CN106635341B - A kind of chemical addition agent and preparation method thereof of the biomass machine oil purifying filter element of fire-retardant, anti-cream - Google Patents

A kind of chemical addition agent and preparation method thereof of the biomass machine oil purifying filter element of fire-retardant, anti-cream Download PDF

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CN106635341B
CN106635341B CN201611191476.3A CN201611191476A CN106635341B CN 106635341 B CN106635341 B CN 106635341B CN 201611191476 A CN201611191476 A CN 201611191476A CN 106635341 B CN106635341 B CN 106635341B
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detersive
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reconciliation
machine oil
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CN106635341A (en
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李佳燕
赵洪斌
赵建新
李旺达
司双来
李国成
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • C10M2207/1443—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
    • C—CHEMISTRY; METALLURGY
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    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

It is a kind of fire-retardant, the chemical addition agent of the biomass machine oil purifying filter element of anti-cream, by the material composition of following parts by weight: 21-22 parts of basicity alkyl calcium salicylate in detersive T109, 10-11 parts of low alkali value calcium alkylbenzenesulfonate of detersive T104, 23-24 parts of macromolecule succimide of dispersing agent T161B, 10.5-11.0 parts of detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, 8.5-9 parts of primary alkyl zinc dithiophosphate of oxidation and corrosion inhibitor T203 long-chain, 0.001-0.003 parts of rongalite sodium bisulphite formaldehyde, NaCl0.0004-0.0006 parts, 2.9-3.0 parts of liquid high molecular weight phenol of anti-oxidant Irganox L135, 13-15 parts of boron nitrogen compound of friction improver B-N-I , 3-3.5 parts of DEEP diethyl ethylphosphate, 1.5-1.6 parts of ethylene glycol, demulsifier T1001 amine with 1.4-1.6 part of epoxides condensation product, Viscoplex 8-310 is viscous to refer to modifier 13-15 parts, base oil 13-15 parts of PAO-40 reconciliation.The present invention is on the basis of enhancing cleaning ability and reducing power and antioxidant, it is often more important that reduces the loss of machine oil burning, increases anti-newborn ability.

Description

A kind of chemical addition agent and its system of the biomass machine oil purifying filter element of fire-retardant, anti-cream Preparation Method
Technical field
The present invention relates to the technical fields for extending online machine oil service life, keeping oil lubricating quality, and in particular to one The chemical addition agent and preparation method thereof of the biomass machine oil purifying filter element of fire-retardant, the anti-cream of kind.
Background technique
Lubricating oil plays an important role during machine work, and especially diesel machine (hereinafter referred to as starts Machine) during the work time, if having lacked lubricating oil, can not work at all.Currently, all how to make in research and development both at home and abroad The effect of lubricating oil and effect are more preferable, and with the rapid development of auto industry, and current engine is that volume is smaller and smaller, and its Power requirement but gets over bigizationner.Under these conditions, harsher to the performance requirement of lubricating oil and use condition.So state Inside and outside each large enterprises are in the lube product for constantly researching and developing and releasing upgrading from one generation to the next, to be suitable for difference The engine of type.
For this purpose, the single-stage machine oil used originally becomes multistage (compound) machine oil.The originally machine oil upgrading of low level quality For the machine oil of high-level quality.But due to the limitation of the working condition of engine and operating condition, regardless of lubricating oil why Sample upgrading, how good quality or effect be.Machine oil does not always escape the destiny being periodically replaced.Under normal circumstances, small vehicle Every 0.6 ten thousand kilometers or so of traveling, every 10,000 kilometers or so of the traveling of medium-sized and oversize vehicle, it is necessary to replace machine oil and relevant filtering Device, this is because lubricating oil its every physical and chemical index in use, is all constantly changing, and therein any one Item physical and chemical index can all influence engine such as impurity, acid value, base number, moisture, flash-point and metal (Fe, Al, Cu) equal size Working condition.So necessary oil change at regular intervals and relevant filter device, could ensure the nominal situation of engine.
