiber at 5~10 μm
After cloth upper surface is dry, brush lower surface is overturn, dried under natural temperature, pollution must be prevented during brushing;
3rd, after brush coating pulp fibres cloth dries, then brushing isocyanates gluing agent, THICKNESS CONTROL is treated at 5~10 μm
After surface is dried, brush lower surface is overturn, dried in natural temperature, pollution must be prevented during brushing.
Application after the adjustment of fiber cloth hardness, the fiber cloth of hardness will be adjusted by the method for the claims 1 ~ 9
Make water pump barrier film.
Using such scheme, the pliability of fiber cloth, hardness is well controlled, the water pump barrier film stiffness of making
It is controlled effectively, it is stable in the range of the alignment request of shore 50 ± 3, also improve the adhesion strength of rubber mass and fiber cloth, bonding
Power is more than 150N/cm, solves the problems, such as that single painting isocyanates gluing agent causes fiber hardening, but also further solves only
Only adjust the control problem that rubber hardness brings to production technology.
Specific embodiment:
A kind of relevant fiber cloth hardness method of adjustment of the present invention, it is to be coated with hardness adjustment glue, the hardness on fiber cloth surface
Adjustment glue using and with polymer, reinforcement and filler body agent, prevent old body agent, plasticizer, novel environment friendly binder, nanoparticle active agent and
Vulcanizing system mixing makes and obtains.The hardness adjusts the weight of each component of glue:And with 100 parts of polymer, reinforcement and filler
90 ~ 110 parts of body agent, anti-2.5 ~ 4 parts of old body agent, 30 ~ 40 parts of plasticizer, 5 ~ 7 parts of novel environment friendly binder, nanoparticle active agent 4 ~
5.5 parts, 4 ~ 6 parts of vulcanizing system;When mixing makes, first will and with polymer on a mill chilling roller it is thin it is logical plasticate, Ran Hou
Banburying in ratcheting type banbury, addition reinforcement and filler body agent, anti-old body agent, novel environment friendly binder, nanoparticle active agent, treats agglomerating
After add plasticizer, then add vulcanizing system on a mill, it is thin it is logical plasticate, plasticity goes out on a mill up to more than 0.60
Flakiness, is put in the container for filling toluene, is ceaselessly stirred with agitator, can use after sizing material is completely dissolved, you can brush
In fiber cloth.
It is described and with polymer include ABS, polybutadiene and styrene-butadiene, wherein propylene it is fine-fourth
The weight ratio of diene, polybutadiene and styrene-butadiene is 7:2:1.
Reinforcement and filler body agent include white carbon, high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black N774, wherein white carbon,
The weight ratio of high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black N774 is 1:5:4.
It is described to prevent that old body agent includes antioxidant 4010NA and age resistor TMQ, wherein antioxidant 4010NA and age resistor TMQ
Weight ratio is 2:1.
The vulcanizing system includes stearic acid, insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and altax, wherein
The weight ratio of stearic acid, insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and altax is 1:1.2:2:0.5:0.3.
The novel environment friendly binder is novel environment friendly binder PN759.
The nanoparticle active agent is nano zine oxide.
It is as follows that be set forth in fiber cloth surface is coated with hardness adjustment glue step:
Firstth, fiber cloth is processed, and is cleaned with toluene, go under the class material that degreases, natural temperature to dry more than 2 hours it is stand-by;
Secondth, again in the fiber cloth dried, the hardness adjustment glue for just having prepared is brushed, THICKNESS CONTROL treats fiber at 5~10 μm
After cloth upper surface is dry, brush lower surface is overturn, dried under natural temperature, pollution must be prevented during brushing;
3rd, after brush coating pulp fibres cloth dries, then brushing isocyanates gluing agent, THICKNESS CONTROL is treated at 5~10 μm
After surface is dried, brush lower surface is overturn, dried in natural temperature, pollution must be prevented during brushing.
