CN106634919A - Consolidated sand system, and preparation method and application method thereof - Google Patents
Consolidated sand system, and preparation method and application method thereof Download PDFInfo
- Publication number
- CN106634919A CN106634919A CN201611052413.XA CN201611052413A CN106634919A CN 106634919 A CN106634919 A CN 106634919A CN 201611052413 A CN201611052413 A CN 201611052413A CN 106634919 A CN106634919 A CN 106634919A
- Authority
- CN
- China
- Prior art keywords
- phenol
- aggregate
- layer
- formaldehyde resin
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/56—Compositions for consolidating loose sand or the like around wells without excessively decreasing the permeability thereof
- C09K8/57—Compositions based on water or polar solvents
- C09K8/575—Compositions based on water or polar solvents containing organic compounds
- C09K8/5751—Macromolecular compounds
- C09K8/5755—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention belongs to the field of oil-gas fields, and particularly relates to a consolidated sand system, and a preparation method and application method thereof. The consolidated sand system comprises proppant particles, wherein the proppant particles comprise aggregate and a consolidating film attached to the outer surface of the aggregate; and the consolidating film comprises a reinforcement layer, a functional layer and a dispersion layer which are sequentially coated on the outer surface of the aggregate. The reinforcement layer comprises a modified phenolic resin and a urotropine water solution; the functional layer comprises an epoxy resin, a modified phenolic resin, an aromatic amine curing agent and a urotropine water solution; and the dispersion base layer comprises a water-soluble anionic surfactant solution. The consolidated sand system has favorable acid/alkali resistance, can solidify in various environments, has high strength, and is convenient for construction.
Description
Technical field
The invention belongs to sand control field, specially a kind of containing consolidated sand system and preparation method thereof and its using method.
Background technology
In the recovery process of fluid ore deposit, because the property of ore body itself is easy to ore body occur to shake out, slight ore body goes out
Sand can affect the structure and mechanical property of ore body, and can cause to subside if ore body shakes out in a large number, therefore, in order to avoid ore body goes out
Impact of the sand to body structural behaviour and the security performance of mining operators, generally come firm ore deposit by the way of the solid sand of chemical sand control
Body.
Common chemical sand control consolidates sandstone by loose sandstone, the cementing stable bottom earth formation of sand grains.Method of operating
For：Resin, surfactant, curing agent etc. is added to be stirred mixing in the base.The main resin for adopting in prior art
For：Phenolic resin, furane resins, polyurethane resin and epoxy resin, but these resins there are still intensity difference, needs specific
Condition solidification, corrosion-resistant the shortcomings of, and every kind of sand-fixing agent and its occupation mode may be only available for a certain kind or
The a certain class fluid ore deposit of person, applicability is narrow.
At present major part oilfield exploitation adopts the stage into three, needs to carry out ter-polymers drive to improve recovery ratio, ternary
Polymer is alkaline system, and general containing consolidated sand system can not consolidate in the basic conditions or not reach required intensity,
Even if a part can be consolidated, alkali resistance is poor after consolidation, it is impossible to use, it is therefore desirable to develop a kind of development of new type alkali-resistant fibre containing consolidated sand.
The content of the invention
To solve above-mentioned technical problem, the present invention provides a kind of containing consolidated sand system, its have good resistance to acids and bases, can be
Solidify and with high intensity under all kinds of environment, while convenient construction.
To realize above-mentioned technical purpose, the technical scheme that the present invention takes is, a kind of to consolidate sand body system, including proppant
Grain, the proppant particles include aggregate and invest the solidified film of aggregate outer surface, and the solidified film includes being coated on successively
The enhancement layer of aggregate outer surface, functional layer and dispersion layer；
The enhancement layer includes following material：Phenol-formaldehyde resin modified and the methenamine aqueous solution；
The functional layer includes following material：Epoxy resin, phenol-formaldehyde resin modified, aromatic amine curing agent and Wu Luotuo
The product aqueous solution；
The diffusion matrix material includes water soluble anionic surfactant solution.