The biomass filtering substrate of volume type filtering in various machine oil purifying filter elements used at present, only to online machine Oil plays the role of single filtering, but online machine oil use process participate in burning and caused by machine oil loss and effect drop It is low, the reduction of oil life and quality is caused, in order to improve and enhance fire-retardant, the anti-newborn ability of online machine oil, extends machine oil Service life is needed to online machine oil reparation, but the biomass filtering substrate of current volume type filtering cannot achieve.
Summary of the invention
The technical problem to be solved by the present invention is in the prior art the shortcomings that and a kind of life of fire-retardant, anti-cream is provided The chemical addition agent of substance machine oil purifying filter element gives online machine oil not by using in volume type biomass machine oil purifying filter element It is disconnected to input fire-retardant, anti-newborn type chemical addition agent, machine caused by greatly reducing online machine oil due to long-term work, participating in burning Oil loss and effect reduce, while enhancing its anti-newborn ability.
It is a further object of the present invention to provide the chemical addition agents of the biomass machine oil purifying filter element of above-mentioned fire-retardant, anti-cream Preparation method.
Technical problem to solve of the invention adopts the following technical scheme that
A kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, by the material composition of following parts by weight: 21-22 parts of basicity alkyl calcium salicylate in detersive T109,10-11 parts of low alkali value calcium alkylbenzenesulfonate of detersive T104, dispersing agent 23-24 parts of T161B macromolecule succimide, 10.5-11.0 parts of detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, antioxygen 8.5-9 parts of primary alkyl zinc dithiophosphate of anti-corrosion additive T203 long-chain, 0.001-0.003 parts of rongalite sodium bisulphite formaldehyde, NaCl0.0004-0.0006 parts, 2.9-3.0 parts of liquid high molecular weight phenol of anti-oxidant Irganox L135, friction improver B-N-I 13-15 parts of boron nitrogen compound, 3-3.5 parts of DEEP diethyl ethylphosphate, 1.5-1.6 parts of ethylene glycol, demulsifier T1001 amine With 1.4-1.6 parts of epoxides condensation product, Viscoplex 8-310 is viscous to refer to modifier 13-15 part, PAO-40 reconciliation base oil 13-15 parts.
A kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, by the material composition of following parts by weight: 21.4 parts of basicity alkyl calcium salicylate in detersive T109,10.7 parts of calcium alkylbenzenesulfonate of detersive T104 low alkali value, dispersing agent 23.6 parts of T161B macromolecule succimide, 10.7 parts of detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, oxidation and corrosion inhibitor 8.6 parts of zinc dithiophosphate of T203 long-chain primary alkyl, 0.002 part of rongalite sodium bisulphite formaldehyde, NaCl0.0005 parts, antioxygen 2.9 parts of phenol of agent Irganox L135 liquid high molecular weight, 15 parts of nitrogen compound of friction improver B-N-I boron, DEEP ethyl phosphine 3 parts of diethyl phthalate, 1.5 parts of ethylene glycol, demulsifier T1001 amine with 1.5 parts of epoxides condensation product, Viscoplex 8-310 is viscous Refer to 15 parts of modifier, 15 parts of base oil of PAO-40 reconciliation.
