CN106637914A - Preparation method of antibacterial health-care fiber or textile - Google Patents

Preparation method of antibacterial health-care fiber or textile Download PDF

Info

Publication number
CN106637914A
CN106637914A CN201710010867.9A CN201710010867A CN106637914A CN 106637914 A CN106637914 A CN 106637914A CN 201710010867 A CN201710010867 A CN 201710010867A CN 106637914 A CN106637914 A CN 106637914A
Authority
CN
China
Prior art keywords
fiber
fabric
textile
preparation
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710010867.9A
Other languages
Chinese (zh)
Inventor
高斌
王建勋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Penglai City Hong Xingran Industry Co Ltd
Original Assignee
Penglai City Hong Xingran Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Penglai City Hong Xingran Industry Co Ltd filed Critical Penglai City Hong Xingran Industry Co Ltd
Priority to CN201710010867.9A priority Critical patent/CN106637914A/en
Publication of CN106637914A publication Critical patent/CN106637914A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides

Abstract

The invention belongs to the technical field of fiber modification and in particular relates to a preparation method of an antibacterial health-care fiber or textile. According to the preparation method, a chemical cross-linking method is adopted and needed metal elements are subjected to cross-linking grafting in a compound form with active groups in the fiber or the textile under the action of a solvent and a catalyst, so as to form stable chemical bonds; the fiber or the textile contains such metal ions, so that the fiber or the textile has an antibacterial health-care function; inherent characteristics of the fiber or the textile are not changed, and the prepared fiber or textile is checked and has a sterilization effect, which is more than 98 percent, on escherichia coli, staphylococcus aureus and candida.