Used as improved technical scheme of the invention, phenol-formaldehyde resin modified and the mass ratio of aggregate are (0.5-5) in enhancement layer：
100, phenol-formaldehyde resin modified is 10-20% with the mass ratio of methenamine；Wherein, phenol-formaldehyde resin modified is epoxide modified phenolic aldehyde tree
Fat, Effect of Organosilicon-modified Phenol-formaldehyde Resin, melamine modified phenolic resin, boron modified phenolic resin, molybdenum P Modification phenolic resin, horse
Come imide series polymer modification phenolic resin or phenol triazine phenol-formaldehyde resin modified, the methenamine is the aqueous solution, quality
Concentration 25-40%.
Used as improved technical scheme of the invention, the quality of functional layer is 3.4-3.9% for aggregate quality；And function
The mass ratio of layer epoxy resin, phenol-formaldehyde resin modified, aromatic amine curing agent and methenamine is 100：100：(5-20)：
(10-20)；Wherein, phenol-formaldehyde resin modified is epoxy modified phenolic resin or dimethylbenzene formaldehyde phenol-formaldehyde resin modified, aromatic series
Amine curing agent is MDA or m-phenylene diamine (MPD), and the methenamine is the aqueous solution, mass concentration 25-40%.
Used as improved technical scheme of the invention, the content of dispersion layer is that the amount that dispersion layer is added under each kilogram of aggregate is
1.5-2.5ml；And the mass fraction of water soluble anionic surfactant solution is 0.1-5% in dispersion layer.
Used as improved technical scheme of the invention, the softening point of the epoxy resin is 60-150 DEG C.
Used as improved technical scheme of the invention, the phenol-formaldehyde resin modified softening point is 80-120 DEG C.
Used as improved technical scheme of the invention, also including reinforcing agent, the reinforcing agent includes epoxy curing agent, molten
The mass ratio of agent and water, wherein epoxy curing agent, solvent and water is (2-20)：(0.1-10)：100；The solvent
Any quality for alcohols, esters or alcohols and esters compares mixture.
Used as improved technical scheme of the invention, the epoxy curing agent is water-soluble fatty amines curing agent, miaow
Two kinds of one kind or any mass ratio in azole curing agent.
Another object of the present invention is to provide a kind of using method of solid sand body system, in formation temperature 60 DEG C are not less than
When, proppant particles injection is directly needed the position of solid sand；When formation temperature is less than 60 DEG C, it is initially charged with proppant
Grain is injected into the position for needing solid sand, and then injecting reinforcing agent in the form of displacement fluid needs the position of solid sand, wherein strengthening
Agent is (1-50) with the mass ratio of proppant：100.
Third object of the present invention is to provide a kind of preparation method of solid sand body system, is comprised the steps：
S1, hot aggregates are until aggregate temperature is 250-350 DEG C；Then by 180-230 DEG C of aggregate stirring cooling, plus to the marrow
The phenol-formaldehyde resin modified of material quality 0.5-5%, stirs 10-60s；
The methenamine of S2, addition phenol-formaldehyde resin modified quality 10-20%, and 15-120s is stirred, formed in aggregate surface
Enhancement layer, the methenamine be the aqueous solution, mass concentration 25-40%.
S3, by each material of functional layer：Epoxy resin, phenol-formaldehyde resin modified and aromatic amine curing agent mix in proportion
Stirring 10-60s, adds the methenamine of the 10-20% of phenolic resin quality, and stirs 15-120s, is formed layer surface is strengthened
Functional layer, mass concentration 25-40% of the methenamine aqueous solution；
S4, addition water soluble anionic surfactant solution, stirring is completely dispersed up to material, in function layer surface shape
Into dispersion layer；
S5, the aggregate to carrying dispersion layer are cooled down, crush and then sieve.
