CN106635508A - Water-soluble sticking cloth resin cleaning agent and preparation method thereof - Google Patents
Water-soluble sticking cloth resin cleaning agent and preparation method thereof Download PDFInfo
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- CN106635508A CN106635508A CN201611052915.2A CN201611052915A CN106635508A CN 106635508 A CN106635508 A CN 106635508A CN 201611052915 A CN201611052915 A CN 201611052915A CN 106635508 A CN106635508 A CN 106635508A
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- water
- cleaning agent
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
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- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a water-soluble sticking cloth resin cleaning agent and a preparation method thereof. The water-soluble cleaning agent which is used for cleaning a guiding belt table adhesive of a textile printing machine is obtained by mixing 1%-5% of propylene glycol methyl ether acetate, 10%-30% of glyceryl triacetate and 50%-80% of ethylene glycol diacetate according to a formula and filtering. The water-soluble sticking cloth resin cleaning agent prepared by the invention has good water solubility and is an organic mixed solvent with a high flashing point and a high ignition point; and the water-soluble sticking cloth resin cleaning agent has no corrosion on a printing guiding belt, has an obvious effect of removing the table adhesive, and has the characteristics of low toxicity, environmental protection, high stability and the like.
Description
Technical field
The present invention relates to a kind of water-soluble patch resin cleaning agent and preparation method thereof, more particularly to it is a kind of for removal spinning
Water-soluble washing agent of fabric guide belt of decorating machine table glue and preparation method thereof.
Background technology
Board-washing water is also referred to as patch resin cleaning agent, is cleaning guide belt of decorating machine surface patch resin in stamp process
Cleaning agent used is commonly called as, and it has a class cleaning agent of dissolving swelling behavior to polyacrylate stamp patch resin.Mesh
Front most widely used class board-washing water is butyl acetate, and its patch resin to polyacrylate has excellent removal effect
Really, and use cost is relatively low, it is that printing and dyeing enterprise is widely used.But, butyl acetate exists in use larger
Potential safety hazard, the volatility of butyl acetate first is very fast, and flash-point is 33 DEG C, and its steam can form deflagrability and mix with air
Thing, meeting naked light, high temperature can cause combustion explosion；Secondly butyl acetate is insoluble in water and density is 0.8825g/ml（Less than water）,
It is discharged in sewer after cleaning patch resin, butyl acetate can be swum on the water surface, chance naked light and strong oxidizer are equally easily
Explode, there is great potential safety hazard.In addition, butyl acetate steam has strong impulse to make in eye and the upper respiratory tract
With, have an anesthetic effect, suction high concentration volatilization steam occur shed tears, pharyngalgia, cough, the symptom such as uncomfortable in chest, shortness of breath, severe patient meeting
There is the disease of cardiovascular and nervous system, conjunctivitis, keratitis, corneal epithelium can be caused to have vacuolization, serious harm behaviour
Make the healthy of workman.There is larger threat in butyl acetate, need to safety in production and worker health in use
The cleaning agent for finding low toxic and environment-friendly safety replaces butyl acetate.
The content of the invention
For the problems referred to above, it is an object of the invention to provide low, safe to use water-soluble of a kind of good water solubility, toxicity
Property patch resin cleaning agent with and preparation method thereof.
For achieving the above object, technical scheme is as follows：
A kind of water-soluble patch resin cleaning agent, comprising following components：
Propylene glycol methyl ether acetate, is dissolved in water, flash-point（Opening）For 51 DEG C, existing ehter bond has carbonyl again in its molecule, and carbonyl is again
Define the construction of ester, while and rich in alkyl, it is existing nonpolar in same molecule, and polarized, these functional groups both that
This restriction exclusion, and its intrinsic effect is each played, there is very strong solvability to polarity and nonpolar material, therefore
It is the outstanding low toxicity advanced industrial solvent of function, it is adaptable to the solvent of the various polymer of high grade paint, ink, including amino first
Base acid esters, vinyl, polyester, cellulose acetate, alkyd resin, acrylic resin, epoxy resin and nitrocellulose etc..Cause
Propylene glycol methyl ether acetate is added in formula and can improve dissolving of the cleaning agent to polyacrylate hot-melt resin by this
Ability, reduces rate of volatilization, improves cleansing power.