Description

A kind of preparation method of antiseptic health care fiber or fabric
Technical field
The invention belongs to fiber technical field of improvement, more particularly to the preparation method of a kind of antiseptic health care fiber or fabric.
Background technology
Antiseptic health care fiber or fabric are that each developed country is all in input at present in the world using increasingly extensive new varieties Huge fund is researched and developed and applied.But because technical threshold is higher, cause the antiseptic health care fiber applied on the market and fabric most It is to be obtained by following two methods：One is dipping absorption method；Two is to add superfines to be blended in fibre-forming material before spinning Spinning.Above two method is all physical method, and the shortcoming of physical method is：1st, with the increase of washing times, fiber is caused And the health-care efficacy of fabric is gradually in nothing；2nd, dosing admixture of powder spinning can be affected by amount of filling and be dropped low-fiber softness The performances such as property, intensity, and the good copper compound of antibiotic health care performance is cannot to obtain superfine powder with practical value at this stage End.
The content of the invention
A kind of deficiency that the present invention exists for above-mentioned prior art, there is provided the preparation side of antiseptic health care fiber or fabric Method.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of preparation side of antiseptic health care fiber or fabric Method, step is as follows：
(1) dye liquor is prepared：Metallic compound, initiator, bleeding agent and solvent are mixed to prepare into dye liquor, wherein the metal The concentration of compound is 0.5-10wt%, and the concentration of the initiator is 0.5-3wt%, and the concentration of the bleeding agent is 0.5- 3wt%, balance of solvent；
(2) by the dye liquor of step (1) and fiber or fabric according to (4-10)：In 1 bath raio input dyeing and finishing kettle, in 85-140 Cross-linked graft under the conditions of DEG C, is incubated 10-100min, after cleaned, dehydration, drying, antiseptic health care fiber or fabric is obtained；
Wherein, described metallic compound is containing potassium element, magnesium elements, aluminium element, Zn-ef ficiency, ferro element, copper Or the hydroxide of silver element, oxide or salt；
Described initiator is benzoyl peroxide or hydrogen peroxide；
Described bleeding agent is penetrating agent JFC；
Described solvent is one or two in deionized water, dimethyl sulfoxide (DMSO), dimethylformamide or tetrahydrofurfuryl alcohol It is mixed above.
Wherein, the content of metallic element is 50-500mg/kg in obtained fiber or fabric.
The invention has the beneficial effects as follows：The present invention adopts chemical crosslink technique, by required metallic element in the form of compound Cross-linked graft is carried out with the active group in fiber or fabric in the presence of solvent and catalyst, stable chemical bond is formed, Make fiber or fabric because there is antimicrobial health care function containing these metal ions, do not change the intrinsic spy of fibrillation or fabric Property, obtained fiber or fabric Jing inspection Escherichia coli, Staphylococcus aureus and beads fungi are had more than 98% sterilizing effect Really.
Specific embodiment
The principle and feature of the present invention are described below in conjunction with example, example is served only for explaining the present invention, and It is non-for limiting the scope of the present invention.
Embodiment 1
A kind of preparation method of antiseptic health care fiber or fabric, step is as follows：
(1) dye liquor is prepared：By 21g zinc dihydrogen phosphates, 21g benzoyl peroxides, 3g penetrating agent JFCs and 500g deionizations Water, 150g dimethyl sulfoxide (DMSO)s, 36g tetrahydrofurfuryl alcohols are mixed to prepare 700g dye liquors, wherein the concentration of the zinc dihydrogen phosphate is 3wt%, the concentration of the initiator benzoyl peroxide is 3wt%；
(2) take 100g viscoses yarn to put into dyeing and finishing kettle with the dye liquor of step (1), the cross-linked graft under the conditions of 85 DEG C is protected Warm 30min, after cleaned, dehydration, drying, finished product；After testing, Zn-ef ficiency content is 110mg/kg in yarn.
Embodiment 2
A kind of preparation method of antiseptic health care fiber or fabric, step is as follows：
(1) dye liquor is prepared：By 7g Kocide SDs, 7g benzoyl peroxides, 3g penetrating agent JFCs and 400g deionized waters, 200g dimethylformamides, 92g tetrahydrofurfuryl alcohols are mixed to prepare 700g dye liquors, wherein the concentration of the Kocide SD is 1wt%, institute The concentration for stating initiator benzoyl peroxide is 1wt%；
(2) take 150g viscose fibers and acrylic fiber blended yarn weaved fabric to put into dyeing and finishing kettle, at 95 DEG C with the dye liquor of step (1) Under the conditions of cross-linked graft, be incubated 30min, it is cleaned, dehydration, drying after, finished product；After testing, copper coin cellulose content in fabric For 185mg/kg.
Embodiment 3
A kind of preparation method of antiseptic health care fiber or fabric, step is as follows：
(1) dye liquor is prepared：10g magnesium hydroxides, 5g benzoyl peroxides, 3g penetrating agent JFCs and 300g tetrahydrofurfuryl alcohols are mixed Close and 500g dye liquors are obtained, wherein the concentration of the magnesium hydroxide is 2wt%, the concentration of the initiator benzoyl peroxide is 1wt%；
(2) take 200g polyester filaments to put into dyeing and finishing kettle with the dye liquor of step (1), the cross-linked graft under the conditions of 138 DEG C is protected Warm 60min, after cleaned, dehydration, drying, finished product；After testing, magnesium element content is 126mg/kg in polyester filament.
Embodiment 4
A kind of preparation method of antiseptic health care fiber or fabric, step is as follows：
(1) dye liquor is prepared：By 7g zinc dihydrogen phosphates, 7g aluminium hydroxides, 2g benzoyl peroxides, 3g penetrating agent JFCs and 300g dimethyl sulfoxide (DMSO)s are mixed to prepare 700g dye liquors, wherein the concentration of the zinc dihydrogen phosphate is 1wt%, the aluminium hydroxide Concentration is 1wt%, and the concentration of the initiator benzoyl peroxide is 1wt%；
(2) take 200g polypropylene fibre and polyamide fibre blended yarn weaved fabric to put into dyeing and finishing kettle, under the conditions of 135 DEG C with the dye liquor of step (1) Cross-linked graft, is incubated 60min, after cleaned, dehydration, drying, finished product；After testing, Zn-ef ficiency content is 85mg/ in fabric Kg, aluminium element content is 32mg/kg.
Embodiment 5
A kind of preparation method of antiseptic health care fiber or fabric, step is as follows：
(1) dye liquor is prepared：5g copper sulphate, 2.5g benzoyl peroxides, 3g penetrating agent JFCs and 200g dimethyl sulfoxide (DMSO)s are mixed Close and 500g dye liquors are obtained, wherein the concentration of the copper sulphate is 1wt%, the concentration of the initiator benzoyl peroxide is 0.5wt%；
(2) 150g vinegar nitrile fabric linings are taken to put into dyeing and finishing kettle with the dye liquor of step (1), is crosslinked under the conditions of 105 DEG C and is connect Branch, is incubated 30min, after cleaned, dehydration, drying, finished product；After testing, copper coin cellulose content is 130mg/kg in fabric.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (2)

1. the preparation method of a kind of antiseptic health care fiber or fabric, it is characterised in that step is as follows：
(1) dye liquor is prepared：Metallic compound, initiator, bleeding agent and solvent are mixed to prepare into dye liquor, wherein the metal compound The concentration of thing is 0.5-10wt%, and the concentration of the initiator is 0.5-3wt%, and the concentration of the bleeding agent is 0.5-3wt%, Balance of solvent；
(2) by the dye liquor of step (1) and fiber or fabric according to (4-10)：In 1 bath raio input dyeing and finishing kettle, in 85-140 DEG C of bar Cross-linked graft under part, is incubated 10-100min, after cleaned, dehydration, drying, antiseptic health care fiber or fabric is obtained；
Wherein, described metallic compound is containing potassium element, magnesium elements, aluminium element, Zn-ef ficiency, ferro element, copper or silver The hydroxide of element, oxide or salt；
Described initiator is benzoyl peroxide or hydrogen peroxide；
Described bleeding agent is penetrating agent JFC；
Described solvent is one or more in deionized water, dimethyl sulfoxide (DMSO), dimethylformamide or tetrahydrofurfuryl alcohol Mixing.
2. preparation method according to claim 1, it is characterised in that the content of metallic element in obtained fiber or fabric For 50-500mg/kg.
CN201710010867.9A 2017-01-06 2017-01-06 Preparation method of antibacterial health-care fiber or textile Pending CN106637914A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710010867.9A CN106637914A (en) 2017-01-06 2017-01-06 Preparation method of antibacterial health-care fiber or textile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710010867.9A CN106637914A (en) 2017-01-06 2017-01-06 Preparation method of antibacterial health-care fiber or textile