Beneficial effect
Containing consolidated sand system is formed by the way that enhancement layer, functional layer and dispersion layer are adhered to successively into aggregate outer surface so that
Containing consolidated sand system has high compression strength and with good adhesive property, while be able to can solidify under all kinds of temperature environments；
During sand-fixing is applied to, the condition of cure of containing consolidated sand system is simple, easy to operate；Containing consolidated sand system after solidification exists
There is high pressure resistance after soda acid immersion；The manufacturing process is simple to operate, and can improve the intensity of containing consolidated sand, caking property and resistance to
Acidity of Aikalinity.
In sum, the containing consolidated sand system of the application can be widely used in all kinds of fluid ore deposits.
Specific embodiment
To make the purpose and technical scheme of the embodiment of the present invention clearer, below to the technical scheme of the embodiment of the present invention
It is clearly and completely described.Obviously, described embodiment is a part of embodiment of the present invention, rather than the reality of whole
Apply example.Based on described embodiments of the invention, those of ordinary skill in the art institute on the premise of without the need for creative work
The every other embodiment for obtaining, belongs to the scope of protection of the invention.
Embodiment 1
It is aggregate to choose the quartz sand that particle diameter is 850-425 μm, after the quartz sand of 2kg is heated to into 350 DEG C, by quartz sand
Stirring cooling in batch mixer is put, epoxy modified phenolic resin 10g stirring 30s is added when quartz sand temperature is down to 230 DEG C, now
Epoxy modified phenolic resin can form enhancement layer in aggregate outer surface；The mass concentration for being subsequently adding 10g is 10% Wu Luotuo
The product aqueous solution, continues to stir 120 seconds so that the aggregate with enhancement layer is uniformly dispersed again；Add 30g Bisphenol A Type Epoxy Resin trees
The mixture of fat, 30g epoxy modified phenolic resins and 6g MDAs is stirred 10 seconds so that the outer surface of enhancement layer
Functional layer can be formed, adds 6g mass concentrations to be that the stirring of the 16% methenamine aqueous solution makes aggregate disperse again in 30 seconds, then
Add 5ml mass concentrations and be completely dispersed up to material for the continuation stirring of 0.5% neopelex, by material cooling, break
It is broken, sieve, both obtained scattered proppant particles.
Embodiment 2
It is aggregate to choose the quartz sand that particle diameter is 850-425 μm, after the quartz sand of 2kg is heated to into 250 DEG C, by quartz sand
Stirring cooling in batch mixer is put, epoxy modified phenolic resin 45g stirring 10s is added when quartz sand temperature is down to 180 DEG C, now
Epoxy modified phenolic resin can form enhancement layer in aggregate outer surface；The mass concentration for being subsequently adding 30g is 15% Wu Luotuo
The product aqueous solution, continues to stir 15 seconds so that the aggregate with enhancement layer is uniformly dispersed again；Add 12.5g Bisphenol A Type Epoxy Resin trees
The mixture of fat, 12.5g epoxy modified phenolic resins and 10g MDAs is stirred 60 seconds so that outside enhancement layer
Surface can form functional layer, add 30g mass concentrations to be that the stirring of the 20% methenamine aqueous solution makes aggregate disperse again in 15 seconds,
It is subsequently adding 4ml mass concentrations and is completely dispersed up to material for the continuation stirring of 1% neopelex, material is cooled down,
Crush, sieve, both obtained scattered proppant particles.
Embodiment 3：
It is aggregate to choose the quartz sand that particle diameter is 850-425 μm, after the quartz sand of 2kg is heated to into 300 DEG C, by quartz sand
Stirring cooling in batch mixer is put, epoxy modified phenolic resin 100g stirring 60s are added when quartz sand temperature is down to 205 DEG C, this
When epoxy modified phenolic resin can aggregate outer surface formed enhancement layer；The mass concentration for being subsequently adding 50g is 20% black Lip river
The tropine aqueous solution, continues to stir 30 seconds so that the aggregate with enhancement layer is uniformly dispersed again；Add 36g Bisphenol A Type Epoxy Resin trees
The mixture of fat, 36g epoxy modified phenolic resins and 1.8g MDAs is stirred 30 seconds so that the appearance of enhancement layer
Face can form functional layer, add 3.6g mass concentrations to be that the stirring of the 10% methenamine aqueous solution makes aggregate disperse again in 120 seconds,
It is subsequently adding 3ml mass concentrations and is completely dispersed up to material for the continuation stirring of 5% neopelex, material is cooled down,
Crush, sieve, both obtained scattered proppant particles.