Glyceryl triacetate, is a kind of low-toxic organic solvent, is slightly dissolved in water, and solubility is 5.9g/ in water when 25 DEG C
100ml, boiling point is 172 DEG C, flash-point（Opening）For 146 DEG C, volatility is low, therefore is not susceptible to blast, and it is fine that it can dissolve nitric acid
Dimension element, cellulose acetate, acrylic resin, polyvinyl acetate etc., add it to that the sudden strain of a muscle of cleaning agent can be improved in filling a prescription
Point.
Ethylene acetate is a kind of micro- malicious water-miscible organic solvent, and solubility when 20 DEG C in water is 160g/L,
Flash-point（Opening）For 105 DEG C, the low smell of volatility is little, for manufacture paint, adhesive and paint remover equal solvent, to polyacrylic acid
Esters resin has preferably dissolving swelling behavior, is added in formula as key component, can improve the water of cleaning agent
Dissolubility and flash-point, reduce the volatility and excitant of cleaning agent.
Further, the percetage by weight of described each component is as follows：
Propylene glycol methyl ether acetate 1 ~ 5%
Glyceryl triacetate 10 ~ 30%
Ethylene acetate 50 ~ 80%.
Simultaneously the invention provides the above-mentioned water-soluble patch resin for removing textile printing machine conduction band table glue is clear
The preparation method of lotion：
（1）At normal temperatures and pressures, the ethylene acetate of formula ratio is added in reactor；
（2）At normal temperatures and pressures, the glyceryl triacetate of formula ratio is added and is mixed with ethylene acetate in reactor, plus
Mechanical agitation is started while material, rotating speed 100r/min is controlled, 8 ~ 10min of stirring is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, the propylene glycol methyl ether acetate of formula ratio is slowly added in reactor be mixed with the first mixture
Close, 5 ~ 8min is stirred under 100r/min rotating speeds, through filter screen filtration, obtain water-soluble patch resin cleaning agent.
Beneficial effects of the present invention
Compared with used butyl acetate cleaning agent, the patch resin cleaning agent prepared by the present invention has excellent water solubility,
For high-flash, the organic mixed solvent of high-flash, detonation and blast are not susceptible to, to print guide belt non-corrosiveness, to patch resin
Removal effect substantially, with toxicity is low, environmentally friendly and the characteristics of high stability.The water-soluble patch resin that the present invention is obtained is clear
Lotion, volatilizees during use without obvious irritation smell, and the consumption for removing a circular screen printer is only the one of butyl acetate
Half.
Specific embodiment
Below by way of specific embodiment, the present invention is described in further detail, but is not the limit to present invention
System.
A kind of water-soluble patch resin cleaning agent, comprising following components：
Propylene glycol methyl ether acetate, is dissolved in water, flash-point（Opening）For 51 DEG C, existing ehter bond has carbonyl again in its molecule, and carbonyl is again
Define the construction of ester, while and rich in alkyl, it is existing nonpolar in same molecule, and polarized, these functional groups both that
This restriction exclusion, and its intrinsic effect is each played, there is very strong solvability to polarity and nonpolar material, therefore
It is the outstanding low toxicity advanced industrial solvent of function, it is adaptable to the solvent of the various polymer of high grade paint, ink, including amino first
Base acid esters, vinyl, polyester, cellulose acetate, alkyd resin, acrylic resin, epoxy resin and nitrocellulose etc..Cause
Propylene glycol methyl ether acetate is added in formula and can improve dissolving of the cleaning agent to polyacrylate hot-melt resin by this
Ability, reduces rate of volatilization, improves cleansing power.
Glyceryl triacetate, is a kind of low-toxic organic solvent, is slightly dissolved in water, and solubility is 5.9g/ in water when 25 DEG C
100ml, boiling point is 172 DEG C, flash-point（Opening）For 146 DEG C, volatility is low, therefore is not susceptible to blast, and it is fine that it can dissolve nitric acid
Dimension element, cellulose acetate, acrylic resin, polyvinyl acetate etc., add it to that the sudden strain of a muscle of cleaning agent can be improved in filling a prescription
Point.