The preparation method of the chemical addition agent of the biomass machine oil purifying filter element of above-mentioned fire-retardant, anti-cream, includes the following steps:
Each substance is weighed according to above-mentioned mass parts；
A, it takes friction improver B-N-I boron nitrogen compound and DEEP diethyl ethylphosphate to be mixed evenly, forms A Solution；
B, the PAO-40 reconciliation base oil for taking 1/3 mass, is then sequentially added into antioxygen into PAO-40 reconciliation base oil Anti-corrosion additive T203 long-chain primary alkyl zinc dithiophosphate, anti-oxidant Irganox L135 liquid high molecular weight phenol, demulsifier T1001 amine is stirred evenly with epoxides condensation product, forms B solution；
C, the PAO-40 reconciliation base oil for taking 1/3 mass, is then added Viscoplex into PAO-40 reconciliation base oil 8-310 is viscous to refer to modifier, is heated to 45-50 DEG C and stirs evenly, forms C solution；
D, the PAO-40 reconciliation base oil of 1/3 mass is taken, is then sequentially added into PAO-40 reconciliation base oil peace and quiet Basicity alkyl calcium salicylate, detersive T104 low alkali value calcium alkylbenzenesulfonate, add dispersing agent T161B macromolecule fourth in agent T109 Rongalite sodium bisulphite formaldehyde and NaCl are added after imidodicarbonic diamide and detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, stirs It mixes uniformly, forms solution D；
E, first A, B solution are mixed, stir evenly, then C, solution D are mixed evenly, finally again mixes them, It is heated to 45-50 DEG C after mixing evenly, is cooled to room temperature, the chemistry for obtaining the biomass machine oil purifying filter element of fire-retardant, anti-cream adds Add agent.
Its ingredient of substance used in the present invention and function are as follows:
T109 is middle basicity alkyl calcium salicylate detersive, has good high temperature detergency, stronger neutralization performance.
T104 is low alkali value calcium alkylbenzenesulfonate detersive, has good detergency, dispersibility and rust-preventing characteristic.
T161B be high nitrogen polybutene succinimide dispersant, with can effectively be solved after detersive compatibility carbon distribution and Compatibilization of the dirty oil mud in oil product.
LAN115B is SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER detersive, and high temperatures, antioxygen, anti-corruption reduce piston tip product Carbon.
Oxidation and corrosion inhibitor T203 long-chain primary alkyl zinc dithiophosphate, antioxygen, anti-corrosion property are good, and thermal stability is fabulous, can have It prevents engine bearing from corroding to effect, oil viscosity is prevented to increase.
B-N-I boron nitrogen compound is friction improver, is made using the acid of Long carbon chain, organic amine and boric acid by raw material, Stable chemical performance can improve the lubricity of oil product, reduce friction, abrasion, save energy consumption.
Irganox L135 is antioxidant, and composition is liquid high molecular weight phenol, and manufacturer is German BASF.
It is Germany evonik that the viscous finger modifier of Viscoplex 8-310, which is polymethacrylates (PMA) manufacturer, Company.
DEEP ethyl phosphonic acid diethylester, is free from the additive flame retardant of halogen, has flame-retarded efficiency height, chemical stability Well, the advantages that easy to use.
Ethylene glycol, good water absorption, tension are larger.
T1001 is demulsifier amine, is amine and epoxides condensation product, and anti-cream ability is strong.
Chemical addition agent of the invention is on the basis of enhancing cleaning ability and reducing power and antioxidant, it is often more important that subtracts The loss of few machine oil burning increases anti-newborn ability.Its oxygen bomb experiment (SH/T0193) is more than 1200 or more, antioxidant rack Test (programFHD, ASTM D5533) antioxidant capacity test, excellent effect, effect can reach CH-4/SJ oil product product Matter.The heavy-duty machinery and superduty of diesel machine and other special industries especially suitable for ship and mine industry are mechanical.
Specific embodiment
Embodiment 1
A kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, by the material composition of following weight: clear Basicity alkyl calcium salicylate 22kg in net agent T109, detersive T104 low alkali value calcium alkylbenzenesulfonate 10kg, dispersing agent T161B high score Sub- succimide 23kg, detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 11.0kg, the primary alkane of oxidation and corrosion inhibitor T203 long-chain Base zinc dithiophosphate 9kg, rongalite sodium bisulphite formaldehyde 0.001kg, NaCl0.0006kg, anti-oxidant Irganox L135 Liquid high molecular weight phenol 3.0kg, friction improver B-N-I boron nitrogen compound 15kg, DEEP diethyl ethylphosphate 3kg, second Glycol 1.6kg, demulsifier T1001 amine and epoxides condensation product 1.4kg, Viscoplex 8-310 are viscous to refer to modifier 15kg, PAO-40 reconciliation base oil 13kg.