Publications (1)

Publication Number Publication Date
CN106637914A true CN106637914A (en) 2017-05-10

Family

ID=58842757

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710010867.9A Pending CN106637914A (en) 2017-01-06 2017-01-06 Preparation method of antibacterial health-care fiber or textile

Country Status (1)

Country Link
CN (1) CN106637914A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108252124A (en) * 2018-01-02 2018-07-06 刘莹艳 A kind of preparation method of the sun-proof fiber of antibacterial or fabric

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730804A (en) * 2005-08-26 2006-02-08 上海汽车集团股份有限公司 Antibacterial fabric and its preparation method
CN101597860A (en) * 2008-06-06 2009-12-09 王家君 A kind of solvay-type anti-bacterial fibre, fabric and preparation method thereof
CN102352551A (en) * 2011-07-21 2012-02-15 苏州邦安新材料科技有限公司 Anti-bacterial anti-mite wool textile and production method thereof
CN102517885A (en) * 2011-12-16 2012-06-27 吴江市利达上光制品有限公司 Silver-loaded textile compound and sliver-loading process thereof
CN103343448A (en) * 2013-06-27 2013-10-09 江苏华艺服饰有限公司 Cotton fabric nano-silver antibacterial production method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730804A (en) * 2005-08-26 2006-02-08 上海汽车集团股份有限公司 Antibacterial fabric and its preparation method
CN101597860A (en) * 2008-06-06 2009-12-09 王家君 A kind of solvay-type anti-bacterial fibre, fabric and preparation method thereof
CN102352551A (en) * 2011-07-21 2012-02-15 苏州邦安新材料科技有限公司 Anti-bacterial anti-mite wool textile and production method thereof
CN102517885A (en) * 2011-12-16 2012-06-27 吴江市利达上光制品有限公司 Silver-loaded textile compound and sliver-loading process thereof
CN103343448A (en) * 2013-06-27 2013-10-09 江苏华艺服饰有限公司 Cotton fabric nano-silver antibacterial production method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108252124A (en) * 2018-01-02 2018-07-06 刘莹艳 A kind of preparation method of the sun-proof fiber of antibacterial or fabric

Similar Documents

Publication Publication Date Title
CN106012495B (en) A kind of linen and preparation method thereof with safeguard function
CN108660755B (en) A kind of preparation method of the modified silk fiber of highly hygroscopic moisture retention
WO1998012369A1 (en) Chitosan-containing acrylic fibers and process for preparing the same
CN110791830A (en) Multifunctional viscose fiber containing plant extract, preparation method thereof and obtained non-woven fabric
CN106012551A (en) Preparation method for blended yarns of hemp cotton and antibacterial fibers
DE112013007131T5 (en) Process for treating textiles during wet washing
CN112210846A (en) Preparation method of plant antibacterial, antiviral, skin-care and health-care cellulose fiber
US9907311B2 (en) Anti-odour and antibacterial fabric in textile goods
CN107476048A (en) A kind of antibacterial ribbon preparation method based on original position
CN102995388A (en) Preparation method of water-washable anion wool fiber and application in home textile product
CN106757600A (en) A kind of preparation method of antibacterial cotton bast yarn and thread
CN106637914A (en) Preparation method of antibacterial health-care fiber or textile
CN105780234A (en) Preparation method of composite yarns
CN115044992A (en) Preparation method of viscose macrobio-fiber containing seaweed active ingredients
CN110273210A (en) One kind having the terylene covered yarn of antibacterial functions and preparation method
JP5865647B2 (en) Antifouling antibacterial fabric and method for producing the same
KR20130113585A (en) Manufacturing method of functional fabrics comprising cold compositions
CN110761073A (en) Antibacterial fabric
JPH083873A (en) Antibacterial textile product and production thereof
CN115029925A (en) Plant traditional Chinese medicine composition and preparation method of mosquito-repelling antibacterial mildew-proof cotton fiber thereof
CN111395005A (en) Production process of mothproof and bacteriostatic woolen sweater
CN112127153A (en) Antibacterial and deodorant textile and preparation method thereof
JP6786057B2 (en) Functional component Sustained release fiber, fiber structure having the fiber and underwear, and method for regenerating them
CN107964785A (en) One kind loads Nanometer Copper anti bacteria natural silk product and preparation method thereof
CN113832562B (en) Large biological viscose fiber containing lily active ingredient

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170510