Ethylene acetate is a kind of micro- malicious water-miscible organic solvent, and solubility when 20 DEG C in water is 160g/L,
Flash-point（Opening）For 105 DEG C, the low smell of volatility is little, for manufacture paint, adhesive and paint remover equal solvent, to polyacrylic acid
Esters resin has preferably dissolving swelling behavior, is added in formula as key component, can improve the water of cleaning agent
Dissolubility and flash-point, reduce the volatility and excitant of cleaning agent.
Further, the percetage by weight of described each component is as follows：
Propylene glycol methyl ether acetate 1 ~ 5%
Glyceryl triacetate 10 ~ 30%
Ethylene acetate 50 ~ 80%.
Simultaneously the invention provides the above-mentioned water-soluble patch resin for removing textile printing machine conduction band table glue is clear
The preparation method of lotion：
（1）At normal temperatures and pressures, the ethylene acetate of formula ratio is added in reactor；
（2）At normal temperatures and pressures, the glyceryl triacetate of formula ratio is added and is mixed with ethylene acetate in reactor, plus
Mechanical agitation is started while material, rotating speed 100r/min is controlled, 8 ~ 10min of stirring is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, the propylene glycol methyl ether acetate of formula ratio is slowly added in reactor be mixed with the first mixture
Close, 5 ~ 8min is stirred under 100r/min rotating speeds, through filter screen filtration, obtain water-soluble patch resin cleaning agent.
The flash-point of water-soluble patch resin cleaning agent can obtain approximation by following formula estimation：
In formula, t is mixed as the approximation of water-soluble patch resin cleaning agent flash-point, unit for DEG C；V1, V2 ..., Vn is each component
Volume fraction；T1, t2 ..., tn for each component flash-point, unit for DEG C.
Rate of volatilization presses the test of acetate butyl method.
Embodiment 1
A kind of water-soluble patch resin cleaning agent, the weight portion of each component is as follows in its formula：
Propylene glycol methyl ether acetate 2%
Glyceryl triacetate 28%
Ethylene acetate 70%.
The preparation of water-soluble patch resin cleaning agent：
（1）At normal temperatures and pressures, 70% ethylene acetate is added in reactor；
（2）At normal temperatures and pressures, 28% glyceryl triacetate is added and is mixed with ethylene acetate in reactor, fed
While start mechanical agitation, control rotating speed 100r/min, stirring 10min is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, 2% propylene glycol methyl ether acetate is slowly added in reactor mix with the first mixture,
8min is stirred under 100r/min rotating speeds, through filter screen filtration, water-soluble patch resin cleaning agent is obtained.
Estimated by formula：
By calculating, approximation t of the formula water solubility patch resin cleaning agent flash-point is 110.7 DEG C, much larger than butyl acetate
Flash-point（Opening）33℃.
Embodiment 2
A kind of water-soluble patch resin cleaning agent, the weight portion of each component is as follows in its formula：
Propylene glycol methyl ether acetate 2%
Glyceryl triacetate 23%
Ethylene acetate 75%.
The preparation of water-soluble patch resin cleaning agent：
（1）At normal temperatures and pressures, 75% ethylene acetate is added in reactor；
（2）At normal temperatures and pressures, 23% glyceryl triacetate is added and is mixed with ethylene acetate in reactor, fed
While start mechanical agitation, control rotating speed 100r/min, stirring 10min is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, 2% propylene glycol methyl ether acetate is slowly added in reactor mix with the first mixture,
8min is stirred under 100r/min rotating speeds, through filter screen filtration, water-soluble patch resin cleaning agent is obtained.
Estimation flash-point is carried out by formula：
By calculating, approximation t of the formula water solubility patch resin cleaning agent flash-point is 109.1 DEG C, much larger than butyl acetate
Flash-point（Opening）33℃.
Embodiment 3
A kind of water-soluble patch resin cleaning agent, the weight portion of each component is as follows in its formula：
Propylene glycol methyl ether acetate 2%
Glyceryl triacetate 18%
Ethylene acetate 80%.
The preparation of water-soluble patch resin cleaning agent：
（1）At normal temperatures and pressures, 80% ethylene acetate is added in reactor；
（2）At normal temperatures and pressures, 18% glyceryl triacetate is added and is mixed with ethylene acetate in reactor, fed
While start mechanical agitation, control rotating speed 100r/min, stirring 10min is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, 2% propylene glycol methyl ether acetate is slowly added in reactor mix with the first mixture,
8min is stirred under 100r/min rotating speeds, through filter screen filtration, water-soluble patch resin cleaning agent is obtained.