Embodiment 4
It is to add reinforcing agent in use with the difference of embodiment 1, reinforcing agent includes diethylenetriamines, fourth
The mass ratio of alcohol and water, wherein diethylenetriamines, butanol and water is 2：10：100；, the quality of reinforcing agent is embodiment 1
(1-50) of the agent gross mass that is supported：100.
Embodiment 5
It is to add reinforcing agent in use with the difference of embodiment 2, reinforcing agent includes diethylenetriamines, fourth
Alcohol, butyl acetate and water, wherein diethylenetriamines, butanol, the mass ratio of butyl acetate and water are 10：1：4：100；Increase
The quality of strong agent is that embodiment 1 is supported (1-50) of agent gross mass：100.
Embodiment 6
Be to add reinforcing agent in use with the difference of embodiment 4, reinforcing agent include imidazole curing agent, two
Ethylenetriamine, ethanol and water, wherein imidazole curing agent, diethylenetriamines, the mass ratio of ethanol and water are 1：1：
1：10；, the quality of reinforcing agent is that embodiment 1 is supported (1-50) of agent gross mass：100.
Embodiment 7 (comparative example)
Heating particle diameter is 850-425 μm of quartz sand to 280 DEG C, and 2kg quartz sands are put into stirring in batch mixer and are cooled to 220 DEG C
When add phenolic resin 80g to stir 30 seconds, the methenamine aqueous solution 40g that 30% is added when cooling to 110 DEG C continues to stir knot
3g calcium stearates are added during block, is continued stirring and is completely dispersed up to material, material is cooled down, is crushed, sieved.
Wherein, embodiment 1-3 is shown in Table 1 with the performance test results of embodiment 7.
Embodiment 1-3 of table 1 and the performance test results of embodiment 7
| Proppant | 52MPa percentages of damage, |
| Embodiment 1 | 1.56 |
| Embodiment 2 | 1.03 |
| Embodiment 3 | 2.05 |
| Embodiment 7 | 3.69 |
Performance test：
First,
Containing consolidated sand in 25g embodiments 1 is added in artificial rock core mould, adds the reinforcing agent in 10ml embodiments 4 to stir
Uniform 25 DEG C of preheatings 10min is mixed, then applies the moment of torsion of 50Nm, be put into 25 DEG C of maintenance 24h of baking oven, demoulding test is anti-without lateral spacing
Compressive Strength.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 250 DEG C of preheating 10min apply 50Nm
Moment of torsion, be put into 250 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
2nd,
Sand in 25g embodiments 2 is added in artificial rock core mould, adds the reinforcing agent in 12.5ml embodiments 4 to stir
Uniform 25 DEG C of preheatings 10min is mixed, then applies the moment of torsion of 50Nm, be put into 25 DEG C of maintenance 24h of baking oven, demoulding test is anti-without lateral spacing
Compressive Strength.