The preparation method of the chemical addition agent of the biomass machine oil purifying filter element of above-mentioned fire-retardant, anti-cream, includes the following steps:
Each substance is weighed according to above-mentioned quality；
A, it takes friction improver B-N-I boron nitrogen compound and DEEP diethyl ethylphosphate to be mixed evenly, forms A Solution；
B, the PAO-40 reconciliation base oil for taking 5 kg, is then sequentially added into the anti-corruption of antioxygen into PAO-40 reconciliation base oil Agent T203 long-chain primary alkyl zinc dithiophosphate, anti-oxidant Irganox L135 liquid high molecular weight phenol, demulsifier T1001 amine It is stirred evenly with epoxides condensation product, forms B solution；
C, the PAO-40 reconciliation base oil for taking 5 kg, is then added Viscoplex 8- into PAO-40 reconciliation base oil 310 viscous finger modifiers, are heated to 45 DEG C and stir evenly, form C solution；
D, the PAO-40 reconciliation base oil for taking 5 kg, is then sequentially added into detersive into PAO-40 reconciliation base oil Basicity alkyl calcium salicylate, detersive T104 low alkali value calcium alkylbenzenesulfonate, add dispersing agent T161B macromolecule fourth two in T109 Rongalite sodium bisulphite formaldehyde and NaCl, stirring are added after acid imide and detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER Uniformly, solution D is formed；
E, first A, B solution are mixed, stir evenly, then C, solution D are mixed evenly, finally again mixes them, It is heated to 50 DEG C after mixing evenly, is cooled to room temperature, obtain the chemistry addition of the biomass machine oil purifying filter element of fire-retardant, anti-cream Agent.
Embodiment 2
A kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, by the material composition of following weight: clear Basicity alkyl calcium salicylate 21kg in net agent T109, detersive T104 low alkali value calcium alkylbenzenesulfonate 11kg, dispersing agent T161B high score Sub- succimide 24kg, detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 10.5kg, the primary alkane of oxidation and corrosion inhibitor T203 long-chain Base zinc dithiophosphate 8.5kg, rongalite sodium bisulphite formaldehyde 0.003kg, NaCl0.0004kg, anti-oxidant Irganox L135 liquid high molecular weight phenol 2.9kg, friction improver B-N-I boron nitrogen compound 13kg, DEEP diethyl ethylphosphate Viscous refer to of 3.5kg, ethylene glycol 1.5kg, demulsifier T1001 amine and epoxides condensation product 1.6kg, Viscoplex 8-310 is improved Agent 13kg, PAO-40 reconciliation base oil 15kg.
The preparation method of the chemical addition agent of the biomass machine oil purifying filter element of above-mentioned fire-retardant, anti-cream, includes the following steps:
Each substance is weighed according to above-mentioned quality；
A, it takes friction improver B-N-I boron nitrogen compound and DEEP diethyl ethylphosphate to be mixed evenly, forms A Solution；
B, the PAO-40 reconciliation base oil for taking 1/3 mass, is then sequentially added into antioxygen into PAO-40 reconciliation base oil Anti-corrosion additive T203 long-chain primary alkyl zinc dithiophosphate, anti-oxidant Irganox L135 liquid high molecular weight phenol, demulsifier T1001 amine is stirred evenly with epoxides condensation product, forms B solution；
C, the PAO-40 reconciliation base oil for taking 1/3 mass, is then added Viscoplex into PAO-40 reconciliation base oil 8-310 is viscous to refer to modifier, is heated to 50 DEG C and stirs evenly, forms C solution；
D, the PAO-40 reconciliation base oil of 1/3 mass is taken, is then sequentially added into PAO-40 reconciliation base oil peace and quiet Basicity alkyl calcium salicylate, detersive T104 low alkali value calcium alkylbenzenesulfonate, add dispersing agent T161B macromolecule fourth in agent T109 Rongalite sodium bisulphite formaldehyde and NaCl are added after imidodicarbonic diamide and detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, stirs It mixes uniformly, forms solution D；
E, first A, B solution are mixed, stir evenly, then C, solution D are mixed evenly, finally again mixes them, It is heated to 45 DEG C after mixing evenly, is cooled to room temperature, obtain the chemistry addition of the biomass machine oil purifying filter element of fire-retardant, anti-cream Agent.