Estimation flash-point is carried out by formula：
By calculating, approximation t of the formula water solubility patch resin cleaning agent flash-point is 107.3 DEG C, much larger than butyl acetate
Flash-point（Opening）33℃.
The performance of the water-soluble patch resin cleaning agent for finally giving is as follows with the contrast of butyl acetate：
Claims (2)
1. a kind of water-soluble patch resin cleaning agent, it is characterised in that percentage includes following components：
Propylene glycol methyl ether acetate 1 ~ 5%
Glyceryl triacetate 10 ~ 30%
Ethylene acetate 50 ~ 80%.
2. the preparation method of water-soluble patch resin cleaning agent according to claim 1, it is characterised in that including following step
Suddenly：
（1）At normal temperatures and pressures, the ethylene acetate of formula ratio is added in reactor；
（2）At normal temperatures and pressures, the glyceryl triacetate of formula ratio is added and is mixed with ethylene acetate in reactor, plus
Mechanical agitation is started while material, rotating speed 100r/min is controlled, 8 ~ 10min of stirring is well mixed and obtains the first mixture；
（3）At normal temperatures and pressures, the propylene glycol methyl ether acetate of formula ratio is slowly added in reactor be mixed with the first mixture
Close, 5 ~ 8min is stirred under 100r/min rotating speeds, through filter screen filtration, obtain water-soluble patch resin cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611052915.2A CN106635508A (en) | 2016-11-25 | 2016-11-25 | Water-soluble sticking cloth resin cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611052915.2A CN106635508A (en) | 2016-11-25 | 2016-11-25 | Water-soluble sticking cloth resin cleaning agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106635508A true CN106635508A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611052915.2A Pending CN106635508A (en) | 2016-11-25 | 2016-11-25 | Water-soluble sticking cloth resin cleaning agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108179430A (en) * | 2017-11-28 | 2018-06-19 | 深圳宣顶实业有限公司 | A kind of auto parts cleaning agent and preparation method thereof |
| CN108728256A (en) * | 2018-07-03 | 2018-11-02 | 阜南县富昌恒业工艺品有限公司 | A kind of Wood craft surface cleaning agent |
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| CN1900248A (en) * | 2005-07-22 | 2007-01-24 | 东京应化工业株式会社 | Cleaning agent for resin composition |
| CN101830320A (en) * | 2008-12-30 | 2010-09-15 | 碧洁家庭护理有限公司 | Hand sprayer with binary bag-valve gear |
| CN102703256A (en) * | 2012-06-15 | 2012-10-03 | 东莞优诺电子焊接材料有限公司 | Multifunctional water-based cleaning agent |
| CN105331471A (en) * | 2015-11-17 | 2016-02-17 | 深圳市合明科技有限公司 | Environment-friendly neutral water-based cleaning agent, preparation method and application |
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2016
- 2016-11-25 CN CN201611052915.2A patent/CN106635508A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| CN1900248A (en) * | 2005-07-22 | 2007-01-24 | 东京应化工业株式会社 | Cleaning agent for resin composition |
| CN101830320A (en) * | 2008-12-30 | 2010-09-15 | 碧洁家庭护理有限公司 | Hand sprayer with binary bag-valve gear |
| CN102703256A (en) * | 2012-06-15 | 2012-10-03 | 东莞优诺电子焊接材料有限公司 | Multifunctional water-based cleaning agent |
| CN105331471A (en) * | 2015-11-17 | 2016-02-17 | 深圳市合明科技有限公司 | Environment-friendly neutral water-based cleaning agent, preparation method and application |
Non-Patent Citations (1)
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108179430A (en) * | 2017-11-28 | 2018-06-19 | 深圳宣顶实业有限公司 | A kind of auto parts cleaning agent and preparation method thereof |
| CN108179430B (en) * | 2017-11-28 | 2019-10-22 | 深圳宣顶实业有限公司 | A kind of auto parts cleaning agent and preparation method thereof |
| CN108728256A (en) * | 2018-07-03 | 2018-11-02 | 阜南县富昌恒业工艺品有限公司 | A kind of Wood craft surface cleaning agent |
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