Sand in 25g embodiments 2 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 2 is added in artificial rock core mould, then 250 DEG C of preheating 10min apply 50Nm
Moment of torsion, be put into 250 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
3rd,
Sand in 25g embodiments 1 is added in artificial rock core mould, adds the reinforcing agent stirring in 4ml embodiments 5 equal
Even 25 DEG C of preheatings 10min, then applies the moment of torsion of 50Nm, is put into 25 DEG C of maintenance 24h of baking oven, demoulding test non-confining strength
Degree.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 1 is added in artificial rock core mould (utility model of early stage application), 250 DEG C of preheatings
10min, then applies the moment of torsion of 50Nm, is put into 250 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
4th,
Sand in 25g embodiments 1 is added in artificial rock core mould, the reinforcing agent stirring in 10ml embodiments 6 is added
Uniform 25 DEG C of preheatings 10min, then applies the moment of torsion of 50Nm, is put into 25 DEG C of maintenance 24h of baking oven, and the demoulding is tested without lateral spacing resistance to compression
Intensity.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 250 DEG C of preheating 10min apply 50Nm
Moment of torsion, be put into 250 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
5th,
Sand in 25g embodiments 3 is added in artificial rock core mould (utility model of early stage application), 10ml realities are added
Apply the reinforcing agent in example 6 and stir 25 DEG C and preheat 10min, then apply the moment of torsion of 50Nm, be put into 25 DEG C of maintenances of baking oven
24h, demoulding test unconfined compressive strength.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 1 is added in artificial rock core mould, then 250 DEG C of preheating 10min apply 50Nm
Moment of torsion, be put into 250 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
6th,
Sand in 25g embodiments 7 is added in artificial rock core mould, plus 25 DEG C of preheating 10min, then apply 50Nm
Moment of torsion, be put into 25 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
Sand in 25g embodiments 7 is added in artificial rock core mould, then 80 DEG C of preheating 10min apply 50Nm's
Moment of torsion, is put into 80 DEG C of maintenance 24h of baking oven, demoulding test unconfined compressive strength.
Sand in 25g embodiments 7 is added in artificial rock core mould, then 250 DEG C of preheating 10min apply 50Nm
Moment of torsion, be put into 250 DEG C of baking oven maintenance 24h, demoulding test unconfined compressive strength.
The performance test results
Consolidated sand sample block after the demoulding is put in 1%NaOH solution or 1%H2SO4Middle immersion 24h tests compression strength.
To the acid-proof alkaline of performance test one-six.
The acid-proof alkaline of the performance test one to six of table 2
Concrete application：The present embodiment is mainly used in cyclic steam stimulation, and cyclic steam stimulation is in current thickened oil recovery
Main Means, but after pressure break during crack closure temperature than relatively low, it is necessary to the low temperature curing properties of sand control proppant,
After proppant solidification, cyclic steam stimulation is carried out, this process temperature is higher, needs that there is suitable heat resistance after consolidation,
High temperature system in functional layer of the present invention is played a role, can not only heatproof, and can under the high temperature conditions increase consolidation strength.
During concrete application, enhancement layer：Increase the compression strength of proppant itself, reach under certain clossing pressure
Use, keep proppant flow conductivity, reach volume increase purpose；Functional layer：Various condition solidifications are realized, is increased between proppant
Bonding, realizes consolidation, and can reach suitable consolidation strength, so as to reach the purpose of sand control；Dispersion layer：In manufacturing process
Because temperature is higher after middle functional layer addition, mutually it is adhered between proppant particles, it is to avoid be adhered addition dispersion layer and disperseed,
Surfactant is added to realize simultaneously hydrophilic, so as to increase the compatibility with fracturing fluid, while reinforcing agent can be increased
Compatibility, so as to increase consolidation strength.
Embodiments of the present invention are these are only, its description is more concrete and detailed, but therefore can not be interpreted as right
The restriction of the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the present invention
On the premise of design, some deformations and improvement can also be made, these belong to protection scope of the present invention.
Claims (10)
1. a kind of solid sand body system, including proppant particles, the proppant particles include aggregate and invest aggregate outer surface
Solidified film, it is characterised in that the solidified film includes being coated on enhancement layer, functional layer and the dispersion of aggregate outer surface successively
Layer；
The enhancement layer includes following material：Phenol-formaldehyde resin modified and the methenamine aqueous solution；
The functional layer includes following material：Epoxy resin, phenol-formaldehyde resin modified, aromatic amine curing agent and methenamine water
Solution；
The diffusion matrix material includes water soluble anionic surfactant solution.