Embodiment:
Following material, ABS are taken by weight:70 parts, polybutadiene:20 parts, styrene-butadiene:10 parts, in vain
Carbon black:10 parts, high wear-resistant carbon black:48 parts, semi-reinforcing hydrocarbon black:42 parts, plasticizer:35 parts, nano zine oxide:5 parts, stearic acid:1
Part, antioxidant 4010NA:2 parts, age resistor TMQ:1 part, novel environment friendly binder PN759:6 parts, insoluble sulfur: 1.2
Part, accelerator CBS:2 parts, Vulcanization accelerator TMTD:0.5 part, altax:0.3 part.By ABS, polybutadiene, benzene
Ethylene-butylene on a mill chilling roller it is thin it is logical plasticate, the then banburying in ratcheting type banbury is addition high wear-resistant carbon black, white
Carbon black, semi-reinforcing hydrocarbon black, nano zine oxide, stearic acid, antioxidant 4010NA, age resistor TMQ, novel environment friendly binder PN759,
Add plasticizer after agglomerating.Add insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and altax on a mill again,
It is thin it is logical plasticate, plasticity is up to more than 0.60.Go out flakiness on a mill, be put in the container for filling toluene, for the ease of stirring
Mix, fill with the 2/3 of whole container.Ceaselessly stirred with agitator, be can use after sizing material is completely dissolved, you can brushed.
In the present embodiment, the fiber cloth that hardness is adjusted as stated above is made into water pump barrier film.Fiber cloth is clear with toluene
Wash, go under the class material that degreases, natural temperature to dry stand-by.Again in the fiber cloth for drying more than 2 hours cleaned with toluene
On, the rubber cement for just having prepared is brushed, THICKNESS CONTROL after fiber cloth upper surface is dry, overturns brush lower surface, certainly at 5~10 μm
So dry at temperature, pollution must be prevented during brushing.After brush coating pulp fibres cloth dries, then brushing isocyanates gluing
Agent(The isocyanates gluing agent is 1 by dilution ratio with toluene:3 mode is used after diluting), THICKNESS CONTROL at 5~10 μm,
After upper surface is dried, brush lower surface is overturn, dried in natural temperature, pollution must be prevented during brushing.Fiber cloth after process
Dry, then required form is cut into cut-off knife, size matches with mould.Upper and lower two panels glue, centre is the fiber cloth for cutting out size,
Mould is put into, is vulcanized by technique is demarcated.Finally product is pruned, is carried out with the sheet metal for coating bonding agent hot sticky
Connect, you can obtain water pump barrier film.The hard softness of gained barrier film is controlled effectively, stable in the alignment request scope of shore 50 ± 3
It is interior, the adhesion strength of rubber mass and fiber cloth is also improved, cohesive force is more than 150N/cm.Also solve single painting isocyanates gluing
Agent causes the problem of fiber hardening, but also further solves, the control that simple condition rubber hardness brings to production technology
Problem.
Above example is only unrestricted to illustrate technical scheme, although with reference to preferred embodiment to this
It is bright to be described in detail, it will be understood by those within the art that, can to invent technical scheme modify or
Person's equivalent and ratio are adjusted, and without deviating from the objective and scope of this technology case, it all should cover will in right of the invention
Ask in the middle of scope.
Claims (10)
1. a kind of fiber cloth hardness method of adjustment, it is characterised in that:Hardness adjustment glue is coated with fiber cloth surface, the hardness is adjusted
Whole glue using and with polymer, reinforcement and filler body agent, anti-old body agent, plasticizer, novel environment friendly binder, nanoparticle active agent and sulphur
The mixing of change system makes and obtains.
2. a kind of fiber cloth hardness method of adjustment according to claim 1, it is characterised in that:The hardness adjusts each of glue
The weight of component is:And with 100 parts of polymer, 90 ~ 110 parts of reinforcement and filler body agent, anti-2.5 ~ 4 parts of old body agent, plasticizer 30 ~ 40
Part, 5 ~ 7 parts of novel environment friendly binder, 4 ~ 5.5 parts of nanoparticle active agent, 4 ~ 6 parts of vulcanizing system;When mixing makes, will be used in combination first
Polymer on a mill chilling roller it is thin it is logical plasticate, the then banburying in ratcheting type banbury, prevents old body at addition reinforcement and filler body agent
Agent, novel environment friendly binder, nanoparticle active agent, add plasticizer after agglomerating, then add vulcanizing system, Bao Tong on a mill
Plasticate, plasticity goes out on a mill flakiness up to more than 0.60, is put in the container for filling toluene, with agitator ceaselessly
Stirring, can use, you can brush in fiber cloth after sizing material is completely dissolved.
3. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:It is described and included with polymer
ABS, polybutadiene and styrene-butadiene, wherein ABS, polybutadiene and styrene-fourth two
The weight ratio of alkene is 7:2:1.
4. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:The reinforcement and filler body agent bag
Containing white carbon, high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black N774, wherein white carbon, high abrasion furnace carbon black N330 and semi-reinforcing hydrocarbon black
The weight ratio of N774 is 1:5:4.
5. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:It is described to prevent old body agent comprising anti-
The weight ratio of old agent 4010NA and age resistor TMQ, wherein antioxidant 4010NA and age resistor TMQ is 2:1.
6. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:The vulcanizing system is comprising hard
Resin acid, insoluble sulfur, accelerator CBS, Vulcanization accelerator TMTD and altax, wherein stearic acid, insoluble sulfur, accelerator
The weight ratio of CBS, Vulcanization accelerator TMTD and altax is 1:1.2:2:0.5:0.3.
7. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:The novel environment friendly binder
It is novel environment friendly binder PN759.
8. a kind of fiber cloth hardness method of adjustment according to claim 2, it is characterised in that:The nanoparticle active agent is to receive
Rice zinc oxide.
9. a kind of fiber cloth hardness method of adjustment according to claim 1, it is characterised in that:Be set forth in fiber cloth surface applies
It is furnished with hardness adjustment glue step as follows:
Firstth, fiber cloth is processed, and is cleaned with toluene, go under the class material that degreases, natural temperature to dry more than 2 hours it is stand-by;
Secondth, again in the fiber cloth dried, the hardness adjustment glue for just having prepared is brushed, THICKNESS CONTROL treats fiber at 5~10 μm
After cloth upper surface is dry, brush lower surface is overturn, dried under natural temperature, pollution must be prevented during brushing;
3rd, after brush coating pulp fibres cloth dries, then brushing isocyanates gluing agent, THICKNESS CONTROL is treated at 5~10 μm
After surface is dried, brush lower surface is overturn, dried in natural temperature, pollution must be prevented during brushing.
10. the application after the adjustment of fiber cloth hardness, it is characterised in that:Hardness will be adjusted by the method for the claims 1 ~ 9
Fiber cloth make water pump barrier film.
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JP2005350793A (en) * | 2004-06-09 | 2005-12-22 | Teijin Techno Products Ltd | Method for producing fiber for reinforcing rubber |
CN103264866A (en) * | 2013-05-31 | 2013-08-28 | 浙江东南橡胶机带有限公司 | High-temperature-resisting aramid fiber conveyer belt and preparation technology thereof |
CN104829880A (en) * | 2015-05-13 | 2015-08-12 | 无锡宝通带业股份有限公司 | Rubber for fabric core laminated flame-retardant conveyor belt covering layer and preparation method thereof |
CN106010370A (en) * | 2016-07-06 | 2016-10-12 | 无锡宝通科技股份有限公司 | Canvas core thermal insulation conveying belt adhesive layer rubber material and preparation method thereof |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005350793A (en) * | 2004-06-09 | 2005-12-22 | Teijin Techno Products Ltd | Method for producing fiber for reinforcing rubber |
CN103264866A (en) * | 2013-05-31 | 2013-08-28 | 浙江东南橡胶机带有限公司 | High-temperature-resisting aramid fiber conveyer belt and preparation technology thereof |
CN104829880A (en) * | 2015-05-13 | 2015-08-12 | 无锡宝通带业股份有限公司 | Rubber for fabric core laminated flame-retardant conveyor belt covering layer and preparation method thereof |
CN106010370A (en) * | 2016-07-06 | 2016-10-12 | 无锡宝通科技股份有限公司 | Canvas core thermal insulation conveying belt adhesive layer rubber material and preparation method thereof |
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