Embodiment 3
A kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, by the material composition of following weight: clear Basicity alkyl calcium salicylate 21.4kg in net agent T109, detersive T104 low alkali value calcium alkylbenzenesulfonate 10.7kg, dispersing agent T161B Macromolecule succimide 23.6kg, detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 10.7kg, oxidation and corrosion inhibitor T203 long Chain primary alkyl zinc dithiophosphate 8.6kg, rongalite sodium bisulphite formaldehyde 0.002kg, NaCl0.0005kg, antioxidant Irganox L135 liquid high molecular weight phenol 2.9kg, friction improver B-N-I boron nitrogen compound 15kg, DEEP ethylphosphonic acid Diethylester 3kg, ethylene glycol 1.5kg, demulsifier T1001 amine and epoxides condensation product 1.5kg, Viscoplex 8-310 are viscous to be referred to Modifier 15kg, PAO-40 reconciliation base oil 15kg.
The preparation method of the chemical addition agent of the biomass machine oil purifying filter element of above-mentioned fire-retardant, anti-cream, includes the following steps:
Each substance is weighed according to above-mentioned quality；
A, it takes friction improver B-N-I boron nitrogen compound and DEEP diethyl ethylphosphate to be mixed evenly, forms A Solution；
B, the PAO-40 reconciliation base oil for taking 5 kg, is then sequentially added into the anti-corruption of antioxygen into PAO-40 reconciliation base oil Agent T203 long-chain primary alkyl zinc dithiophosphate, anti-oxidant Irganox L135 liquid high molecular weight phenol, demulsifier T1001 amine It is stirred evenly with epoxides condensation product, forms B solution；
C, the PAO-40 reconciliation base oil for taking 5 kg, is then added Viscoplex 8- into PAO-40 reconciliation base oil 310 viscous finger modifiers, are heated to 50 DEG C and stir evenly, form C solution；
D, the PAO-40 reconciliation base oil for taking 5 kg, is then sequentially added into detersive into PAO-40 reconciliation base oil Basicity alkyl calcium salicylate, detersive T104 low alkali value calcium alkylbenzenesulfonate, add dispersing agent T161B macromolecule fourth two in T109 Rongalite sodium bisulphite formaldehyde and NaCl, stirring are added after acid imide and detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER Uniformly, solution D is formed；
E, first A, B solution are mixed, stir evenly, then C, solution D are mixed evenly, finally again mixes them, It is heated to 50 DEG C after mixing evenly, is cooled to room temperature, obtain the chemistry addition of the biomass machine oil purifying filter element of fire-retardant, anti-cream Agent.

Claims (3)

1. a kind of chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream, it is characterised in that by following parts by weight Material composition: 21-22 parts of basicity alkyl calcium salicylate in detersive T109, detersive T104 low alkali value calcium alkylbenzenesulfonate 10-11 Part, 23-24 parts of macromolecule succimide of dispersing agent T161B, detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 10.5- 11.0 parts, 8.5-9 parts of primary alkyl zinc dithiophosphate of oxidation and corrosion inhibitor T203 long-chain, rongalite sodium bisulphite formaldehyde 0.001- 0.003 part, NaCl0.0004-0.0006 parts, 2.9-3.0 parts of liquid high molecular weight phenol of anti-oxidant Irganox L135, friction changes Into 13-15 parts of boron nitrogen compound of agent B-N-I, 3-3.5 parts of DEEP diethyl ethylphosphate, 1.5-1.6 parts of ethylene glycol, demulsifier T1001 amine with 1.4-1.6 part of epoxides condensation product, Viscoplex 8-310 is viscous to refer to modifier 13-15 parts, PAO-40 reconciliation 13-15 parts of base oil.
2. the chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, the anti-cream of one kind according to claim 1, feature It is by the material composition of following parts by weight: 21.4 parts of basicity alkyl calcium salicylate in detersive T109, the low alkali of detersive T104 10.7 parts of calcium alkylbenzenesulfonate of value, 23.6 parts of succimide of dispersing agent T161B macromolecule, the vulcanization of detersive LAN115B high base number 10.7 parts of alkyl phenol calcium, 8.6 parts of zinc dithiophosphate of oxidation and corrosion inhibitor T203 long-chain primary alkyl, rongalite sodium bisulphite formaldehyde 0.002 part, NaCl0.0005 parts, 2.9 parts of phenol of anti-oxidant Irganox L135 liquid high molecular weight, friction improver B-N-I boron 15 parts of nitrogen compound, 3 parts of DEEP diethyl ethylphosphate, 1.5 parts of ethylene glycol, demulsifier T1001 amine and epoxides are condensed 1.5 parts of object, Viscoplex 8-310 is viscous to refer to 15 parts of modifier, 15 parts of base oil of PAO-40 reconciliation.
3. the system of the chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, the anti-cream of one kind according to claim 1 or 2 Preparation Method, it is characterised in that include the following steps:
Each substance is weighed according to above-mentioned mass parts；
A, it takes friction improver B-N-I boron nitrogen compound and DEEP diethyl ethylphosphate to be mixed evenly, it is molten to form A Liquid；
B, the PAO-40 reconciliation base oil for taking 1/3 mass, is then sequentially added into the anti-corruption of antioxygen into PAO-40 reconciliation base oil Agent T203 long-chain primary alkyl zinc dithiophosphate, anti-oxidant Irganox L135 liquid high molecular weight phenol, demulsifier T1001 amine It is stirred evenly with epoxides condensation product, forms B solution；
C, the PAO-40 reconciliation base oil for taking 1/3 mass, is then added Viscoplex 8-310 into PAO-40 reconciliation base oil It is viscous to refer to modifier, it is heated to 45-50 DEG C and stirs evenly, form C solution；
D, the PAO-40 reconciliation base oil for taking 1/3 mass, is then sequentially added into detersive into PAO-40 reconciliation base oil Basicity alkyl calcium salicylate, detersive T104 low alkali value calcium alkylbenzenesulfonate, add dispersing agent T161B macromolecule fourth two in T109 Rongalite sodium bisulphite formaldehyde and NaCl, stirring are added after acid imide and detersive LAN115B SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER Uniformly, solution D is formed；
E, first A, B solution are mixed, stirs evenly, then C, solution D are mixed evenly, finally again mixes them, heated After mixing evenly to 45-50 DEG C, it is cooled to room temperature, obtains the chemical addition agent of the biomass machine oil purifying filter element of fire-retardant, anti-cream.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101082011A (en) * 2006-05-29 2007-12-05 孙国中 Direct rapid kinetic oil having self-repairing function
CN101780345A (en) * 2009-01-16 2010-07-21 兰州龙志工贸有限责任公司 High-efficiency purification energy-saving filter core
CN105542922A (en) * 2016-01-07 2016-05-04 北京雅士科莱恩石油化工有限公司 Energy-saving diesel engine oil with ultra-long oil change mileage and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101082011A (en) * 2006-05-29 2007-12-05 孙国中 Direct rapid kinetic oil having self-repairing function
CN101780345A (en) * 2009-01-16 2010-07-21 兰州龙志工贸有限责任公司 High-efficiency purification energy-saving filter core
CN105542922A (en) * 2016-01-07 2016-05-04 北京雅士科莱恩石油化工有限公司 Energy-saving diesel engine oil with ultra-long oil change mileage and preparation method thereof

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