2. a kind of solid sand body system according to claim 1, it is characterised in that：Phenol-formaldehyde resin modified and aggregate in enhancement layer
Mass ratio is (0.5-5)：100, phenol-formaldehyde resin modified is 10-20% with the mass ratio of methenamine；Wherein, phenol-formaldehyde resin modified
For epoxy modified phenolic resin, Effect of Organosilicon-modified Phenol-formaldehyde Resin, melamine modified phenolic resin, boron modified phenolic resin, molybdenum
P Modification phenolic resin, maleimide based polymer phenol-formaldehyde resin modified or phenol triazine phenol-formaldehyde resin modified, the black Lip river
Tropine is the aqueous solution, mass concentration 25-40%.
3. a kind of solid sand body system according to claim 1, it is characterised in that：The quality of functional layer is for aggregate quality
3.4-3.9%；And the quality of functional layer epoxy resin, phenol-formaldehyde resin modified, aromatic amine curing agent and methenamine
Than for 100：100：(5-20)：(10-20)；Wherein, phenol-formaldehyde resin modified is epoxy modified phenolic resin or dimethylbenzene formaldehyde
Phenol-formaldehyde resin modified, aromatic amine curing agent is MDA or m-phenylene diamine (MPD), and the methenamine is water-soluble
Liquid, mass concentration 25-40%.
4. a kind of solid sand body system according to claim 1, it is characterised in that：The content of dispersion layer is under each kilogram of aggregate
The amount for adding dispersion layer is 1.5-2.5ml；And the mass fraction of water soluble anionic surfactant solution is in dispersion layer
0.1-5%.
5. a kind of solid sand body system according to claim 1, it is characterised in that the softening point of the epoxy resin is 60-150
℃。
6. a kind of solid sand body system according to claim 1, it is characterised in that the phenol-formaldehyde resin modified softening point is 80-
120℃。
7. a kind of solid sand body system described in claim 1, it is characterised in that also including reinforcing agent, the reinforcing agent includes epoxy
The mass ratio of resin curing agent, solvent and water, wherein epoxy curing agent, solvent and water is (2-20)：(0.1-10)：
100；The solvent compares mixture for any quality of alcohols, esters or alcohols and esters.
8. a kind of solid sand body system according to claim 7, it is characterised in that the epoxy curing agent is water-soluble fat
Two kinds of one kind or any mass ratio in fat amine curing agent, imidazole curing agent.
9. a kind of using method of sand body system admittedly as claimed in claim 7, it is characterised in that be not less than 60 DEG C in formation temperature
When, proppant particles injection is directly needed the position of solid sand；When formation temperature is less than 60 DEG C, it is initially charged with proppant
Grain is injected into the position for needing solid sand, and then injecting reinforcing agent in the form of displacement fluid needs the position of solid sand, wherein strengthening
Agent is (1-50) with the mass ratio of proppant：100 .
10. a kind of preparation method of sand body system admittedly as claimed in claim 1, it is characterised in that comprise the steps：
S1, hot aggregates are until aggregate temperature is 250-350 DEG C；Then by 180-230 DEG C of aggregate stirring cooling, aggregate matter is added
The phenol-formaldehyde resin modified of amount 0.5-5%, stirs 10-60s；
The methenamine of S2, addition phenol-formaldehyde resin modified quality 10-20%, and 15-120s is stirred, being formed in aggregate surface strengthens
Layer；
S3, by each material of functional layer：Epoxy resin, phenol-formaldehyde resin modified and aromatic amine curing agent are mixed in proportion
10-60s, adds the methenamine of the 10-20% of phenolic resin quality, and stirs 15-120s, and layer surface is strengthened function is formed
Layer；
S4, addition water soluble anionic surfactant solution, stirring is completely dispersed up to material, is formed in function layer surface and divided
Scattered layer；
S5, the aggregate to carrying dispersion layer are cooled down, crush and then sieve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611052413.XA CN106634919B (en) | 2016-11-25 | 2016-11-25 | A kind of containing consolidated sand system and preparation method thereof and application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611052413.XA CN106634919B (en) | 2016-11-25 | 2016-11-25 | A kind of containing consolidated sand system and preparation method thereof and application method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106634919A true CN106634919A (en) | 2017-05-10 |
| CN106634919B CN106634919B (en) | 2019-06-28 |
Family
ID=58811598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611052413.XA Active CN106634919B (en) | 2016-11-25 | 2016-11-25 | A kind of containing consolidated sand system and preparation method thereof and application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106634919B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111690399A (en) * | 2020-04-27 | 2020-09-22 | 北京大德广源石油技术服务有限公司 | Sand control agent for fracturing and use method thereof |
| CN115124984A (en) * | 2022-07-07 | 2022-09-30 | 北京化科开源新材料科技有限公司 | Solid particle capable of being adhered and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368442A (en) * | 2015-11-12 | 2016-03-02 | 北京昆仑隆源石油开采技术有限公司 | Low-density superhigh-strength corrosion-resistant propping agent and preparation method thereof |
-
2016
- 2016-11-25 CN CN201611052413.XA patent/CN106634919B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368442A (en) * | 2015-11-12 | 2016-03-02 | 北京昆仑隆源石油开采技术有限公司 | Low-density superhigh-strength corrosion-resistant propping agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111690399A (en) * | 2020-04-27 | 2020-09-22 | 北京大德广源石油技术服务有限公司 | Sand control agent for fracturing and use method thereof |
| CN111690399B (en) * | 2020-04-27 | 2021-09-07 | 北京大德广源石油技术服务有限公司 | Sand control agent for fracturing and use method thereof |
| CN115124984A (en) * | 2022-07-07 | 2022-09-30 | 北京化科开源新材料科技有限公司 | Solid particle capable of being adhered and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106634919B (en) | 2019-06-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3976135A (en) | Method of forming a highly permeable solid mass in a subterranean formation | |
| CN102660245B (en) | Pre-coated film propping agent, preparation method of pre-coated film propping agent and sand prevention method adopting pre-coated film propping agent | |
| CN103173195B (en) | A kind of high temperature resistant sand control propping agent and high temperature resistant sand control curing system | |
| CN108033710A (en) | A kind of Ultralight overlay film proppant and preparation method thereof | |
| CN110002817A (en) | A kind of cement stabilized macadam material and its preparation process | |
| CN103160271B (en) | A kind of preparation method of lumpish sand prevention proppant | |
| CN102485830A (en) | Profile control oil-displacement agent for core-shell type inorganic/organic polymer composite microballoon | |
| CN104152148B (en) | Soil curing agent stablizes the method that iron tailings prepares road surface base layer material | |
| CN104277821B (en) | A kind of preparation method of lipophilic-hydrophobic property overlay film proppant | |
| CN104694096B (en) | A kind of oil field development blocking agent | |
| CN106244136B (en) | A kind of curable sand control proppant and preparation method thereof | |
| CN101747882A (en) | Tectorial membrane sand solidifying system suitable for low-temperature reservoir sand prevention | |
| CN105400503B (en) | A kind of reservoir profile water shutoff agent of resisting high temperature, high salt and preparation method thereof | |
| CN105542739B (en) | A kind of sand control coated sand and preparation method thereof | |
| US3759327A (en) | Internally catalyzed well consolidation method | |
| CN108659805A (en) | A kind of emulsion-type low temperature sand-fixating agent and the preparation method and application thereof | |
| CN106634919A (en) | Consolidated sand system, and preparation method and application method thereof | |
| CN106675548A (en) | Self-suspension propping agent and preparation method thereof | |
| WO2013044861A1 (en) | Preparation method for fracturing proppant, fracturing proppant and use thereof | |
| CN109370560B (en) | Heavy metal mineralized substance warm-curing resin precoated sand and preparation method and application thereof | |
| CN111285642A (en) | Plugging agent, preparation method and application thereof | |
| CN101200632A (en) | Method and technique for preparing low-density propping agent | |
| CN107815131A (en) | A kind of heat regeneration asphalt mixture and preparation method thereof | |
| CN111607374B (en) | Low-temperature curing oil-permeable water-blocking precoated sand and preparation method thereof | |
| CN104830306A (en) | Sand control agent used for steam huff-puff oil well at high temperature |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |